Fish Canyon Tuff榍石He扩散及(U-Th)/He年代学研究

榍石富含U和Th,是(U-Th)/He定年的理想矿物之一。本文以Fish Canyon Tuff榍石为例,开展了榍石He扩散行为和榍石(U-Th)/He定年实验方法研究。榍石分步加热扩散实验结果表明He扩散系数ln(D/a2)与温度倒数呈负相关,与期望的热活化扩散过程一致。测试Fish Canyon Tuff榍石(U-Th)/He年龄分布在28.3~24.6 Ma之间,平均值为26.7±1.2 Ma(1σ),Th/U分布在4.6~5.5之间,平均值为5.2±0.2,在误差范围内与国际上已出版数据一致,表明建立的榍石(U-Th)/He定年实验方法可靠。本次测试15粒榍石碎片外表层(~20μm)存在不同程度的磨蚀(即不完整晶体),且榍石表层磨蚀厚度随着等效半径的增加而增大。榍石碎片(U-Th)/He年龄介于完整晶体(U-Th)/He年龄和真实(U-Th)/He年龄之间,且随着榍石等效半径及表层磨蚀厚度(<20μm)的增大,(U-Th)/He年龄更接近真实年龄,这表明榍石(U-Th)/He年龄不确定度与等效半径大小和表层磨蚀厚度有关。

Studying Tuff Rings and Volcanic Hazards in a Tropical Setting: The Case of the Batoke Tuff Ring, Limbe, SW Region Cameroon

In subtropical volcanic environments, there are often few accessible outcrops. These are often highly weathered and of very poor quality. Soil development is rapid (1 cm/y) and small eruptions are unlikely to be preserved in the geological record. Reconstructing past eruptions and assessing hazards is a challenge. Here, we studied a poorly outcropping tuff ring (very poor, incomplete sections) with the best outcrop observed at a beach cliff (up to ca. 5 - 10 m high) at Batoke, to the south of Mt Cameroon volcano. Mt Cameroon has a few tuff rings, currently of unknown ages, near the SW coast of Cameroon. In the Batoke case, the sequence is dominated by gently dipping tuff beds varying in the proportion of lithics, juvenile clasts, and accretionary lapilli (acc-laps). Several beds are close-packed with acc-laps of up to 10 - 15 mm diameter. Part of the section is gullied by mud flow deposits. The rocks are highly weathered but differential weathering enhances relationships. Quantitative data can be extracted from a detailed study of outcrops’ external surfaces. The preserved section is close to where the deposits were initially thickest and where acc-laps were most abundant and largest. There is an empirical correlation between maximum acc-lap size in the thickest outcrop and eruption column height. This and the deposit features suggest that the Batoke eruption was pulsating but dominated by fallout, with a water and ice-rich eruption column reaching 10 - 15 km high. Recycling of water drops and ice-coated fine ash accumulated during eruption. At switch off, wholesale gravitational collapse of this material produced the mud flows, which gullied the previously-laid down deposits. Such ash fall and mud flows can represent a substantial hazard, e.g. they can gully down through towns and roads and cut evacuation routes. This study illustrates how, at subtropical tuff rings, it is possible to extract key data needed for hazard assessment from only 1 - 2 poor outcrops.

High-precision Dating and Geological Significance of Chang 7 Tuff Zircon of the Triassic Yanchang Formation, Ordos Basin in Central China

The Ordos Basin, as the second largest petroliferous basin of China, contains abundant oil and gas resources, oil shale, and sandstone-type uranium mineral resources. Chang 7 shale is not only the major source rock of the Mesozoic petroliferous system of the Basin, but is also crucial in determining the space-time distribution relationship of the shale section for the effective exploration and development of the Basin's oil and gas resources. To obtain a highly precise age of the shale development section, we collected tuff samples from the top and bottom profile of the Chang 7 Member, Yishi Village, Yaoqu Town, Tongchuan District, on the southern margin of the Ordos Basin and performed high-precision chemical abrasion(CA)–isotope dilution(ID)–thermal ionization mass spectrometry(TIMS) zircon U-Pb dating on the basis of extensive laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS) zircon U-Pb dating data. Our results show the precise ages of the top and bottom zircon in the Chang 7 shale to be 241.06±0.12 Ma and 241.558±0.093 Ma, respectively. We first obtained Chang 7 age data with Grade 0.1-Ma precision and then determined the age of the shale development in the Chang 7 Member to be the early-Middle Triassic Ladinian. This result is supported by paleontological evidence. The deposition duration of the Chang 7 shale is 0.5 Ma with an average deposition rate of the shale section being 5.3 cm/ka. Our research results provide time scale and basic data for further investigation of the basin–mountain coupling relation of the shale section, the sedimentary environment and volcanic ash and organic-matter-rich shale development relation, and the organism break-out and organic-matter enrichment mechanism.

Compaction Rate of an Early Permian Volcanic Tuff from Wuda Coalfield, Inner Mongolia

Compaction rates of sediments or volcaniclastic material are needed to reconstruct original thickness of a bed, which in turn is required to reconstruct subsidence rates, sea-level rise, or in the case of volcanielastic, the location or direction of the eruption site. The knowledge of compaction rates can also aid in the reconstruction of deformed fossils. The known shape of deformed fossils can allow the determination of the compaction they experienced. Here we report the compaction rate in an early Permian volcanic tuff from Wuda, Inner Mongolia, determined from the deformation of standing tree fern stems of known anatomy. The compaction rate has been found to be 0.56 in this case, indicating that 44% of original thickness remains.

Geochemistry and zircon U-Pb geochronology of the rhyolitic tuff on Port Island, Hong Kong： Implications for early Cretaceous tectonic setting

Early Cretaceous rhyolitic tuffs, widely distributed on Port Island, provide insights into the volcanism and tectonic setting of Hong Kong. In this paper we present petrological, geochronological and geochemical data of the rhyolitic tuff to constrain the diagenesis age and petrogenesis of the rocks, tectonic setting and early Cretaceous volcanism of Hong Kong. The first geochronological data show that the zircons in the volcanic rocks have U-Pb age of 141.1-139.5 Ma, which reveals that the rhyolitic tuff on Port Island was formed in the early Cretaceous （K1）. Geochemically, these acid rocks, which are enriched in large ion lithophile elements （LILEs） and light rare earth elements （LREEs）, and depleted in high field strength elements （HFSEs）, belong to the high K calc-alkaline to shoshonite series with strongly-peraluminous characteristic. The geochemical analyses suggest that the volcanic rocks were derived from deep melting in the continental crust caused by basaltic magma underplating. Based on the geochemical analysis and previous studies, we concluded that the rhyolitic tufts on Port Island were formed in a back- arc extension setting in response to the subduction of the Paleo-Pacific Plate beneath the Eurasian Plate.

Usability of a Natural Tuff as Admixture in Clinker and Its Influence on the Physico-Chemical and Mechanical Properties of Mortar

The mechanical and physical properties of TUFF from Korsimoro (Burkina Faso) were investigated for use as admixtures in clinker to make pozzolanic cement. Six different cement mortar specimens were prepared by replacing clinker with TUFF in ratios of 0%, 5%, 8%, 10%, 13% and 15% by mass. The flexural and compressive strengths of the specimens were determined at the ages of 2, 7, 28 and 60 days. The effects of the TUFF replacement ratio on workability, setting time and volume expansion were also examined. Based on the results, it was concluded that Korsimoro TUFF has pozzolanic activity and is suitable for use as an alternative adherent material in the cement industry.

Oxidation of Solid Phase and Ionic Strength Effect to the Cesium Adsorption on Pumice Tuff

In-situ oxidation of solid phase was considered to investigate adsorption behavior under different geochemical parameters like pH, initial concentration and ionic strength. Pumice tuff, a potential host rock for low and intermediate radioactive wastes, has been affected by the redox zone. The characterization of the fresh and oxidized tuff was performed by X-ray diffractometer, scanning electron microscope and mercury intrusion porosimetry. In order to compare the difference of distribution coefficient (Kd) in fresh and oxidized pumice tuffs, a batch adsorption study was carried out at the range of pH (4 - 12), ionic strength (0.003, 0.1, 1.0 and 3.0 mol/dm3) and initial cesium concentration (10dž, 10LJ, 10Lj and 10lj mol/dm3). Based on experimental Kd values, ionic strength was found to be the most influential factor, whereas the effects of pH, initial Cs concentration and weathering condition of pumice tuff were negligible. The recalculated Kd values suggest that the existing surface complexation model is applicable to explain the sorption coefficients through the wide range of solution conditions.

Tuff beds in Kurnool subbasin,southern India and implications for felsic volcanism in Proterozoic intracratonic basins

A first report on tuff beds from the Owk Shale in the Proterozoic Kurnool sub-basin in southern India is presented. The rhyolitic to rhodacitic tufts, overlying shelfal limestones formed at depths below storm wave base, have rheomorphie features indicative of viscoplastic flow, and geochem- ical signatures of rhyolitic to rhyodacitic unwelded to welded tufts, similar to those described from other Proterozoic intracratonic basins like Vindhyan and Chhattisgarh basins in India. Fragmentary nature of altered glass with perlitic cracks and local admixture with intrabasinal sediments suggest phreatomag- matic reactions. The widespread and repeated occurrences of felsic tufts in these basins, possibly derived from low degree melting of continental crust, suggest intermittent tectonothermal instability which likely influenced basinal topography and cyclic development of the carbonate platforms.

Are They Formed by Undercooling Crystallization or Devitrification？－On Origin of Various Textures inPlasticFragmentsofWeldedTuffs

A comprehensive petrographic observation contributes to classification of various textures in welded tuffs into two types, the textures in plastic fragments and the ones in rigid fragments. A detailed petrographic study of the textures in plastic fragments leads to suggestion that thesetextures are not a type of devitrification textures. and also that they were formed not by devitrification but by undercooling crystallization. This viewpoint is supported by results of undercooling crystallization experiments. The petrographic characteristics of these textures are satisfactorily demonstrated by the undercooling crystallization theory.

Late Cretaceous K-rich rhyolitic crystal tuffs from the Chuduoqu area in Eastern Qiangtang subterrane:evidence for crustal thickening of the central Tibetan Plateau prior to India–Asia collision

In order to constrain whether the Lhasa–Qiangtang collision contributed to an early crustal thickening of the central Tibetan Plateau prior to the India–Asia collision,we present zircon LA–ICP–MS U–Pb ages,wholerock geochemistry,and zircon Hf isotopic compositions of the newly discovered rhyolitic crystal tuffs from the Chuduoqu area in the eastern Qiangtang subterrane,central Tibet.Zircon U–Pb dating suggests that the Chuduoqu rhyolitic crystal tuffs were emplaced at ca.68 Ma.The Chuoduoqu rhyolitic crystal tuffs display high SiO_(2) and K2 O,and low MgO,Cr,and Ni.Combined with their zircon Hf isotopic data,we suggest that they were derived from partial melting of the juvenile lower crust,and the magma underwent fractional crystallization and limited upper continental crustal assimilation during its evolution prior to eruption.They should be formed in a post-collisional environment related to lithospheric mantle delamination.The Chuduoqu rhyolitic crystal tuffs could provide important constraints on the Late Cretaceous crustal thickening of the central Tibetan Plateau caused by the Lhasa–Qiangtang collision.

Geochronology and geochemistry of Baicaogou tuff in Yanji,NE China and its tectonic implications for Early Cretaceous

The authors studied zircon U-Pb age and geochemical data of Baicaogou tuff in Yanji,Jilin Province.The results indicate that the rocks formed in Early Cretaceous( 125. 6 ± 2. 3 Ma). Geochemically,these tuffs have high Si O2 and total Na2 O + K2 O,low Mg O and Fe O,and they belong to metaluminous series,the rock are enriched in LREEs and LILEs,depleted in HREEs and HFSEs such as Nb,Ta,Ti,and P,exhibiting an affinity to I-type granite. All these characteristics implied that the volcanic rocks were derived from partial melting of lower crust. Combined with the geochronology and geochemical features of the coeval igneous rocks within NE China,it is concluded that Yanji area was in a back-arc extensional setting in response to the subduction of the Paleo-Pacific Plate beneath the Eurasian Plate.

Pozzolanic Activity of Old Volcanic Tuffs of Mako Area (Senegal-Oriental, West African Craton): An Economic and Environmental Interest

The volcanic tuffs of Senegal-Oriental in Mako area are produced during a calc-alkaline volcanism which occurs in this region and which is dated from about 2.3 - 1.95 Ga. Despite their altered appearance, the X-Ray diffractions show mineral paragenesis: Quartz-Kaolinite-Illite and an important amorphous phase. On the Ternary Keil-Rankin diagram for the CaO-SiO2-Al2O3 the volcanic tuffs of Mako area are situated between pozzolan and the fly ash. The difference between silica and lime is greater than 34% in these volcanic tuffs. In this study, they have been mixed with Portland cement to obtain pozzolanic cements respectively with 20%, 30%, 35% and 40% of addition of volcanic tuffs. The pozzolanic reactivity is highlighted by the compressive strength increase until 90 days of conservation in water. It supposes that the vitreous phase of the volcanic tuffs reacts with the free CaO (CaOf) of Portland cement to produce new hydrated minerals. This study has a positive economic and environmental impact. Because the time of grinding of pozzolanic cements is reduced. Also, the addition of volcanic tuffs reduces the production of clinker, then the CO2 emission.

Contribution to the Study of Paleoproterozoic Materials for the Improvement of Social Housing in the Kedougou Region: Case of Mako Andesitic Meta-Tuffs

The objective of this project is the valorization of Mako andesitic volcanic tuffs for use in social housing in the Kedougou region. To achieve these objectives, a geotechnical characterization of the tuff samples was carried out and the geopolymerization stabilization was adopted for the manufacture of bricks. These bricks stabilized by an alkaline activation offer compressive strengths that exceed the threshold value (2.9 MPa) set by the standard (NF P14-304). The best compressive strengths (12.14 MPa) and flexural tensile strengths (5.43 MPa) are obtained in the series of bricks made with 35% of the mass of a solution of caustic soda at 12 molars concentration with a curing temperature cooking of 185°C and an average absorbance of 13.21%.

The Geological,Petrographical and Engineering Properties of Rhyolitic Tuffs(Can Stone)in Can-Etili Area(Canakkale),NW Turkey:Their Usage as Building and Covering Stones

In this study, the geological, petrographical properties of rhyolitic tuffs exposed around ?an-Etili in the Biga Peninsula (NW Turkey) which are pyroclastic products of Late Oligocene-Early Miocene aged ?an Volcanism were investigated, also physical and mechanical characteristics of tuffs introduced and tried to determine the impact on engineering properties of petrographical features. In the region, rhyolitic tuffs called locally “?an stone” have been used as covering and building stones for many years. These tuffs generally have light yellowish, beige, brown colored and different patterns with light yellowish, cream, reddish and brown colors caused by iron oxidation of hydrothermal alteration. They are preferred as coatings and decorative stone with these patterns. ?an stone which consisted of rhyolitic composition, lithic and locally crystalline tuffs has compact structure. The mineral assemblage of tuffs is mainly composed of quartz, plagioclase, rarely biotite, amphibole (hornblende) phenocrystals and opaque mineral with particles of volcanic glass and lithic fragments. Not only petrographical and geochemical analyses were carried out but also standard rock mechanic tests (unit weight, specific gravity, porosity, water absorption and uniaxial compressive strength) on rhyolitic tuffs samples collected from four different quarries (Hoppa Hill, Halilaga, Uzunalan, Dereoba). Simple regression analysis of test results obtained from four different regions and correlations were found good correlation between engineering proper- ties and the petrographical and chemical properties of rhyolitic tuffs.

Adsorption of ^133Cs and ^87Sr on pumice tuff：A comparative study between powder and intact solid phase

This study examines the use of intact samples as an alternative to powder in conventional batch sorption studies to determine the distribution coefficient(K_d).Stable cesium(^(133)Cs) and strontium(^(87)Sr) were used under specified geochemical conditions to compare the Kdvalues of powder and block pumice tuff samples. The aim of the study was to infer any Kddifference under laboratory and field conditions. Kdvalues for block samples were found to be less than one order of magnitude lower than powder materials for both Cs and Sr on fresh tuff, and more than one order of magnitude lower in oxidized tuff. Destruction of micropores in oxidized tuff was estimated to be mainly responsible for reducing Kdvalues in oxidized tuff. However, approximately one order of magnitude difference in Kdvalues indicates that homogenously prepared intact samples can be used for sorption coefficient measurement at closer to in situ conditions. Pore size distribution analysis using mercury intrusion porosimetry revealed that lower Kdvalues on block samples result from lower surface area available as sorption sites due to inaccessible closed pores in the intact solid.

Petroleum exploration of shallow marine deposit Carboniferous volcanic tuff reservoir in the western margin of Junggar Basin

In 2011,petroleum exploration of shallow marine deposits Carboniferous and volcanic tuff reservoir realized breakthroughs at Chepaizi slope in the western margin of Junggar Basin. Pai 61 well,with 855.7 ~ 949.6 m section,in the conventional test oil obtained 6 t/d industrial oil flow. The surface viscosity is 390 mPa· s(50℃). The marine deposit of Carboniferous are deep oil source rocks and high-quality reservoir. Magma volcanic activity provides the basis for volcanic reservoir development and distribution. The weathering crust and secondary cracks developed volcanic tuff by strong rock weathering and dissolution of organic acids which has become top quality reservoir. Deep Permian oil- gas migrated and accumulated to high parts along Hong- Che fault belt and stratigraphic unconformity stripping. Permian and Triassic volcanic rocks or dense mudstone sedimentary cover as a regional seal for the late Carboniferous oil-gas to save critically. The seismic pre-stack time migration processing technologies for the problem of poor inner structures of Carboniferous were developed. Response of volcanic rock seismic and logging are obvious. The application imaging logging and nuclear magnetic technology achieved the qualitative identification and quantification of fracture description.

Multi-Scale Pore Structure Heterogeneity in Tuff Reservoirs Investigated with Multi-Experimental Method and Fractal Dimensions in Chang 7 Formation,Southern Ordos Basin

The tight tuff reservoir is an unusual type of unconventional reservoir with strong heterogeneity.However,there is a lack of research on the microscopic pore structure that causes the heterogeneity of tuff reservoirs.Using the Chang 7 Formation in Ordos Basin,China as a case study,carbon-dioxide gas adsorption,nitrogen gas adsorption and high-pressure mercury injection are integrated to investigate the multi-scale pore structure characteristics of tuff reservoirs.Meanwhile,the fractal dimension is introduced to characterize the complexity of pore structure in tuff reservoirs.By this multi-experimental method,the quantitative characterizations of the full-range pore size distribution of four tuff types were obtained and compared in the size ranges of micropores,mesopores and macropores.Fractal dimension curves derived from full-range pores are divided into six segments as D1,D2,D3,D4,D5 and D6 corresponding to fractal characteristics of micropores,smaller mesopores,larger mesopores,smaller macropores,medium macropores and larger macropores,respectively.The macropore volume,average macropore radius and fractal dimension D5 significantly control petrophysical properties.The larger macropore volume,average macropore radius and D5 correspond to favorable pore structure and good reservoir quality,which provides new indexes for the tuff reservoir evaluation.This study enriches the understanding of the heterogeneity of pore structures and contributes to unconventional oil and gas exploration and development.

First Discovery of Late Triassic Tuffs in the South Qilian Basin: Geochemical Characteristics, Zircon LA-ICP-MS U-Pb Ages and Potential Source Regions

This investigation reports the first discovery of more than 70 tuff intervals in the Upper Triassic,South Qilian Basin.Petrographic and geochemical analyses were carried out on ten tuff samples and zircon U-Pb dating were on three.Thin section and X-ray diffraction(XRD)results indicate that the tuffs were composed of crystal shards and altered glass shards;crystal shards include plagio-clase and quartz.Most of the tuffs had been transformed into illite/smectite mixed-layers(I/S).In addition,calcite,pyrite,dolomite and siderite were also identified in some of the tuff samples.Analysis of major elements suggests that the tuffs are peraluminous high-K calcalkaline series.Trace elements indicate that the tuffs are enriched in high field strength elements(HFSE),including Th,U,Ta,Zr and Hf.Geochemical characteristics suggest that the tuffs originated from comendite pantellerite and rhyolite from within plate setting.Zircon U-Pb dating(236.0±1.7,231.4±1.6,and 223.1±3.9 Ma)indicate that the tuffs were erupted in the Late Triassic.Comparative chronology and geochemical analyses suggest that the West Qinling belt and the East Kunlun belt are the potential source regions of these tuffs,and they originated from the within plate magma during a post-collisional period.

云南墨江金矿区内凝灰岩的成因及对金成矿作用的意义

云南墨江金厂金矿是哀牢山金矿带内的一个大型金矿床,矿床受剪切带控制,矿体赋存于古生代浅变质岩中,其成矿物质来源一直是争论的焦点。为进一步精确约束赋矿地层的形成时代和大地构造背景,探讨其与金成矿物质来源和成矿作用之间的关系,本文对古生代浅变质岩中的凝灰岩开展了年代学、地球化学、黄铁矿成分和同位素特征研究。LA-ICP-MS锆石U-Pb定年结果(256.6±2.3Ma)表明墨江金矿区内存在晚二叠世火山碎屑岩。锆石稀土元素含量较高,Ce正异常(δCe=2.02~32.98)和Eu负异常明显(δEu=0.06~0.38)。岩石具有低钛(TiO_(2)=0.47%~0.71%)、较高铝(Al_(2)O_(3)=10.96%~16.33%)、富铁(Fe_(2)O_(3)T=3.21%~9.12%)和硫(S=0.95%~3.92%)等特征,属于英安质-流纹质凝灰岩;此外,所有样品轻重稀土元素分馏显著((La/Yb)_(N)=7.50~15.7),Eu异常明显(δEu=0.54~0.68),亏损Nb、Ta、Ti、Sr、Ba,富集K、Pb,显示出弧火山岩的地球化学特征。Nd同位素(ε_(Nd)=-9.24~-9.61)显示富集特征,二阶段钕模式年龄为1.61~1.79Ga。凝灰岩中富含黄铁矿,黄铁矿属铁亏损型(S/Fe=2.00~2.09),存在Ni对Fe、As对S的类质同象置换;S主要来自地壳(δ^(34)SV-CDT=-8.8‰~-9.7‰);Co、Ni含量高但没有相关性,指示其为火山成因,后期受到了富Ni流体交代;黄铁矿的Au含量偏高,但未发现独立金矿物,推测可能存在纳米金。全岩地球化学特征、Nd同位素特征和锆石微量元素特征指示墨江金矿区凝灰岩形成于陆缘弧构造背景,为古特提斯洋俯冲消减过程中玄武质岩浆底侵导致古元古代变质基底重熔的产物,岩浆形成过程中伴有地幔物质的加入,同时存在金的初始富集,形成含金黄铁矿,并在随后的区域变质作用及构造热事件中发生金的活化迁移,为金矿床的最终形成提供成矿物质。晚二叠世弧岩浆作用对于墨江金矿的形成具有重要意义。