To investigate the interaction of the bolt-reinforced rock and the surface support,an analytical model of the convergence-confinement type is proposed,considering the sequential installation of the fully grouted rockb...To investigate the interaction of the bolt-reinforced rock and the surface support,an analytical model of the convergence-confinement type is proposed,considering the sequential installation of the fully grouted rockbolts and the surface support.The rock mass is assumed to be elastic-brittle-plastic material,obeying the linear Mohr-Coulomb criterion or the non-linear Hoek-Brown criterion.According to the strain states of the tunnel wall at bolt and surface support installation and the relative magnitude between the bolt length and the plastic depth during the whole process,six cases are categorized upon solving the problem.Each case is divided into three stages due to the different effects of the active rockbolts and the passive surface support.The fictitious pressure is introduced to quantify the threedimensional(3D)effect of the tunnel face,and thus,the actual physical location along the tunnel axis of the analytical section can be considered.By using the bolt-rock strain compatibility and the rocksurface support displacement compatibility conditions,the solutions of longitudinal tunnel displacement and the reaction pressure of surface support along the tunnel axis are obtained.The proposed analytical solutions are validated by a series of 3D numerical simulations.Extensive parametric studies are conducted to examine the effect of the typical parameters of rockbolts and surface support on the tunnel displacement and the reaction pressure of the surface support under different rock conditions.The results show that the rockbolts are more effective in controlling the tunnel displacement than the surface support,which should be installed as soon as possible with a suitable length.For tunnels excavated in weak rocks or with restricted displacement control requirements,the surface support should also be installed or closed timely with a certain stiffness.The proposed method provides a convenient alternative approach for the optimization of rockbolts and surface support at the preliminary stage of tunnel design.展开更多
The control of large deformation problems in layered soft rock tunnels needs to solve urgently.The roof problem is particularly severe among the deformation issues in tunnels.This study first analyzes the asymmetric d...The control of large deformation problems in layered soft rock tunnels needs to solve urgently.The roof problem is particularly severe among the deformation issues in tunnels.This study first analyzes the asymmetric deformation modes in layered soft rock tunnels with large deformations.Subsequently,we construct a mechanical model under ideal conditions for controlling the roof of layered soft rock tunnels through high preload with the support of NPR anchor cables.The prominent roles of long and short NPR anchor cables in the support system are also analyzed.The results indicate the significance of high preload in controlling the roof of layered soft rock tunnels.The short NPR anchor cables effectively improve the integrity of the stratified soft rock layers,while the long NPR anchor cables effectively mobilize the self-bearing capacity of deep-stable rock layers.Finally,the high-preload support method with NPR anchor cables is validated to have a good effect on controlling large deformations in layered soft rock tunnels through field monitoring data.展开更多
Face stability is an essential issue in tunnel design and construction.Layered rock masses are typical and ubiquitous;uncertainties in rock properties always exist.In view of this,a comprehensive method,which combines...Face stability is an essential issue in tunnel design and construction.Layered rock masses are typical and ubiquitous;uncertainties in rock properties always exist.In view of this,a comprehensive method,which combines the Upper bound Limit analysis of Tunnel face stability,the Polynomial Chaos Kriging,the Monte-Carlo Simulation and Analysis of Covariance method(ULT-PCK-MA),is proposed to investigate the seismic stability of tunnel faces.A two-dimensional analytical model of ULT is developed to evaluate the virtual support force based on the upper bound limit analysis.An efficient probabilistic analysis method PCK-MA based on the adaptive Polynomial Chaos Kriging metamodel is then implemented to investigate the parameter uncertainty effects.Ten input parameters,including geological strength indices,uniaxial compressive strengths and constants for three rock formations,and the horizontal seismic coefficients,are treated as random variables.The effects of these parameter uncertainties on the failure probability and sensitivity indices are discussed.In addition,the effects of weak layer position,the middle layer thickness and quality,the tunnel diameter,the parameters correlation,and the seismic loadings are investigated,respectively.The results show that the layer distributions significantly influence the tunnel face probabilistic stability,particularly when the weak rock is present in the bottom layer.The efficiency of the proposed ULT-PCK-MA is validated,which is expected to facilitate the engineering design and construction.展开更多
With the development of China's economy,the implementation scale and scope of hydraulic engineering projects are increasing,and the application of anti-seepage technology has an important influence on the construc...With the development of China's economy,the implementation scale and scope of hydraulic engineering projects are increasing,and the application of anti-seepage technology has an important influence on the construction quality of hydraulic engineering.In this paper,the significance and problems of the application of anti-seepage technology in the construction of hydraulic engineering projects were mainly analyzed,and specific application strategies were proposed.展开更多
We have proposed a methodology to assess the robustness of underground tunnels against potential failure.This involves developing vulnerability functions for various qualities of rock mass and static loading intensiti...We have proposed a methodology to assess the robustness of underground tunnels against potential failure.This involves developing vulnerability functions for various qualities of rock mass and static loading intensities.To account for these variations,we utilized a Monte Carlo Simulation(MCS)technique coupled with the finite difference code FLAC^(3D),to conduct two thousand seven hundred numerical simulations of a horseshoe tunnel located within a rock mass with different geological strength index system(GSIs)and subjected to different states of static loading.To quantify the severity of damage within the rock mass,we selected one stress-based(brittle shear ratio(BSR))and one strain-based failure criterion(plastic damage index(PDI)).Based on these criteria,we then developed fragility curves.Additionally,we used mathematical approximation techniques to produce vulnerability functions that relate the probabilities of various damage states to loading intensities for different quality classes of blocky rock mass.The results indicated that the fragility curves we obtained could accurately depict the evolution of the inner and outer shell damage around the tunnel.Therefore,we have provided engineers with a tool that can predict levels of damages associated with different failure mechanisms based on variations in rock mass quality and in situ stress state.Our method is a numerically developed,multi-variate approach that can aid engineers in making informed decisions about the robustness of underground tunnels.展开更多
Rock mass quality serves as a vital index for predicting the stability and safety status of rock tunnel faces.In tunneling practice,the rock mass quality is often assessed via a combination of qualitative and quantita...Rock mass quality serves as a vital index for predicting the stability and safety status of rock tunnel faces.In tunneling practice,the rock mass quality is often assessed via a combination of qualitative and quantitative parameters.However,due to the harsh on-site construction conditions,it is rather difficult to obtain some of the evaluation parameters which are essential for the rock mass quality prediction.In this study,a novel improved Swin Transformer is proposed to detect,segment,and quantify rock mass characteristic parameters such as water leakage,fractures,weak interlayers.The site experiment results demonstrate that the improved Swin Transformer achieves optimal segmentation results and achieving accuracies of 92%,81%,and 86%for water leakage,fractures,and weak interlayers,respectively.A multisource rock tunnel face characteristic(RTFC)dataset includes 11 parameters for predicting rock mass quality is established.Considering the limitations in predictive performance of incomplete evaluation parameters exist in this dataset,a novel tree-augmented naive Bayesian network(BN)is proposed to address the challenge of the incomplete dataset and achieved a prediction accuracy of 88%.In comparison with other commonly used Machine Learning models the proposed BN-based approach proved an improved performance on predicting the rock mass quality with the incomplete dataset.By utilizing the established BN,a further sensitivity analysis is conducted to quantitatively evaluate the importance of the various parameters,results indicate that the rock strength and fractures parameter exert the most significant influence on rock mass quality.展开更多
This study focuses on the analytical prediction of subsurface settlement induced by shield tunnelling in sandy cobble stratum considering the volumetric deformation modes of the soil above the tunnel crown.A series of...This study focuses on the analytical prediction of subsurface settlement induced by shield tunnelling in sandy cobble stratum considering the volumetric deformation modes of the soil above the tunnel crown.A series of numerical analyses is performed to examine the effects of cover depth ratio(C/D),tunnel volume loss rate(h t)and volumetric block proportion(VBP)on the characteristics of subsurface settle-ment trough and soil volume loss.Considering the ground loss variation with depth,three modes are deduced from the volumetric deformation responses of the soil above the tunnel crown.Then,analytical solutions to predict subsurface settlement for each mode are presented using stochastic medium theory.The influences of C/D,h t and VBP on the key parameters(i.e.B and N)in the analytical expressions are discussed to determine the fitting formulae of B and N.Finally,the proposed analytical solutions are validated by the comparisons with the results of model test and numerical simulation.Results show that the fitting formulae provide a convenient and reliable way to evaluate the key parameters.Besides,the analytical solutions are reasonable and available in predicting the subsurface settlement induced by shield tunnelling in sandy cobble stratum.展开更多
This study is focused on the effect of vibration induced by moving trains in tunnels on the surrounding ground and structures.A three-dimensional finite element model is established for a one-track railway tunnel and ...This study is focused on the effect of vibration induced by moving trains in tunnels on the surrounding ground and structures.A three-dimensional finite element model is established for a one-track railway tunnel and an adjacent twelve-storey building frame by using commercial software Midas GTS-NX(2019)and Midas Gen.This study considered the moving load effect of a complete train,which varies with space as well as with time.The effect of factors such as train speed,overburden pressure on the tunnel and variation in soil properties are studied in the time domain.As a result,the variations in horizontal and vertical acceleration for two different sites,i.e.,the free ground surface(without structure)and the area containing the structure,are compared.Also,the displacement pattern of the raft foundation is plotted for different train velocities.At lower speeds,the heaving phenomenon is negligible,but as the speed increases,both the heaving and differential settlement increase in the foundation.This study demonstrates that the effect of moving train vibrations should be considered in the design of new nearby structures and proper ground improvement should be considered for existing structures.展开更多
Engineering shallow,large-span rock tunnels challenges deformation control and escalates construction costs.This study investigates the excavation compensation method(ECM)and its associated technologies to address the...Engineering shallow,large-span rock tunnels challenges deformation control and escalates construction costs.This study investigates the excavation compensation method(ECM)and its associated technologies to address these issues.Utilizing five key technologies,the ECM effectively modulates radial stress post-excavation,redistributes stress in the surrounding rock,and eliminates tensile stress at the excavation face.Pre-tensioning measures further enhance the rock’s residual strength,establishing a new stability equilibrium.Field tests corroborate the method’s effectiveness,demonstrating a crown settlement reduction of 3–8 mm,a nearly 50%decrease compared to conventional construction approaches.Additionally,material consumption and construction duration were reduced by approximately 30%–35%and 1.75 months per 100 m,respectively.Thus,the ECM represents a significant innovation in enhancing the stability and construction efficiency of large-span rock tunnels,marking a novel contribution to the engineering field.展开更多
To achieve the loading of the stress path of hard rock,the spherical discrete element model(DEM)and the new flexible membrane technology were utilized to realize the transient loading of three principal stresses with ...To achieve the loading of the stress path of hard rock,the spherical discrete element model(DEM)and the new flexible membrane technology were utilized to realize the transient loading of three principal stresses with arbitrary magnitudes and orientations.Furthermore,based on the deep tunnel of China Jinping Underground Laboratory II(CJPL-II),the deformation and fracture evolution characteristics of deep hard rock induced by excavation stress path were analyzed,and the mechanisms of transient loading-unloading and stress rotation-induced fractures were revealed from a mesoscopic perspective.The results indicated that the stressestrain curve exhibits different trends and degrees of sudden changes when subjected to transient changes in principal stress,accompanied by sudden changes in strain rate.Stress rotation induces spatially directional deformation,resulting in fractures of different degrees and orientations,and increasing the degree of deformation anisotropy.The correlation between the degree of induced fracture and the unloading magnitude of minimum principal stress,as well as its initial level is significant and positive.The process of mechanical response during transient unloading exhibits clear nonlinearity and directivity.After transient unloading,both the minimum principal stress and minimum principal strain rate decrease sharply and then tend to stabilize.This occurs from the edge to the interior and from the direction of the minimum principal stress to the direction of the maximum principal stress on theε1-ε3 plane.Transient unloading will induce a tensile stress wave.The ability to induce fractures due to changes in principal stress magnitude,orientation and rotation paths gradually increases.The analysis indicates a positive correlation between the abrupt change amplitude of strain rate and the maximum unloading magnitude,which is determined by the magnitude and rotation of principal stress.A high tensile strain rate is more likely to induce fractures under low minimum principal stress.展开更多
Face bolting has been widely utilized to enhance the stability of tunnel face,particularly in soft soil tunnels.However,the influence of bolt reinforcement and its layout on tunnel face stability has not been systemat...Face bolting has been widely utilized to enhance the stability of tunnel face,particularly in soft soil tunnels.However,the influence of bolt reinforcement and its layout on tunnel face stability has not been systematically studied.Based on the theory of linear elastic mechanics,this study delved into the specific mechanisms of bolt reinforcement on the tunnel face in both horizontal and vertical dimensions.It also identified the primary failure types of bolts.Additionally,a design approach for tunnel face bolts that incorporates spatial layout was established using the limit equilibrium method to enhance the conventional wedge-prism model.The proposed model was subsequently validated through various means,and the specific influence of relevant bolt design parameters on tunnel face stability was analyzed.Furthermore,design principles for tunnel face bolts under different geological conditions were presented.The findings indicate that bolt failure can be categorized into three stages:tensile failure,pullout failure,and comprehensive failure.Increasing cohesion,internal friction angle,bolt density,and overlap length can effectively enhance tunnel face stability.Due to significant variations in stratum conditions,tailored design approaches based on specific failure stages are necessary for bolt design.展开更多
Twin curved tunnels are often encountered in shield tunnelling,where significant complexities in densely exploited underground space are observed.In this study,the ground settlement and tunnel deformation due to twin-...Twin curved tunnels are often encountered in shield tunnelling,where significant complexities in densely exploited underground space are observed.In this study,the ground settlement and tunnel deformation due to twin-curved shield tunnelling in soft ground were investigated using numerical simulation and field monitoring.Different curvature radii of twin curved tunnels and subsequent effects of tunnel construction were considered to reveal the tunnelling effect on ground surface settlement and tunnel deformation.The results show that the settlement trough yields one offset towards inside of curved shield tunnelling.The location of settlement trough and maximum settlement were affected by curvature radius but except for the shape and width of settlement trough.Adjacent parallel twin-curved shield tunnelling could increase the offset of existing settlement trough and maximum settlement.Then,an empirical prediction of surface settlement trough due to twin-curved shield tunnelling with same tunnel diameters in soft clay was proposed,which was applicable to curvature radius less than 800 m.Finally,a minimum radius of 600 m of curvature tunnel was proposed in terms of allowable convergence deformation of tunnel.The result could provide guidance on safety evaluation for twin curved shield tunnelling construction.展开更多
Burial depth is a crucial factor affecting the forces and deformation of tunnels during earthquakes.One key issue is a lack of understanding of the effect of a change in the buried depth of a single-side tunnel on the...Burial depth is a crucial factor affecting the forces and deformation of tunnels during earthquakes.One key issue is a lack of understanding of the effect of a change in the buried depth of a single-side tunnel on the seismic response of a double-tunnel system.In this study,shaking table tests were designed and performed based on a tunnel under construction in Dalian,China.Numerical models were established using the equivalent linear method combined with ABAQUS finite element software to analyze the seismic response of the interacting system.The results showed that the amplification coefficient of the soil acceleration did not change evidently with the burial depth of the new tunnel but decreased as the seismic amplitude increased.In addition,the existing tunnel acceleration,earth pressure,and internal force were hardly affected by the change in the burial depth;for the new tunnel,the acceleration and internal force decreased as the burial depth increased,while the earth pressure increased.This shows that the earth pressure distribution in a double-tunnel system is relatively complex and mainly concentrated on the arch spandrel and arch springing of the relative area.Overall,when the horizontal clearance between the center of the two tunnels was more than twice the sum of the radius of the outer edges of the two tunnels,the change in the burial depth of the new tunnel had little effect on the existing one,and the tunnel structure was deemed safe.These results provide a preliminary understanding and reference for the seismic performance of a double-tunnel system.展开更多
In comparison to ferromagnets,antiferromagnets are believed to have superior advantages for applications in next-generation magnetic storage devices,including fast spin dynamics,vanishing stray fields and robust again...In comparison to ferromagnets,antiferromagnets are believed to have superior advantages for applications in next-generation magnetic storage devices,including fast spin dynamics,vanishing stray fields and robust against external magnetic field,etc.However,unlike ferromagnetic orders,which could be detected through tunneling magnetoresistance effect in magnetic tunnel junctions,the antiferromagnetic order(i.e.,Néel vector)cannot be effectively detected by the similar mechanism due to the spin degeneracy of conventional antiferromagnets.Recently discovered spin-splitting noncollinear antiferromagnets,such as Mn_(3)Pt with momentum-dependent spin polarization due to their special magnetic space group,make it possible to achieve remarkable tunneling magnetoresistance effects in noncollinear antiferromagnetic tunnel junctions.Through first-principles calculations,we demonstrate that the tunneling magnetoresistance ratio can reach more than 800% in Mn_(3)Pt/perovskite oxides/Mn_(3)Pt antiferromagnetic tunnel junctions.We also reveal the switching dynamics of Mn_(3)Pt thin film under magnetic fields using atomistic spin dynamic simulation.Our study provides a reliable method for detecting Néel vector of noncollinear antiferromagnets through the tunnel magnetoresistance effect and may pave its way for potential applications in antiferromagnetic memory devices.展开更多
Introduction: Amyloidosis are systemic conditions and carpal tunnel syndrome (CTS) precedes the principal systemic complications and can be used as an early marker. Our objective was to determine the frequency of amyl...Introduction: Amyloidosis are systemic conditions and carpal tunnel syndrome (CTS) precedes the principal systemic complications and can be used as an early marker. Our objective was to determine the frequency of amyloid deposition in idiopathic CTS and its systemic impact. Methods: We retrospectively evaluated patients with CTS between September 2019 to January 2020. Samples from the anterior carpal ligament were pathologically evaluated and amyloid deposition was confirmed by apple-green birefringence on polarized light using Congo red stain. When amyloid was detected we performed genetic testing for transthyretin variants (ATTRv), immunofixation electrophoresis in serum and urine for light chains and multidisciplinary evaluation. Results: Thirty consecutive patients were included, 19 women, 11 men, mean age 70 years old (range 42 - 89 years). We identified 3 patients (10%) with amyloid deposits (mean age: 78.6 years, 2 men, 1 woman). Genetic testing for ATTRv and light chains studies were negative. During follow-up: The first patient required aortic valve replacement. The second patient developed progressive cardiac failure with syncopal episodes, atrioventricular block and atrial fibrillation and required a pacemaker and anticoagulation. The third patient had unexplained chronic edemas. The cardiac evaluation in all 3 patients revealed left ventricular hypertrophy and myocardial uptake (Perugini Score > 2) in their nuclear bone scintigraphies with technetium pyrophosphate. Two patients were treated with tafamidis and one patient died due to refractory cardiac insufficiency. Discussion: Our findings underline the importance of investigating amyloidosis in idiopathic CTS. The identification of deposits allows early diagnosis of cardiac amyloidosis leading to timely intervention and treatment.展开更多
Highly permeable geological structures such as dissolution channels, open fractures, and faults create environmental challenges regard to hydrological and hydrogeological aspects of underground construction, often cau...Highly permeable geological structures such as dissolution channels, open fractures, and faults create environmental challenges regard to hydrological and hydrogeological aspects of underground construction, often causing significant groundwater inflow during drilling due to the limitations of empirical and analytical methods. This study aims to identify the geological factors influencing water flow into the tunnel. High-flow zones' geological features have been identified and examined for this purpose. According to the geological complexity of the Nowsud tunnel, presence of different formations with different permeability and karstification have led to a high volume of underground inflow water (up to 4700 L/s) to the tunnel. The Nowsud tunnel faces significant geological and hydrogeological challenges due to its passage through the Ilam formation's LI2 unit, characterized by dissolution channels, faults, and fractures. The highest inflow rate (4700 L/s) occurred in the Hz-9 zone within the Zimkan anticline. The relationship between geological features and groundwater inflow indicates that anticlines are more susceptible to inflow than synclines. Additionally, different types of faults exhibit varying hydraulic effects, with strike-slip faults having the most significant impact on groundwater inflow, thrust faults conducting less water into the tunnel, and inflow through normal faults being negligible compared to the other two types of faults. The novelty of this paper lies in its detailed analysis of geological features influencing groundwater inflow into the Nowsud tunnel, providing empirical data on high-flow zones and differentiating the hydraulic effects of various fault types, which enhances the understanding and prediction of groundwater inflow in underground constructions.展开更多
Incident particles in the Klein tunnel phenomenon in quantum mechanics can pass a very high potential barrier.Introducing the concept of tunneling into the analysis of phononic crystals can broaden the application pro...Incident particles in the Klein tunnel phenomenon in quantum mechanics can pass a very high potential barrier.Introducing the concept of tunneling into the analysis of phononic crystals can broaden the application prospects.In this study,the structure of the unit cell is designed,and the low frequency(<1 k Hz)valley locked waveguide is realized through the creation of a phononic crystal plate with a topological phase transition interface.The defect immunity of the topological waveguide is verified,that is,the wave can propagate along the original path in the cases of impurities and disorder.Then,the tunneling phenomenon is introduced into the topological valley-locked waveguide to analyze the wave propagation,and its potential applications(such as signal separators and logic gates)are further explored by designing phononic crystal plates.This research has broad application prospects in information processing and vibration control,and potential applications in other directions are also worth exploring.展开更多
The stability of strip footings subjected to eccentrically inclined loads is critical for reliable foundation design.This study investigates the effect of a circular unlined tunnel in a rock mass on the ultimate beari...The stability of strip footings subjected to eccentrically inclined loads is critical for reliable foundation design.This study investigates the effect of a circular unlined tunnel in a rock mass on the ultimate bearing capacity(UBC)of a foundation with width B under inclined and eccentric loads.Adaptive finite element limit analysis was employed to evaluate the reduction in UBC of the footing resting above a tunnel.The examined critical parameters include normalized load eccentricity(e/B),load inclination(β),and horizontal and vertical distances of the tunnel from the foundation(P/B and Q/B,respectively),along with rock mass properties.The results reveal that for e/B≥0.25 and β≤60°,the reduction coefficient,R_(c)≥0.90,suggesting that the presence of a tunnel has a minimal impact on the load-bearing capacity of the footing,with failure primarily governed by load eccentricity and inclination.Additionally,potential failure mechanisms are explored,showing that at lower e/B,higher β,and lower Q/B,the tunnel significantly affects footing's failure envelope.Conversely,at higher e/B and lower β,failure is due to rotational effects of footing,regardless of the tunnel's position.To predict the Rc more accurately,due to the time-consuming nature of direct calculations,both MLR and ANN models were developed.The MLR model provided a baseline for comparison,while the ANN model,with a coefficient of determination(R2)of 0.98,demonstrated superior accuracy compared to the R2=0.96 of MLR.Using both approaches ensured robust and efficient predictions of Rc.Since Rc does not directly provide the reduced UBC of footing due to presence of tunnel,the study introduced bearing capacity factor(Nc)to enable direct calculation of the reduced UBC of footing.These findings offer theoretical guidelines for preliminary design and provide practitioners with an effective tool for evaluating UBC reduction in complex loading scenarios involving tunnels.展开更多
The response of tunnels subjected to seismic loading is a complex mechanism and depends not only on the seismic nature but also on tunnel structure and surrounding soil properties.The individual behavior of circular,r...The response of tunnels subjected to seismic loading is a complex mechanism and depends not only on the seismic nature but also on tunnel structure and surrounding soil properties.The individual behavior of circular,rectangular,and sub-rectangular tunnels subjected to seismic loadings has already been studied in the literature.In the present research,two case scenarios of circular,rectangular tunnels and four sub-rectangular shaped tunnels,with similar cross-section areas,were adopted to perform a comprehensive numerical investigation.The purpose of the study was to determine the mechanical behavior of tunnels of different shapes,depending upon seismic conditions.Analyses were performed by considering the influence of soil-lining interaction,soil parameters,and lining thickness,as well as lining rigidity.Computations were performed for no-slip and full-slip conditions.The results indicate that the tunnel shape design is of great importance when regarding the mechanical behavior of the surrounding soil.This concerns no-slip as well as full-slip soil-lining interaction,especially when the lining is subjected to seismic loading.Moreover,it is shown that changes in incremental bending moments for circular,rectangular and sub-rectangular tunnels that depend upon the soil-lining interaction conditions differ significantly.展开更多
We report here the in situ electrochemical scanning tunneling microscopy(ECSTM) study of cobalt phthalocyanine(CoPc)-catalyzed O_(2) evolution reaction(OER) and the dynamics of CoPc-O_(2) dissociation.The self-assembl...We report here the in situ electrochemical scanning tunneling microscopy(ECSTM) study of cobalt phthalocyanine(CoPc)-catalyzed O_(2) evolution reaction(OER) and the dynamics of CoPc-O_(2) dissociation.The self-assembled CoPc monolayer is fabricated on Au(111) substrate and resolved by ECSTM in 0.1 M KOH electrolyte.The OH^(-)adsorption on CoPc prior to OER is observed in ECSTM images.During OER,the generated O_(2) adsorbed on Co Pc is observed in the CoPc monolayer.Potential step experiment is employed to monitor the desorption of OER-generated O_(2) from CoPc,which results in the decreasing surface coverage of CoPc-O_(2) with time.The rate constant of O_(2) desorption is evaluated through data fitting.The insights into the dynamics of Co-O_(2) dissociation at the molecular level via in situ imaging help understand the role of Co-O_(2) in oxygen reduction reaction(ORR) and OER.展开更多
基金funding support from the Fundamental Research Funds for the Central Universities(Grant No.2023JBZY024)the National Natural Science Foundation of China(Grant Nos.52208382 and 52278387).
文摘To investigate the interaction of the bolt-reinforced rock and the surface support,an analytical model of the convergence-confinement type is proposed,considering the sequential installation of the fully grouted rockbolts and the surface support.The rock mass is assumed to be elastic-brittle-plastic material,obeying the linear Mohr-Coulomb criterion or the non-linear Hoek-Brown criterion.According to the strain states of the tunnel wall at bolt and surface support installation and the relative magnitude between the bolt length and the plastic depth during the whole process,six cases are categorized upon solving the problem.Each case is divided into three stages due to the different effects of the active rockbolts and the passive surface support.The fictitious pressure is introduced to quantify the threedimensional(3D)effect of the tunnel face,and thus,the actual physical location along the tunnel axis of the analytical section can be considered.By using the bolt-rock strain compatibility and the rocksurface support displacement compatibility conditions,the solutions of longitudinal tunnel displacement and the reaction pressure of surface support along the tunnel axis are obtained.The proposed analytical solutions are validated by a series of 3D numerical simulations.Extensive parametric studies are conducted to examine the effect of the typical parameters of rockbolts and surface support on the tunnel displacement and the reaction pressure of the surface support under different rock conditions.The results show that the rockbolts are more effective in controlling the tunnel displacement than the surface support,which should be installed as soon as possible with a suitable length.For tunnels excavated in weak rocks or with restricted displacement control requirements,the surface support should also be installed or closed timely with a certain stiffness.The proposed method provides a convenient alternative approach for the optimization of rockbolts and surface support at the preliminary stage of tunnel design.
基金financial support from the Second Tibetan Plateau Scientific Expedition and Research Program(STEP)(No.2019QZKK0708)the National Natural Science Foundation of China(No.41941018)the Special Fund of Yueqi Scholars(No.800015Z1207).
文摘The control of large deformation problems in layered soft rock tunnels needs to solve urgently.The roof problem is particularly severe among the deformation issues in tunnels.This study first analyzes the asymmetric deformation modes in layered soft rock tunnels with large deformations.Subsequently,we construct a mechanical model under ideal conditions for controlling the roof of layered soft rock tunnels through high preload with the support of NPR anchor cables.The prominent roles of long and short NPR anchor cables in the support system are also analyzed.The results indicate the significance of high preload in controlling the roof of layered soft rock tunnels.The short NPR anchor cables effectively improve the integrity of the stratified soft rock layers,while the long NPR anchor cables effectively mobilize the self-bearing capacity of deep-stable rock layers.Finally,the high-preload support method with NPR anchor cables is validated to have a good effect on controlling large deformations in layered soft rock tunnels through field monitoring data.
基金supported by Science and Technology Project of Yunnan Provincial Transportation Department(Grant No.25 of 2018)the National Natural Science Foundation of China(Grant No.52279107)The authors are grateful for the support by the China Scholarship Council(CSC No.202206260203 and No.201906690049).
文摘Face stability is an essential issue in tunnel design and construction.Layered rock masses are typical and ubiquitous;uncertainties in rock properties always exist.In view of this,a comprehensive method,which combines the Upper bound Limit analysis of Tunnel face stability,the Polynomial Chaos Kriging,the Monte-Carlo Simulation and Analysis of Covariance method(ULT-PCK-MA),is proposed to investigate the seismic stability of tunnel faces.A two-dimensional analytical model of ULT is developed to evaluate the virtual support force based on the upper bound limit analysis.An efficient probabilistic analysis method PCK-MA based on the adaptive Polynomial Chaos Kriging metamodel is then implemented to investigate the parameter uncertainty effects.Ten input parameters,including geological strength indices,uniaxial compressive strengths and constants for three rock formations,and the horizontal seismic coefficients,are treated as random variables.The effects of these parameter uncertainties on the failure probability and sensitivity indices are discussed.In addition,the effects of weak layer position,the middle layer thickness and quality,the tunnel diameter,the parameters correlation,and the seismic loadings are investigated,respectively.The results show that the layer distributions significantly influence the tunnel face probabilistic stability,particularly when the weak rock is present in the bottom layer.The efficiency of the proposed ULT-PCK-MA is validated,which is expected to facilitate the engineering design and construction.
文摘With the development of China's economy,the implementation scale and scope of hydraulic engineering projects are increasing,and the application of anti-seepage technology has an important influence on the construction quality of hydraulic engineering.In this paper,the significance and problems of the application of anti-seepage technology in the construction of hydraulic engineering projects were mainly analyzed,and specific application strategies were proposed.
基金funding received by a grant from the Natural Sciences and Engineering Research Council of Canada(NSERC)(Grant No.CRDPJ 469057e14).
文摘We have proposed a methodology to assess the robustness of underground tunnels against potential failure.This involves developing vulnerability functions for various qualities of rock mass and static loading intensities.To account for these variations,we utilized a Monte Carlo Simulation(MCS)technique coupled with the finite difference code FLAC^(3D),to conduct two thousand seven hundred numerical simulations of a horseshoe tunnel located within a rock mass with different geological strength index system(GSIs)and subjected to different states of static loading.To quantify the severity of damage within the rock mass,we selected one stress-based(brittle shear ratio(BSR))and one strain-based failure criterion(plastic damage index(PDI)).Based on these criteria,we then developed fragility curves.Additionally,we used mathematical approximation techniques to produce vulnerability functions that relate the probabilities of various damage states to loading intensities for different quality classes of blocky rock mass.The results indicated that the fragility curves we obtained could accurately depict the evolution of the inner and outer shell damage around the tunnel.Therefore,we have provided engineers with a tool that can predict levels of damages associated with different failure mechanisms based on variations in rock mass quality and in situ stress state.Our method is a numerically developed,multi-variate approach that can aid engineers in making informed decisions about the robustness of underground tunnels.
基金supported by the National Natural Science Foundation of China(Nos.52279107 and 52379106)the Qingdao Guoxin Jiaozhou Bay Second Submarine Tunnel Co.,Ltd.,the Academician and Expert Workstation of Yunnan Province(No.202205AF150015)the Science and Technology Innovation Project of YCIC Group Co.,Ltd.(No.YCIC-YF-2022-15)。
文摘Rock mass quality serves as a vital index for predicting the stability and safety status of rock tunnel faces.In tunneling practice,the rock mass quality is often assessed via a combination of qualitative and quantitative parameters.However,due to the harsh on-site construction conditions,it is rather difficult to obtain some of the evaluation parameters which are essential for the rock mass quality prediction.In this study,a novel improved Swin Transformer is proposed to detect,segment,and quantify rock mass characteristic parameters such as water leakage,fractures,weak interlayers.The site experiment results demonstrate that the improved Swin Transformer achieves optimal segmentation results and achieving accuracies of 92%,81%,and 86%for water leakage,fractures,and weak interlayers,respectively.A multisource rock tunnel face characteristic(RTFC)dataset includes 11 parameters for predicting rock mass quality is established.Considering the limitations in predictive performance of incomplete evaluation parameters exist in this dataset,a novel tree-augmented naive Bayesian network(BN)is proposed to address the challenge of the incomplete dataset and achieved a prediction accuracy of 88%.In comparison with other commonly used Machine Learning models the proposed BN-based approach proved an improved performance on predicting the rock mass quality with the incomplete dataset.By utilizing the established BN,a further sensitivity analysis is conducted to quantitatively evaluate the importance of the various parameters,results indicate that the rock strength and fractures parameter exert the most significant influence on rock mass quality.
基金This study was supported by the National Natural Science Foundation of China(Grant Nos.51538001 and 51978019).
文摘This study focuses on the analytical prediction of subsurface settlement induced by shield tunnelling in sandy cobble stratum considering the volumetric deformation modes of the soil above the tunnel crown.A series of numerical analyses is performed to examine the effects of cover depth ratio(C/D),tunnel volume loss rate(h t)and volumetric block proportion(VBP)on the characteristics of subsurface settle-ment trough and soil volume loss.Considering the ground loss variation with depth,three modes are deduced from the volumetric deformation responses of the soil above the tunnel crown.Then,analytical solutions to predict subsurface settlement for each mode are presented using stochastic medium theory.The influences of C/D,h t and VBP on the key parameters(i.e.B and N)in the analytical expressions are discussed to determine the fitting formulae of B and N.Finally,the proposed analytical solutions are validated by the comparisons with the results of model test and numerical simulation.Results show that the fitting formulae provide a convenient and reliable way to evaluate the key parameters.Besides,the analytical solutions are reasonable and available in predicting the subsurface settlement induced by shield tunnelling in sandy cobble stratum.
文摘This study is focused on the effect of vibration induced by moving trains in tunnels on the surrounding ground and structures.A three-dimensional finite element model is established for a one-track railway tunnel and an adjacent twelve-storey building frame by using commercial software Midas GTS-NX(2019)and Midas Gen.This study considered the moving load effect of a complete train,which varies with space as well as with time.The effect of factors such as train speed,overburden pressure on the tunnel and variation in soil properties are studied in the time domain.As a result,the variations in horizontal and vertical acceleration for two different sites,i.e.,the free ground surface(without structure)and the area containing the structure,are compared.Also,the displacement pattern of the raft foundation is plotted for different train velocities.At lower speeds,the heaving phenomenon is negligible,but as the speed increases,both the heaving and differential settlement increase in the foundation.This study demonstrates that the effect of moving train vibrations should be considered in the design of new nearby structures and proper ground improvement should be considered for existing structures.
基金Projects(42377148,51674265)supported by the National Natural Science Foundation of ChinaProject(2018YFC0603705)supported by the National Key Research and Development Program of China。
文摘Engineering shallow,large-span rock tunnels challenges deformation control and escalates construction costs.This study investigates the excavation compensation method(ECM)and its associated technologies to address these issues.Utilizing five key technologies,the ECM effectively modulates radial stress post-excavation,redistributes stress in the surrounding rock,and eliminates tensile stress at the excavation face.Pre-tensioning measures further enhance the rock’s residual strength,establishing a new stability equilibrium.Field tests corroborate the method’s effectiveness,demonstrating a crown settlement reduction of 3–8 mm,a nearly 50%decrease compared to conventional construction approaches.Additionally,material consumption and construction duration were reduced by approximately 30%–35%and 1.75 months per 100 m,respectively.Thus,the ECM represents a significant innovation in enhancing the stability and construction efficiency of large-span rock tunnels,marking a novel contribution to the engineering field.
基金the financial support from the National Natural Science Foundation of China(Grant No.51839003)Liaoning Revitalization Talents Program(Grant No.XLYCYSZX 1902)Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources(Grant No.2023zy002).
文摘To achieve the loading of the stress path of hard rock,the spherical discrete element model(DEM)and the new flexible membrane technology were utilized to realize the transient loading of three principal stresses with arbitrary magnitudes and orientations.Furthermore,based on the deep tunnel of China Jinping Underground Laboratory II(CJPL-II),the deformation and fracture evolution characteristics of deep hard rock induced by excavation stress path were analyzed,and the mechanisms of transient loading-unloading and stress rotation-induced fractures were revealed from a mesoscopic perspective.The results indicated that the stressestrain curve exhibits different trends and degrees of sudden changes when subjected to transient changes in principal stress,accompanied by sudden changes in strain rate.Stress rotation induces spatially directional deformation,resulting in fractures of different degrees and orientations,and increasing the degree of deformation anisotropy.The correlation between the degree of induced fracture and the unloading magnitude of minimum principal stress,as well as its initial level is significant and positive.The process of mechanical response during transient unloading exhibits clear nonlinearity and directivity.After transient unloading,both the minimum principal stress and minimum principal strain rate decrease sharply and then tend to stabilize.This occurs from the edge to the interior and from the direction of the minimum principal stress to the direction of the maximum principal stress on theε1-ε3 plane.Transient unloading will induce a tensile stress wave.The ability to induce fractures due to changes in principal stress magnitude,orientation and rotation paths gradually increases.The analysis indicates a positive correlation between the abrupt change amplitude of strain rate and the maximum unloading magnitude,which is determined by the magnitude and rotation of principal stress.A high tensile strain rate is more likely to induce fractures under low minimum principal stress.
基金financially supported by the Fundamental Research Funds for the Central Universities,CHD(300102212706)the National Natural Science Foundation of China[Grant No.52108360]the Science and Technology Project of Department of Transportation of Yunnan Province(No.YJKJ[2019]59)。
文摘Face bolting has been widely utilized to enhance the stability of tunnel face,particularly in soft soil tunnels.However,the influence of bolt reinforcement and its layout on tunnel face stability has not been systematically studied.Based on the theory of linear elastic mechanics,this study delved into the specific mechanisms of bolt reinforcement on the tunnel face in both horizontal and vertical dimensions.It also identified the primary failure types of bolts.Additionally,a design approach for tunnel face bolts that incorporates spatial layout was established using the limit equilibrium method to enhance the conventional wedge-prism model.The proposed model was subsequently validated through various means,and the specific influence of relevant bolt design parameters on tunnel face stability was analyzed.Furthermore,design principles for tunnel face bolts under different geological conditions were presented.The findings indicate that bolt failure can be categorized into three stages:tensile failure,pullout failure,and comprehensive failure.Increasing cohesion,internal friction angle,bolt density,and overlap length can effectively enhance tunnel face stability.Due to significant variations in stratum conditions,tailored design approaches based on specific failure stages are necessary for bolt design.
基金financially supported by the National Natural Science Foundation of China(Grant No.42307260)the Sichuan Natural Science Foundation(Grant No.2023NSFSC0882)the Open Project of the Research Center of Tunnelling and Underground Engineering of Ministry of Education(Grant No.TUC2022-03).
文摘Twin curved tunnels are often encountered in shield tunnelling,where significant complexities in densely exploited underground space are observed.In this study,the ground settlement and tunnel deformation due to twin-curved shield tunnelling in soft ground were investigated using numerical simulation and field monitoring.Different curvature radii of twin curved tunnels and subsequent effects of tunnel construction were considered to reveal the tunnelling effect on ground surface settlement and tunnel deformation.The results show that the settlement trough yields one offset towards inside of curved shield tunnelling.The location of settlement trough and maximum settlement were affected by curvature radius but except for the shape and width of settlement trough.Adjacent parallel twin-curved shield tunnelling could increase the offset of existing settlement trough and maximum settlement.Then,an empirical prediction of surface settlement trough due to twin-curved shield tunnelling with same tunnel diameters in soft clay was proposed,which was applicable to curvature radius less than 800 m.Finally,a minimum radius of 600 m of curvature tunnel was proposed in terms of allowable convergence deformation of tunnel.The result could provide guidance on safety evaluation for twin curved shield tunnelling construction.
基金Scientific Research Fund of Liaoning Provincial Education Department under Grant No.LJKZ0336。
文摘Burial depth is a crucial factor affecting the forces and deformation of tunnels during earthquakes.One key issue is a lack of understanding of the effect of a change in the buried depth of a single-side tunnel on the seismic response of a double-tunnel system.In this study,shaking table tests were designed and performed based on a tunnel under construction in Dalian,China.Numerical models were established using the equivalent linear method combined with ABAQUS finite element software to analyze the seismic response of the interacting system.The results showed that the amplification coefficient of the soil acceleration did not change evidently with the burial depth of the new tunnel but decreased as the seismic amplitude increased.In addition,the existing tunnel acceleration,earth pressure,and internal force were hardly affected by the change in the burial depth;for the new tunnel,the acceleration and internal force decreased as the burial depth increased,while the earth pressure increased.This shows that the earth pressure distribution in a double-tunnel system is relatively complex and mainly concentrated on the arch spandrel and arch springing of the relative area.Overall,when the horizontal clearance between the center of the two tunnels was more than twice the sum of the radius of the outer edges of the two tunnels,the change in the burial depth of the new tunnel had little effect on the existing one,and the tunnel structure was deemed safe.These results provide a preliminary understanding and reference for the seismic performance of a double-tunnel system.
基金supported by the National Natural Science Foundation of China(Grant Nos.T2394475,T2394470,and 12174129)。
文摘In comparison to ferromagnets,antiferromagnets are believed to have superior advantages for applications in next-generation magnetic storage devices,including fast spin dynamics,vanishing stray fields and robust against external magnetic field,etc.However,unlike ferromagnetic orders,which could be detected through tunneling magnetoresistance effect in magnetic tunnel junctions,the antiferromagnetic order(i.e.,Néel vector)cannot be effectively detected by the similar mechanism due to the spin degeneracy of conventional antiferromagnets.Recently discovered spin-splitting noncollinear antiferromagnets,such as Mn_(3)Pt with momentum-dependent spin polarization due to their special magnetic space group,make it possible to achieve remarkable tunneling magnetoresistance effects in noncollinear antiferromagnetic tunnel junctions.Through first-principles calculations,we demonstrate that the tunneling magnetoresistance ratio can reach more than 800% in Mn_(3)Pt/perovskite oxides/Mn_(3)Pt antiferromagnetic tunnel junctions.We also reveal the switching dynamics of Mn_(3)Pt thin film under magnetic fields using atomistic spin dynamic simulation.Our study provides a reliable method for detecting Néel vector of noncollinear antiferromagnets through the tunnel magnetoresistance effect and may pave its way for potential applications in antiferromagnetic memory devices.
文摘Introduction: Amyloidosis are systemic conditions and carpal tunnel syndrome (CTS) precedes the principal systemic complications and can be used as an early marker. Our objective was to determine the frequency of amyloid deposition in idiopathic CTS and its systemic impact. Methods: We retrospectively evaluated patients with CTS between September 2019 to January 2020. Samples from the anterior carpal ligament were pathologically evaluated and amyloid deposition was confirmed by apple-green birefringence on polarized light using Congo red stain. When amyloid was detected we performed genetic testing for transthyretin variants (ATTRv), immunofixation electrophoresis in serum and urine for light chains and multidisciplinary evaluation. Results: Thirty consecutive patients were included, 19 women, 11 men, mean age 70 years old (range 42 - 89 years). We identified 3 patients (10%) with amyloid deposits (mean age: 78.6 years, 2 men, 1 woman). Genetic testing for ATTRv and light chains studies were negative. During follow-up: The first patient required aortic valve replacement. The second patient developed progressive cardiac failure with syncopal episodes, atrioventricular block and atrial fibrillation and required a pacemaker and anticoagulation. The third patient had unexplained chronic edemas. The cardiac evaluation in all 3 patients revealed left ventricular hypertrophy and myocardial uptake (Perugini Score > 2) in their nuclear bone scintigraphies with technetium pyrophosphate. Two patients were treated with tafamidis and one patient died due to refractory cardiac insufficiency. Discussion: Our findings underline the importance of investigating amyloidosis in idiopathic CTS. The identification of deposits allows early diagnosis of cardiac amyloidosis leading to timely intervention and treatment.
文摘Highly permeable geological structures such as dissolution channels, open fractures, and faults create environmental challenges regard to hydrological and hydrogeological aspects of underground construction, often causing significant groundwater inflow during drilling due to the limitations of empirical and analytical methods. This study aims to identify the geological factors influencing water flow into the tunnel. High-flow zones' geological features have been identified and examined for this purpose. According to the geological complexity of the Nowsud tunnel, presence of different formations with different permeability and karstification have led to a high volume of underground inflow water (up to 4700 L/s) to the tunnel. The Nowsud tunnel faces significant geological and hydrogeological challenges due to its passage through the Ilam formation's LI2 unit, characterized by dissolution channels, faults, and fractures. The highest inflow rate (4700 L/s) occurred in the Hz-9 zone within the Zimkan anticline. The relationship between geological features and groundwater inflow indicates that anticlines are more susceptible to inflow than synclines. Additionally, different types of faults exhibit varying hydraulic effects, with strike-slip faults having the most significant impact on groundwater inflow, thrust faults conducting less water into the tunnel, and inflow through normal faults being negligible compared to the other two types of faults. The novelty of this paper lies in its detailed analysis of geological features influencing groundwater inflow into the Nowsud tunnel, providing empirical data on high-flow zones and differentiating the hydraulic effects of various fault types, which enhances the understanding and prediction of groundwater inflow in underground constructions.
基金supported by the National Natural Science Foundation of China(No.12172297)the Open Foundation of State Key Laboratory of Structural Analysis for Industrial Equipment of China(No.GZ22106)the Innovation Foundation for Doctor Dissertation of Northwestern Polytechnical University of China(No.CX2023055)。
文摘Incident particles in the Klein tunnel phenomenon in quantum mechanics can pass a very high potential barrier.Introducing the concept of tunneling into the analysis of phononic crystals can broaden the application prospects.In this study,the structure of the unit cell is designed,and the low frequency(<1 k Hz)valley locked waveguide is realized through the creation of a phononic crystal plate with a topological phase transition interface.The defect immunity of the topological waveguide is verified,that is,the wave can propagate along the original path in the cases of impurities and disorder.Then,the tunneling phenomenon is introduced into the topological valley-locked waveguide to analyze the wave propagation,and its potential applications(such as signal separators and logic gates)are further explored by designing phononic crystal plates.This research has broad application prospects in information processing and vibration control,and potential applications in other directions are also worth exploring.
基金supported by the Civil Engineering Department, Madan Mohan Malaviya University of Technology, Gorakhpur, India
文摘The stability of strip footings subjected to eccentrically inclined loads is critical for reliable foundation design.This study investigates the effect of a circular unlined tunnel in a rock mass on the ultimate bearing capacity(UBC)of a foundation with width B under inclined and eccentric loads.Adaptive finite element limit analysis was employed to evaluate the reduction in UBC of the footing resting above a tunnel.The examined critical parameters include normalized load eccentricity(e/B),load inclination(β),and horizontal and vertical distances of the tunnel from the foundation(P/B and Q/B,respectively),along with rock mass properties.The results reveal that for e/B≥0.25 and β≤60°,the reduction coefficient,R_(c)≥0.90,suggesting that the presence of a tunnel has a minimal impact on the load-bearing capacity of the footing,with failure primarily governed by load eccentricity and inclination.Additionally,potential failure mechanisms are explored,showing that at lower e/B,higher β,and lower Q/B,the tunnel significantly affects footing's failure envelope.Conversely,at higher e/B and lower β,failure is due to rotational effects of footing,regardless of the tunnel's position.To predict the Rc more accurately,due to the time-consuming nature of direct calculations,both MLR and ANN models were developed.The MLR model provided a baseline for comparison,while the ANN model,with a coefficient of determination(R2)of 0.98,demonstrated superior accuracy compared to the R2=0.96 of MLR.Using both approaches ensured robust and efficient predictions of Rc.Since Rc does not directly provide the reduced UBC of footing due to presence of tunnel,the study introduced bearing capacity factor(Nc)to enable direct calculation of the reduced UBC of footing.These findings offer theoretical guidelines for preliminary design and provide practitioners with an effective tool for evaluating UBC reduction in complex loading scenarios involving tunnels.
基金supported by Vietnam Ministry of Education and Training under Grant No. B2022-MDA-06
文摘The response of tunnels subjected to seismic loading is a complex mechanism and depends not only on the seismic nature but also on tunnel structure and surrounding soil properties.The individual behavior of circular,rectangular,and sub-rectangular tunnels subjected to seismic loadings has already been studied in the literature.In the present research,two case scenarios of circular,rectangular tunnels and four sub-rectangular shaped tunnels,with similar cross-section areas,were adopted to perform a comprehensive numerical investigation.The purpose of the study was to determine the mechanical behavior of tunnels of different shapes,depending upon seismic conditions.Analyses were performed by considering the influence of soil-lining interaction,soil parameters,and lining thickness,as well as lining rigidity.Computations were performed for no-slip and full-slip conditions.The results indicate that the tunnel shape design is of great importance when regarding the mechanical behavior of the surrounding soil.This concerns no-slip as well as full-slip soil-lining interaction,especially when the lining is subjected to seismic loading.Moreover,it is shown that changes in incremental bending moments for circular,rectangular and sub-rectangular tunnels that depend upon the soil-lining interaction conditions differ significantly.
基金National Key R&D Program of China (2021YFA1501002)National Natural Science Foundation of China (22132007)。
文摘We report here the in situ electrochemical scanning tunneling microscopy(ECSTM) study of cobalt phthalocyanine(CoPc)-catalyzed O_(2) evolution reaction(OER) and the dynamics of CoPc-O_(2) dissociation.The self-assembled CoPc monolayer is fabricated on Au(111) substrate and resolved by ECSTM in 0.1 M KOH electrolyte.The OH^(-)adsorption on CoPc prior to OER is observed in ECSTM images.During OER,the generated O_(2) adsorbed on Co Pc is observed in the CoPc monolayer.Potential step experiment is employed to monitor the desorption of OER-generated O_(2) from CoPc,which results in the decreasing surface coverage of CoPc-O_(2) with time.The rate constant of O_(2) desorption is evaluated through data fitting.The insights into the dynamics of Co-O_(2) dissociation at the molecular level via in situ imaging help understand the role of Co-O_(2) in oxygen reduction reaction(ORR) and OER.