Realizing efficient emission and triple-mode photoluminescence switching in air-stable tin(IV)-based metal halides via antimony doping and rational structural modulation

Recently,many lead-free metal halides with diverse structures and highly efficient emission have been reported.However,their poor stability and single-mode emission color severely limit their applications.Herein,three homologous Sb^(3+)-doped zero-dimensional(0D)air-stable Sn(IV)-based metal halides with different crystal structures were developed by inserting a single organic ligand into SnCl_(4)lattice,which brings different optical properties.Under photoexcitation,(C_(25)H_(22)P)SnC_(l5)@Sb⋅CH_(4O)(Sb^(3+)−1)does not emit light,(C_(25)H_(22)P)_(2)SnC_(l6)@Sb-α(Sb^(3+)−2α)shines bright yellow emission with a photoluminescence quantum yield(PLQY)of 92%,and(C_(25)H_(22)P)_(2)SnC_(l6)@Sb-β(Sb^(3+)−2β)exhibits intense red emission with a PLQY of 78%.The above three compounds show quite different optical properties should be due to their different crystal structures and the lattice distortions.Particularly,Sb^(3+)−1 can be successfully converted into Sb^(3+)−2αunder the treatment of C_(25)H_(22)PCl solution,accompanied by a transition from nonemission to efficient yellow emission,serving as a“turn-on”photoluminescence(PL)switching.Parallelly,a reversible structure conversion between Sb^(3+)−2αand Sb^(3+)−2βwas witnessed after dichloromethane or volatilization treatment,accompanied by yellow and red emission switching.Thereby,a triple-mode tunable PL switching of off-onI-onII can be constructed in Sb^(3+)-doped Sn(IV)-based compounds.Finally,we demonstrated the as-synthesized compounds in fluorescent anticounterfeiting,information encryption,and optical logic gates.

A Low-Profile Cylindrical Dielectric Resonator Antenna with Bandwidth-Enhancement Under Triple-Mode Resonance

A low-profile cylindrical dielectric resonator antenna(CDRA)with enhanced impedance bandwidth is proposed via sharing a single triple-mode dielectric resonator.Initially,the resonant frequencies of TM01d and TM02d modes of a conventional CDRA are maintained far away from each other under central probe feed.Next,a circular disk with an annular ring is loaded around the conventional CDRA,aiming to excite an additional mode between these dual modes.The electric fields demon-strate that the previous TM_(02δ) mode is transformed into the TM03d mode for the modified CDRA,and an additional TM_(02δ) mode is successfully excited between the TM_(01δ) and TM_(03δ) modes.As a result,the resonant frequencies of these three radiative modes are reallocated in proximity to each other,thus achieving the desired bandwidth enhancement.In addition,considering the small input impedance of the CDRA,a microstrip feeding line is introduced underneath the central probe for good impedance matching.With these arrangements,the resultant antenna can generate an extended bandwidth under simultaneous radiation of TM_(01δ),TM_(02δ),and TM_(03δ) modes.Finally,the proposed CDRA is designed,fabricated,and measured to validate the predicted per-formance.The simulated and measured results show that the impedance bandwidth(|S11|<-10 dB of the antenna is dramatically extended from 8%to about 62%(2.835.36 GHz),while keeping a stable conical radiation pattern.In particular,a low profile property of about 0.15 free space wavelength is achieved as well.

Pencil drawn interdigitated capacitive sensors on wood substrate

This research presents the fabrication and characterization of an interdigitated capacitive(IDC)sensor on a wooden substrate using pencil traces.The resistance of the pencil traces decreased from 100 kΩto 5 kΩas the pencil grade shifted from HB to 8B.Concurrently,capacitance measurements revealed an increase from approximately 5 pF for a 5-finger IDC made with HB pencil to around 32 pF for an 8B pencil counterpart.Increasing the number of pencil traces from 10 to 50 resulted in a significant decrease in resistance and a proportional increase in capacitance.Application of the IDC sensor demonstrated notable changes in capacitance upon proximity and touch,with a significant decrease upon removal.The interdigitated capacitance sensor exhibits good proximity effects and contact sensitivity in touch,with capacitance increasing exponentially from 0.3 pF(7 cm)to 1.2 pF(direct contact),highlighting its ability to detect objects with high precision.Additionally,environmental factors such as temperature and humidity influence capacitance values.These findings underscore the potential of pencil-drawn IDC sensors for responsive and adaptable applications in various fields.