First-principles study and electronic structures of Mn-doped ultrathin ZnO nanofilms

The first-principles density functional calculation is used to investigate the electronic structures and magnetic properties of Mn-doped and N-co-doped ZnO nanofilms.The band structure calculation shows that the band gaps of ZnO films with 2,4,and 6 layers are larger than the band gap of the bulk with wurtzite structure and decrease with the increase of film thickness.However,the four-layer ZnO nanofilms exhibit ferromagnetic phases for Mn concentrations less than 24% and 12% for Mn-doping performed in the whole layers and two layers of the film respectively,while they exhibit spin glass phases for higher Mn concentrations.It is also found,on the one hand,that the spin glass phase turns into the ferromagnetic one,with the substitution of nitrogen atoms for oxygen atoms,for nitrogen concentrations higher than 16% and 5% for Mn-doping performed in the whole layers and two layers of the film respectively.On the other hand,the spin-glass state is more stable for ZnO bulk containing 5% of Mn impurities,while the ferromagnetic phase is stable by introducing the p-type carriers into the bulk system.Moreover,it is shown that using the effective field theory for ferromagnetic system,the Curie temperature is close to the room temperature for the undamped Ruderman-Kittel-Kasuya-Yoshida（RKKY） interaction.

Structure and Properties of Self-reinforced Material Made from Ultra-high Molecular Weight Polyethylene-montmorillonite Nanocomposite

High-strength and high-modulus ultra-high molecular weight polyethylene(UHMWPE), named self-reinforced material, was obtained by the elongation of UHMWPE-montmorillonite nanocomposite at melting temperature. According to the scanning electron microscope(SEM) analysis, a great deal of fibrillar texture formed in the direction of elongation, and the tensile fractured surface was similar to that of highly oriented fiber. The transmission electron microscope(TEM) and selective area electron diffraction(SAED) analyses reveal that the reinforced phase of the self-reinforced material is an extended chain crystal and its size is about 50_200 nm wide and several microns long, and the montmorillonite layers are broken up to pieces in the size from 100 to 10 nm. The broken layers which have a huge surface area interacting strongly with macromolecules reduces the entanglement density of UHMWPE and induces the chain orientation in flow field. It is supposed that the astriction of montmorillonite layers to polyethylene chains is not only end-tethered but also side-tethered. The differential scan calorimetry(DSC) analysis shows that there are two endothermal peaks for the self-reinforced material, of which the peak at a higher temperature(136.4 ℃) is ascribed to the melting of the reinforced phase.

Observation on Ultra-micro Structure of Eggshell and Analysis of Composition of Eggshell and Feather in Great Bustard

Ultra-micro structure of eggshell was observed and compositions of eggshell and feather were analyzed. The results showed that the structure of eggshell has special characters besides common structure. The content of poisonous elements in wild great bustard(Otis talda) eggshell and feather is significant lower than that in eggshell of crested foes(Nipponis nippon) and in feather of red crown crane(Grus japonesis) because of less disturbance by people. The contents of 14 elements of female’s feather all are higher than those of male’s.

The control effect of low-amplitude structure on oil-gaswater enrichment and development performance of ultra-low permeability reservoirs

Based on drilling, logging, test production and dynamic monitoring data, the control effects of low-amplitude structure on hydrocarbon accumulation and development performance of ultra-low permeability reservoirs were discussed by using the methods of dense well pattern, multi-factor geological modeling, macro and micro analysis and static and dynamic analysis. The results show that the low-amplitude structure always had a significant control and influence on the distribution and accumulation of original hydrocarbon and water and the evolution trend of water flooding performance in ultra-low permeability reservoirs, and it was not only the direction of oil and gas migration, but also a favorable place for relative accumulation of oil and gas. The controlling effect of low-amplitude structure on ultra-low permeability reservoir mainly depended on its tectonic amplitude and scale;the larger the tectonic amplitude and scale, and the higher the tectonic position of the low amplitude structure, the better the reservoir characteristic parameters, oil and gas enrichment degree and development effect, and the larger the spatial scope it controlled and influenced;water cut and oil well output always fluctuated orderly with the height of the low-amplitude structure;the dynamic response of waterflooding was closely related to the relative structural position of the injection and production wells;the injected water always advanced to the low-lying area of the structure first and then moved up to the high-lying area of the structure gradually;with the continuous expansion of the flooded area, part of the oil and gas in the low-lying part of the structure was forced to be distributed to the high part of the structure, resulting in a new oil and gas enrichment, so that the dynamic reserves of oil wells in the high part increased, and the production capacity remained stable.

New Method ＆ Practice of SegmentalStructure Design fo r Ultra-Deep Shield Tunnel

The study on the mechanism ofthe super-diameter shield tunnel with 60 m burieddepth is carried out. With the background of SouthHongmei Rd. Tunnel project, it is the first time tocapture the soil pressure data of the tunnel structureunder the depth condition and to find out the loaddistribution law of ultra depth shield tunnel throughthe in-situ measurement method. By presentingthe new internal force calculation model of tunnelstructure, the structural design theory of ultra-deepburied shield tunnel is improved. Because of thenew method in this project, the amount of segmentcontaining steel is obviously reduced with creatinggreat economic benefits, which may provide newmethod ＆ basis for the design of similar tunnelengineering in soft soil area.

Optimization of Honing Wheel Structure Parameters in Ultra-precision Plane Honing

Free abrasive particle machining in simple machine such as: honing, polishing can get higher surface finish mirror, but surface error, and working procedure is hard to control. Therefore, the vertical disposed ultra-precision plane honing method by ultra-particle diamond honing wheel is put forward to. The results of experiments indicate: plane-honing wheel has higher machining accuracy and machining efficiency. But at the same time the structure parameters of honing wheel effects on machining accuracy. By analyzing the relation of honing wheel structure parameters and workpiece machining accuracy, the relation of honing wheel and wear coefficient, then this paper gets honing wheel structure parameters in the condition of best accuracy coefficient and wear coefficient, and resolve the problem of choosing honing wheel structure parameters in ultra-precision plane honing at last. This paper analyses the relation of honing wheel structure parameters and workpiece machining accuracy coefficient and wear coefficient, by building relative movement math model of honing wheel and workpiece in plane honing. Through theory calculating, the result indicate: about honing machine tools for large volume manufacture, honing wheel wear is main effect factor, so honing wheel should adopt obverse triangle radial structure. About honing machining for high accuracy and low-batch quantities, machining accuracy coefficient is main factors; so honing wheel should adopt reverse triangle radial structure. Neglected the manufacturing factors of honing wheel, then we can design honing wheel with high power curve structure to meet the need of machining accuracy coefficient and honing wheel wear coefficient in higher accuracy honing.

深层-超深层致密储层天然裂缝分布特征及发育规律

天然裂缝是深层-超深层致密储层的有效储集空间和主要渗流通道,影响着致密储层油气的运移、富集、单井产能、开发方式及开发效果。通过对近年来致密储层裂缝研究成果总结和文献综述,分析了深层-超深层致密储层天然裂缝分布特征及发育规律。将致密储层天然裂缝分为大尺度裂缝、中尺度裂缝、小尺度裂缝和微尺度裂缝4个级别。不同尺度裂缝分布具有幂律分布的特点,裂缝尺度越大,数量越少;裂缝尺度越小,数量越多。大、中尺度裂缝主要起渗流作用,小尺度裂缝主要起渗流和储集作用,而微尺度裂缝主要起储集作用。在地层埋藏过程中的应力体制演化决定了不同时期天然裂缝的类型、产状及其力学性质;构造应力大小、岩石力学层的力学性质和厚度差异控制了多尺度裂缝的形成分布及其发育程度。构造变形导致不同构造部位的局部应力和应变分布产生差异,增强了裂缝发育的非均质性。逆冲断层通过控制其上盘地层变形控制了“裂缝域”的分布规律;走滑断层的组合样式、活动方式和岩石力学层共同控制了相关裂缝的三维空间展布。裂缝形成演化过程中的开启-闭合规律决定了裂缝的储集空间,记录了裂缝有效性的演化历史。

Prediction of Protein OmpH in Structure of C47-8 Pasteurella multocida

[Objective] This study aimed to predict the structure of protein OmpH from Pasteurella multocida C47-8 （PmC47-8） strain of yak. [Method] Online BLAST, signal peptide prediction, secondary structure prediction and protein characteristics of sequencing result of gene OmpH from PmC47-8 strain were analyzed. [Result] The similarities of gene OmpH from PmC47-8 with the published 81 OmpH genes were between 84% and 99%; a signal peptide was found with the cleavage sites between 20 and 21 in the polypeptide; secondary structure prediction showed that folding structure accounted for 49.8% and loop structure for 50.2%; it predicted that there were 7 O-glycosylation sites in OmpH protein with the amino acid residual sites of 2, 45, 48, 330, 716, 721, 723, respectively, and 2 N-glycosylation sites with the amino acid residual sites of 15 and 35. [Conclusion] This study lays the foundation for the study on the immunity of OmpH gene from yak.

6082-T6铝合金构件及其超大跨空间结构的受力性能与设计方法

针对6082-T6铝合金,从材料力学性能、轴压与偏压构件稳定承载力、受弯构件受力性能方面进行了系统试验和数值仿真研究;建立了国产铝合金构件试验数据库,评估了中、欧、美规范及DSM、CSM共5种设计方法的可靠度水平;对6082-T6铝合金圆管及泡沫铝填充复合管开展侧向冲击试验与数值仿真研究,提出了构件动态响应计算方法,并建立了冲击下构件变形的预测方法;针对超大跨度铝合金巨型网格结构开展了探索性研究,提出了适用于超大跨度结构的新型节点形式及稳定受力性能分析。研究成果将对6082-T6铝合金构件及结构在工程中的推广应用、提升结构的承载与抗冲击防御能力提供依据与技术支撑。

钢-薄层UHPC组合桥面结构中PBL剪力键抗剪性能试验

为探究钢-超高性能混凝土(UHPC)组合桥面结构中PBL剪力键的抗剪性能,以抗剪钢板尺寸、贯穿钢筋设置和端部承压状态为试验参数,完成了16个PBL试件的推出试验。结果表明:(1)随着抗剪钢板尺寸的增加,试件由UHPC榫无明显损伤时的钢板剪断破坏转变为UHPC榫局部压碎或整体压碎后的钢板剪断破坏,PBL的极限承载力随之相应提高,但其延性系数无明显变化;(2)贯穿钢筋对PBL承载能力的影响与UHPC榫的损伤状态密切相关,其对PBL抗剪承载能力的提高由榫无明显损伤时的5.3%增加到榫局部压碎时的9.7%和榫整体压碎时的14.9%;(3)对于钢-UHPC组合桥面结构中平行阵列布置的多列PBL,当列间距不小于10倍贯穿钢筋直径或12倍抗剪钢板厚度时,相邻列剪力键间相互作用的影响较小。基于试验结果,提出了适用于组合桥面结构中PBL剪力键的抗剪承载力计算公式,并以本文及其它文献的试验结果验证了其适用性。

INFLUENCE OF ELECTROACUPUNCTURE ON THE ULTRASTRUCTURE OF CA3 REGION OF THE HIPPOCAMPUS IN VD RATS

Objective: To observe the effect of electroacupuncture (EA) on learning and memory abilities and ultrastructure of synapses in CA3 region of the hippocampus in vascular dementia (VD) rats. Methods: A total of 32 SD rats were randomized into control (sham-operation, n=7), model (n=7), EA (n=9) and medication (n=9) groups. VD model was established by occlusion of the bilateral vertebral arteries (electrocoagulation) and bilateral common carotid arteries (occlusion for 5 min and reperfusion for 10 min , repeated the procedure for 3 times to induce global ischemia). EA ( 150 Hz , 1 mA ) was applied to “Baihui”(百会 GV 20), “Geshu”(膈俞 BL 17), “Pishu”(脾俞 BL 20) and “Shenshu”(肾俞 BL 23) for 20 min , once daily and continuously for 15 days. In medication group, the rats were fed with Nimotong (12 mg/kg), once daily and continuously for 15 days. Morris water maze method was used to test the animals’ learning and memory abilities (latencies to find the hidden platform determined by place navigation trials, and latencies to cross on the location of the removed platform determined by spatial probe trials) after the treatment. Ultrastructural changes (numerical density, N_A,surface density, Sv and volume density, Vv) of Gray type 1 synapses in CA3 region of the hippocampus were observed by using transmission electronic microscope and automatic image analysis system. Results: 1) Place navigation test showed that in comparison with control group, the average escape latency of VD group was significantly longer (P<0.01), while in comparison with VD group, the latencies of both EA and medication groups decreased significantly (P<0.01). No significant difference was found between EA and medication groups in the escape latency (P>0.05). 2) Spatial probe-test displayed that in comparison with control group, the times which the animals crossed the target platform in VD group decreased significantly (P<0.01), while compared with VD group, those of both EA and medication groups increased considerably (P<0.01). No significant differences were found between EA and medication groups in the times for rats to cross the target quadrant and among the 4 groups in the times for rats to cross the other quadrants. 3) Compared with control group, N_A, Sv, and Vv of VD group decreased significantly (P<0.01), while in comparison with VD group, the 3 indexes of both EA and medication groups increased significantly (P<0.01), no significant differences were found between EA and medication groups in these 3 indexes (P>0.05). Conclusion: EA can restrain the loss of Gray type Ⅰsynapses in CA3 region of the hippocampus to improve learning and memory abilities in VD rats.

Periodic oscillation and fine structure of wedge-induced oblique detonation waves

An oblique detonation wave for a Mach 7 inlet flow over a long enough wedge of 30 turning angle is simulated numerically using Euler equation and one-step rection model.The fifth-order WENO scheme is adopted to capture the shock wave.The numerical results show that with the compression of the wedge wall the detonation wave front structure is divided into three sections：the ZND model-like strcuture,single-sided triple point structure and dual-headed triple point strucuture.The first structure is the smooth straight,and the second has the characteristic of the triple points propagating dowanstream only with the same velocity,while the dual-headed triple point structure is very complicated.The detonation waves facing upstream and downstream propagate with different velocities,in which the periodic collisions of the triple points cause the oscillation of the detonation wave front.This oscillation process has temporal and spatial periodicity.In addition,the triple point trace are recorded to obtain different cell structures in three sections.

MICROSTRUCTURE TRANSFORMATION IN THE WELDING HEAT AFFECTED ZONE OF 800MPa GRADE ULTRA FINE STRUCTURED STEEL

The transformation behavior and microstructure development in the heat affected zone(HAZ)of 800MPa grade ultra fine structured steel was investigated.It was found that the HAZ has intermediate temperature transformation characteristics in a wide range of cooling rates,with the bainite sheaves consisting of bainite ferrite plates without carbide precipitation and retained austenite in the fast cooling regime.At relatively high cooling rates,which corresponded to low heat inputs,the hardness of the simulated HAZ was above that of the base metal.When the cooling rate was below 9C/s,the welding HAZ would have an obvious softening.The analysis of transformation rates in continuous cooling processes was completed by numerical differential method.The result indicated that the microstructure transformation rate of the HAZ in 800MPa grade ultra fine structured steel changed sharply to slow speeds when the cooling time t8/5 is longer than 7s.

Isolation Enhancement in a Compact Four-Element MIMO Antenna for Ultra-Wideband Applications

Mutual coupling reduction or isolation enhancement in antenna arrays is an important area of research as it severely affects the performance of an antenna.In this paper,a new type of compact and highly isolated Multiple-Input-Multiple-Output(MIMO)antenna for ultra-wideband(UWB)applications is presented.The design consists of four radiators that are orthogonally positioned and confined to a compact 40×40×0.8 mm3 space.The final antenna design uses an inverted L shape partial ground to produce an acceptable reflection coefficient(S11<−10 dB)in an entire UWB band(3.1–10.6)giga hertz(GHz).Moreover,the inter-element isolation has also been enhanced to>20 db for majority of the UWB band.The antenna was fabricated and tested with the vector network analyzer(VNA)and in an anechoic chamber for scattering parameters and radiation patterns.Furthermore,different MIMO diversity performance metrics are also measured to validate the proposed model.The simulation results and the experimental results from the constructed model agree quite well.The proposed antenna is compared with similar designs in recently published literature for various performance metrics.Because of its low envelope correlation coefficient(ECC<0.1),high diversity gain(DG>9.99 dB),peak gain of 4.6 dB,reduced channel capacity loss(CCL<0.4 b/s/Hz),and average radiation efficiency of over 85%,the proposed MIMO antenna is ideally suited for practical UWB applications.

Continental- Margin Structure of Northeast China and Its Adjacent Areas

The continental margin of Northeast China and its adjacent areas is composed of two tectonic belts. The inner belt is a collage made up of fragments resulting from breakup of an old land with the north part related to the evolution of the Palaeo-Asian Ocean and the south part to the evolution of the Palaeo - Pacific Ocean. The outer belt is a Mesozoic terrane, which is a melange made up of fragments of the Late Palaeozoic to Early Mesozoic oceanic crust and the Late M esozoic trench accumulations.There existed another ocean-the Palaeo - Pacific Ocean during the period from the closing of the Palaeo-Asian Ocean to the opening of the modern Pacific Ocean or from the Devonian to Jurassic, and the ocean-floor spreading of the Palaeo - Pacific Ocean led to the formation of the above-mentioned tectonic belts. The development of the strike-slip fault system after the Late Jurassic and the formation of an epicontinental volcano -plutonic rock belt in the Late Cretaceous to Early Tertiary are attributed to the interaction between the modern Pacific plate and the Eurasian plate.

Synthesis and Structure of 2-Isobutyl-6-(2',4'-dichlorophenyl)imidazo[2,1-b]-1,3,4-thiadiazole

The crystal structure of the title compound, 2-isobutyl-6-(2?4?dichlorophenyl)- imidazo[2,1-b]-1,3,4-thiadiazole (C14H13Cl2N3S, Mr = 326.23), has been synthesized by the treatment of 2-amino-5-isobutyl-1,3,4-thiadiazole with a-chloroaceto-2,4-dichlorophenone and determined by single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group P21/n with a = 12.483(7), b = 8.420(4), c = 14.998(8) ? b = 105.770(10)? V = 1517.0(14) 3, Z = 4, Dc = 1.428 g/cm3, S = 0.902, m(MoKa) = 0.558 mm-1, F (000) = 672, R = 0.0579 and wR = 0.1186. The X-ray analytic results showed that all ring atoms in the imidazothiadiazole moiety are almost coplanar. The dihedral angel between the phenyl group and hetero-cycle is 16.8(0.2)?

敲除CISH敲入并IL-15显著增强NK细胞抗肿瘤活性的研究

背景白细胞介素(interleukin,IL)-15是调节自然杀伤细胞(natural killer cell,NK细胞)功能的关键细胞因子,而CISH可负向调控IL-15信号通路,从而影响NK细胞功能。靶向CISH基因和IL-15基因对NK细胞进行基因编辑,可增强NK细胞抗肿瘤活性。目的探讨CISH基因、IL-15基因对NK细胞的细胞毒性的影响。方法采用AsCas12a Ultra基因编辑工具敲除CISH基因,并敲入IL-15基因,对NK细胞进行基因编辑,并通过基因测序检测CISH基因敲除效率,采用ELISA检测IL-15的表达,用LDH检测基因编辑后的NK细胞对H358细胞系的杀伤活性,评估CISH基因敲除、IL-15基因敲入对NK细胞抗肿瘤功能的影响。结果与对照组相比,CISH基因敲除组和CISH基因敲除+IL-15基因敲入组杀伤效率显著增强[E∶T=2∶1组,34.57%±6.32%vs 71.40%±5.81%和69.23%±4.28%,P<0.001]。结论敲除CISH基因可上调IL-15信号通路,增强NK细胞抗肿瘤活性。

Symplectic analysis for elastic wave propagation in two-dimensional cellular structures

On the basis of the finite element analysis, the elastic wave propagation in cellular structures is investigated using the symplectic algorithm. The variation principle is first applied to obtain the dual variables and the wave propagation problem is then transformed into two-dimensional （2D） symplectic eigenvalue problems, where the extended Wittrick-Williams algorithm is used to ensure that no phase propagation eigenvalues are missed during computation. Three typical cellular structures, square, triangle and hexagon, are introduced to illustrate the unique feature of the symplectic algorithm in higher-frequency calculation, which is due to the conserved properties of the structure-preserving symplectic algorithm. On the basis of the dispersion relations and phase constant surface analysis, the band structure is shown to be insensitive to the material type at lower frequencies, however, much more related at higher frequencies. This paper also demonstrates how the boundary conditions adopted in the finite element modeling process and the structures＇ configurations affect the band structures. The hexagonal cells are demonstrated to be more efficient for sound insulation at higher frequencies, while the triangular cells are preferred at lower frequencies. No complete band gaps are observed for the square cells with fixed-end boundary conditions. The analysis of phase constant surfaces guides the design of 2D cellular structures where waves at certain frequencies do not propagate in specified directions. The findings from the present study will provide invaluable guidelines for the future application of cellular structures in sound insulation.

超深层逆冲推覆构造致密砂岩储层地应力场扰动特征——以塔里木盆地博孜-大北地区白垩系储层为例

塔里木盆地库车坳陷博孜—大北地区白垩系致密砂岩储层在由北向南的逆冲推覆下,发育了一系列大规模的北倾断层和叠瓦状堆叠的褶皱构造。复杂的构造形貌致使该区地应力复杂多变,储层改造效果差异明显。因此,亟需厘清研究区内复杂构造对地应力的扰动特征。结合多种方法对单井现今地应力的精确解释,分别分析断裂、褶皱和断褶复合构造对地应力的扰动效果,明确了相关扰动机理,并绘制了研究区地应力扰动特征分区图。基于扰动特征,绘制了不同构造的地应力扰动特征模式图,并提出井位、井轨迹建议。断裂对地应力有卸载作用,断裂附近水平主应力梯度出现不同程度的降低,其中最大水平主应力梯度降低约0.3 MPa/hm;近EW走向的断裂使得近SN向的区域应力方向发生顺时针偏转,偏转角度最大达60°;不同规模断裂的扰动范围为断距的60%。当地层曲率超过0.4 km^(-1)时,褶皱对地应力存在扰动,褶皱地层上部张性扰动区地应力较区域应力减小,下部挤压扰动区地应力增加;张性扰动区最大水平主应力梯度最大约降低0.3 MPa/hm,地应力方向逆时针偏转,偏转角度最大达70°;褶皱变形曲率越大,张性扰动区厚度越大,扰动越明显。断褶复合构造下,断裂扰动区和褶皱张性扰动区叠加会使得地应力进一步减小,地应力方向在两者扰动效果抵消后较区域应力偏转较小或不偏转。综合考虑储层改造难易程度和致密气富集特征,应优先于断褶复合构造带断裂和褶皱张性扰动叠合区部署钻井,建议钻深不超过褶皱中性面,水平井轨迹沿EW向设计。

Synthesis, Crystal Structure, Fluorescent Property and DFT Calculations of a New Zn(Ⅱ) Complex Based on 3-(2-Pyridyl)-5-(4-pyridyl)-1H-1,2,4-triazole

A new coordination compound Zn（2,4＇-bpt）2（H2O）（1） based on the versatile ligand 2,4＇-Hbpt（2,4？-Hbpt = 3-（2-pyridyl）-5-（4-pyridyl）-1H-1,2,4-triazole） was prepared by hydrothermal reactions. The structure of complex 1 has been characterized by X-ray single-crystal diffraction, elemental analysis, X-ray powder diffraction, IR spectrum analysis and thermogravimetric analysis. Single-crystal X-ray diffraction analysis indicates that the complex belongs to monoclinic system, space group C2/c with a = 23.877（3）, b = 0.7483（9）, c = 1.2492（2） A, b = 92.681（2）°, V = 2230.6（4） A^3, Z = 4, Dc = 1.572 g/cm^3, m = 1.143 mm^-1, Mr = 527.85 and F（000） = 1080. The final R = 0.0581 and wR = 0.0898 with I 〉 2s（I）. 1 is a 0D motif which is connected by hydrogen bonds to form a corrugated 1D pattern. In addition, 1 shows strong photoluminescent emissions in the solid state at room temperature which can be used as potential optical materials. Theoretical calculations based on density functional theory（DFT） were employed in order to explicate the stability and chemical reactivity of 2,4＇-Hbpt with different conformations. The results indicated that conformation I is more stable and prior to coordination in the reactions.