The diversity of interface morphologies is observed for directionally solidified Sn-0.65%Cd alloy under a travelling magnetic field (TMF) in the 4 mm-diameter sample. Under an upward TMF, planar and cellular interfa...The diversity of interface morphologies is observed for directionally solidified Sn-0.65%Cd alloy under a travelling magnetic field (TMF) in the 4 mm-diameter sample. Under an upward TMF, planar and cellular interface morphologies transform alternately with increasing magnetic flux density (B≤10.3 mT). The interface morphology transforms from shallow cellular to deep cellular morphology under a weak downward TMF (B=3.2 mT). When the magnetic flux density increases further, both sides of the interface morphology appear to be slightly inconsistent, but they roughly tend to be planar under a strong downward TMF (BS10.3 mT). The interface instability may be attributed to the flow driven by the TMF. Moreover, the shape of interface appears to be almost flat under an upward TMF, but deflective under a downward TMF.展开更多
Interface morphology has important influence on the bond quality of titanium clad steel plates. The mechanical properties of titanium clad steel plates with wavy and straight interfaces were investigated by tensile-sh...Interface morphology has important influence on the bond quality of titanium clad steel plates. The mechanical properties of titanium clad steel plates with wavy and straight interfaces were investigated by tensile-shear tests and bending tests. The interface morphology of the plates was examined by optical microscopy (OM) and scanning electron microscopy (SEM). The experimental results show that the shear strength of a wavy interface is higher than that of a straight interface. A wavy interface is the guarantee for obtaining high shear strength to provide a greater shear resistance. During the maerobending process, cracks appear in the swirl of the wave tip and ferrotitanium intermetallies. For in-situ observing the bending process by SEM, the wave tip of a wavy interface and the massive ferrotitartium intermetallies of a straight interface are places where cracks initiate and propagate. The results are the same as those observed in the macrobending process. Became of high hardness, the wave tip and the massive ferrotitanium intermetallies are hard in terms of compatible deformation.展开更多
Based on theoretical analyses, the effect of electric current density on stability of solidification interface morphology of QAl 4 alloy was studied experimentally. The results show that the experimental results agree...Based on theoretical analyses, the effect of electric current density on stability of solidification interface morphology of QAl 4 alloy was studied experimentally. The results show that the experimental results agree well with the theoretical analyses, and the following conclusions can be drawn: the increase of electric current density improves the stability of the solidification interface morphology under the condition of no convection of the liquid metal. Otherwise this convection will slow down the trend of solidification interface developing to stability caused by increasing electric current density.展开更多
Because the bonding interface of dissimilar metal joint between AZ31 B Mg alloy and DP600 galvanized steel by keyholeless friction stir spot welding(KFSSW)is permanent bonding,the interface morphology cannot be direct...Because the bonding interface of dissimilar metal joint between AZ31 B Mg alloy and DP600 galvanized steel by keyholeless friction stir spot welding(KFSSW)is permanent bonding,the interface morphology cannot be directly observed.If the joint is separated by external force,the original features of bonding interface of joint will be destroyed,which has influence on the accuracy for observation and analysis of the result.In this paper,the coordinates of the key point at the interface of every cross-section at intervals of 0.2 mm were measured and connected into an outline.The outline of all interfaces makes up the three-dimensional morphologies of bonding interface between AZ31 B Mg alloy and DP600 steel by KFSSW,which was constructed by Solidworks software to restore the real mechanical bonding state of joint.Combined with the microhardness analysis of cross-section and results of in-situ tensile test,the unique bonding state and morphology of Mg and steel in the welded joint were confirmed.展开更多
The effect of TGO ( thermally grown oxide ) growth based on typical interface morphology on residual stresses distribution in thermal barrier coatings was analyzed by ABAQUS software. TGO oxidation kinetics, the rel...The effect of TGO ( thermally grown oxide ) growth based on typical interface morphology on residual stresses distribution in thermal barrier coatings was analyzed by ABAQUS software. TGO oxidation kinetics, the relationship between TGO thickness and thermal cycles number, and typical morphology including sinusoid , cone and groove were considered in the calculation process. 13 FEM (finite element method) models with different TGO thickness based on uniform interface morphology were established for analysis. The calculation results show that TCC ( top ceramic coating ) /TGO and TGO/BC (bond coating) interface residual stresses are affected significantly by inter)hce morphology and TGO thickness, both of which increase significantly with TGO growth ; the stress level in TCC/TGO interface is greater than that of TGO/BC interface ; each morphology peak exhibits tensile stress while each valley exhibits compressive stress in TCC/TGO interface; stress concentrates in such locations as each morphology center with sharp angle and the stress reaches the maximal value at the tip of each angle.展开更多
Motivated by inconveniences of present hybrid methods,a gradient-augmented hybrid interface capturing method(GAHM) is presented for incompressible two-phase flow.A front tracking method(FTM) is used as the skeleto...Motivated by inconveniences of present hybrid methods,a gradient-augmented hybrid interface capturing method(GAHM) is presented for incompressible two-phase flow.A front tracking method(FTM) is used as the skeleton of the GAHM for low mass loss and resources.Smooth eulerian level set values are calculated from the FTM interface,and are used for a local interface reconstruction.The reconstruction avoids marker particle redistribution and enables an automatic treatment of interfacial topology change.The cubic Hermit interpolation is employed in all steps of the GAHM to capture subgrid structures within a single spacial cell.The performance of the GAHM is carefully evaluated in a benchmark test.Results show significant improvements of mass loss,clear subgrid structures,highly accurate derivatives(normals and curvatures) and low cost.The GAHM is further coupled with an incompressible multiphase flow solver,Super CE/SE,for more complex and practical applications.The updated solver is evaluated through comparison with an early droplet research.展开更多
The austenite medium Mn steel modified with controlled additions of Ca, Y, Si were directionally solidified using the vertical Bridgman method to study the effects of Ca(Y)-Si modifier on the solid-liquid (S-L) in...The austenite medium Mn steel modified with controlled additions of Ca, Y, Si were directionally solidified using the vertical Bridgman method to study the effects of Ca(Y)-Si modifier on the solid-liquid (S-L) interface morphology and solute segregation. The interface morphology and the C and Mn segregation of the steel directionally solidified at 6.9 μtrn/s were investigated with an image analysis and a scanning electron microscope equipped with energy dispersive X-ray analysis. The 0.5wt% Ca-Si modified steel is solidified with a planar S-L interface. The interface of the 1.0wt% Ca-Si modified steel is similar to that of the 0.5wt% Ca-Si modified steel, but with larger nodes. The 1.5wt% Ca-Si modified steel displays a cellular growth parttern. The S-L interface morphology of the 0.5wt% Ca-Si+1.0wt% Y-Si modified Mn steel appears as dendritic interface, and primary austenite dendrites reveal developed lateral branching at the quenched liquid. In the meantime, the independent austenite colonies are formed ahead of the S-L interface. A mechanism involving constitutional supercooling explains the S-L interface evolution. It depends mainly on the difference in the contents of Ca, Y, and Si ahead of the S-L interface. The segregation of C and Mn ahead of the S-L interface enhanced by the modifiers is observed.展开更多
The solid-liquid interracial morphology evolution was investigated in directional solidification (DS) of Al-1.5%Cu alloy (mass fraction). The results show that the solidified microstructural evolution is gradual o...The solid-liquid interracial morphology evolution was investigated in directional solidification (DS) of Al-1.5%Cu alloy (mass fraction). The results show that the solidified microstructural evolution is gradual other than sharp, and the microstructure patterns are interesting and diversiform at the pulling rate ranging from 30 μm/s to 1500 μm/s. Indeed, dendrite to cell transition follows this sequence: dendrites→→banded cellular dendrites→elongated cells and part of dendrites→main elongated cells and little dendrites. Moreover, the present microstructure is not normal microstructure as we saw before. Further, according to the experimental phenomenon, the dendrite to cell transition was studied theoretically. Dendrite tip shape is an important parameter to characterize the dendrite to cell transition. As the dendrite to cell transition is far from equilibrium solidification, non-equilibrium solidification is taken into consideration in calculation. Finally, it is speculated that the dendrite to cell transition would occur at the minimum tip radius.展开更多
The interface morphologies and microstruetures of the directionally solidified Ni-5wt-% Cu alloy during dendrite-to-cell transition at high growth rates have been investigated with a newly developed apparatus for unid...The interface morphologies and microstruetures of the directionally solidified Ni-5wt-% Cu alloy during dendrite-to-cell transition at high growth rates have been investigated with a newly developed apparatus for unidirectional solidification with the temperature gradient at the solid/liquid interface higher than 1000 K/cm.The results show that in the vicinity of dendrite-to-cell transition point,the well developed sidebranches become shrivelled with the increase of growth rate and disappear at the dendrite-to-cell transition,and the primary spacing decreases simultaneously.Moreover,the length of mushy zone decreases greatly dur- ing the dendrite-to-cell transition.Cells obtained at high growth rates have very similar morphologies to those at low growth rates,but with much smaller cell spacings and unsmoothed cell walls which may be attributed to the different stability conditions of the cell walls at low and high growth rates respectively.展开更多
The solid-liquid interface morphology and solute segregation behaviour of AI-Li alloy 8090 during unidirectional solidification were studied by the liquid metal quenehing method under varied processing conditions.When...The solid-liquid interface morphology and solute segregation behaviour of AI-Li alloy 8090 during unidirectional solidification were studied by the liquid metal quenehing method under varied processing conditions.When solidification rate,R<O.13 or>O.75 mm/min (temper- ature gradient,G_L=130℃/cm),the structure revealed of planar or dendritic interface respectively.With the increase of R,the interface morphology becomes cellular from planar gradually,within a narrow range.And the greater the R,the,finer the dendrite.Segregation of element Cu and impurity elements Fe and Si are quite severe,the interface morphology markedly influences on solute segregation.During solidification at coarse dendrite interface, their segregation ratios are rather great and solidified structure is coarse.展开更多
Interfaces play critical roles in electronic devices and provide great diversity of film morphology and device performance.We retrospect the substrate mediated vacuum film growth of benchmark high mobility material 2,...Interfaces play critical roles in electronic devices and provide great diversity of film morphology and device performance.We retrospect the substrate mediated vacuum film growth of benchmark high mobility material 2,7-dioctyl[1]benzothieno[3,2-b]benzothiophene(C8-BTBT)and the interface electronic structures.The film growth of C8-BTBT molecules is diversified depending on the substrate-molecule and molecule-molecule interactions.On atomic smooth substrates C8-BTBT film grows in layer-by-layer mode while on coarse substrate it grows in islands mode.The initial molecular layer at dielectric,semiconductor and conductive substrates displays slight different lattice structure.The initial molecule orientation depends on the substrate and will gradually change to standing up configuration as in bulk phase.C8-BTBT behaves as electron donor when contacting with dielectric and stable conductive materials.This usually induces a dipole layer pointing to C8-BTBT and an upward bend bending in C8-BTBT side toward the interface.Although it is air stable,C8-BTBT is chemically reactive with some transition metals and compounds.The orientation change from lying down to standing up in the film usually leads to decrease of ionization potential.The article provides insights to the interface physical and chemical processes and suggestions for optimal design and fabrication of C8-BTBT based devices.展开更多
The exposure of Al-5Cu alloy to an external stress with normal aging was carried out. The effects of external stress-aging on the morphology and precipitation behavior of θ" phase were investigated by transmission e...The exposure of Al-5Cu alloy to an external stress with normal aging was carried out. The effects of external stress-aging on the morphology and precipitation behavior of θ" phase were investigated by transmission electron microscopy (TEM), differential scanning calorimetry (DSC) and first principle calculation. The size of the θ" phase precipitated plates in stress-aging (453 K, 6 h, 50 MPa) is 19.83 nm, which is smaller than that of those present (28.79 nm) in stress-flee aging (453 K, 6 h). The precipitation process of θ" phase is accelerated by loading external stress aging according to the analysis of DSC results. The apparent activation energy for the external stress-aging is 10% lower than the stress-free one. The first principle calculation results show that the external stress makes a decrease of 6% in the interface energy. The effects of the stress on aging process of the alloy are discussed on the basis of the classical theory. The external stress changes the morphology and precipitation behavior of θ" phase because the critical nucleation energy is decreased by 19% under stress aging.展开更多
Organic photovoltaic devices are on the verge of commercialization with power conversion efficiencies exceeding 10 % in laboratory cells and above 8.5 % in modules. However, one of the main limitations hindering their...Organic photovoltaic devices are on the verge of commercialization with power conversion efficiencies exceeding 10 % in laboratory cells and above 8.5 % in modules. However, one of the main limitations hindering their mass scale production is the debatable inferior stability of organic photovoltaic devices in comparison to other technologies.Adequate donor/acceptor morphology of the active layer is required to provide carrier separation and transport to the electrodes. Unfortunately, the beneficial morphology for device performance is usually a kinetically frozen state which has not reached thermodynamic equilibrium. During the last 5 years, special efforts have been dedicated to isolate the effects related to morphology changes taking place within the active layer and compare to those affecting the interfaces with the external electrodes. The current review discusses some of the factors affecting the donor/acceptor morphology evolution as one of the major intrinsic degradation pathways. Special attention is paid to factors in the nano- and microscale domain.For example, phase segregation of the polymer and fullerene domains due to Ostwald ripening is a major factor in the microscale domain and is affected by the presence of additives, glass transition temperature of the polymers or use of crosslinkers in the active layer. Alternatively, the role of vertical segregation profile toward the external electrodes is key for device operation, being a clear case of nanoscale morphology evolution. For example, donor and acceptor molecules actually present at the external interfaces will determine the leakage current of the device, energy-level alignment, and interfacial recombination processes. Different techniques have been developed over the last few years to understand its relationship with the device efficiency. Of special interest are those techniques which enable in situ analysis being nondestructive as they can be used to study accelerated degradation experiments and some will be discussed here.展开更多
In this study,interface shapes of horizontal oil–water two-phase flow are predicted by using Young-Laplace equation model and minimum energy model.Meanwhile,the interface shapes of horizontal oil–water twophase flow...In this study,interface shapes of horizontal oil–water two-phase flow are predicted by using Young-Laplace equation model and minimum energy model.Meanwhile,the interface shapes of horizontal oil–water twophase flow in a 20 mm inner diameter pipe are measured by a novel conductance parallel-wire array probe(CPAP).It is found that,for flow conditions with low water holdup,there is a large deviation between the model-predicted interface shape and the experimentally measured one.Since the variation of pipe wetting characteristics in the process of fluid flow can lead to the changes of the contact angle between the fluid and the pipe wall,the models mentioned above are modified by considering dynamic contact angle.The results indicate that the interface shapes predicted by the modified models present a good consistence with the ones measured by CPAP.展开更多
The wavy interface for similar or the same metal explosive welding(EXW) and the universal mechanism of wavy interface formation in EXW were studied in this work. Based on a new established model, it was deduced that...The wavy interface for similar or the same metal explosive welding(EXW) and the universal mechanism of wavy interface formation in EXW were studied in this work. Based on a new established model, it was deduced that the evolution frequencies of the instability were constrained in a limited range. Then experiments of identical metal EXW were performed and welding interfaces were characterized for examining the final morphology. By calculating the fractal dimensions and multifractal spectra of welding interface, the fractal characteristics of interface were revealed and a quantitative description was achieved for EXW interface structure. Thus, the formation, evolution and final morphology of wavy interface were systemically researched.展开更多
The effect of far-field uniform flow on the morphological evolution of a spherical particle in a supersaturated solution affected by a far-field uniform flow is studied by using the matched asymptotic expansion method...The effect of far-field uniform flow on the morphological evolution of a spherical particle in a supersaturated solution affected by a far-field uniform flow is studied by using the matched asymptotic expansion method. The analytical solution for the interface shape, concentration field, and interface velocity of the particle growth shows that the convection induced by the far-field uniform flow facilitates the growth of the spherical particle, the upstream flow imposed on the particle enhances the growth velocity of the interface when the flow comes in, the downstream flow lowers the growth velocity of the surface when the flow goes out, and the interface morphology evolves into a peach-like shape.展开更多
An identification technique for sharp interface and penetrated isolated particles is developed for simulating two-dimensional,incompressible and immiscible two-phase flows using meshless particle methods in this paper...An identification technique for sharp interface and penetrated isolated particles is developed for simulating two-dimensional,incompressible and immiscible two-phase flows using meshless particle methods in this paper.This technique is based on the numerically computed density gradient of fluid particles and is suitable for capturing large interface deformation and even topological changes such as merging and breaking up of phases.A number of assumed particle configurations will be examined using the technique,including these with different level of randomness of particle distribution.The tests will show that the new technique can correctly identify almost all the interface and isolated particles,and also show that it is better than other existing popular methods tested.展开更多
In this study,a numerical model for simulating two-phase flow is developed.The Cartesian grid with Adaptive Mesh Refinement(AMR)is adopted to reduce the computational cost.An explicit projection method is used for the...In this study,a numerical model for simulating two-phase flow is developed.The Cartesian grid with Adaptive Mesh Refinement(AMR)is adopted to reduce the computational cost.An explicit projection method is used for the time integration and the Finite Difference Method(FDM)is applied on a staggered grid for the discretization of spatial derivatives.The Volume of Fluid(VOF)method with Piecewise-Linear Interface Calculation(PLIC)is extended to the AMR grid to capture the gas-water interface accurately.A coarse-fine interface treatment method is developed to preserve the flux conservation at the interfaces.Several two-dimensional(2D)and three-dimensional(3D)benchmark cases are carried out for the validation of the model.2D and 3D shear flow tests are conducted to validate the extension of the VOF method to the AMR grid.A 2D linear sloshing case is considered in which the model is proved to have 2nd-order accuracy in space.The efficiency of applying the AMR grid is discussed with a nonlinear sloshing problem.Finally,2D solitary wave past stage and 2D/3D dam break are simulated to demonstrate that the model is able to simulate violent interface problems.展开更多
From the macroscopic point of view, expressions involving reservoir and operational parameters are established for investigating the stability of moving interface in piston- and non-piston-like displacements. In the c...From the macroscopic point of view, expressions involving reservoir and operational parameters are established for investigating the stability of moving interface in piston- and non-piston-like displacements. In the case of axisymmetrical piston-like displacement, the stability is related to the moving interface position and water to oil mobility ratio. The capillary effect on the stability of moving interface depends on whether or not the moving interface is already stable and correlates with the wettability of the reservoir rock. In the case of non-piston-like displacement, the stability of the front is governed by both the relative permeability and the mobility ratio.展开更多
基金Project(50774061) supported by the National Natural Science Foundation of ChinaProject(28-TP-2009) supported by the Research Fund of State Key Laboratory of Solidification Processing(NWPU),China
文摘The diversity of interface morphologies is observed for directionally solidified Sn-0.65%Cd alloy under a travelling magnetic field (TMF) in the 4 mm-diameter sample. Under an upward TMF, planar and cellular interface morphologies transform alternately with increasing magnetic flux density (B≤10.3 mT). The interface morphology transforms from shallow cellular to deep cellular morphology under a weak downward TMF (B=3.2 mT). When the magnetic flux density increases further, both sides of the interface morphology appear to be slightly inconsistent, but they roughly tend to be planar under a strong downward TMF (BS10.3 mT). The interface instability may be attributed to the flow driven by the TMF. Moreover, the shape of interface appears to be almost flat under an upward TMF, but deflective under a downward TMF.
文摘Interface morphology has important influence on the bond quality of titanium clad steel plates. The mechanical properties of titanium clad steel plates with wavy and straight interfaces were investigated by tensile-shear tests and bending tests. The interface morphology of the plates was examined by optical microscopy (OM) and scanning electron microscopy (SEM). The experimental results show that the shear strength of a wavy interface is higher than that of a straight interface. A wavy interface is the guarantee for obtaining high shear strength to provide a greater shear resistance. During the maerobending process, cracks appear in the swirl of the wave tip and ferrotitanium intermetallies. For in-situ observing the bending process by SEM, the wave tip of a wavy interface and the massive ferrotitartium intermetallies of a straight interface are places where cracks initiate and propagate. The results are the same as those observed in the macrobending process. Became of high hardness, the wave tip and the massive ferrotitanium intermetallies are hard in terms of compatible deformation.
文摘Based on theoretical analyses, the effect of electric current density on stability of solidification interface morphology of QAl 4 alloy was studied experimentally. The results show that the experimental results agree well with the theoretical analyses, and the following conclusions can be drawn: the increase of electric current density improves the stability of the solidification interface morphology under the condition of no convection of the liquid metal. Otherwise this convection will slow down the trend of solidification interface developing to stability caused by increasing electric current density.
基金supported by Natural Science Foundation of Shandong Province(No.ZR2019PEE042)。
文摘Because the bonding interface of dissimilar metal joint between AZ31 B Mg alloy and DP600 galvanized steel by keyholeless friction stir spot welding(KFSSW)is permanent bonding,the interface morphology cannot be directly observed.If the joint is separated by external force,the original features of bonding interface of joint will be destroyed,which has influence on the accuracy for observation and analysis of the result.In this paper,the coordinates of the key point at the interface of every cross-section at intervals of 0.2 mm were measured and connected into an outline.The outline of all interfaces makes up the three-dimensional morphologies of bonding interface between AZ31 B Mg alloy and DP600 steel by KFSSW,which was constructed by Solidworks software to restore the real mechanical bonding state of joint.Combined with the microhardness analysis of cross-section and results of in-situ tensile test,the unique bonding state and morphology of Mg and steel in the welded joint were confirmed.
基金This work was supported by National Natural Science Foundation of China (No. 60879018).
文摘The effect of TGO ( thermally grown oxide ) growth based on typical interface morphology on residual stresses distribution in thermal barrier coatings was analyzed by ABAQUS software. TGO oxidation kinetics, the relationship between TGO thickness and thermal cycles number, and typical morphology including sinusoid , cone and groove were considered in the calculation process. 13 FEM (finite element method) models with different TGO thickness based on uniform interface morphology were established for analysis. The calculation results show that TCC ( top ceramic coating ) /TGO and TGO/BC (bond coating) interface residual stresses are affected significantly by inter)hce morphology and TGO thickness, both of which increase significantly with TGO growth ; the stress level in TCC/TGO interface is greater than that of TGO/BC interface ; each morphology peak exhibits tensile stress while each valley exhibits compressive stress in TCC/TGO interface; stress concentrates in such locations as each morphology center with sharp angle and the stress reaches the maximal value at the tip of each angle.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.10972010,11028206,11371069,11372052,11402029,and 11472060)the Science and Technology Development Foundation of China Academy of Engineering Physics(CAEP),China(Grant No.2014B0201030)the Defense Industrial Technology Development Program of China(Grant No.B1520132012)
文摘Motivated by inconveniences of present hybrid methods,a gradient-augmented hybrid interface capturing method(GAHM) is presented for incompressible two-phase flow.A front tracking method(FTM) is used as the skeleton of the GAHM for low mass loss and resources.Smooth eulerian level set values are calculated from the FTM interface,and are used for a local interface reconstruction.The reconstruction avoids marker particle redistribution and enables an automatic treatment of interfacial topology change.The cubic Hermit interpolation is employed in all steps of the GAHM to capture subgrid structures within a single spacial cell.The performance of the GAHM is carefully evaluated in a benchmark test.Results show significant improvements of mass loss,clear subgrid structures,highly accurate derivatives(normals and curvatures) and low cost.The GAHM is further coupled with an incompressible multiphase flow solver,Super CE/SE,for more complex and practical applications.The updated solver is evaluated through comparison with an early droplet research.
基金This work is financially supported by the National Natural Science Foundation of China (No.50001008 and No. 50271042).
文摘The austenite medium Mn steel modified with controlled additions of Ca, Y, Si were directionally solidified using the vertical Bridgman method to study the effects of Ca(Y)-Si modifier on the solid-liquid (S-L) interface morphology and solute segregation. The interface morphology and the C and Mn segregation of the steel directionally solidified at 6.9 μtrn/s were investigated with an image analysis and a scanning electron microscope equipped with energy dispersive X-ray analysis. The 0.5wt% Ca-Si modified steel is solidified with a planar S-L interface. The interface of the 1.0wt% Ca-Si modified steel is similar to that of the 0.5wt% Ca-Si modified steel, but with larger nodes. The 1.5wt% Ca-Si modified steel displays a cellular growth parttern. The S-L interface morphology of the 0.5wt% Ca-Si+1.0wt% Y-Si modified Mn steel appears as dendritic interface, and primary austenite dendrites reveal developed lateral branching at the quenched liquid. In the meantime, the independent austenite colonies are formed ahead of the S-L interface. A mechanism involving constitutional supercooling explains the S-L interface evolution. It depends mainly on the difference in the contents of Ca, Y, and Si ahead of the S-L interface. The segregation of C and Mn ahead of the S-L interface enhanced by the modifiers is observed.
基金Project(SKLSP201418)supported by the Fund of the State Key Laboratory of Solidification Processing in North China University of Technology,ChinaProjects(51171151,51331005)supported by the National Natural Science Foundation of China
文摘The solid-liquid interracial morphology evolution was investigated in directional solidification (DS) of Al-1.5%Cu alloy (mass fraction). The results show that the solidified microstructural evolution is gradual other than sharp, and the microstructure patterns are interesting and diversiform at the pulling rate ranging from 30 μm/s to 1500 μm/s. Indeed, dendrite to cell transition follows this sequence: dendrites→→banded cellular dendrites→elongated cells and part of dendrites→main elongated cells and little dendrites. Moreover, the present microstructure is not normal microstructure as we saw before. Further, according to the experimental phenomenon, the dendrite to cell transition was studied theoretically. Dendrite tip shape is an important parameter to characterize the dendrite to cell transition. As the dendrite to cell transition is far from equilibrium solidification, non-equilibrium solidification is taken into consideration in calculation. Finally, it is speculated that the dendrite to cell transition would occur at the minimum tip radius.
文摘The interface morphologies and microstruetures of the directionally solidified Ni-5wt-% Cu alloy during dendrite-to-cell transition at high growth rates have been investigated with a newly developed apparatus for unidirectional solidification with the temperature gradient at the solid/liquid interface higher than 1000 K/cm.The results show that in the vicinity of dendrite-to-cell transition point,the well developed sidebranches become shrivelled with the increase of growth rate and disappear at the dendrite-to-cell transition,and the primary spacing decreases simultaneously.Moreover,the length of mushy zone decreases greatly dur- ing the dendrite-to-cell transition.Cells obtained at high growth rates have very similar morphologies to those at low growth rates,but with much smaller cell spacings and unsmoothed cell walls which may be attributed to the different stability conditions of the cell walls at low and high growth rates respectively.
文摘The solid-liquid interface morphology and solute segregation behaviour of AI-Li alloy 8090 during unidirectional solidification were studied by the liquid metal quenehing method under varied processing conditions.When solidification rate,R<O.13 or>O.75 mm/min (temper- ature gradient,G_L=130℃/cm),the structure revealed of planar or dendritic interface respectively.With the increase of R,the interface morphology becomes cellular from planar gradually,within a narrow range.And the greater the R,the,finer the dendrite.Segregation of element Cu and impurity elements Fe and Si are quite severe,the interface morphology markedly influences on solute segregation.During solidification at coarse dendrite interface, their segregation ratios are rather great and solidified structure is coarse.
基金Project(2017YFA0206602)supported in part by the National Key Research and Development Program of China。
文摘Interfaces play critical roles in electronic devices and provide great diversity of film morphology and device performance.We retrospect the substrate mediated vacuum film growth of benchmark high mobility material 2,7-dioctyl[1]benzothieno[3,2-b]benzothiophene(C8-BTBT)and the interface electronic structures.The film growth of C8-BTBT molecules is diversified depending on the substrate-molecule and molecule-molecule interactions.On atomic smooth substrates C8-BTBT film grows in layer-by-layer mode while on coarse substrate it grows in islands mode.The initial molecular layer at dielectric,semiconductor and conductive substrates displays slight different lattice structure.The initial molecule orientation depends on the substrate and will gradually change to standing up configuration as in bulk phase.C8-BTBT behaves as electron donor when contacting with dielectric and stable conductive materials.This usually induces a dipole layer pointing to C8-BTBT and an upward bend bending in C8-BTBT side toward the interface.Although it is air stable,C8-BTBT is chemically reactive with some transition metals and compounds.The orientation change from lying down to standing up in the film usually leads to decrease of ionization potential.The article provides insights to the interface physical and chemical processes and suggestions for optimal design and fabrication of C8-BTBT based devices.
基金Project(2012CB619506)supported by the National Basic Research Program of ChinaProject(51071177)supported by the National Natural Science Foundation of China
文摘The exposure of Al-5Cu alloy to an external stress with normal aging was carried out. The effects of external stress-aging on the morphology and precipitation behavior of θ" phase were investigated by transmission electron microscopy (TEM), differential scanning calorimetry (DSC) and first principle calculation. The size of the θ" phase precipitated plates in stress-aging (453 K, 6 h, 50 MPa) is 19.83 nm, which is smaller than that of those present (28.79 nm) in stress-flee aging (453 K, 6 h). The precipitation process of θ" phase is accelerated by loading external stress aging according to the analysis of DSC results. The apparent activation energy for the external stress-aging is 10% lower than the stress-free one. The first principle calculation results show that the external stress makes a decrease of 6% in the interface energy. The effects of the stress on aging process of the alloy are discussed on the basis of the classical theory. The external stress changes the morphology and precipitation behavior of θ" phase because the critical nucleation energy is decreased by 19% under stress aging.
基金supported by FP7 European collaborative project SUNFLOWER(FP7-ICT-2011-7contract No.287594)the Spanish Ministerio de Economía y Competitividad(project MAT2013-47192-C3-1-R)+1 种基金Generalitat Valenciana(project ISIC/2012/008 Institute of Nanotechnologies for Clean Energies)the Spanish Ministerio de Economía y Competitividad for a Ramón y Cajal Fellowship(RYC2014-16809)
文摘Organic photovoltaic devices are on the verge of commercialization with power conversion efficiencies exceeding 10 % in laboratory cells and above 8.5 % in modules. However, one of the main limitations hindering their mass scale production is the debatable inferior stability of organic photovoltaic devices in comparison to other technologies.Adequate donor/acceptor morphology of the active layer is required to provide carrier separation and transport to the electrodes. Unfortunately, the beneficial morphology for device performance is usually a kinetically frozen state which has not reached thermodynamic equilibrium. During the last 5 years, special efforts have been dedicated to isolate the effects related to morphology changes taking place within the active layer and compare to those affecting the interfaces with the external electrodes. The current review discusses some of the factors affecting the donor/acceptor morphology evolution as one of the major intrinsic degradation pathways. Special attention is paid to factors in the nano- and microscale domain.For example, phase segregation of the polymer and fullerene domains due to Ostwald ripening is a major factor in the microscale domain and is affected by the presence of additives, glass transition temperature of the polymers or use of crosslinkers in the active layer. Alternatively, the role of vertical segregation profile toward the external electrodes is key for device operation, being a clear case of nanoscale morphology evolution. For example, donor and acceptor molecules actually present at the external interfaces will determine the leakage current of the device, energy-level alignment, and interfacial recombination processes. Different techniques have been developed over the last few years to understand its relationship with the device efficiency. Of special interest are those techniques which enable in situ analysis being nondestructive as they can be used to study accelerated degradation experiments and some will be discussed here.
基金supported by the National Natural Science Foundation of China(Grant Nos.41974139,41504104,11572220,51527805)Natural Science Foundation of Tianjin,China(19JCYBJC18400)。
文摘In this study,interface shapes of horizontal oil–water two-phase flow are predicted by using Young-Laplace equation model and minimum energy model.Meanwhile,the interface shapes of horizontal oil–water twophase flow in a 20 mm inner diameter pipe are measured by a novel conductance parallel-wire array probe(CPAP).It is found that,for flow conditions with low water holdup,there is a large deviation between the model-predicted interface shape and the experimentally measured one.Since the variation of pipe wetting characteristics in the process of fluid flow can lead to the changes of the contact angle between the fluid and the pipe wall,the models mentioned above are modified by considering dynamic contact angle.The results indicate that the interface shapes predicted by the modified models present a good consistence with the ones measured by CPAP.
基金Funded by the National Natural Science Foundation of China(Nos.11202093 and 11662010)
文摘The wavy interface for similar or the same metal explosive welding(EXW) and the universal mechanism of wavy interface formation in EXW were studied in this work. Based on a new established model, it was deduced that the evolution frequencies of the instability were constrained in a limited range. Then experiments of identical metal EXW were performed and welding interfaces were characterized for examining the final morphology. By calculating the fractal dimensions and multifractal spectra of welding interface, the fractal characteristics of interface were revealed and a quantitative description was achieved for EXW interface structure. Thus, the formation, evolution and final morphology of wavy interface were systemically researched.
基金supported by the National Natural Science Foundation of China (Grant No. 10972030)the Fundamental Research Funds for the Central University, China (Grant No. FRF-BR-11-034B)the Overseas Distinguished Scholar Program of the Ministry of Education, China (Grant No. MS2010bjkj005)
文摘The effect of far-field uniform flow on the morphological evolution of a spherical particle in a supersaturated solution affected by a far-field uniform flow is studied by using the matched asymptotic expansion method. The analytical solution for the interface shape, concentration field, and interface velocity of the particle growth shows that the convection induced by the far-field uniform flow facilitates the growth of the spherical particle, the upstream flow imposed on the particle enhances the growth velocity of the interface when the flow comes in, the downstream flow lowers the growth velocity of the surface when the flow goes out, and the interface morphology evolves into a peach-like shape.
文摘An identification technique for sharp interface and penetrated isolated particles is developed for simulating two-dimensional,incompressible and immiscible two-phase flows using meshless particle methods in this paper.This technique is based on the numerically computed density gradient of fluid particles and is suitable for capturing large interface deformation and even topological changes such as merging and breaking up of phases.A number of assumed particle configurations will be examined using the technique,including these with different level of randomness of particle distribution.The tests will show that the new technique can correctly identify almost all the interface and isolated particles,and also show that it is better than other existing popular methods tested.
基金This work was financially supported by the National Natural Science Foundation of China(Nos.51779049,51879058,52071098,51979053).
文摘In this study,a numerical model for simulating two-phase flow is developed.The Cartesian grid with Adaptive Mesh Refinement(AMR)is adopted to reduce the computational cost.An explicit projection method is used for the time integration and the Finite Difference Method(FDM)is applied on a staggered grid for the discretization of spatial derivatives.The Volume of Fluid(VOF)method with Piecewise-Linear Interface Calculation(PLIC)is extended to the AMR grid to capture the gas-water interface accurately.A coarse-fine interface treatment method is developed to preserve the flux conservation at the interfaces.Several two-dimensional(2D)and three-dimensional(3D)benchmark cases are carried out for the validation of the model.2D and 3D shear flow tests are conducted to validate the extension of the VOF method to the AMR grid.A 2D linear sloshing case is considered in which the model is proved to have 2nd-order accuracy in space.The efficiency of applying the AMR grid is discussed with a nonlinear sloshing problem.Finally,2D solitary wave past stage and 2D/3D dam break are simulated to demonstrate that the model is able to simulate violent interface problems.
基金the National Basic Research Program of China (2005CB221300)the Innovative Project of Chinese Academy of Sciences (KJCX-SW-L08)
文摘From the macroscopic point of view, expressions involving reservoir and operational parameters are established for investigating the stability of moving interface in piston- and non-piston-like displacements. In the case of axisymmetrical piston-like displacement, the stability is related to the moving interface position and water to oil mobility ratio. The capillary effect on the stability of moving interface depends on whether or not the moving interface is already stable and correlates with the wettability of the reservoir rock. In the case of non-piston-like displacement, the stability of the front is governed by both the relative permeability and the mobility ratio.