Effect of cooling rates on clustering towards icosahedra in rapidly solidified Cu_(56)Zr_(44) alloy

The rapid solidification processes of liquid Cu56Zr44 alloys at different cooling rates （γ） were simulated by a molecular dynamics （MD） method. In order to assess the influence of cooling rate on the clustering tendency and degree towards icosahedrons, a ten-indices＇ cluster-type index method was suggested to characterize the local atomic structures in the super-cooled liquid and the rapidly solidified solid. And their clustering and ordering degrees as well as the packing density of ieosahedral clusters were also evaluated by an icosahedral clustering degree （fI）, the chemical order parameter （ηαβ） and densification coefficients （D0, DI and DIS）, respectively. Results show that the main local atomic configurations in Cu56Zr44 alloy system are Z12 clusters centered by Cu, and most of which are （12 0 12 0 0 0 0 0 0 0） standard icosahedra and （12 0 8 0 0 0 2 2 0 0） as well as （12 2 8 2 0 0 0 0 0 0） defective icosahedra. Below glass transition temperature （Tg）, these icosahedral clusters will be coalesced to various icosahedral medium-range orders （IMROs） by IS linkages, namely, icosahedral bond, and their number N, size n, order parameter ηαβ as well as spatial distributions vary with y. As the cooling rate exceeds the critical value （γc） at which a glassy transition can take place, a lower cooling rate, e.g., γ1=10^1K/ns, is demonstrated to be favorable to uplift the number of icosahedra and enlarge the size of IMROs compared with the higher cooling rates, e.g., γ5=10^5 K/ns, and their packing density and clustering degree towards icosahedra in the rapidly solidified solid can also benefit from the slow cooling process.

Advanced run-out table cooling technology based on ultra fast cooling and laminar cooling in hot strip mill

In order to meet the severe requirements of market and reduce production costs of high quality steels,advanced run-out table cooling based on ultra fast cooling(UFC) and laminar cooling(LC) was proposed and applied to industrial production.Cooling mechanism of UFC and LC was introduced first,and then the control system and control models were described.By using UFC and LC,low-cost Q345B strips had been produced in a large scale,and industrial trials of producing low-cost dual phase strips were completed successfully.Application results show that the ultra fast cooling is uniform along the strip width and length,and does not affect the flatness of strips.The run-out table cooling system runs stably with a high precision,and makes it possible for the user to develop more high quality steels with low costs.

Control and application of cooling path after rolling for hot strip based on ultra fast cooling

Hot rolled strip requires diverse and flexible control of cooling path in order to take full advantages of strengthening mechanisms such as fine grain strengthening, precipitation strengthening, and transformation strengthening, adapting to the development of advanced steel materials and the requirement of reduction-manufacturing. Ultra fast cooling can achieve a great range of cooling rate, which provides the means that the hardened austenite obtained in high temperature region can keep at different dynamic transformation temperatures. Meanwhile, through the rational allocation of the UFC （ultra fast cooling） and LFC （laminar flow cooling）, more flexible cooling path control and cooling strategy of hot rolled strip are obtained. Temperature distribution and control strategies under different cooling paths based on UFC are investigated. The process control temperature can be limited within 18 ℃, and the mechanical properties of the steels get a great leap forward due to the cooling paths and strategies, which can decrease costs and create great economic benefits for the iron and steel enterprises.

Microstructure and texture evolution of fine-grained Mg-Zn-Y-Nd alloy micro-tubes for biodegradable vascular stents processed by hot extrusion and rapid cooling

Magnesium alloys have narrow available slip result from close-packed hexagonal structure that limit their processing properties.In the recent work,the Mg-2Zn-0.46Y-0.5Nd,as materials for degradable stents,was applied to produce as-extruded micro-tube with an outer diameter of 3.0mm and a wall thickness of 0.35mm by hot extrusion with an extrusion ratio of 105:1 at 653K and rapid cooling.The fine microstructure of the dynamic recrystallization of as-extruded micro-tube could be preserved by rapid cooling such as water-cooled,resulting in more excellent mechanical properties relative to air-cooled micro-tube.The addition of rare earth elements Y and Nd results in continuous dynamic recrystallization dominated the dynamic recrystallization mechanism.During the hot extrusion process,the activation of the non-basal slip system,especially the pyramidal(c+a)slip,could significantly weaken the texture strength,and the as-extruded micro-tube exhibits weak"RE"texture components(011^(-)1)||ED and(1^(-)21^(-)1)||ED.Hence,the magnesium alloy micro-tube prepared by the rapid cooling has fine microstructure and weak texture,which is favorable for further process and governance.

Precipitation Behavior of Nb in Steel under Ultra Fast Cooling Conditions

By measuring the expansion curves of a Nb bearing steel at different cooling rates by using Gleeble-3800 thermomechanical simulator, combining with metallographic analysis, different phase zones were determined. Also, precipitation behavior of Nb at different phase zones was investigated under ultra fast cooling conditions. The experimental results showed that adopting a proper deformation temperature, the ultra fast cooling process can restrain the precipitation of Nb at austenite phase zone. More quantities and smaller size precipitates of Nb can be found at the ferrite or bainite phase zone by controlling the ultra fast cooling ending temperature. With the increase of holding time at austenite, ferrite and bainite phase zones respectively, the volume fraction of precipitation, density, and average size of precipitates will increase obviously. With the decrease of early ultra fast cooling ending temperature, the density of Nb precipitates first increase（at ferrite phase zone） and then decrease（at bainite phase zone）, the volume fraction of Nb precipitation decreases and precipitates can be refined. The optimal early ultra fast cooling ending temperature is located at ferrite phase zone. The combination of high rolling temperature with early ultra fast cooling technology opens the way for new cooling schedules and makes the production of high strength steels easier and cheaper by making full use of Nb precipitation strengthening effect.

Ultra Fast Spray Cooling and Critical Droplet Daimeter Estimation from Cooling Rate

Spray cooling is an effective tool to dissipate high heat fluxes from hot surfaces. This paper thoroughly investigates the effects of spray parameters on the cooling time and cooling rate under varying inlet pressure using water as the coolant. Cylindrical samples of stainless steel with constant diameter, D = 25 mm, and thickness δ: 8.5 mm, 13 mm, 17.5 mm and 22 mm were investigated. Critical droplet diameter to achieve an ultrafast cooling rate of 300°C/s was estimated by using analytical model for samples of varying thickness. At an inlet pressure of 0.8 MPa, maximum cooling rates of 424.2°C/s, 502.81°C/s and 573.1°C/s were achieved for wall super heat ΔT = 600°C, 700°C and 800°C respectively.

Liquid phase separation of Cu-Cr alloys during rapid cooling

The ribbons of Cu-Cr alloys with high Cr content (15%- 35%, mass fraction) were prepared by rapid solidification. The microstructures of solidified samples were analyzed by scanning electron microscopy and transmission electron microscopy. The results reveal that a representative liquid phase separation microstructures are observed in Cu75Cr25 ribbons solidified at a cooling rate of about 104K/s. The liquid phase separation is not restrained when the cooling rate is enhanced to about 107K/s. However, the size of Cr particles solidified from Cr-rich liquid or Cr-rich regions in alloy melts could be refined by increasing the cooling rates. The size of Cr particles increases with increasing Cr contents when the ribbons contain 15% to 35%Cr.

Case-Based Reasoning(CBR) Model for Ultra-Fast Cooling in Plate Mill

New generation thermo-mechanical control process（TMCP） based on ultra-fast cooling is being widely adopted in plate mill to product high-performance steel material at low cost. Ultra-fast cooling system is complex because of optimizing the temperature control error generated by heat transfer mathematical model and process parameters. In order to simplify the system and improve the temperature control precision in ultra-fast cooling process, several existing models of case-based reasoning（CBR） model are reviewed. Combining with ultra-fast cooling process, a developed R5 CBR model is proposed, which mainly improves the case representation, similarity relation and retrieval module. Certainty factor is defined in semantics memory unit of plate case which provides not only internal data reliability but also product performance reliability. Similarity relation is improved by defined power index similarity membership function. Retrieval process is simplified and retrieval efficiency is improved apparently by windmill retrieval algorithm. The proposed CBR model is used for predicting the case of cooling strategy and its capability is superior to traditional process model. In order to perform comprehensive investigations on ultra-fast cooling process, different steel plates are considered for the experiment. The validation experiment and industrial production of proposed CBR model are carried out, which demonstrated that finish cooling temperature（FCT） error is controlled within±25℃ and quality rate of product is more than 97%. The proposed CBR model can simplify ultra-fast cooling system and give quality performance for steel product.

The development and application of ultra fast cooling in hot-rolled

Ultra fast cooling is a new technology which used to control the hot-rolling strip cooling in recent years on the international developed.If suitably cooperated with a number of other new controlled rolling technologies,can achieve fast and accurate temperature control in the hot-rolled strip production process to obtain corresponding transformation microstructure and ideal mechanical properties.This article describes the technical principle and layout of ultra fast cooling in hot-rolled as well as application profiles in the major iron and steel enterprise in China and abroad.Carried out the layout of ultra fast cooling analysis on the adaptability of steel that install between the finishing mill and laminar cooling,on this basis,proposed the use of ultra fast cooling technology proposals.

New research developments on ultra fast cooling technologies and new generation TMCP

Since the 21^(st) century,great attention has been paid to ultra fast cooling(UFC) technology in the whole world.The industries and the research institutions began to carry out investigations on basic theories and industrial applications.Since 2003,the RAL of Northeastern University has made some progresses on microstructure control theories,understanding of strengthening mechanisms and their industrial applications.In this paper,these achievements since the last Baosteel BAC in 2008 will be reported on the industrialization of UFC, strengthening mechanism,development of new steel grades,and so on.

Microstructure and Mechanical Properties of Nb-B bearing Low Carbon Steel Plate: Ultrafast Cooling versus Accelerated Cooling

The microstructure and mechanical properties of low carbon bainite high strength steel plate were studied via different cooling paths at the pilot scale. There was a significant increase in mechanical properties, and notably, the yield strength, tensile strength, and toughness at-40 ℃ for the tested steel processed by ultra-fast cooling were 126 MPa, 98 MPa and 69 J, respectively, in relation to steel processed by accelerated cooling. The ultra-fast cooling rate not only refined the microstructure, precipitates, and martensiteaustenite（M/A） islands, but also contributed to the refinement of microstructure in thick plates. The large size M/A constituents formed at lower cooling rate experienced stress concentration and were potential sites for crack initiation, which led to deterioration of low-temperature impact toughness. In contrast, the acicular ferrite and lath bainite with high fraction of high-angle grain boundaries were formed in steel processed by ultra-fast cooling, which retarded cleavage crack propagation.

Microstructural Transformation and Precipitation of an Ultra-high Strength Steel under Continuous Cooling

We investigated phase transition and precipitation of ultra-high strength steel（UHSS）in a new ＂short process＂ with controlled rolling and controlled cooling.Thermalexpansion test combined with metallographic observation was used to research the continuous cooling transformation（CCT）curve.Moreover,the microstructuraltransformation and precipitation law was revealed by morphologicalobservation and alloying elements by electron probe micro-analyzer（EPMA）.Transmission electron microscopy（TEM）was utilized to analyze the composition and grain orientation of microstructure.The study showed that the measured criticaltransformation temperatures of Ac1 and Ac3 were 746 and 868 ℃,respectively.The CCT curve indicated that the undercooled austenite was transformed into proeutectoid ferrite and bainite with HV 520 in a broad range of cooling rate 0.1^（-1） ℃·s^（-1）.When subjected to a cooling rate of 1 ℃·s^（-1）,the undercooled austenite was divided into small-sized blocks by formed martensite.With further increase of cooling rate,micro-hardness increased dramatically,the microstructure of specimen was mainly lathe bainite（LB）,granular bainite（GB）,lath martensite（LM）and residualaustenite.By diffraction test analysis,it was identified that there was K-S orientation relationship between martensite and austenite for {110}_α//{111}_γ,{111}_α//{101}_γ.EPMA clearly showed that carbon diffused adequately due to staying for a long time at high temperature with a lower cooling rate of 2 ℃·s-1.Phase transition drive force was lower and the residualaustenite existed in the block form of Martensite austenite island（M-A）.With the increase of cooling rate to 10 ℃·s^（-1）,the block residualaustenite reduced,the carbon content of residualaustenite increased and α phase around the residualaustenite formed into a low carbon bainite form.

Comparative Study of Tensile and Charpy Impact Properties of X70 and X80 Linepipe Steels After Ultra Fast Cooling Processing

Ultra fast cooling（UFC） processing after hot deformation was conducted on X70 and X80 linepipe steels. Tensile and charpy impact properties of both steels have been investigated in this work. The results have shown that the mechanical properties satisfy all the standard requirements of the X70 and X80 steels. UFC results in a presence of microstructure containing quasi polygonal（QF）, acicular ferrite（AF） and granular bainite（GB）. The alloying elements and UFC enhance the strengthening contribution caused by solid solution, dispersion, dislocation and precipitation strengthening. The size and distribution of precipitates in the linepipe steels are fine and dispersed. MA is also homogeneously dispersed due to UFC. Average grain size in the X80 steel is finer than that in the X70 steel. The volume fractions of secondary phases in the X80 steel are greater than those in the X70 steel. The X80 steel remains finer and more dispersed precipitates compared to the X70 steel. As a result, the tensile properties of X80 steel are higher than those of X70 steel. The Charpy absorbed energies of X70 and X80 steels at-10 ℃ reached 436 and 460 J, respectively. They reached 433 and 461 J at-15 ℃, respectively. This is mainly attributed to the presence of larger amounts of AFs in the X80 steel. A microstructure of AF for the X80 steel results in combining high strength and high toughness.

Study on temper-rapid cooling process of low carbon steel produced by CSP

On the basis of the effect of carbon precipitation on the microstructure and properties of steel products below At temperature, a new thermal treatment method （temper-rapid cooling process） was studied. By the temper-rapid cooling process, the yield strengths of the high strength low carbon （HSLC） steel ZJ330 and SPA-H produced using the compact strip production （CSP） process increased from 340 to about 410 MPa and from 410 to about 450 MPa, respectively. The results indirectly indicated that there existed nanoscaled iron-carbon precipitates that have obvious precipitation effect on low carbon steel produced by CSP. The prospect of application is discussed.

Nozzle Spray Diffusivity Changing Law for Ultra Fast Cooling in Hot Strip Mill

Slot nozzle and intensive nozzle can be used in ultra fast cooling equipment. The spray cooling method with higher water pressure can be taken in order to achieve ultra fast cooling for hot rolled strip. Water will be diffused after it is sprayed out from ultra fast cooling nozzle. Spray diffusivity will affect water velocity and penetrability of water into residual water layer on top of the strip,and then it will affect strip cooling effect. Water spraying process can be simulated by Fluent and some conclusions were obtained. Slot nozzle width and outlet velocity within setting range could not affect the length of potential core zone and the spray diffusivity. Intensive nozzle diameter and outlet velocity will affect the length of potential core zone and the spray diffusivity with different extent. These conclusions will provide referenced role for confirming ultra fast cooling nozzle size and distance between ultra fast cooling nozzle and hot rolled strip.

The mechanics and deformation of high temperature steel frame rapidly cooled by spray water in fire fighting

A finite element is established for analyzing the dynamical mechanics and deformation of steel frame at high temperature when it is rapidly cooled down by spray water in fire fighting, The simulation result shows that remarkable mechanical coupling effects are produced in the process, and the sectional stress in rapid cooling down is found considerably larger than that in heating-up. Meanwhile, the stress and deformation of a beam mainly related to cooling rate and location are much larger than those of a column in rapid cooling, In fire fighting, the structure on the first or second floor was more dangerous than those on other floors in rapid cooling, These results could provide a theoretical reference for the design of steel structure and fire fighting.

Mathematic modeling on flexible cooling system in hot strip mill

A novel cooling system combining ultra fast cooling rigs with laminar cooling devices was investigated.Based on the different cooling mechanisms,a serial of mathematic models were established to describe the relationship between water flow and spraying pressure and the relationship between water spraying heat flux and layout of nozzles installed on the top and bottom cooling headers.Model parameters were validated by measured data.Heat transfer models including air convection model,heat radiation model and water cooling capacity model were detailedly introduced.In addition,effects on cooling capacity by water temperature and different valve patterns were also presented.Finally,the comparison results from UFC used or not have been provided with respect to temperature evolution and mechanical properties of Q235B steel grade with thickness of 7.8 mm.Since online application of the sophisticated CTC process control system based on these models,run-out table cooling control system has been running stably and reliably to produce resource-saving,low-cost steels with smaller grain size.

STABILITY OF MICROSTRUCTURES DURING COOLING PROCESSES OF Al LIQUID METAL

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Cycle Time Reduction in Injection Molding by Using Milled Groove Conformal Cooling

This paper presents simulation study on Milled Grooved conformal cooling channels(MGCCC)in injection molding.MGCCC has a more effective cooling surface area which helps to provide efficient cooling as compared to conventional cooling.A case study of Encloser part is investigated for cycle time reduction and quality improvement.The performance designs of straight drilled are compared with MGCCC by using Autodesk Moldflow Insight(AMI)2016.The results show total 32.1% reduction of cooling time and 9.86% reduction of warpage in case of MGCCC as compared to conventional cooling.

Rapid Screening of 26 Organophosphorus Pesticides in Fresh Milk by Ultra Liquid Chromatography Coupled With Quadrupole-Time of Flight Mass Spectrometry

[Objectives]A rapid screening and analysis method for 26 organophosphorus agrochemicals in fresh milk was established using ultra performance liquid chromatography coupled with quadrupole-time of flight mass spectrometry.[Methods]Raw milk was extracted with acetonitrile solution containing 0.2%formic acid by volume,and purified with a Dikma ProElut QuECHERS solid phase extraction cartridge.Target compounds were separated on a Waters ACQUITY UPLC HSS T3 chromatographic column(2.1 mm×50 mm,1.8μm)with methanol-water solution as a mobile phase for gradient elution,and through scanning with an electrospray ion source in positive ion mode,26 kinds of organophosphorus agrochemicals could be accurately qualitatively determined within 10 min.[Results]When using formic acid acetonitrile with a volume fraction of 0.2%,there were more types of detected compounds and a greater recovery;and using B cartridge could effectively eliminate the interference of non-polar substances such as phospholipids,achieve higher number of detected compounds than those of A and C,and well separate the 26 kinds of agrochemical residues.[Conclusions]This study provides a reference method for the rapid screening of agrochemical residues in dairy cows in the future.