Deep brain implantable microelectrode arrays for detection and functional localization of the subthalamic nucleus in rats with Parkinson’s disease

The subthalamic nucleus(STN)is considered the best target for deep brain stimulation treatments of Parkinson’s disease(PD).It is difficult to localize the STN due to its small size and deep location.Multichannel microelectrode arrays(MEAs)can rapidly and precisely locate the STN,which is important for precise stimulation.In this paper,16-channel MEAs modified with multiwalled carbon nanotube/poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)(MWCNT/PEDOT:PSS)nanocomposites were designed and fabricated,and the accurate and rapid identification of the STN in PD rats was performed using detection sites distributed at different brain depths.These results showed that nuclei in 6-hydroxydopamine hydrobromide(6-OHDA)-lesioned brains discharged more intensely than those in unlesioned brains.In addition,the MEA simultaneously acquired neural signals from both the STN and the upper or lower boundary nuclei of the STN.Moreover,higher values of spike firing rate,spike amplitude,local field potential(LFP)power,and beta oscillations were detected in the STN of the 6-OHDA-lesioned brain,and may therefore be biomarkers of STN localization.Compared with the STNs of unlesioned brains,the power spectral density of spikes and LFPs synchronously decreased in the delta band and increased in the beta band of 6-OHDA-lesioned brains.This may be a cause of sleep and motor disorders associated with PD.Overall,this work describes a new cellular-level localization and detection method and provides a tool for future studies of deep brain nuclei.

Telecom-band multiwavelength vertical emitting quantum well nanowire laser arrays

Highly integrated optoelectronic and photonic systems underpin the development of next-generation advanced optical and quantum communication technologies,which require compact,multiwavelength laser sources at the telecom band.Here,we report on-substrate vertical emitting lasing from ordered InGaAs/InP multi-quantum well core–shell nanowire array epitaxially grown on InP substrate by selective area epitaxy.To reduce optical loss and tailor the cavity mode,a new nanowire facet engineering approach has been developed to achieve controlled quantum well nanowire dimensions with uniform morphology and high crystal quality.Owing to the strong quantum confinement effect of InGaAs quantum wells and the successful formation of a vertical Fabry–Pérot cavity between the top nanowire facet and bottom nanowire/SiO_(2) mask interface,stimulated emissions of the EH11a/b mode from single vertical nanowires from an on-substrate nanowire array have been demonstrated with a lasing threshold of~28.2μJ cm^(−2) per pulse and a high characteristic temperature of~128 K.By fine-tuning the In composition of the quantum wells,room temperature,single-mode lasing is achieved in the vertical direction across a broad near-infrared spectral range,spanning from 940 nm to the telecommunication O and C bands.Our research indicates that through a carefully designed facet engineering strategy,highly ordered,uniform nanowire arrays with precise dimension control can be achieved to simultaneously deliver thousands of nanolasers with multiple wavelengths on the same substrate,paving a promising and scalable pathway towards future advanced optoelectronic and photonic systems.

Manipulating d-d orbital hybridization induced by Mo-doped Co_(9)S_(8) nanorod arrays for high-efficiency water electrolysis

Precisely refining the electronic structure of electrocatalysts represents a powerful approach to further optimize the electrocatalytic performance.Herein,we demonstrate an ingenious d-d orbital hybridization concept to construct Mo-doped Co_(9)S_(8) nanorod arrays aligned on carbon cloth(CC)substrate(abbreviated as Mo-Co_(9)S_(8)@CC hereafter)as a high-efficiency bifunctional electrocatalyst toward water electrolysis.It has experimentally and theoretically validated that the 4d-3d orbital coupling between Mo dopant and Co site can effectively optimize the H_(2)O activation energy and lower H^(*)adsorption energy barrier,thereby leading to enhanced hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)activities.Thanks to the unique electronic and geometrical advantages,the optimized Mo-Co_(9)S_(8)@CC with appropriate Mo content exhibits outstanding bifunctional performance in alkaline solution,with the overpotentials of 75 and 234 mV for the delivery of a current density of 10 mA cm^(-2),small Tafel slopes of 53.8 and 39.9 mV dec~(-1)and long-term stabilities for at least 32 and 30 h for HER and OER,respectively.More impressively,a water splitting electrolylzer assembled by the self-supported Mo-Co_(9)S_(8)@CC electrode requires a low cell voltage of 1.53 V at 10 mA cm^(-2)and shows excellent stability and splendid reversibility,demonstrating a huge potential for affordable and scalable electrochemical H_(2) production.The innovational orbital hybridization strategy for electronic regulation herein provides an inspirable avenue for developing progressive electrocatalysts toward new energy systems.

Joint 2D DOA and Doppler frequency estimation for L-shaped array using compressive sensing

A joint two-dimensional(2D)direction-of-arrival(DOA)and radial Doppler frequency estimation method for the L-shaped array is proposed in this paper based on the compressive sensing(CS)framework.Revised from the conventional CS-based methods where the joint spatial-temporal parameters are characterized in one large scale matrix,three smaller scale matrices with independent azimuth,elevation and Doppler frequency are introduced adopting a separable observation model.Afterwards,the estimation is achieved by L1-norm minimization and the Bayesian CS algorithm.In addition,under the L-shaped array topology,the azimuth and elevation are separated yet coupled to the same radial Doppler frequency.Hence,the pair matching problem is solved with the aid of the radial Doppler frequency.Finally,numerical simulations corroborate the feasibility and validity of the proposed algorithm.

The wave and vibratory power transmission in a finite L-shaped Mindlin plate with two simply supported opposite edges

In this paper,wave and vibratory power transmission in a finite L-shaped Mindlin plate with two simply supported opposite edges are investigated using the wave approach.The dynamic responses,active and reactive power flow in the finite plate are calculated by the Mindlin plate theory （MPT） and classic plate theory （CPT）.To satisfy the boundary conditions and continuous conditions at the coupled junction of the finite L-shaped plate,the near-field and far-field waves are entirely contained in the wave approach.The in-plane longitudinal and shear waves are also considered.The results indicate that the vibratory power flow based on the MPT is different from that based on the CPT not only at high frequencies but also at low and medium frequencies.The influence of the plate thickness on the vibrational power flow is investigated.From the results it is seen that the shear and rotary inertia correction of the MPT can influence the active and reactive power at the junction of the L-shaped plate not only at high frequencies but also at low and medium frequencies.Furthermore,the effects of structural damping on the active and reactive power flow at the junction are also analyzed.

Axial Compression Behavior and Analytical Method of L-Shaped Column Composed of Concrete-Filled Square Steel Tubes

Based on the characteristics of an L-shaped column composed of concrete-filled square steel tubes, the axial compression experiment and nonlinear finite element analysis were carried out to study the mechanical property of the L-shaped column. The load-displacement curve for the L-shaped column, the deflection and load-strain curves for the mono columns were obtained by the axial compression experiment. The results show that the L-shaped column exhibits a flexural-torsional buckling failure mode. The numerical simulation by the finite element analysis shows that the bearing capacity and failure mode are in accordance with those of the axial compression experiment and the feasi- bility of the finite element analysis is proved. For the calculation of the bearing capacity of the L-shaped column com- posed of concrete-filled square steel tubes, an analytical method is proposed based on the theory of the elastic stability and spatial truss model. The results of the analytical method are in good agreement with those of the axial compression experiment and the finite element analysis.

Research on vibration characteristics of L-shaped plate using a mobility power flow approach

L-shaped plates have become an important focuses in structural vibration research. To determine their vibration characteristics, this paper applied a mobility power flow method. Firstly, the L-shaped plate was divided into two substructures to simplify analysis. The coupled bending moment was then deduced by applying a continuous vibration property on the common edge. Next, the response on any point of the plate and the input and transmitted power flow formulas were calculated. Numerical simulations showed the distribution of the coupled bending moment and the response of the whole structure. The validity of this method was verified by the SEA approach.

Laboratory test on the combined cooling effect of L-shaped thermosyphons and thermal insulation on high-grade roadway construction in permafrost regions

With the completion of the Qinghai-Tibetan Railway,economic development of related areas has been greatly accelerated.This,in return,calls for building or upgrading more roadways,especially high-grade roadways.In cold regions,the thawing of permafrost can induce settlement damage of and even failure to railway (or roadway) embankments.Thermosyphons (self-powered refrigera-tion devices that are used to help keep the permafrost cool) have proved effective in mitigating thaw settlement by maintaining the thermal stability of the embankments.However,for high-grade roadway embankments of great width,stabilizing or cooling ef-fects of traditional geotechnological measures may be limited.To enhance the cooling effect of thermosyphons,an L-shaped thermosyphon was designed.A laboratory test was carried out to study the combined cooling effect of the L-shaped thermosyphon and thermal insulation applying to roadbed construction.The angle between the evaporator and condenser sections of the L-shaped thermosyphon is 134 degrees,and the L-shaped thermosyphon was inserted into the soil at an angle of 5 degrees with the road surface.The tested results show that the L-shaped thermosyphon is effective in removing heat from a roadway in winter.When the ambient air temperature is lower than the soil temperature,the thermosyphon is active and extracts the heat in the soil around it.When the ambient air temperature is higher than the soil temperature,the thermosyphon is inactive,and no heat is in-jected into the soil through the L-shaped thermosyphon.Compared to embankments with straight thermosyphons,the inner parts of the embankments with L-shaped thermosyphons were significantly cooled.It is hoped that the present study would be useful to the application of L-shaped thermosyphons in the construction of high-grade roadways in cold regions.

Test on mechanical behavior of SRC L-shaped columns under combined torsion and bending moment

Investigations of the seismic behavior of steel reinforced concrete L-shaped columns under constant axial compression and cycled bending-shear-torsion load were performed.Six specimens,which considered two parameters,i.e.,the moment ratio of torsion to bending(γ)and the aspect ratio(column length-to-depth ratio,φ),were prepared for the experiment.In this study,the failure process,torsion-displacement hysteresis curves,and flexure-displacement hysteresis curves were obtained.The failure characteristics,mechanical behavior of specimens such as the failure patterns,hysteresis curves,rigidity degradation,ductility and energy dissipation,are analyzed.The experimental research indicated that the major failures of the specimens were bending failure,bending-shear failure and bending-torsion failure as the moment ratio of torsion to bending(γ)increased.The torsion-displacement hysteresis curves were pinched in the middle,formed a slip platform,and the phenomenon of“load drop”occurred after the peak load.The bending-displacement hysteresis curves were plump,which showed that bending capacity of the specimen was better than its torsion capacity.Additionally,the energy dissipation of the specimen was dominated by torsion in the early stage and ultimately governed by the bending moment in the later phase.Test results also indicated that the displacement ductility coefficient and interstory rotation angle of the failure point were less than 3.0 and 1/50,respectively,which means the test specimen performance does not meet the requirement of the Chinese Code for Seismic Design of Buildings(GB 50011-2014)in this respect.

A core-shell copper oxides-cobalt oxides heterostructure nanowire arrays for nitrate reduction to ammonia with high yield rate

Electrochemical nitrate reduction to ammonia(NRA) can realize the green synthesis of ammonia(NH3) at ambient conditions, and also remove nitrate contamination in water. However, the current catalysts for NRA still face relatively low NH3yield rate and poor stability. We present here a core-shell heterostructure comprising cobalt oxide anchored on copper oxide nanowire arrays(CuO NWAs@Co_(3)O_(4)) for efficient NRA. The CuO NWAs@Co_(3)O_(4)demonstrates significantly enhanced NRA performance in alkaline media in comparison with plain CuO NWAs and Co_(3)O_(4)flocs. Especially, at-0.23 V vs. RHE, NH_(3) yield rate of the CuO NWAs@Co_(3)O_(4)reaches 1.915 mmol h^(-1)cm^(-2),much higher than those of CuO NWAs(1.472 mmol h^(-1)cm^(-2)), Co_(3)O_(4)flocs(1.222 mmol h^(-1)cm^(-2)) and recent reported Cu-based catalysts.It is proposed that the synergetic effects of the heterostructure combing atom hydrogen adsorption and nitrate reduction lead to the enhanced NRA performance.

Bandwidth Numerical Analysis of Triangular Patch Antenna Fed by L-Shaped Probe

A single layer triangular patch antenna fed by an L-shaped probe was investigated numerically by using FDTD (Finite Difference Time Domain) method. It achieves >40% impedance bandwidth (VSWR<2) and stable radiation pattern across the passband. The triangular patch antenna with two orientations of L-shaped probe has almost the same characteristics, such as impedance bandwidth and radiation pattern. The bandwidth vs feeding position was also investigated, the broadband characteristic can be observed when the feeding position is only in a small segment along the centerline.

The Effects of Cross Sectional Dimensions on the Behavior of L-Shaped RC Structural Members

The behavior of L-Shaped RC （reinforced concrete） shear walls was investigated in the Erciyes University Earthquake Investigation Laboratory under the influence of constant axial load together with reversed cyclic lateral load. The objective of this study was to evaluate the effects of cross sectional dimensions on the behavior of L-shaped structural members and to assess their earthquake performance. In order to investigate L-shaped RC structural members, the special experiment setup and four type of 1/2 scaled specimens which have different aspect ratio were constructed. The specimens were loaded in line with the major principal axes direction laterally. Axial load ratio was 0.1 and cross section height to thickness ratios were＇ 3：1, 5：1, 8：1, 10：1. Cross section thickness was 120 mm which corresponds to （360：120）, （600：120）, （960：120）, （1,200：120） wall legs cross sectional dimensions in mm. The specimens height was 1,500 mm, together with upper and lower slabs overall height was 2,000 mm. Concrete compression strength was 30 N/mm2, steel yield stress 420 N/mm2 and vertical reinforcement ratio was 1% for all specimens. According to the test results, the specimen of which the aspect ratio is 3 （360：120） has shown column behavior, the specimen of which the aspect ratio is 5 （600：120） has shown slender wall behavior and last two specimens of which the aspect ratios are 8 （960：120） and 10 （1,200：120） have shown squat wall behavior. When considering the cracking patterns and hysteretic behavior, since the aspect ratio 8, the specimens show flexure-shear interaction behavior and prone to brittle failure.

Multicut L-Shaped Algorithm for Stochastic Convex Programming with Fuzzy Probability Distribution

Two-stage problem of stochastic convex programming with fuzzy probability distribution is studied in this paper. Multicut L-shaped algorithm is proposed to solve the problem based on the fuzzy cutting and the minimax rule. Theorem of the convergence for the algorithm is proved. Finally, a numerical example about two-stage convex recourse problem shows the essential character and the efficiency.

Bidirectional visible light absorber based on nanodisk arrays

A perfect bidirectional broadband visible light absorber composed of titanium nitride and tungsten nanodisk arrays is proposed.The average absorption of the absorber exceeds 89%at 400 nm–800 nm when light is normally incident on the front-side.Illumination from the opposite direction(back-side)results in absorption of more than 75%.Through the theoretical analysis of the electric and magnetic fields,the physical mechanism of the broadband perfect absorption is attributed to the synergy of localized surface plasmons,propagating surface plasmons,and plasmonic resonant cavity modes.Furthermore,the absorber also exhibits excellent polarization-independence performance and a high angular tolerance of~30°for both front-and back-side incidence.The designed bidirectional broadband visible light absorber here has wide application prospects in the fields of solar cells and ink-free printing.

Controllable and large-area growth of ZnO nanosheet arrays under ambient condition as superior anodes for scalable aqueous batteries

Two-dimensional(2D)oxides have been the focus of substantial research interest recently,owing to their fascinating physico-chemical properties.However,fabrication of large-area 2D oxide materials in a controlled manner under mild conditions still remains a formidable challenge.Herein,we develop a facile and universal strategy based on the sonochemistry approach for controllable and large-area growth of quasi-aligned single-crystalline ZnO nanosheets on a Zn substrate(Zn@SC-ZnO)under ambient conditions.The obtained ZnO nanosheets possess the desired exclusively exposed(001)facets,which have been confirmed to play a critical role in significantly reducing the activation energy and facilitating the stripping/plating processes of Zn.Accordingly,the constructed Zn@SC-ZnO||Zn@SC-ZnO symmetric cell has very low polarization overpotential down to~20 mV,with limited dendrite growth and side reactions for Zn anodes.The developed Zn@SC-ZnO//MnO_(2)aqueous Zn-ion batteries(ZIBs)show a voltage efficiency of 88.2%under 500 mA g^(-1)at the stage of 50%depth of discharge,which is state of the art for ZIBs reported to date.Furthermore,the as-assembled large-size cell(5 cm×5 cm)delivers an open circuit potential of 1.648 V,and can be robustly operated under a high current of 20 mA,showing excellent potential for future scalable applications.

Homogenous metallic deposition regulated by abundant lithiophilic sites in nickel/cobalt oxides nanoneedle arrays for lithium metal batteries

Although lithium(Li)metal delivers the highest theoretical capacity as a battery anode,its high reactivity can generate Li dendrites and"dead"Li during cycling,resulting in poor reversibility and low Li utilization.Inducing uniform Li plating/stripping is the core of solving these problems.Herein,we design a highly lithiophilic carbon film with an outer sheath of the nanoneedle arrays to induce homogeneous Li plating/stripping.The excellent conductivity and 3D framework of the carbon film not only offer fast charge transport across the entire electrode but also mitigate the volume change of Li metal during cycling.The abundant lithiophilic sites ensure stable Li plating/stripping,thereby inhibiting the Li dendritic growth and"dead"Li formation.The resulting composite anode allows for stable Li stripping/plating under 0.5 mA cm^(-2) with a capacity of 0.5 mA h cm^(-2) for 4000 h and 3 mA cm^(-2) with a capacity of3 mA h cm^(-2) for 1000 h.The Ex-SEM analysis reveals that lithiophilic property is different at the bottom,top,or channel in the structu re,which can regulate a bottom-up uniform Li deposition behavior.Full cells paired with LFP show a stable capacity of 155 mA h g^(-1) under a current density of 0.5C.The pouch cell can keep powering light-emitting diode even under 180°bending,suggesting its good flexibility and great practical applications.

Developing Three-Dimensional Beamshaping Techniques on Volumetric Random Arrays to Suppress Array Sidelobes

This paper proposes a three-dimensional (3-D) amplitude tapering technique on volumetric random arrays to minimize array sidelobes and emulate phased array operations on mobile platforms. Our ultimate goal is to realize wireless phased array applications carried out by mobile platforms;in this paper, we focus on the development of collaborative beamforming algorithms. This beamshaping technique mitigates the discontinuity of the current distribution along the array aperture and lower array sidelobe level (SLL) by specially paying attention to the array element’s depth deviation. In this work, step by step amplitude tapering procedures are clearly illustrated. Further, a reconfigurable phased array with sixteen patch antennas is tested to verify the fidelity of the 3-D beamshaping algorithm. Measured and simulated radiation patterns are benchmarked to evaluate the sidelobe suppression results, and the best sidelobe suppressed region is around the array’s main beam.

Shear wave splitting analysis of local earthquakes from dense arrays in Shimian,Sichuan

The Shimian area of Sichuan sits at the junction of the Bayan Har block.Sichuan-Yunnan rhombic block,and Yangtze block,where several faults intersect.This region features intense tectonic activity and frequent earthquakes.In this study,we used local seismic waveform data recorded using dense arrays deployed in the Shimian area to obtain the shear wave splitting parameters at 55 seismic stations and thereby determine the crustal anisotropic characteristics of the region.We then analyzed the crustal stress pattern and tectonic setting and explored their relationship in the study area.Although some stations returned a polarization direction of NNW-SSE.a dominant polarization direction of NW-SE was obtained for the fast shear wave at most seismic stations in the study area.The polarization directions of the fast shear wave were highly consistent throughout the study-area.This orientation was in accordance with the direction of the regional principal compressive stress and parallel to the trend of the Xianshuihe and Daliangshan faults.The distribution of crustal anisotropy in this area was affected by the regional tectonic stress field and the fault structures.The mean delay time between fast and slow shear waves was 3.83 ms/km.slightly greater than the values obtained in other regions of Sichuan.This indicates that the crustal media in our study area had a high anisotropic strength and also reveals the influence of tectonic complexity resulting from the intersection of multiple faults on the strength of seismic anisotropy.

Influence of MnO_(x)deposition on TiO_(2)nanotube arrays for electrooxidation

TiO_(2)has demonstrated outstanding performance in electrochemical advanced oxidation processes(EAOPs)due to its structural stability and high oxygen overpotential.However,there is still much room for improving its electrochemical activity.Herein,narrow bandgap manganese oxide(MnO_(x))was composited with TiO_(2)nanotube arrays(TiO_(2)NTAs)that in-situ oxidized on porous Ti sponge,forming the MnO_(x)-TiO_(2)NTAs anode.XANES and XPS analysis further proved that the composition of MnO_(x)is Mn2O3.Electrochemical characterizations revealed that increasing the composited concentration of MnO_(x)can improve the conductivity and reduce oxygen evolution potential so as to improve the electrochemical activity of the composited MnO_(x)-TiO_(2)NTAs anode.Meanwhile,the optimal degradation rate of benzoic acid(BA)was achieved using MnO_(x)-TiO_(2)NTAs with a MnO_(x)concentration of 0.1 mmol L^(-1),and the role of MnO_(x)was proposed based on DFT calculation.Additionally,the required electrical energy(EE/O)to destroy BA was optimized by varying the composited concentration of MnO_(x)and the degradation voltage.These quantitative results are of great significance for the design and application of high-performance materials for EAOPs.

Atomic Dispersion of Rh on Interconnected Mo_(2)C Nanosheet Network Intimately Embedded in 3D Ni_(x)MoO_(y) Nanorod Arrays for pH-Universal Hydrogen Evolution

Herein,a simple synthetic approach is employed for the atomic dispersion of Rh atoms(Rh SAs)over the surface of interconnected Mo_(2)C nanosheets intimately embedded in a three-dimensional Ni_(x)MoO_(y)nanorod arrays(Ni_(x)MoO_(y)NRs)framework;we found that the introduction of both isolated Rh SAs and Ni_(x)MoO_(y)NRs adjusts the electrocatalytic function of the host Mo_(2)C toward the direction of being an advanced and highly stable electrocatalyst for efficient hydrogen evolution at pH-universal conditions.As a result,the proposed catalyst outperforms most recently reported transition metal-based catalysts,and its performance even rivals that of commercial Pt/C,as demonstrated by its ultralow overpotentials of 31.7,109.7,and 95.4 mV at a current density of 10 mA cm^(-2),along with its small Tafel slopes of 42.4,51.2,and 46.8 mV dec^(-1)in acidic,neutral,and alkaline conditions,respectively.In addition,the catalyst shows remarkable long-term stability over all pH values with good maintenance of its catalytic activity and structural characteristics after continuous operation.