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Liquid–liquid two-phase mass transfer characteristics in a rotating helical microchannel 被引量:4
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作者 Yan Cao Jun Li +2 位作者 Yang Jin Jianhong Luo Yubin Wang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2019年第12期2937-2947,共11页
In this work,the mass transfer characteristics of two immiscible fluids were investigated in a rotating helical microchannel with hydraulic diameter of 932μm.Aqueous phosphoric acid solution and 80%tri-n-butyl phosph... In this work,the mass transfer characteristics of two immiscible fluids were investigated in a rotating helical microchannel with hydraulic diameter of 932μm.Aqueous phosphoric acid solution and 80%tri-n-butyl phosphate(TBP)in kerosene were selected for the investigation of mass transfer performance in quartz glass/high density polyethylene(HDPE)microchannel.High dispersion between the two immiscible fluids can be obtained in the microchannel due to the intensifying action of centrifugal force,and the majority of the droplets with average diameter of 20–100μm were produced in the microchannel.The flow rate and rotation speed were found to have great effects on the extraction efficiency and average residence time.The empirical correlation of average residence time based on experimental data was developed by theoretical analysis and data fitting method,and a mathematical model of the mass transfer coefficient in dispersed phase was proposed. 展开更多
关键词 Microchannels mass transfer Extraction IMMISCIBLE fluids MULTIPHASE flow
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Study on liquid–liquid two-phase mass transfer characteristics in the microchannel with deformed insert
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作者 Qinyan Wang Yang Jin +2 位作者 Jun Li Yongbo Zhou Ming Chen 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第2期114-126,共13页
In this work, the liquid-liquid two-phase mass transfer characteristics in the microchannel with deformed insert were studied. The experiment used di-(2-ethylhexyl) phosphoric acid/kerosene-Cu^(2+)as the mass transfer... In this work, the liquid-liquid two-phase mass transfer characteristics in the microchannel with deformed insert were studied. The experiment used di-(2-ethylhexyl) phosphoric acid/kerosene-Cu^(2+)as the mass transfer evaluation system. The effects of some key factors such as the total flow velocity,channel inner diameter, channel length, insert diameter, extractant concentration on the extraction efficiency and mass transfer coefficient were systematically investigated. Compared with a simple microreactor, the liquid-liquid mass transfer enhancement effect of the insert was quantitatively analyzed. The study found that the regular deformation of the insert could cause fluid interface deformation and promote flow state chaos, effectively increasing the mass transfer rate. And the enhancement effect of the insert was more significant at high flow velocities. The highest mass transfer coefficient in the microchannel with deformed insert was 7.886 s^(-1), the enhancement factor could reach 4.17. And only needed 0.095 s to approach the extraction equilibrium. The deformed center insert exhibited an effective liquid-liquid mass transfer enhancement effect, which can be used as a micro-chemical process enhancement method to be applied in the fields of higher throughput mass transfer and chemical synthesis,and at the same time provide ideas for development and structural optimization of microreactors. 展开更多
关键词 MICROCHANNEL INSERT DEFORMATION Liquid–liquid extraction mass transfer enhancement
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Discharge and mass transfer characteristics of atmospheric pressure gas-solid two-phase gliding arc
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作者 Min ZHU Yuchen PING +2 位作者 Yinghao ZHANG Chaohai ZHANG Shuqun WU 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第9期88-96,共9页
In this work,a gas-solid two-phase gliding arc discharge(GS-GAD)reactor was built.Gliding arc was formed in the gap between the blade electrodes,and solid powder was deposited on the sieve plate positioned beneath the... In this work,a gas-solid two-phase gliding arc discharge(GS-GAD)reactor was built.Gliding arc was formed in the gap between the blade electrodes,and solid powder was deposited on the sieve plate positioned beneath the blade electrodes.A range of experimental parameters,including the inter-electrode spacing,gas flow rate,applied voltage,and the type of the powder,were systematically varied to elucidate the influence of solid powder matter on the dynamics of gliding arc discharge(GAD).The discharge images were captured by ICCD and digital camera to investigate the mass transfer characteristics of GS-GAD,and the electrical parameters,such as the effective values of voltage,current,and discharge power were record to reveal the discharge characteristics of GS-GAD.The results demonstrate that powder undergoes spontaneous movement towards the upper region of the gliding arc due to the influence of electric field force.Increasing the discharge voltage,decreasing relative dielectric constant of the powder and reducing the electrode-to-sieve-plate distance all contribute to a greater involvement of powder in the GAD process,subsequently resulting in an enhanced powder concentration within the GAD region.Additionally,powder located beneath the gliding arc experiences downward resistance caused by the opposing gas flow and arc.Excessive gas flow rate notably hampers the powder concentration within the discharge region,and the velocity of powder motion in the upper part of the GAD region is reduced.Under the condition of electrode-to-sieve-plate distance of 30 mm,gas flow rate of 1.5 L/min,and peak-to-peak voltage of 31 kV,the best combination of arc gliding and powder spark discharge phenomena can be achieved with the addition of Al_(2)O_(3) powder. 展开更多
关键词 gliding arc discharge atmospheric pressure plasma multiphase discharge mass transfer
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Mass transfer intensification and mechanism analysis of gas–liquid two-phase flow in the microchannel embedding triangular obstacles 被引量:3
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作者 Xuanyu Nie Chunying Zhu +1 位作者 Taotao Fu Youguang Ma 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2022年第11期100-108,共9页
An effective mass transfer intensification method was proposed by embedding different triangular obstacles to improve the gas-liquid mass transfer efficiency in microchannel.The influences of triangle obstacles config... An effective mass transfer intensification method was proposed by embedding different triangular obstacles to improve the gas-liquid mass transfer efficiency in microchannel.The influences of triangle obstacles configuration,obstacle interval and flow rate on the volumetric mass transfer coefficient,pressure drop and energy consumption were investigated experimentally.The enhancement factor was used to quantify the mass transfer enhancement effect of triangle obstacles.It was found that the isosceles or equilateral triangle obstacles are superior to the rectangular obstacles.The maximum enhancement factor of equilateral triangle obstacles was 2.35.Considering comprehensively mass transfer enhancement and energy consumption,the isosceles triangle obstacle showed the best performance,its maximum enhancement factor was 2.1,while the maximum pressure drop increased only 0.41 kPa(22%)compared to the microchannel without obstacles.Furthermore,a micro-particle image velocimetry(micro-PIV)was utilized to observe the flow field distribution and evolution,in order to understand and analyze the enhancement mechanism.The micro-PIV measurement indicated that the obstacle structure could induce the formation of vortex,which promotes convective mass transfer and thins the flow boundary layer,accordingly,the gas-liquid mass transfer efficiency is remarkably improved.This study can provide theoretical guidance and support for the design and optimization of microchannel with triangular obstacles. 展开更多
关键词 Enhancement factor Microchannels Gas-liquid flow mass transfer Triangular obstacle
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Measurement of Mass Transfer Coefficients and Their Modelling of Continuous Counter-Current Aqueous Two-Phase System in a Packed Extraction Column 被引量:1
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作者 阎恭喜 朱自强 +1 位作者 关怡新 韩兆熊 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 1999年第3期196-204,共9页
Overall dispersed side volumetric mass transfer coefficients for protein and amino acids were measured in continuous countercurrent PEG4000/KHP aqueous two-phase systems in a 57mm I.D. packed extraction column. A mode... Overall dispersed side volumetric mass transfer coefficients for protein and amino acids were measured in continuous countercurrent PEG4000/KHP aqueous two-phase systems in a 57mm I.D. packed extraction column. A model for overall dispersed side volumetric mass transfer coefficients was derived by describing the motion of the drops based upon Navier-Stokes equation combined with the relationship between mass transfer coefficients and the drop velocity. The model provides good predictions and can be successfully used in aqueous two-phase extraction. The average relative deviation between calculated values and experimental data ranges from 8% to 14%. 展开更多
关键词 aqueous two-phase system continuous countercurrent extraction mass transfer coefficient MODEL packed column
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Liquid-liquid two-phase flow in a wire-embedded concentric microchannel: Flow pattern and mass transfer performance
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作者 Ming Chen Huiyan Jiao +3 位作者 Jun Li Zhibin Wang Feng He Yang Jin 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第4期281-289,共9页
In this work, flow pattern and mass transfer of liquid-liquid two-phase flow in a wire-embedded concentric microchannel are studied using toluene-water system. Droplet flow, slug flow, oval flow and annular flow are o... In this work, flow pattern and mass transfer of liquid-liquid two-phase flow in a wire-embedded concentric microchannel are studied using toluene-water system. Droplet flow, slug flow, oval flow and annular flow are observed in the wire-embedded concentric microchannel. The effects of embedded wires and physical properties on flow patterns are investigated. The embedded wire insert is conducive to the formation of annular flow. The flow pattern distribution regions are distinguished by the Caaq(capillary number)±We_(org)(Weber number) flow pattern map. When Weorg<0.001, slug flow is the main flow pattern, and when Weorg>0.1, annular flow is the main flow pattern. Oval flow and droplet flow are between We_(org)= 0.001-0.1, and oval flow is transformed into droplet flow with the increase of Caaq. The effect of flow rate, phase ratio, initial acetic acid concentration, insert shape and flow patterns on mass transfers are studied. Mass transfer process is enhanced under annular flow conditions, the volumetric mass transfer coefficient is up to 0.36 s^(-1) because of the high interfacial area and interface renewal rate of annular flow. 展开更多
关键词 Flow pattern mass transfer Microchannels two-phase flow
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Heat and Mass Transfers in a Two-Phase Stratified Turbulent Fluid Flow in a Geothermal Pipe with Chemical Reaction
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作者 Eric M. Nyariki Mathew N. Kinyanjui Jeconia O. Abonyo 《Journal of Applied Mathematics and Physics》 2023年第2期484-513,共30页
This research focused on the study of heat and mass transfers in a two-phase stratified turbulent fluid flow in a geothermal pipe with chemical reaction. The derived non-linear partial differential equations governing... This research focused on the study of heat and mass transfers in a two-phase stratified turbulent fluid flow in a geothermal pipe with chemical reaction. The derived non-linear partial differential equations governing the flow were solved using the Finite Difference Method. The effects of various physical parameters on the concentration, skin friction, heat, and mass transfers have been determined. Analysis of the results obtained indicated that the coefficient of skin friction decreased with an increase in Reynolds number and solutal Grasholf number, the rate of heat transfer increased with an increase in Eckert number, Prandtl number, and angle of inclination, and the rate of mass transfer increased with increase in Reynolds number, Chemical reaction parameter and angle of inclination. The findings would be useful to engineers in designing and maintaining geothermal pipelines more effectively. 展开更多
关键词 two-phase Turbulence Non-Newtonian INCLINATION Heat transfer mass transfer STRATIFIED
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Research on shell-side heat and mass transfer with multi-component in LNG spiral-wound heat exchanger under sloshing conditions
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作者 Xue-Ping Du Guang-Lei Yu +3 位作者 Ya-Cheng Xu Zhi-Jie Chen Nai-Liang Li Huan-Guang Wang 《Petroleum Science》 SCIE EI CAS CSCD 2024年第2期1333-1345,共13页
The spiral-wound heat exchanger(SWHE) is the primary low-temperature heat exchanger for large-scale LNG plants due to its high-pressure resistance, compact structure, and high heat exchange efficiency. This paper stud... The spiral-wound heat exchanger(SWHE) is the primary low-temperature heat exchanger for large-scale LNG plants due to its high-pressure resistance, compact structure, and high heat exchange efficiency. This paper studied the shell-side heat and mass transfer characteristics of vapor-liquid two-phase mixed refrigerants in an SWHE by combining a multi-component model in FLUENT software with a customized multicomponent mass transfer model. Besides, the mathematical model under the sloshing condition was obtained through mathematical derivation, and the corresponding UDF code was loaded into FLUENT as the momentum source term. The results under the sloshing conditions were compared with the relevant parameters under the steady-state condition. The shell-side heat and mass transfer characteristics of the SWHE were investigated by adjusting the component ratio and other working conditions. It was found that the sloshing conditions enhance the heat transfer performance and sometimes have insignificant effects. The sloshing condition is beneficial to reduce the flow resistance. The comprehensive performance of multi-component refrigerants has been improved and the improvement is more significant under sloshing conditions, considering both the heat transfer and pressure drop.These results will provide theoretical support for the research and design of multi-component heat and mass transfer enhancement of LNG SWHE under ocean sloshing conditions. 展开更多
关键词 Spiral-wound heat exchanger Sloshing conditions two-phase flow MULTI-COMPONENT Heat and mass transfer
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Numerical modeling and parametric sensitivity analysis of heat transfer and two-phase oil and water flow characteristics in horizontal and inclined flowlines using OpenFOAM 被引量:3
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作者 Nsidibe Sunday Abdelhakim Settar +1 位作者 Khaled Chetehouna Nicolas Gascoin 《Petroleum Science》 SCIE EI CAS CSCD 2023年第2期1183-1199,共17页
Estimating the oil-water temperatures in flowlines is challenging especially in deepwater and ultra-deepwater offshore applications where issues of flow assurance and dramatic heat transfer are likely to occur due to ... Estimating the oil-water temperatures in flowlines is challenging especially in deepwater and ultra-deepwater offshore applications where issues of flow assurance and dramatic heat transfer are likely to occur due to the temperature difference between the fluids and the surroundings. Heat transfer analysis is very important for the prediction and prevention of deposits in oil and water flowlines, which could impede the flow and give rise to huge financial losses. Therefore, a 3D mathematical model of oil-water Newtonian flow under non-isothermal conditions is established to explore the complex mechanisms of the two-phase oil-water transportation and heat transfer in different flowline inclinations. In this work, a non-isothermal two-phase flow model is first modified and then implemented in the InterFoam solver by introducing the energy equation using OpenFOAM® code. The Low Reynolds Number (LRN) k-ε turbulence model is utilized to resolve the turbulence phenomena within the oil and water mixtures. The flow patterns and the local heat transfer coefficients (HTC) for two-phase oil-water flow at different flowlines inclinations (0°, +4°, +7°) are validated by the experimental literature results and the relative errors are also compared. Global sensitivity analysis is then conducted to determine the effect of the different parameters on the performance of the produced two-phase hydrocarbon systems for effective subsea fluid transportation. Thereafter, HTC and flow patterns for oil-water flows at downward inclinations of 4°, and 7° can be predicted by the models. The velocity distribution, pressure gradient, liquid holdup, and temperature variation at the flowline cross-sections are simulated and analyzed in detail. Consequently, the numerical model can be generally applied to compute the global properties of the fluid and other operating parameters that are beneficial in the management of two-phase oil-water transportation. 展开更多
关键词 Flow assurance Flow pattern Heat transfer Flowlines two-phase flow Global sensitivity analysis
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The dual action of N_(2)on morphology regulation and mass-transfer acceleration of CO_(2)hydrate film
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作者 Jinrong Zhong Yu Tian +6 位作者 Yifei Sun Li Wan Yan Xie Yujie Zhu Changyu Sun Guangjin Chen Yuefei Zhang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第9期120-129,共10页
The morphology characteristics of CH_(4),CO_(2),and CO_(2)+N_(2)hydrate film forming on the suspending gas bubbles are studied using microscopic visual method at supercooling conditions from 1.0 to 3.0 K.The hydrate f... The morphology characteristics of CH_(4),CO_(2),and CO_(2)+N_(2)hydrate film forming on the suspending gas bubbles are studied using microscopic visual method at supercooling conditions from 1.0 to 3.0 K.The hydrate film vertical growth rate and thickness along the planar gas-water interface are measured to study the hydrate formation kinetics and mass transfer process.Adding N_(2)in the gas mixture plays the same role as lowering the supercooling conditions,both retarding the crystal nucleation and growth rates,which results in larger single crystal size and rough hydrate morphology.N_(2)in the gas mixture helps to delay the secondary nucleation on the hydrate film,which is beneficial to maintain the porethroat structure and enhance the mass transfer.The vertical growth rate of hydrate film mainly depends on the supercooling conditions and gas compositions but has weak dependence on the experimental temperature and pressure.Under the same gas composition condition,the final film thickness shows a linear relationship with the supercooling conditions.The mass transfer coefficient of CH_(4)molecules in hydrates ranges from 4.54×10^(-8)to 7.54×10^(-8)mol·cm^(-2)·s^(-1)·MPa^(-1).The maximum mass transfer coefficient for CO_(2)t N_(2)hydrate occurs at the composition of 60%CO_(2)t 40%N_(2),which is 3.98×10^(-8)mol·cm^(-2)·s^(-1)·MPa^(-1). 展开更多
关键词 Gas hydrate MORPHOLOGY Secondary nucleation Formation kinetics mass transfer
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Effect of surfactant frequently used in soil flushing on oxygen mass transfer in micro-nano-bubble aeration system
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作者 Mei Bai Zhibin Liu +3 位作者 Zhu Liu Chenfei He Zhanhuang Fan Miaoxin Yuan 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第3期174-181,共8页
In-site soil flushing and aeration are the typical synergetic remediation technology for contaminated sites.The surfactant present in flushing solutions is bound to affect the aeration efficiency.The purpose of this s... In-site soil flushing and aeration are the typical synergetic remediation technology for contaminated sites.The surfactant present in flushing solutions is bound to affect the aeration efficiency.The purpose of this study is to evaluate the effect of surfactant frequently used in soil flushing on the oxygen mass transfer in micro-nano-bubble(MNB)aeration system.Firstly,bio-surfactants and chemical surfactants were used to investigate their effects on Sauter mean diameter of bubble(dBS),gas holdup(ε),volumetric mass-transfer coefficient(kLa)and liquid-side mass-transfer coefficient(kL)in the MNB aeration system.Then,based upon the experimental results,the Sardeing's and Frossling's models were modified to describe the effect of surfactant on kL in the MNB aeration.The results showed that,for the twenty aqueous surfactant solutions,with the increase in surfactant concentration,the value of dBS,kLa and kL decreased,while the value ofεand gas-liquid interfacial area(a)increased.These phenomena were mainly attributed to the synergistic effects of immobile bubble surface and the suppression of coalescence in the surfactant solutions.In addition,with the presence of electric charge,MNBs in anionic surfactant solutions were smaller and higher in number than in non-ionic surfactant solutions.Furthermore,the accumulation of surfactant on the gas-liquid interface was more conspicuous for small MNB,so the reduction of kL in anionic surfactant solutions was larger than that in non-ionic surfactant solutions.Besides,the modified Frossling's model predicted the effect of surfactant on kL in MNB aeration system with reasonable accuracy. 展开更多
关键词 Soil flushing Micro-nano-bubble aeration Bio-surfactant mass transfer coefficient
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PVDF-assisted pyrolysis strategy for corrugated plate oxygen electrocatalysis nanoreactor:Simultaneously realizing efficient active sites and rapid mass transfer
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作者 Chenxi Xu Liang Chen +6 位作者 Haihui Zhou Shifeng Qin Zhaohui Hou Yangyang Chen Jiale Sun Junwei Xu Zhongyuan Huang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第10期612-621,I0013,共11页
Though Zn-air batteries(ZABs)are one of the most promising system for energy storage and conversion,challenge still persists in its commercial application due to the sluggish kinetics of oxygen reduction/evolution rea... Though Zn-air batteries(ZABs)are one of the most promising system for energy storage and conversion,challenge still persists in its commercial application due to the sluggish kinetics of oxygen reduction/evolution reaction(ORR/OER).Hereby,a polyvinylidene fluoride(PVDF)-assisted pyrolysis strategy is proposed to develop a novel corrugated plate-like bifunctional electrocatalyst using two-dimensional zeolitic imidazolate frameworks(2D ZIF-67)as the precursor.The employed PVDF plays an important role in inheriting the original 2D structure of ZIF-67 and modulating the composition of the final products.As a result,a corrugated plate-like electrocatalyst,high-density Co nanoparticles decorated 2D Co,N,and F tri-doped carbon nanosheets,can be obtained.The acquired electrocatalyst enables efficient active sites and rapid mass transfer simultaneously,thus showing appreciable electrocatalytic performance for rechargeable Zn-air batteries.Undoubtedly,our proposed strategy offers a new perspective to the design of advanced oxygen electrocatalysts. 展开更多
关键词 Active sites mass transfer Corrugated plate Oxygen electrocatalyst Zn-air batteries
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Numerical investigation of turbulent mass transfer processes in turbulent fluidized bed by computational mass transfer
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作者 Hailun Ren Liang Zeng +3 位作者 Wenbin Li Shuyong Chen Zhongli Tang Donghui Zhang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第12期64-74,共11页
Turbulent fluidized bed possesses a distinct advantage over bubbling fluidized bed in high solids contact efficiency and thus exerts great potential in applications to many industrial processes.Simulation for fluidiza... Turbulent fluidized bed possesses a distinct advantage over bubbling fluidized bed in high solids contact efficiency and thus exerts great potential in applications to many industrial processes.Simulation for fluidization of fluid catalytic cracking(FCC)particles and the catalytic reaction of ozone decomposition in turbulent fluidized bed is conducted using the EulerianeEulerian approach,where the recently developed two-equation turbulent(TET)model is introduced to describe the turbulent mass diffusion.The energy minimization multi-scale(EMMS)drag model and the kinetic theory of granular flow(KTGF)are adopted to describe gaseparticles interaction and particleeparticle interaction respectively.The TET model features the rigorous closure for the turbulent mass transfer equations and thus enables more reliable simulation.With this model,distributions of ozone concentration and gaseparticles two-phase velocity as well as volume fraction are obtained and compared against experimental data.The average absolute relative deviation for the simulated ozone concentration is 9.67%which confirms the validity of the proposed model.Moreover,it is found that the transition velocity from bubbling fluidization to turbulent fluidization for FCC particles is about 0.5 m$se1 which is consistent with experimental observation. 展开更多
关键词 Turbulent fluidized bed Simulation Computational mass transfer TURBULENCE Computational fluid dynamics
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Calculation of Mass Concrete Temperature and Creep Stress under the Influence of Local Air Heat Transfer
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作者 Heng Zhang Chao Su +2 位作者 Xiaohu Chen Zhizhong Song Weijie Zhan 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第9期2977-3000,共24页
Temperature-induced cracking during the construction of mass concrete is a significant concern.Numerical simulations of concrete temperature have primarily assumed that the concrete is placed in an open environment.Th... Temperature-induced cracking during the construction of mass concrete is a significant concern.Numerical simulations of concrete temperature have primarily assumed that the concrete is placed in an open environment.The problem of heat transfer between the air and concrete has been simplified to the concrete’s heat dissipation boundary.However,in the case of tubular concrete structures,where air inlet and outlet are relatively limited,the internal air temperature does not dissipate promptly to the external environment as it rises.To accurately simulate the temperature and creep stress in tubular concrete structures with enclosed air spaces during construction,we establish an air–concrete coupled heat transfer model according to the principles of conjugate heat transfer,and the accuracy of the model is verified through experiments.Furthermore,we conduct a case study to analyze the impact of airflow within the ship lock corridor on concrete temperature and creep stress.The results demonstrate that enhancing airflow within the corridor can significantly reduce the maximum concrete temperature.Compared with cases in which airflow within the corridor is neglected,the maximum concrete temperature and maximum tensile stress can be reduced by 12.5℃ and 0.7 MPa,respectively,under a wind speed of 4 m/s.The results of the traditional calculation method are relatively close to those obtained at a wind speed of 1 m/s.However,the temperature reduction process in the traditional method is faster,and the method yields greater tensile stress values for the corridor location. 展开更多
关键词 Conjugate heat transfer temperature field mass concrete creep stress
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Effect of bipolar-plates design on corrosion,mass and heat transfer in proton-exchange membrane fuel cells and water electrolyzers:A review
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作者 Jiuhong Zhang Xiejing Luo +2 位作者 Yingyu Ding Luqi Chang Chaofang Dong 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第7期1599-1616,共18页
Attaining a decarbonized and sustainable energy system,which is the core solution to global energy issues,is accessible through the development of hydrogen energy.Proton-exchange membrane water electrolyzers(PEMWEs)ar... Attaining a decarbonized and sustainable energy system,which is the core solution to global energy issues,is accessible through the development of hydrogen energy.Proton-exchange membrane water electrolyzers(PEMWEs)are promising devices for hydrogen production,given their high efficiency,rapid responsiveness,and compactness.Bipolar plates account for a relatively high percentage of the total cost and weight compared with other components of PEMWEs.Thus,optimization of their design may accelerate the promotion of PEMWEs.This paper reviews the advances in materials and flow-field design for bipolar plates.First,the working conditions of proton-exchange membrane fuel cells(PEMFCs)and PEMWEs are compared,including reaction direction,operating temperature,pressure,input/output,and potential.Then,the current research status of bipolar-plate substrates and surface coatings is summarized,and some typical channel-rib flow fields and porous flow fields are presented.Furthermore,the effects of materials on mass and heat transfer and the possibility of reducing corrosion by improving the flow field structure are explored.Finally,this review discusses the potential directions of the development of bipolar-plate design,including material fabrication,flow-field geometry optimization using threedimensional printing,and surface-coating composition optimization based on computational materials science. 展开更多
关键词 bipolar-plates flow design mass and heat transfer CORROSION water electrolyzers fuel cells
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Structural engineering of Fe single-atom oxygen reduction catalyst with high site density and improved mass transfer
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作者 Jiawen Wu Yuanzhi Zhu +3 位作者 An Cai Xiaobin Fan Wenchao Peng Yang Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第11期634-644,共11页
Fe-N-C catalysts are widely considered as promising non-precious-metal candidates for electrocatalytic oxygen reduction reaction(ORR),Yet despite their high catalytic activity through rational modulation,challenges re... Fe-N-C catalysts are widely considered as promising non-precious-metal candidates for electrocatalytic oxygen reduction reaction(ORR),Yet despite their high catalytic activity through rational modulation,challenges remain in their low site density and unsatisfactory mass transfer structure.Herein,we present a structural engineering approach employing a soft-template coating strategy to fabricate a hollow and hierarchically porous N-doped carbon framework anchored with atomically dispersed Fe sites(FeNCh) as an efficient ORR catalyst.The combination of hierarchical porosity and high exterior surface area is proven crucial for exposing more active sites,which gives rise to a remarkable ORR performance with a half-wave potential of 0.902 V in 0.1 m KOH and 0.814 V in 0.1 m HClO_(4),significantly outperforming its counterpart with solid structure and dominance of micropores(FeNC-s).The mass transfer property is revealed by in-situ electrochemical impedance spectroscopy(EIS) measurement.The distribution of relaxation time(DRT) analysis is further introduced to deconvolve the kinetic and mass transport processes,which demonstrates an alleviated mass transport resistance for FeNC-h,validating the effectiveness of structural engineering.This work not only provides an effective structural engineering approach but also contributes to the comprehensive mass transfer evaluation on advanced electrocatalyst for energy conversion applications. 展开更多
关键词 Single-atom catalysts Oxygen reduction reaction Structural engineering Active site density mass transfer Zinc-air batteries
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Mass transfer enhancement and hydrodynamic performance with wire mesh coupling solid particles in bubble column reactor
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作者 Chuanjun Di Jipeng Dong +3 位作者 Fei Gao Guanghui Chen Pan Zhang Jianlong Li 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第3期195-205,共11页
It is of vital significance to investigate mass transfer enhancements for chemical engineering processes.This work focuses on investigating the coupling influence of embedding wire mesh and adding solid particles on b... It is of vital significance to investigate mass transfer enhancements for chemical engineering processes.This work focuses on investigating the coupling influence of embedding wire mesh and adding solid particles on bubble motion and gas-liquid mass transfer process in a bubble column.Particle image velocimetry(PIV)technology was employed to analyze the flow field and bubble motion behavior,and dynamic oxygen absorption technology was used to measure the gas-liquid volumetric mass transfer coefficient(kLa).The effect of embedding wire mesh,adding solid particles,and wire mesh coupling solid particles on the flow characteristic and kLa were analyzed and compared.The results show that the gas-liquid interface area increases by 33%-72%when using the wire mesh coupling solid particles strategy compared to the gas-liquid two-phase flow,which is superior to the other two strengthening methods.Compared with the system without reinforcement,kLa in the bubble column increased by 0.5-1.8 times with wire mesh coupling solid particles method,which is higher than the sum of kLa increases with inserting wire mesh and adding particles,and the coupling reinforcement mechanism for affecting gas-liquid mass transfer process was discussed to provide a new idea for enhancing gas-liquid mass transfer. 展开更多
关键词 Fluid mechanics BUBBLE mass transfer Wire mesh coupling solid particles Particle image velocimetry Hydrodynamics
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Heat and Mass Transfer on Non-Newtonian Peristaltic Flow in a Channel in Presence of Magnetic Field: Analytical and Numerical Analysis
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作者 Md. Maruf Hasan Md. Enamul Karim Md. Abdus Samad 《Applied Mathematics》 2024年第8期568-583,共16页
A study has been arranged to investigate the flow of non-Newtonian fluid in a vertical asymmetrical channel using peristalsis. The porous medium allows the electrically conductive fluid to flow in the channel, while a... A study has been arranged to investigate the flow of non-Newtonian fluid in a vertical asymmetrical channel using peristalsis. The porous medium allows the electrically conductive fluid to flow in the channel, while a uniform magnetic field is applied perpendicular to the flow direction. The analysis takes into account the combined influence of heat and mass transfer, including the effects of Soret and Dufour. The flow’s non-Newtonian behavior is characterized using a Casson rheological model. The fluid flow equations are examined within a wave frame of reference that has a wave velocity. The analytic solution is examined using long wavelengths and a small Reynolds number assumption. The stream function, temperature, concentration and heat transfer coefficient expressions are derived. The bvp4c function from MATLAB has been used to numerically solve the transformed equations. The flow characteristics have been analyzed using graphs to demonstrate the impacts of different parameters. 展开更多
关键词 Stream Function mass transfer Vertical Channel Casson Fluid
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Mass Transfer-Promoted Fe^(2+)/Fe^(3+)Circulation Steered by 3D Flow-Through Co-Catalyst System Toward Sustainable Advanced Oxidation Processes
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作者 Weiyang Lv Hao Li +6 位作者 Jinhui Wang Lixin Wang Zenglong Wu Yuge Wang Wenkai Song Wenkai Cheng Yuyuan Yao 《Engineering》 SCIE EI CAS CSCD 2024年第5期264-275,共12页
Realizing fast and continuous generation of reactive oxygen species(ROSs)via iron-based advanced oxidation processes(AOPs)is significant in the environmental and biological fields.However,current AOPs assisted by co-c... Realizing fast and continuous generation of reactive oxygen species(ROSs)via iron-based advanced oxidation processes(AOPs)is significant in the environmental and biological fields.However,current AOPs assisted by co-catalysts still suffer from the poor mass/electron transfer and non-durable promotion effect,giving rise to the sluggish Fe^(2+)/Fe^(3+)cycle and low dynamic concentration of Fe^(2+)for ROS production.Herein,we present a three-dimensional(3D)macroscale co-catalyst functionalized with molybdenum disulfide(MoS_(2))to achieve ultra-efficient Fe^(2+)regeneration(equilibrium Fe^(2+)ratio of 82.4%)and remarkable stability(more than 20 cycles)via a circulating flow-through process.Unlike the conventional batch-type reactor,experiments and computational fluid dynamics simulations demonstrate that the optimal utilization of the 3D active area under the flow-through mode,initiated by the convectionenhanced mass/charge transfer for Fe^(2+)reduction and then strengthened by MoS_(2)-induced flow rotation for sufficient reactant mixing,is crucial for oxidant activation and subsequent ROS generation.Strikingly,the flow-through co-catalytic system with superwetting capabilities can even tackle the intricate oily wastewater stabilized by different surfactants without the loss of pollutant degradation efficiency.Our findings highlight an innovative co-catalyst system design to expand the applicability of AOPs based technology,especially in large-scale complex wastewater treatment. 展开更多
关键词 Advanced oxidation processes 3D co-catalyst Flow-through mode Enhanced mass transfer Complex wastewater treatment
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Mass transfer process of peanut protein extracted by bis(2-ethylhexyl)sodium sulfosuccinate reverse micelles
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作者 Chenxian Yang Tianci Li +5 位作者 Tingwei Zhu Xiaojie Duan Yibao Chen Yandong Xu Fusheng Chen Kunlun Liu 《Grain & Oil Science and Technology》 CAS 2024年第1期60-67,共8页
The liquid-liquid extraction method using reverse micelles can simultaneously extract lipid and protein of oilseeds,which have become increasingly popular in recent years.However,there are few studies on mass transfer... The liquid-liquid extraction method using reverse micelles can simultaneously extract lipid and protein of oilseeds,which have become increasingly popular in recent years.However,there are few studies on mass transfer processes and models,which are helpful to better control the extraction process of oils and proteins.In this paper,mass transfer process of peanut protein extracted by bis(2-ethylhexyl)sodium sulfosuccinate(AOT)/isooctane reverse micelles was investigated.The effects of stirring speed(0,70,140,and 210 r/min),temperature of extraction(30,35,40,45,and 50℃),peanut flour particle size(0.355,0.450,0.600,and 0.900 mm)and solidliquid ratio(0.010,0.0125,0.015,0.0175,and 0.020 g/mL)on extraction rate were examined.The results showed that extraction rate increased with temperature rising,particle size reduction as well as solid-liquid ratio increase respectively,while little effect of stirring speed(P>0.05)was observed.The apparent activation energy of extraction process was calculated as 10.02 kJ/mol and Arrhenius constant(A)was 1.91 by Arrhenius equation.There was a linear relationship between reaction rate constant and the square of the inverse of initial particle radius(1/r_(0)^(2))(P<0.05).This phenomenon and this shrinking core model were anastomosed.In brief,the extraction process was controlled by the diffusion of protein from the virgin zone interface of particle through the reacted zone and it was in line with the first order reaction.Mass transfer kinetics of peanut protein extracted by reverse micelles was established and it was verified by experimental results.The results provide an important theoretical guidance for industrial production of peanut protein separation and purification. 展开更多
关键词 AOT reverse micelles Peanut protein KINETICS Shrinking core model mass transfer
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