Surface modification by physical adsorption of Tween 20 was accomplished on polypropylene microporous membranes (PPMMs). Attenuated total reflection-Fourier transform infrared spectroscopy (ATR/FT-IR) and field em...Surface modification by physical adsorption of Tween 20 was accomplished on polypropylene microporous membranes (PPMMs). Attenuated total reflection-Fourier transform infrared spectroscopy (ATR/FT-IR) and field emission scanning electron microscope (FE- SEM) were used to characterize the chemical and morphological changes on the membrane surfaces. Water contact angles and relative pure water fluxes were measured. The data showed that the hydrophilic performance for the modified membranes increased with the increase in the adsorption amount of Tween 20 onto the surface or into the pores of polypropylene microporous membranes. To test the antifouling property of the membranes by the adsorption of Tween 20 in a membrane bioreactor (MBR), filtration for active sludge was performed using synthetic wastewater. With the help of the data of water fluxes and the FE-SEM photos of the modified PPMMs before or after operating in a MBR for about 12 d, the PPMMs with monolayer adsorption of Tween 20 showed higher remained flux and stronger antifouling ability than unmodified membrane and other modification membranes studied.展开更多
以大豆分离蛋白(soy protein isolate,SPI)和核桃油为主要原料,添加不同浓度的小分子表面活性剂Tween 20,利用高压均质技术制备水包油型(oil in water,O/W)乳液,研究含有蛋白质与小分子表面活性剂混合乳化剂对乳液的界面特性、物理和氧...以大豆分离蛋白(soy protein isolate,SPI)和核桃油为主要原料,添加不同浓度的小分子表面活性剂Tween 20,利用高压均质技术制备水包油型(oil in water,O/W)乳液,研究含有蛋白质与小分子表面活性剂混合乳化剂对乳液的界面特性、物理和氧化稳定性的影响。结果表明:当Tween 20质量浓度由0增加到10 g/L时,乳液粒度趋于集中分布,乳滴粒径和微观形态呈现逐渐减小的趋势;Zeta电位的绝对值和表面张力降低;在贮藏期间蛋白质色氨酸荧光强度减弱,氢过氧化物值与硫代巴比妥酸产物值(thiobarbituric acid reactive substances,TBARS)升高。上述结果表明,乳液中Tween 20浓度增加,乳液的物理稳定性得到较好改善,但由于Tween 20取代界面上的SPI,减弱了乳液氧化稳定性。该研究通过分析界面组成对含有混合乳化剂的乳液物理、氧化稳定性的影响,为含小分子表面活性剂的蛋白质乳液在食品加工中的应用提供了参考。展开更多
基金Project supported by the High-Tech Research and Development Program (863)of China(No.2002AA601230)the Science-Research Program of Jiaxing City,China(No.2005AY3013).
文摘Surface modification by physical adsorption of Tween 20 was accomplished on polypropylene microporous membranes (PPMMs). Attenuated total reflection-Fourier transform infrared spectroscopy (ATR/FT-IR) and field emission scanning electron microscope (FE- SEM) were used to characterize the chemical and morphological changes on the membrane surfaces. Water contact angles and relative pure water fluxes were measured. The data showed that the hydrophilic performance for the modified membranes increased with the increase in the adsorption amount of Tween 20 onto the surface or into the pores of polypropylene microporous membranes. To test the antifouling property of the membranes by the adsorption of Tween 20 in a membrane bioreactor (MBR), filtration for active sludge was performed using synthetic wastewater. With the help of the data of water fluxes and the FE-SEM photos of the modified PPMMs before or after operating in a MBR for about 12 d, the PPMMs with monolayer adsorption of Tween 20 showed higher remained flux and stronger antifouling ability than unmodified membrane and other modification membranes studied.
基金supported by the National Natural Science Foundation of China(21521003,21233002)National Key Basic Research Special Foundation of China(2012CB917304)~~