A series of sandwich-type tungstoarsenates heteropoly compounds with As/W ratio of 4/30, Na16[As4W30M4(H2O)2O112]·XH2O (M = Zn,Cu,Co,Ni,Mn and Cd), have been synthesized for the first time and structurally charac...A series of sandwich-type tungstoarsenates heteropoly compounds with As/W ratio of 4/30, Na16[As4W30M4(H2O)2O112]·XH2O (M = Zn,Cu,Co,Ni,Mn and Cd), have been synthesized for the first time and structurally characterized by elemental analysis, IR and 183W NMR spectra. The crystal structure of Na16[As4W30Cu4(H2O)2O112]·63H2O was determined to be a triclinic system, of P1 symmetry, a = 1.2721(3) nm, b = 2.451 6(5) nm, c = 2.6450(5) nm,展开更多
A new organic-inorganic hybrid copper-substituted arsenatotungstate complex formulated as [{Cu（phen）（en）} {Cu（phen）} {Cu3（phen）3（α-AsW9033）}]（OH）·3H2O （1, en = ethylene-diamine, 1,10-phen = 1,10-phe...A new organic-inorganic hybrid copper-substituted arsenatotungstate complex formulated as [{Cu（phen）（en）} {Cu（phen）} {Cu3（phen）3（α-AsW9033）}]（OH）·3H2O （1, en = ethylene-diamine, 1,10-phen = 1,10-phenanthroline） has been synthesized by controlling the reaction process and characterized by infrared （IR） spectroscopy, elemental analysis, and thermogravimetric （TG） analysis. Crystal data for 1： C62H56AsCusN12O37W9, Mr=3608.46, monoclinic, space group P21/n, a = 13.245（4）, b = 25.692（9）, c = 24.670（8） A, fl = 99.251（6）°, V= 8286（5） A3, Z = 4, GOOF = 1.103, R = 0.0560, wR = 0.1285. In 1, the vacant sites of the trivacant Keggin anion [α-AsW9O33]9- are occupied by three same copper coordination cations [Cu（phen）]2＋. Meanwhile, the lacunary anion [α-AsWgO33]9-, is capped by two kinds of copper coordination cations [Cu（phen）]2＋ and [Cu（Dhen）（en）]2＋, resulting in an unorecedented Dolvcation structure with Cs svmmetrv.展开更多
文摘A series of sandwich-type tungstoarsenates heteropoly compounds with As/W ratio of 4/30, Na16[As4W30M4(H2O)2O112]·XH2O (M = Zn,Cu,Co,Ni,Mn and Cd), have been synthesized for the first time and structurally characterized by elemental analysis, IR and 183W NMR spectra. The crystal structure of Na16[As4W30Cu4(H2O)2O112]·63H2O was determined to be a triclinic system, of P1 symmetry, a = 1.2721(3) nm, b = 2.451 6(5) nm, c = 2.6450(5) nm,
基金supported by the Foundation of Education Department of Henan Province(14A150028)
文摘A new organic-inorganic hybrid copper-substituted arsenatotungstate complex formulated as [{Cu（phen）（en）} {Cu（phen）} {Cu3（phen）3（α-AsW9033）}]（OH）·3H2O （1, en = ethylene-diamine, 1,10-phen = 1,10-phenanthroline） has been synthesized by controlling the reaction process and characterized by infrared （IR） spectroscopy, elemental analysis, and thermogravimetric （TG） analysis. Crystal data for 1： C62H56AsCusN12O37W9, Mr=3608.46, monoclinic, space group P21/n, a = 13.245（4）, b = 25.692（9）, c = 24.670（8） A, fl = 99.251（6）°, V= 8286（5） A3, Z = 4, GOOF = 1.103, R = 0.0560, wR = 0.1285. In 1, the vacant sites of the trivacant Keggin anion [α-AsW9O33]9- are occupied by three same copper coordination cations [Cu（phen）]2＋. Meanwhile, the lacunary anion [α-AsWgO33]9-, is capped by two kinds of copper coordination cations [Cu（phen）]2＋ and [Cu（Dhen）（en）]2＋, resulting in an unorecedented Dolvcation structure with Cs svmmetrv.
