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Janus Quasi‑Solid Electrolyte Membranes with Asymmetric Porous Structure for High‑Performance Lithium‑Metal Batteries
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作者 Zerui Chen Wei Zhao +4 位作者 Qian Liu Yifei Xu Qinghe Wang Jinmin Lin Hao Bin Wu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第6期221-232,共12页
Quasi-solid electrolytes(QSEs)based on nanoporous materials are promising candidates to construct high-performance Limetal batteries(LMBs).However,simultaneously boosting the ionic conductivity(σ)and lithium-ion tran... Quasi-solid electrolytes(QSEs)based on nanoporous materials are promising candidates to construct high-performance Limetal batteries(LMBs).However,simultaneously boosting the ionic conductivity(σ)and lithium-ion transference number(t^(+)) of liquid electrolyte confined in porous matrix remains challenging.Herein,we report a novel Janus MOFLi/MSLi QSEs with asymmetric porous structure to inherit the benefits of both mesoporous and microporous hosts.This Janus QSE composed of mesoporous silica and microporous MOF exhibits a neat Li^(+) conductivity of 1.5.10^(–4)S cm^(−1) with t^(+) of 0.71.A partially de-solvated structure and preference distribution of Li^(+)near the Lewis base O atoms were depicted by MD simulations.Meanwhile,the nanoporous structure enabled efficient ion flux regulation,promoting the homogenous deposition of Li^(+).When incorporated in Li||Cu cells,the MOFLi/MSLi QSEs demonstrated a high Coulombic efficiency of 98.1%,surpassing that of liquid electrolytes(96.3%).Additionally,NCM 622||Li batteries equipped with MOFLi/MSLi QSEs exhibited promising rate performance and could operate stably for over 200 cycles at 1 C.These results highlight the potential of Janus MOFLi/MSLi QSEs as promising candidates for next-generation LMBs. 展开更多
关键词 Metal-organic frameworks Mesoporous silicas Quasi-solid electrolytes janus structure Lithium-metal battery
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Janus织物的结构设计及其单向导湿性能
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作者 单明景 安春耕 《天津工业大学学报》 CAS 北大核心 2024年第2期36-42,48,共8页
针对传统单向导湿Janus织物制备方法生产效率低、稳定性差等问题,利用存在润湿性差异的莫代尔和涤纶2种纤维构建Janus织物,探究接结点数量、织物组织等结构参数对Janus织物基础性能和单向导湿性能的影响规律。结果表明:莫代尔纤维和涤... 针对传统单向导湿Janus织物制备方法生产效率低、稳定性差等问题,利用存在润湿性差异的莫代尔和涤纶2种纤维构建Janus织物,探究接结点数量、织物组织等结构参数对Janus织物基础性能和单向导湿性能的影响规律。结果表明:莫代尔纤维和涤纶纤维通过机织法可以制备Janus织物;随着接结点数量的增加,织物的单向导湿性能降低;平纹组织的单向导湿效果优于2/2纬重平、2/2斜纹组织;接结点数量为1,两侧均为平纹组织时Janus织物的单向传递指数可达382.72,单向导湿性能相对最优。 展开更多
关键词 janus织物 结构设计 单向导湿 接结点数量 织物组织
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Janus ZrBrI光电性质的第一性原理计算
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作者 马婷婷 蒲毓臻 +2 位作者 杨文军 何诗怡 黄兴勇 《宜宾学院学报》 2024年第6期76-82,共7页
基于密度泛函理论,采用第一性原理的平面波赝势法系统计算ZrI_(2)和Janus ZrBrI的几何结构、电子性质和光学性质.几何结构分析发现Janus结构对键长及单层厚度都存在一定影响.基于HSE06泛函计算结果表明ZrI_2和Janus ZrBrI均为准直接带... 基于密度泛函理论,采用第一性原理的平面波赝势法系统计算ZrI_(2)和Janus ZrBrI的几何结构、电子性质和光学性质.几何结构分析发现Janus结构对键长及单层厚度都存在一定影响.基于HSE06泛函计算结果表明ZrI_2和Janus ZrBrI均为准直接带隙半导体,禁带宽度分别为0.84、1.01 eV,其价带和导带主要由Zr的4d态电子构成.同时,Janus结构能形成内建电场,进一步抑制电子空穴对的复合.利用介电函数计算得到折射率、反射谱、吸收谱、光电导率和能量损失函数等光学参数,光学性质分析表明ZrI_(2)和Janus ZrBrI在可见光的吸收系数可达10^(-4)cm^(-1),Janus结构能够实现吸收峰的蓝移. 展开更多
关键词 janus ZrBrI 第一性原理 电子结构 光学性质
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Effect of strain on structure and electronic properties of monolayer C_(4)N_(4)
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作者 陈昊 徐瑛 +1 位作者 赵家石 周丹 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第5期595-600,共6页
The first-principles calculations are performed to examine structural,mechanical,and electronic properties at large strain for a monolayer C_(4)N_(4),which has been predicted as an anchoring promising material to atte... The first-principles calculations are performed to examine structural,mechanical,and electronic properties at large strain for a monolayer C_(4)N_(4),which has been predicted as an anchoring promising material to attenuate shuttle effect in Li–S batteries stemming from its large absorption energy and low diffusion energy barrier.Our results show that the ideal strengths of C_(4)N_(4)under tension and pure shear deformation conditions reach 13.9 GPa and 12.5 GPa when the strains are 0.07 and 0.28,respectively.The folded five-membered rings and diverse bonding modes between carbon and nitrogen atoms enhance the ability to resist plastic deformation of C_(4)N_(4).The orderly bond-rearranging behaviors under the weak tensile loading path along the[100]direction cause the impressive semiconductor–metal transition and inverse semiconductor–metal transition.The present results enrich the knowledge of the structure and electronic properties of C_(4)N_(4)under deformations and shed light on exploring other two-dimensional materials under diverse loading conditions. 展开更多
关键词 two-dimensional materials strain effect structural evolution electronic properties
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不同浓度Mg掺杂单层Janus WSSe的第一性原理研究
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作者 安梦雅 谢泉 +1 位作者 张和森 梁前 《原子与分子物理学报》 CAS 北大核心 2024年第2期124-130,共7页
二维Janus WSSe作为一种新型过渡金属硫族化合物(TMDs)材料由于其独特的面外非对称结构及众多新颖的物理特性,在自旋电子器件中具有巨大的应用潜力.本文基于密度泛函理论的第一性原理平面波赝势方法,通过构建四种掺杂模型W_(9-x)Mg_(x)S... 二维Janus WSSe作为一种新型过渡金属硫族化合物(TMDs)材料由于其独特的面外非对称结构及众多新颖的物理特性,在自旋电子器件中具有巨大的应用潜力.本文基于密度泛函理论的第一性原理平面波赝势方法,通过构建四种掺杂模型W_(9-x)Mg_(x)S_(9)Se_(9)(x=0、1、2、3),分别计算了不同浓度Mg掺杂单层WSSe的电子结构和光学性质.结果表明:掺杂使得WSSe由直接带隙半导体变为间接带隙半导体,并且随着掺杂浓度的增加,带隙逐渐减小,费米能级穿过价带,使得掺杂体系变成P型半导体,当x=3时,掺杂体系呈现金属性.此外,掺杂体系的静态介电常数随着掺杂浓度的增加而变大,极化程度显著增强,介电函数虚部和光吸收峰都发生了红移,说明掺杂有利于可见光的吸收.并且,静态折射率随着掺杂浓度的增加而呈现上升趋势,同时消光系数的峰值也与Mg原子的掺杂浓度呈现正相关. 展开更多
关键词 janus WSSe 几何结构 电子结构 光学性质
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Janus hydrogel/electrospun-membrane dressing enhancing wound healing in rats
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作者 Zi-Rui Zhu Jia-Na Huang +3 位作者 Jin-Ze Li Hao Cao Zhao-Yi Lin Yan Li 《Biomedical Engineering Communications》 2024年第2期17-25,共9页
Background:Excessive exudate secreted from chronic wounds often leads to overhydration and infection.Although a variety of dressings are currently available in clinical applications,they frequently fail to provide mul... Background:Excessive exudate secreted from chronic wounds often leads to overhydration and infection.Although a variety of dressings are currently available in clinical applications,they frequently fail to provide multifunction to promote chronic wound healing.The dressings with a Janus structure,featuring distinct properties on each side,are potential to improve wound healing.Methods:Composite dressings with a Janus structure were fabricated,comprising freeze-dried polycaprolactone(PCL)electrospun membrane and alginate-based hydrogel.The PCL fibrous membrane provided air permeability,while the hydrogel loaded with Deferoxamine,composed of alginate and poly(N-isopropylacrylamide)(PNIPAM),exhibited hygroscopic properties.The inclusion of PNIPAM imparted thermo-responsivity.Results:The hydrogel(thickness of 2.778±0.082 mm)exhibited a robust adhesion to the fiber membrane(thickness of 0.261±0.041 mm).For ANDC(Alginate-PNIPAM hydrogel with Deferoxamine/PCL membrane)samples,the water vapor transmission rate(WVTR)was measured to be 3364.80±23.23 g∙m−2∙day−1 and the swelling ratio at 2 h was determined to be 1179±125%.The thermo-responsivity of ANDC samples manifested in an increased swelling rate,escalating from 797±189%at 37°C to 1132±147%at 4°C.The elastic modulus was assessed for lyophilized and rehydrated ANDC sample.When theωof the rheometer rotor was decreased from 10 rad/s to 0.1 rad/s,the lyophilized dressing exhibited a decrease from 2.65±0.01 MPa to 1.80±0.90 MPa,while the rehydrated dressing demonstrated an increase from 133.65±55.68 Pa to 264.23±141.71 Pa.The pro-healing properties of the dressings were evaluated using full-thickness skin defect model on SD rats,and a circular wound of diameter 10 mm healed completely by day 12.Conclusion:The dressings not only protected the wound and absorbed excess exudate,but also demonstrated nondestructive peelability upon cooling,providing a novel approach for accelerating wound healing and management. 展开更多
关键词 janus structure composite dressing wound healing
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Structured mirror array for two-dimensional collimation of a chromium beam in atom lithography 被引量:2
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作者 张万经 马艳 +4 位作者 李同保 张萍萍 邓晓 陈晟 肖盛炜 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第2期228-231,共4页
Direct-write atom lithography,one of the potential nanofabrication techniques,is restricted by some difficulties in producing optical masks for the deposition of complex structures.In order to make further progress,a ... Direct-write atom lithography,one of the potential nanofabrication techniques,is restricted by some difficulties in producing optical masks for the deposition of complex structures.In order to make further progress,a structured mirror array is developed to transversely collimate the chromium atomic beam in two dimensions.The best collimation is obtained when the laser red detunes by natural line-width of transition 7S3 → 7P40 of the chromium atom.The collimation ratio is 0.45 vertically(in x axis),and it is 0.55 horizontally(in y axis).The theoretical model is also simulated,and success of our structured mirror array is achieved. 展开更多
关键词 atom lithography structured mirror array laser Doppler cooling two-dimensional collimation
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Encryption/decryption and microtarget capturing by pH-driven Janus microstructures fabricated by the same femtosecond laser printing parameters 被引量:4
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作者 Zhaoxin Lao Rui Sun +6 位作者 Dongdong Jin Zhongguo Ren Chen Xin Yachao Zhang Shaojun Jiang Yiyuan Zhang Li Zhang 《International Journal of Extreme Manufacturing》 EI 2021年第2期89-97,共9页
Several natural organism can change shape under external stimuli. These natural phenomena have inspired a vast amount of research on exploration and implementation of reconfigurable shape transformation. The Janus str... Several natural organism can change shape under external stimuli. These natural phenomena have inspired a vast amount of research on exploration and implementation of reconfigurable shape transformation. The Janus structure is a promising approach to achieve shape transformation based on its heterogeneous chemical or physical properties on opposite sides.However, the heterogeneity is generally realized by multi-step processing, different materials,and/or different processing parameters. Here, we present a simple and flexible method of producing p H-sensitive Janus microactuators from a single material, using the same laser printing parameters. These microactuators exhibit reversible structural deformations with large bending angles of ~31°and fast response(~0.2 s) by changing the p H value of the aqueous environment. Benefited from the high flexibility of the laser printing technique and the spatial arrangements, pillar heights, and bending directions of microactuators are readily controlled,enabling a variety of switchable ordered patterns and complex petal-like structures on flat surfaces and inside microchannels. Finally, we explore the potential applications of this method in information encryption/decryption and microtarget capturing. 展开更多
关键词 micro actuator smart material pH hydrogel janus structure laser printing
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Band gaps structure and semi-Dirac point of two-dimensional function photonic crystals 被引量:1
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作者 张斯淇 陆景彬 +6 位作者 梁禺 马季 李宏 李雪 刘晓静 吴向尧 孟祥东 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第2期242-249,共8页
Two-dimensional function photonic crystals, in which the dielectric constants of medium columns are the functions of space coordinates , are proposed and studied numerically. The band gaps structures of the photonic c... Two-dimensional function photonic crystals, in which the dielectric constants of medium columns are the functions of space coordinates , are proposed and studied numerically. The band gaps structures of the photonic crystals for TE and TM waves are different from the two-dimensional conventional photonic crystals. Some absolute band gaps and semiDirac points are found. When the medium column radius and the function form of the dielectric constant are modulated, the numbers, width, and position of band gaps are changed, and the semi-Dirac point can either occur or disappear. Therefore,the special band gaps structures and semi-Dirac points can be achieved through the modulation on the two-dimensional function photonic crystals. The results will provide a new design method of optical devices based on the two-dimensional function photonic crystals. 展开更多
关键词 two-dimensional photonic crystals function dielectric constants band gaps structures
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TWO-DIMENSIONAL ALGEBRAIC SOLITARY WAVE AND ITS VERTICAL STRUCTURE IN STRATIFIED FLUID
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作者 苏晓冰 魏岗 戴世强 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2005年第10期1255-1265,共11页
The algebraic solitary wave and its associated eigenvalue problem in a deep stratified fluid with a free surface and a shallow upper layer were studied. And its vertical structure was examined. An exact solution for t... The algebraic solitary wave and its associated eigenvalue problem in a deep stratified fluid with a free surface and a shallow upper layer were studied. And its vertical structure was examined. An exact solution for the derived 2D Benjamin-Ono equation was obtained, and physical explanation was given with the corresponding dispersion relation. As a special case, the vertical structure of the weakly nonlinear internal wave for the Holmboe density distribution was numerically investigated, and the propagating mechanism of the internal wave was studied by using the ray theory. 展开更多
关键词 two-dimensional Benjamin-Ono equation stratified fluid EIGENVALUE vertical structure
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Crystal Structure And Magnetic Property of the Complex of Hydrogen-bonded Two-dimensional Layer Copper(Ⅱ)Acrylate with Trimethyl Phosphate
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作者 WANG Yaoyu SHI Qian +2 位作者 YANG Bingqin GAO Yici SHI Qizhen 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2000年第2期176-178,共3页
关键词 Copper(Ⅱ) acrylate Trimethyl phosphate two-dimensional layer Crystal structure Magnetic property
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过渡金属原子X(X=Mn、Fe、Co)掺杂单层Janus WSSe的第一性原理研究 被引量:1
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作者 安梦雅 谢泉 +4 位作者 钱国林 梁前 陈蓉 张和森 王远帆 《无机化学学报》 SCIE CAS CSCD 北大核心 2023年第2期272-280,共9页
二维Janus WSSe作为一种新兴的过渡金属硫族化合物(TMDs)材料,由于其打破了面外镜像对称性,且具有内在垂直压电和强Rashba自旋轨道耦合效应等丰富的物理特性,在自旋电子器件中具有巨大的应用潜力。本文基于密度泛函理论的第一性原理平... 二维Janus WSSe作为一种新兴的过渡金属硫族化合物(TMDs)材料,由于其打破了面外镜像对称性,且具有内在垂直压电和强Rashba自旋轨道耦合效应等丰富的物理特性,在自旋电子器件中具有巨大的应用潜力。本文基于密度泛函理论的第一性原理平面波赝势方法计算了过渡金属原子X(X=Mn、Fe、Co)掺杂单层Janus WSSe的电子结构、磁性和光学性质。结果表明:在Chalcogen-rich(硫族元素为多数元素)条件下的掺杂比在W-rich(钨元素为多数元素)条件下的掺杂展现出更高的稳定性,且掺杂后所有体系均表现出磁性。值得一提的是,对该体系进行Mn掺杂后,自旋向上通道出现杂质能级,WSSe由原来的非磁性半导体转变成磁矩为1.043μ_(B)的铁磁性半金属。而Fe、Co的掺杂使得自旋向上通道和自旋向下通道均出现杂质能级,呈现出磁矩分别为1.584μ_(B)、2.739μ_(B)的金属性。此外,掺杂体系的静态介电常数都显著增加,极化程度增强,且介电函数虚部和光吸收峰都发生了红移,说明掺杂有利于对可见光的吸收。 展开更多
关键词 第一性原理 janus WSSe 电子结构 磁性 光学性质
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Janus二维双层MoSSe/WSSe异质结光电性质的第一性原理研究
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作者 周春起 张会 礼楷雨 《人工晶体学报》 CAS 北大核心 2023年第9期1668-1673,共6页
通过第一性原理计算研究了四种二维双层MoSSe/WSSe范德瓦耳斯异质结的光电性质。声子谱表明四种结构具有可靠的热力学稳定性。根据堆垛方式的不同,双层MoSSe/WSSe异质结可以是间接或直接半导体。而且,两种Janus型MoSSe/WSSe异质结具有1... 通过第一性原理计算研究了四种二维双层MoSSe/WSSe范德瓦耳斯异质结的光电性质。声子谱表明四种结构具有可靠的热力学稳定性。根据堆垛方式的不同,双层MoSSe/WSSe异质结可以是间接或直接半导体。而且,两种Janus型MoSSe/WSSe异质结具有1.22和1.88 eV的适中带隙、显著的可见光吸收系数、跨越了水氧化还原电位的带边位置。因此,Janus型的MoSSe/WSSe异质结构在光催化水分解领域具有一定的应用前景。 展开更多
关键词 第一性原理计算 janus二维异质结 光催化水分解 声子色散谱 电子结构 光吸收
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High-temperature ferromagnetism and strongπ-conjugation feature in two-dimensional manganese tetranitride
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作者 闫明 谢志远 高淼 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第3期436-440,共5页
Two-dimensional(2D)magnetic materials have attracted tremendous research interest because of the promising application in the next-generation microelectronic devices.Here,by the first-principles calculations,we propos... Two-dimensional(2D)magnetic materials have attracted tremendous research interest because of the promising application in the next-generation microelectronic devices.Here,by the first-principles calculations,we propose a twodimensional ferromagnetic material with high Curie temperature,manganese tetranitride MnN4monolayer,which is a square-planar lattice made up of only one layer of atoms.The structure is demonstrated to be stable by the phonon spectra and the molecular dynamic simulations,and the stability is ascribed to theπ–d conjugation betweenπorbital of N=N bond and d orbital of Mn.More interestingly,the MnN_(4)monolayer displays robust 2D ferromagnetism,which originates from the strong exchange couplings between Mn atoms due to theπ–d conjugation.The high critical temperature of 247 K is determined by solving the Heisenberg model using the Monte Carlo method. 展开更多
关键词 electronic structure first-priciples calculations two-dimensional materials FERROMAGNETISM
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Two-dimensional horizontal visibility graph analysis of human brain aging on gray matter
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作者 倪黄晶 杜若瑜 +3 位作者 梁磊 花玲玲 朱丽华 秦姣龙 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第7期558-563,共6页
Characterizing the trajectory of the healthy aging brain and exploring age-related structural changes in the brain can help deepen our understanding of the mechanism of brain aging.Currently,most structural magnetic r... Characterizing the trajectory of the healthy aging brain and exploring age-related structural changes in the brain can help deepen our understanding of the mechanism of brain aging.Currently,most structural magnetic resonance imaging literature explores brain aging merely from the perspective of morphological features,which cannot fully utilize the grayscale values containing important intrinsic information about brain structure.In this study,we propose the construction of two-dimensional horizontal visibility graphs based on the pixel intensity values of the gray matter slices directly.Normalized network structure entropy(NNSE)is then introduced to quantify the overall heterogeneities of these graphs.The results demonstrate a decrease in the NNSEs of gray matter with age.Compared with the middle-aged and the elderly,the larger values of the NNSE in the younger group may indicate more homogeneous network structures,smaller differences in importance between nodes and thus a more powerful ability to tolerate intrusion.In addition,the hub nodes of different adult age groups are primarily located in the precuneus,cingulate gyrus,superior temporal gyrus,inferior temporal gyrus,parahippocampal gyrus,insula,precentral gyrus and postcentral gyrus.Our study can provide a new perspective for understanding and exploring the structural mechanism of brain aging. 展开更多
关键词 two-dimensional horizontal visibility graph brain aging structural magnetic resonance imaging network structure entropy
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Electronic modulation of two-dimensional bismuth-based nanosheets for electrocatalytic CO_(2) reduction to formate: A review
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作者 Guan Wang Fangyuan Wang +5 位作者 Peilin Deng Jing Li Chongtai Wang Yingjie Hua Yijun Shen Xinlong Tian 《Materials Reports(Energy)》 2023年第1期51-64,I0002,共15页
Electrocatalytic CO_(2) reduction reaction(eCO_(2) RR)has significant relevance to settle the global energy crisis and abnormal climate problem via mitigating the excess emission of waste CO_(2) and producing high-val... Electrocatalytic CO_(2) reduction reaction(eCO_(2) RR)has significant relevance to settle the global energy crisis and abnormal climate problem via mitigating the excess emission of waste CO_(2) and producing high-value-added chemicals.Currently,eCO_(2) RR to formic acid or formate is one of the most technologically and economically viable approaches to realize high-efficiency CO_(2) utilization,and the development of efficient electrocatalysts is very urgent to achieve efficient and stable catalytic performance.In this review,the recent advances for two-dimensional bismuth-based nanosheets(2D Bi-based NSs)electrocatalysts are concluded from both theoretical and experimental perspectives.Firstly,the preparation strategies of 2D Bi-based NSs in aspects to precisely control the thickness and uniformity are summarized.In addition,the electronic regulation strategies of 2D Bi-based NSs are highlighted to gain insight into the effects of the structure-property relationship on facilitating CO_(2) activation,improving product selectivity,and optimizing carrier transport dynamics.Finally,the considerable challenges and opportunities of 2D Bi-based NSs are discussed to lighten new directions for future research of eCO_(2) RR. 展开更多
关键词 CO_(2) electroreduction two-dimensional structure Bismuth-based catalysts Preparation strategy Electronic structure regulation FORMATE
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The Synthesis and Structural Characterization of Two-dimensional Coordination Polymer {[Ni(phen)H_2O](μ_4-C_( 10)H_2O_8)_(1/2)}_n 被引量:1
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作者 YE Ling PAN Cheng-ling +3 位作者 CHU De-qing WANG Li-min MU Zhong-cheng XU Ji-qing 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2002年第4期474-477,共4页
关键词 two-dimension Hydrothermal synthesis Inorganic-organic hybrid material Crystal structure
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Two-Dimensional Riemann Problems:Transonic Shock Waves and Free Boundary Problems
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作者 Gui-Qiang G.Chen 《Communications on Applied Mathematics and Computation》 2023年第3期1015-1052,共38页
We are concerned with global solutions of multidimensional(M-D)Riemann problems for nonlinear hyperbolic systems of conservation laws,focusing on their global configurations and structures.We present some recent devel... We are concerned with global solutions of multidimensional(M-D)Riemann problems for nonlinear hyperbolic systems of conservation laws,focusing on their global configurations and structures.We present some recent developments in the rigorous analysis of two-dimensional(2-D)Riemann problems involving transonic shock waves through several prototypes of hyperbolic systems of conservation laws and discuss some further M-D Riemann problems and related problems for nonlinear partial differential equations.In particular,we present four different 2-D Riemann problems through these prototypes of hyperbolic systems and show how these Riemann problems can be reformulated/solved as free boundary problems with transonic shock waves as free boundaries for the corresponding nonlinear conservation laws of mixed elliptic-hyperbolic type and related nonlinear partial differential equations. 展开更多
关键词 Riemann problems two-dimensional(2-D) Transonic shocks Solution structure Free boundary problems Mixed elliptic-hyperbolic type Global configurations Large-time asymptotics Global attractors Multidimensional(M-D) Shock capturing methods
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离子分离用电荷Janus结构单价选择性阳离子交换膜
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作者 王文广 张艳秋 +3 位作者 杨晓彬 孙海翔 吴亚东 邵路 《Engineering》 SCIE EI CAS CSCD 2023年第6期204-213,M0008,共11页
单价选择性阳离子交换膜(M-CEMs)已被广泛应用于环境修复和能量收集等领域,例如,从卤水和海水中提取Na^(+)或Li^(+)。然而,由于膜结构和材料的限制,M-CEMs存在渗透选择性低的问题。在此,我们提出了一种简单的方法以构建具有电荷Janus结... 单价选择性阳离子交换膜(M-CEMs)已被广泛应用于环境修复和能量收集等领域,例如,从卤水和海水中提取Na^(+)或Li^(+)。然而,由于膜结构和材料的限制,M-CEMs存在渗透选择性低的问题。在此,我们提出了一种简单的方法以构建具有电荷Janus结构的新型M-CEMs,该结构由荷正电的均苯三甲酸/聚乙烯亚胺选择层和荷负电的商业阳离子交换膜(CEM)组成。选择性电渗析(SED)分析结果表明,具有电荷Janus结构的M-CEMs可以有效抑制多孔阳离子交换膜中存在的阴离子迁移问题,因而使这种具有电荷Janus结构的M-CEMs具有较高的渗透选择性和总阳离子通量。与最先进的单价选择性阳离子交换膜的分离性能相比,具有电荷Janus结构的M-CEMs对于Na^(+)/Mg^(2+)的最高渗透选择性可以达到145.77,这超过了目前单价选择性阳离子交换膜性能的“上限”,且对于Li^(+)/Mg^(2+)也具有优异的渗透选择性(14.11),在离子分离领域具有巨大的应用潜力。这项研究可以为具有电荷Janus结构的M-CEMs的设计提供新的见解,并应用于不同的环境和能源领域。 展开更多
关键词 阳离子交换膜 渗透选择性 聚乙烯亚胺 荷负电 能量收集 环境修复 均苯三甲酸 迁移问题
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二维Janus单层Mg_(2)P_(2)S_(3)Se_(3)的热电性能
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作者 冯翥妤 《科学技术创新》 2023年第1期5-8,共4页
Janus结构在热电材料中具有实际的应用价值,近年来其成功制备引起了广泛的关注。从理论上研究了二维(2D)Janus Mg_(2)P_(2)S_(3)Se_(3)单层的热电性能。Janus Mg_(2)P_(2)S_(3)Se_(3)单层是直接带隙半导体,带隙为2.01 eV。在300 K下,电... Janus结构在热电材料中具有实际的应用价值,近年来其成功制备引起了广泛的关注。从理论上研究了二维(2D)Janus Mg_(2)P_(2)S_(3)Se_(3)单层的热电性能。Janus Mg_(2)P_(2)S_(3)Se_(3)单层是直接带隙半导体,带隙为2.01 eV。在300 K下,电子和空穴载流子迁移率分别为1379.66和300.14 cm^(2)V^(-1)s^(-1)。在室温下晶格热导率κ_(1)为8.31 Wm^(-1)K^(-1)。此外,在恰当掺杂载流子浓度下,800 K时Janus Mg_(2)P_(2)S_(3)Se_(3)的n型和p型最大热电优值zT分别为2.24和0.91。计算结果表明,Janus Mg_(2)P_(2)S_(3)Se_(3)单层是一种潜在的n型候补热电材料。 展开更多
关键词 二维 janus结构 电子结构 热电材料
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