Two-step pyrolysis of ZIF-8 functionalized with ammonium ferric citrate for efficient oxygen reduction reaction

Zeolitic imidazolate frameworks（ZIFs） are widely employed in catalyst synthesis as parental materials for electrochemical energy storage and conversion. Herein, we have demonstrated a facile synthesis of highly efficient catalyst for oxygen reduction reaction in both alkaline and acidic medium, which is derived from ZIF-8 functionalized with ammonium ferric citrate via two-step pyrolysis in Ar and NHatmosphere.The results reveal that the catalytic activity improvement after NH3 pyrolysis benefits from mesoporedominated morphology and high utilization of Fe-containing active sites. The optimum catalyst shows excellent performance in zinc-air battery and polymer electrolyte membrane fuel cell tests.

Estimation on Global Reaction Heat for the Aromatization Process of Liquefied Petroleum Gas

The reaction heat effect analysis for the aromatization process of Liquefied Petroleum Gas (LPG) was completed in this paper. In order to characterize this complex reaction system, one set of independent reactions was determined by means of atomic coefficient matrix method. Based on reaction thermodynamic and stoichiometric knowledge, the heat effect, Gibbs free energy change and equilibrium constant for each independent reaction was calculated for the specified conditions. Under these conditions, based on the initial and final composition data from LPG aromatization experiments, the actual extent of reaction for each independent reaction was determined. Furthermore, the global reaction heat and adiabatic temperature rise of LPG aromatization reaction system could be estimated. This work would provide a theoretical guidance for the design and scale-up of reactor for LPG aromatization process, as well as for the selection of proper operating conditions.

Misconceptions in global reactions and formula writing

The frequently used concept of "global reaction" is discussed and the reason for the confusion behind explained. The misconception is cleared by formula writing based on the donor–acceptor(donac) reaction concept and by applying the Grand Rule of Formula Writing that is based on it.

Global existence and blow up of solutions for two classes of reaction diffusion systems with two nonlinear source terms in bounded domain

In this paper we deal with the initial boundary value problem for two classes of reaction diffusion systems with two source terms in bounded domain. Under some assumptions on the exponents and the initial data, applying the comparison principle, the maximum prin- ciple and the supersolution-subsolution method, we prove the global existence and blow up of solutions. We also establish some upper blow up rates.

A NOTE ON THE GLOBAL SOLUTIONS OF A SEMILINEAR REACTION DIFFUSION SYSTEM

This note studies the global solutions of a semilineear reaction diffusion system which comes from an exothermic themical reaction.This is a complement of paper[1]and gives a positive answer to the question mentioned by paper[2].

Forecast of the Luminescent Phenomena of Silicon Rich Oxide Films off Stoichiometry by Means of the Global Reaction Model

The Global Reaction Model describes a set of chemical reactions that can potentially occur during the process of obtaining silicon rich oxide (SRO) films, regardless of the technique used to grow such films which are an outside stoichiometry material. Particularly, chemical reactions that occur during the process of growing of SRO films by LPCVD technique are highlighted in this model. We suggest and evaluate either some types of molecules or resulting nanostructures and we predict theoretically, by applying the density functional theory, the contribution that they may have to the phenomenon of luminescence which is measured in SRO films. Also, we have calculated the opto-electronic properties of SRO films. The suggested model provides enough information required to identify the molecular structures resulting from the presence of defects in SRO films and also those corresponding to charged structures. It is also possible to detect the molecular structures which are modified due to the effect of heat treatment, and identify the presence of different oxidation states inclusive the formation of siloxanes.

The Role of Enthalpy of Reaction in the Process of Global Warming: What Can We Learn from Basic Thermodynamics*

An increase of carbon dioxide content accompanied by an increase of the temperature is observed in the atmosphere during the last 200 years. This behaviour can be explained by examination of correlations between tree generally accepted data sets of the recent past, world population, carbon dioxide content in the atmosphere, and rise of global temperature as function of time. No return to climate situations from hundred thousand of years before present is necessary. The world climate is a dynamic equilibrium between all energy generating processes on earth, especially sun energy, and the radiation of energy into space. Since approx. 200 years the dynamic equilibrium is changed additionally by means of fossil energy carriers, whose depots were put on in passed geological epochs, a climatic disturbance was produced. It is shown that the consumption of energy per year by the mankind can warm up the atmosphere by about one degree. This quantity cannot be neglected in climatic calculations;therefore it is the cause of mankind made warming of the atmosphere. The qualitative analyses presented here have shown that the use of so-called renewable energy sources does not necessarily lead to the avoidance of global warming. It can be expected that some techniques will have no or even small effect. Especially the model calculations to the operation of wind turbines and its influence on the temperature of the atmosphere show that it is difficult to estimate their influence and cannot be foreknown.

Global Bounded Solutions for Reaction-diffusion Systems with a Full Matrix of Diffusion Coefficients and a Balance Law

This paper deals with an initial boundary value problem for the strongly coupledreaction-diffusion systems with a full matrix of diffusion coefficients. The global existence ofsolutions is proved by using the techniques based on invariant regions, Lyapunov functionalmethods, and local Lp prior estimates independent of time.

Global attractors associated with general partly dissipative reaction-diffusion systems in unbounded domains

The asymptotic behaviour of solutions for general partly dissipative reaction-diffusion systems in Rn is studied. The asymptotic compactness of the solutions and then the existence of the global attractor are proved in L2(Rn )× L2(Rn ) .

Heat Propagation of Eyring-Prandtl Double Reaction and Pressure Driven Hydromagnetic Viscous Heating Fluid in a Device

The effect toxic industrial discharge on the environment and ecosystem cannot be overlooked. This is owing to a partial combustion of hydrocarbon arising from industrial activities and human endeavours. As such, this investigation focuses on the pressure driven flow and heat propagation of combustible Prandtl-Eyring viscous heating fluid in a horizontal device. The combustion-reaction of the viscoplastic material is considered to be inspired by two-step exothermic reaction. With negligible reactant consumption, the flowing fluid is influenced by a chemical kinetic, activation energy and electromagnetic force. An invariant transformation of the partial derivative model to an ordinary derivative model is obtained through an applied dimensionless variable. The solutions to the unsteady thermal fluid flow model are obtained via a semi-implicit difference scheme, and the outputs of the solution are displayed in plots and tables. As revealed, an enhanced heat propagation is obtained that in turn encourages the combustion process of the system. Also, increasing material dilatant simulated fluid molecular bond and viscosity. Therefore, the outcomes of this study are treasured to the thermal and chemical engineering, and the environmental management.

GLOBAL EXISTENCE OF SOLUTIONS FOR A STRONGLY COUPLED REACTION-DIFFUSION SYSTEM

This paper is concerned with an Initial Boundary Value Problem (IBVP) for a strongly coupled semilinear reaction-diffusion system. By using the upper and lower solutions method and Leray-Schauder fixed point theorem and so on, the authors prove the global existence and uniqueness of a. smooth. solution for this IBVP under some appropriate conditions.

矩形管下气相螺旋爆轰的结构及传播方式

为探索极限条件下矩形管道截面长宽比对于螺旋爆轰传播的影响,采用基于五阶WENO有限差分格式和两步总包反应模型的Euler方程,对三维气相螺旋爆轰波在矩形截面管道中的结构及其传播方式进行了数值研究。通过模拟不同管道截面尺寸下爆轰波的三波线运动轨迹、流场分布及高压印记结构,揭示了截面几何尺寸对气相临界爆轰波稳定传播的影响规律。结果表明:螺旋爆轰能在一定范围的小管道截面尺寸内通过横、竖两条三波线及其相互作用形成的斜三波线的运动来维持传播;随着管道截面尺寸长宽比的增加,螺旋爆轰在壁面上形成的高压印记逐渐由倾斜的条带结构变成局部点状分布结构,波阵面上的斜三波线的轨迹也由方管中沿着单一方向的圆周运动逐渐发展为具有转向机制的复杂运动轨迹;当长宽比进一步增加时,三维螺旋爆轰存在向二维结构的单头爆轰结构退化的趋势。

一个含对流项的反应扩散捕食模型正解的存在性

本文研究了一个含对流项的反应扩散捕食模型正解的存在性,该模型描述了两物种间的捕食关系及捕食者选择在远离高密度食饵区域捕猎的倾向.基于模型正解的先验估计,本文利用特征值理论和齐次化理论获得了模型正解关于两物种增长率的不存在性,然后利用分歧理论获得了模型正解在某些参数条件下的存在性.

Blow-up for a Class of Degenerate Reaction-diffusion Equation with Nonlocal Source

这份报纸与非局部的来源，一起处理非局部的退化反应散开方程的一个班的答案的性质题目到空 Dirichlet 边界 condition.We 首先给足够的条件因为答案全球性存在或在有限 time.Then 炸毁发作时间，这也最后是 given.At ，我们获得不同于发作集合是哪个的本地来源的一个性质全部间隔。

The Nucleon-Actinide Global Optical Model Potential Below 300 MeV

A set of new global phenomenological optical model potential parameters has been obtained in the mass range of target nuclei 220≤A≤260 with incident energies below 300 MeV, by simultaneously fitting the experimental data of 232Th and 23Su, and these potential parameters are analyzed and used to calculate the reaction cross sections, energy spectra and double differ- ential cross sections for p＋232Th reaction. Comparison of calculated results using these potential parameters with available experimental data shows that the present form of global optical model potential could reproduce experimental data for both the neutron and the proton.

Global Asymptotic Stability and Hopf Bifurcation in a Homogeneous Diffusive Predator-Prey System with Holling Type II Functional Response

In this paper, we considered a homogeneous reaction-diffusion predator-prey system with Holling type II functional response subject to Neumann boundary conditions. Some new sufficient conditions were analytically established to ensure that this system has globally asymptotically stable equilibria and Hopf bifurcation surrounding interior equilibrium. In the analysis of Hopf bifurcation, based on the phenomenon of Turing instability and well-done conditions, the system undergoes a Hopf bifurcation and an example incorporating with numerical simulations to support the existence of Hopf bifurcation is presented. We also derived a useful algorithm for determining direction of Hopf bifurcation and stability of bifurcating periodic solutions correspond to j ≠0 and j = 0, respectively. Finally, all these theoretical results are expected to be useful in the future study of dynamical complexity of ecological environment.

Adsorption of CO₂and H₂on Cu and Zn Micro-Cluster Surfaces Studied by Quantum Chemistry and Theory of Absolute Reaction Rates

Statistical mechanics and semi-empirical molecular orbital theory (PM6) are used to calculate the surface coverage of CO2 and H2 molecular species chemically adsorbed on the surface of Cu and Zn micro clusters. The calculation shows that CO2 is adsorbed well both on the surface of Cu and Zn micro clusters. Although H2 is adsorbed well on the surface of Zn micro clusters, H2 absorption on the surface of Cu micro clusters is much more limited in the pressure range of 20 - 100 atm and temperature range of 200 - 1000 K. Reaction rates are also estimated for some chemical adsorption process of H2 gas using theory of absolute reaction rates. It is found that the values of the reaction rate calculated in the present paper agree reasonably well with the experimental values.

Gamma Cascade Transition of ⁵¹V(n_th, <i>g </i>)⁵²V Reaction

The thermal neutron capture gamma radiations for 51V(n, g)52V reaction have been studied at Dalat Nuclear Research Reactor (DNRR). The gamma two-step cascade transition was measured by event-event coincidence spectrometer. The added-neutron binding energy in 52V was measured as 7.31 MeV. Energy and the intensity transition of cascades were consistent with prediction of single particle model. Furthermore, the spin and the parity of levels were confined.

GLOBAL EXISTENCE AND ASYMPTOTIC BEHAVIOR OF SOLUTIONS FOR SOME COUPLED SYSTEMS VIA A LYAPUNOV FUNCTIONAL

The purpose of this work is to study the global existence and asymptotic behavior of solutions to a coupled reaction-diffusion system describing epidemiological or chemical situations. Our analytical proofs are based on the Lyapunov functional methods.

Critical Fujita Exponents for Localized Reaction Diffusion Systems

In this paper, we prove the existence of cirtical Fujita exponents for a class of localized reaction diffusion systems.