Zr substitution for Ti was investigated to modify the dielectric properties of Ba6-3xLa8+2xTi18O54(x=2/3) ceramics.A single-phase solid solution with tungstenbronze-like structure was formed in the range of 0<z<...Zr substitution for Ti was investigated to modify the dielectric properties of Ba6-3xLa8+2xTi18O54(x=2/3) ceramics.A single-phase solid solution with tungstenbronze-like structure was formed in the range of 0<z<0.2 in Ba6-3xLa8+2x(Ti1-zZrz)18O54 ceramics.As Zr content exceeded this range,a secondary phase of Ba2ZrO4 was detected.This is correlated with the decrease of tolerance factor.As Zr content increased,there was an expansion of the b-axis and c-axis,and increase in the cell volume.Incorporation ...展开更多
文摘Zr substitution for Ti was investigated to modify the dielectric properties of Ba6-3xLa8+2xTi18O54(x=2/3) ceramics.A single-phase solid solution with tungstenbronze-like structure was formed in the range of 0<z<0.2 in Ba6-3xLa8+2x(Ti1-zZrz)18O54 ceramics.As Zr content exceeded this range,a secondary phase of Ba2ZrO4 was detected.This is correlated with the decrease of tolerance factor.As Zr content increased,there was an expansion of the b-axis and c-axis,and increase in the cell volume.Incorporation ...
