Effects of gravel on the water absorption characteristics and hydraulic parameters of stony soil

The eastern foothills of the Helan Mountains in China are a typical mountainous region of soil and gravel,where gravel could affect the water movement process in the soil.This study focused on the effects of different gravel contents on the water absorption characteristics and hydraulic parameters of stony soil.The stony soil samples were collected from the eastern foothills of the Helan Mountains in April 2023 and used as the experimental materials to conduct a one-dimensional horizontal soil column absorption experiment.Six experimental groups with gravel contents of 0%,10%,20%,30%,40%,and 50%were established to determine the saturated hydraulic conductivity(K_(s)),saturated water content(θ_(s)),initial water content(θ_(i)),and retention water content(θ_(r)),and explore the changes in the wetting front depth and cumulative absorption volume during the absorption experiment.The Philip model was used to fit the soil absorption process and determine the soil water absorption rate.Then the length of the characteristic wetting front depth,shape coefficient,empirical parameter,inverse intake suction and soil water suction were derived from the van Genuchten model.Finally,the hydraulic parameters mentioned above were used to fit the soil water characteristic curves,unsaturated hydraulic conductivity(K_(θ))and specific water capacity(C(h)).The results showed that the wetting front depth and cumulative absorption volume of each treatment gradually decreased with increasing gravel content.Compared with control check treatment with gravel content of 0%,soil water absorption rates in the treatments with gravel contents of 10%,20%,30%,40%,and 50%decreased by 11.47%,17.97%,25.24%,29.83%,and 42.45%,respectively.As the gravel content increased,inverse intake suction gradually increased,and shape coefficient,K_(s),θ_(s),andθ_(r)gradually decreased.For the same soil water content,soil water suction and K_(θ)gradually decreased with increasing gravel content.At the same soil water suction,C(h)decreased with increasing gravel content,and the water use efficiency worsened.Overall,the water holding capacity,hydraulic conductivity,and water use efficiency of stony soil in the eastern foothills of the Helan Mountains decreased with increasing gravel content.This study could provide data support for improving soil water use efficiency in the eastern foothills of the Helan Mountains and other similar rocky mountainous areas.

Determination of Ultratrace Amounts of Copper(Ⅱ) in Water Samples by Electrothermal Atomic Absorption Spectrometry After Cloud Point Extraction

A novel approach was developed for the determination of ultratrace amounts of copper in water samples by using electrothermal atomic absorption spectrometry （ETAAS） after cloud point extraction （ CPE ）. 1-（ 2-Pyridylazo ） -2- naphthol was used as the chelating reagent and Triton X-114 as the mieellar-forming surfactant. CPE was conducted in a pH 8. 0 medium at 40 ℃ for 10 rain. After the separation of the phases by contrifugafion, the surfactant-rieh phase was diluted with 1 mL of a methanol solution of 0. 1 mol/L HNO3. Then 20μL of the diluted surfactant-rieh phase was injected into the graphite furnace for atomization in the absence of any matrix modifier. Various experimental conditions that affect the extraction and atomization processes were optimized. A detection limit of 5 ng/L was obtained after preconeentration. The linear dynamic range of the copper mass concentration was found to be 0-2.0 ng/mL, and the relative standard deviation was found to be less than 3. 1% for a sample containing 1.0 ng/mL Cu （ Ⅱ ）. This developed method was successfully applied to the determination of uhratraee amounts of Cu in drinking water, tap water, and seawater samples.

A new algorithm of retrieving a petroleum substances absorption coefficient in sea water based on a remote sensing image

Establishing the remote sensing algorithm of retrieving the absorption coefficient of seawater petroleum substances is an efficient way to improve the accuracy of retrieving a seawater petroleum concentration using a remote sensing technology. A remote sensing reflectance is a basic physical parameter in water color remote sensing. Apply it to directly retrieve the absorption coefficient of seawater petroleum substances is of potential advantage. The absorption coefficient of waters containing petroleum [ACWCP, a_o（λ）], consists of the absorption coefficient of pure water [ACPW, a_w（λ）], plankton [ACP, a_（ph）（λ）], colored scraps [ACCS, a_（d,g）（λ）], and petroleum substance [ACPS, a_（oil）（λ）]. Among those, ACCS consists of the absorption coefficient of nonalgal particle [ACNP, a_d（λ）] and colored dissolved organic matter [ACCDOM, a_g（λ）]. For waters containing petroleum, the retrieved ACCS using the existing method is a combination absorption coefficient of ACNP,ACCDOM and ACPA [CAC, a_（d,g,oil）（λ）]. Therefore, the principle question is how to extract ACPS from CAC.Through the analysis of the three proportion tests conducted between the year of 2013 and 2015 and the corresponding remote sensing data, an algorithm of retrieving the absorption coefficient of petroleum substances is proposed based on remote sensing reflectance. First of all, ACPS and CAC are retrieved from the reflectance using the quasi-analytical algorithm（QAA）, with some parameter modified. Secondly, given the fact that the backscatter coefficient [BC, b_（bp）（555）] of total particles at 555 nm can be obtained completely from the reflectance, the relation between BC and ACNP in petroleum contaminated water can be established. As a result, ACNP can be calculated. Then, combining the remote sensing retrieving algorithm of a_g（440）, the method of achieving the spectral slope of the absorption coefficient can be established, from which ACCDOM,can be calculated. Finally, ACPS can be computed as the residual. The accuracy of ACPS based on this algorithm is 86% compared with the in situ measurements.

A study on water absorption in freestanding polyurethane films filled with nano-TiO_2 pigments by capacitance measurements

The electrochemical impedance spectroscopy （EIS） was used to evaluate the water transport and dielectric properties of polyurethane films filled with nano-TiO2 at different pigment/base （P/B） values in 0.5 mol/L NaCl solutions. EIS results were compared with gravimetric measurements on the freestanding films. The amount of water absorption showed great discrepancy between the two methods. The diffusion coefficient in the polyurethane film with P/B：30% was the smallest among those filled with nano-TiO2 pigments. The dielectric constant ε of the polyurethane varnish film obtained from the initial capacitance was in the range of typical values of polymers. SEM was used to measure the distribution of nano-TiO2 particles in the polyurethane films.

Influencing factors and mechanism of water absorption process of iron ores during sintering

The appropriate content and distribution of sinter moisture play an important role in the granulation of iron ores. In this study, the effects of porosity, size distribution, and particle shape on the water absorption rate （WAR） of four types of iron ores were analyzed by using the immersion method and capillary water absorption method. In addition, the mechanism underlying the water absorption process in iron ores was unraveled. It is found that the WARs of iron ores decrease quickly with the increase in water absorption time at the initial stages of water absorption. With further increase in absorption time, the WARs decrease gradually, until near 0. Iron ores with higher porosity, smaller particle size, and plate-like structure have the higher WARs. Compared with pores in the single-particle iron ore, voids among particles in the multi-particle iron oxide play an important role at the initial stages of water absorption. The water absorption mechanism of all single-particle and multi-particle iron ores analyzed in this study includes four steps, wherein the first three steps play a significant role in the sintering pro-cess.

Effect of Water Vapor Absorption on Measurements of Atmospheric Nitrate Radical by LP-DOAS

During the measurement of atmospheric nitrate radical by long-path differential optical absorption spectroscopy, water vapor strong absorption could affect the measurement of nitrate radical and detection limits of system. Under the tropospheric condition, the optical density of water vapor absorption is non-linearly dependent on column density. An effective method was developed to eliminate the effect of water vapor absorption. Reference spectra of water vapor based on the daytime atmospheric absorption spectra, when fitted together with change of cross section with water vapor column densities, gave a more accurate fitting of water vapor absorptions, thus its effect on the measurements of nitrate radical could be restricted to a minimum and detection limits of system reached 3.6 ppt. The modified method was applied during an intensive field campaign in the Pearl River Delta, China. The NO3 concentration in polluted air masses varied from 3.6 ppt to 82.5 ppt with an average level of 23.6±1.8 ppt.

Research on the coefficient of sound absorption in turbid water

China’s coastal waters are turbid and the properties of the seabed are complex. This negatively impacts the performance of underwater detection equipment. The properties of sound absorption in turbid water are not well understood. In this paper, the coefficient of sound absorption in turbid water was measured by the reverberation technique. All work was done in a reverberation barrel made of seamless aluminum. First, pure water was poured into the reverberation barrel and its reverberation time measured. Next, various concentrations of turbid water were poured into the barrel and their reverberation time measured. After all data had been gathered, the coefficient of sound absorption in turbid water of different concentrations was calculated. From this we determined a law of sound absorption in turbid water as summarized in the paper.

Effect of water absorption ratio on tensile strength of red sandstone and morphological analysis of fracture surfaces

Brazilian disc tests were undertaken on a number of red sandstone samples with different water absorption ratios.The tensile strength of the red sandstone decreases as the water absorption ratio increases.The fracture surfaces of failed red sandstone discs were scanned by Talysurf CLI 2000.With the aid of Talymap Gold software,based on ISO25178,a set of statistical parameters was obtained for the fracture surfaces.The maximum peak height(S_p),maximum pit height(S_v) and maximum height(S_z) of the fracture surfaces exhibited the same decreasing trend with increasing water absorption.Sa and Sku values for the fracture surfaces showed a downward trend as the water absorption ratio increased.The fractal dimensions of fracture surfaces were calculated and found to decrease as the water absorption ratio increased.Through analysis of PSD curves,the smallest dominant wavelength was observed to reflect the roughness of the fracture surfaces.Additionally,the results suggest that the roughness of fracture surfaces becomes small as the water absorption ratio increases.

Analytical Methods for Prediction of Water Absorption in Cement-Based Material

The capillary absorption of water by unsaturated cement-based material is the main reason of degradation of the structures subjected to an aggressive environment since water often acts as the transporting medium for damaging contaminants. It is well known that the capillarity coefficient and sorptivity are two important parameters to characterize the water absorption of porous materials. Generally, the former is used to describe the penetration depth or height of water transport, which must be measured by special and advanced equipment. In contrast, the sorptivity represents the relationship between cumulative volume of water uptake and the squareroot of the elapsed time, which can be easily measured by the gravimetric method in a normal laboratory condition. In the present study, an analytical method is developed to build up a bridge between these two parameters, with the purpose that the sorptivity or the gravimetric method can be used to predict the penetration depth of water absorption. Additionally, a new model to explain the dependence of sorptivity on initial water content of the material is developed in order to fit the in situ condition. The comparison of predicted results by the analytical method with experimental data or numerical calculation results, as well as some previous models, validates the feasibility of the methods presented in this paper.

Effect of Soaking Temperature on Water Absorption Characteristics of Selected Ghanaian Cowpea Varieties

The water absorption kinetics of three cowpea varieties (Asontem, Hewale and Asomdwee) was studied following the phenomenological models derived from Fick’s law of diffusion. Soaking of seeds from each cowpea variety was carried out for 10 h at four temperatures (30°C, 40°C, 50°C and 60°C). The saturation moisture content was higher for Asontem (106.9 g water/1000 g dry weight) and Hewale varieties (108.7 g water/1000 g dry weight) and lower for Asomdwee hybrid (100.7 g water/1000 g dry weight), respectively. The proposed Fick’s law of diffusion satisfactorily described the kinetics of water absorption regardless of the variety and temperature. The estimated values for water diffusion coefficient for Asontem, Hewale and Asomdwee varied from 5.12 × 10-10 m2/s to 6.64 × 10-10 m2/s, 3.96 × 10-10 m2/s to 5.12 × 10-10 m2/s, 4.93 × 10-10 m2/s to 6.08 × 10-10 m2/s, respectively. The strong influence of temperature on the water diffusion coefficient was adequately described by an Arrhenius-type equation with activation energy values for Asontem, Hewale and Asomdwee as 7.27 kJ/mol, 7.26 kJ/mol and 6.26 kJ/mol, respectively.

Characterization of Water Constituents Spectra Absorption in Chagan Lake of Jilin Province, Northeast China

Research on the optical characteristics of water color constituents in Chagan Lake of Jilin Province,Northeast China was carried out in order to investigate the variability of the spectra absorption parameters as inputs to bio-optical models and remote sensing algorithms for converting observed spectral signals into water quality information.Samples of total particulates,non-algal particles and colored dissolved organic matter (CDOM) were first prepared by quantitative filter technique (QFT) and then absorption coefficients of these color producing agents were determined by spectrophotometry.Spectral characteristics of absorption coefficients by total particulate matter,spectral specific absorption dependency on chlorophyll concentration (Chl-a) of phytoplankton,spectral absorption slopes variation for CDOM and non-algal particles and their corresponding reasons were examined and clarified over five months of 2009 and 2010 in this study.Results suggest that total particulate spectral absorption in Chagan Lake is mainly dominated by non-algal particles in most cases,but phytoplankton could be the dominant contributor when chlorophyll concentration is high (up to 84.48 mg/m3 in autumn 2010).The specific absorption coefficients of phytoplankton particulate (a*ph(λ)) dependency on Chl-a is significantly variable due to relative contributions of package effect and accessory pigments,and the parameters of power function are clearly biased on a long time span.The sources of variability in spectral absorption slopes of CDOM and non-algal particles are mainly attributed to the changing proportions of high molecular weight humic acids and mineral suspended sediments in waters,respectively.

Speciation of Dissolved Trace Nickel in Environmental Waters by On-Line Sonodigestion-Flow Injection Solid Phase Extraction Coupled to Flame Atomic Absorption Spectrometry

A simple on-line sonodigestion system was successfully used for breakdown organic nickel complexes in environmental waters acidified with diluted nitric acid prior to flow injection total dissolved nickel preconcentration in a microcolumn containing a chelating resin (Chelite Che with iminodiacetic acid groups) and determination by flame atomic absorption spectrometry. For the determination of the dissolved labile nickel fraction, microcolumns packed with the chelating resin were loaded in-situ with the sample without sample pH modification, and once in the laboratory were inserted in the flow injection device where nickel elution-detection was carried out. The performance of the chelating resin was investigated in order to elucidate its behavior in the presence of dissolved nickel species. The results obtained reveal that the resin, at the experimental employed conditions, retained only dissolved free nickel ions and nickel bound to weak complexes (labile fraction). The figures of merit for determinations in both nickel fractions are given and the obtained values are discussed. The speciation scheme is applied to the analysis of nickel in river and seawater samples collected in Galicia (Northwest, Spain). The results of fractionation showed that Ni are mainly in the dissolved labile fraction in river water, while in seawater samples analyzed was mainly present in the organic fraction.

Simulation of Gas-Fired Triple-Effect LiBr/Water Absorption Cooling System with Exhaust Heat Recovery Generator

An exhaust heat recovery generator is proposed to be integrated with conventional gas-fired triple-effect LiBr/water absorption cooling cycles to improve system energy efficiency. As a case study, simulation of the novel cycle based on promising parallel flow with cooling capacity of 1 150 kW is carried out under various heat recovery generator vapor production ratios ranging from 0 to 3.5%. The life cycle saving economic analysis, for which the annual gas conservation is estimated with Bin method, is employed to prove the worthiness of extra expenditure. Results show that the optimum gas saving revenue is obtained at 2.8% heat recovery generator vapor production ratio with 42 kW exhaust heat recovered, and the system energy efficiency is improved from 1.78 to 1.83. The initial investment of exchanger can be paid back within 7 years and 9 000 CNY of gas saving revenue will be achieved over the 15-year life cycle of the machine. This technology can be easily implemented and present desirable economic effects, which is feasible to the development of triple-effect absorption cycles.

Synthesis,Characterization and Water Absorption Analysis of Highly Hygroscopic Bio-based Co-polyamides 56/66

This study aims to develop highly hygroscopic bio-based co-polyamides(CPs)by melt co-polycondensation of polyamide(PA)56 salt and PA66 salt with varying molar fractions.The functional groups and the chemical structure of the prepared samples were determined by Fourier transform infrared(FTIR)spectroscopy and proton nuclear magnetic resonance(^(1)H-NMR)spectroscopy.The relative viscosity was determined with an Ubbelohde viscometer.The melting behavior and the thermal stability of CPs were investigated by differential scanning calorimetry(DSC)and thermogravimetric analysis(TGA).Furthermore,the water absorption behavior of CP hot-pressed film was studied.The results reveal that the melting point,the crystallization temperature and the crystallinity of CPs firstly decrease and then increase with the molar fraction of PA66 in CPs.The copolymerization of PA56 with PA66 leads to an obvious increase in water absorption.The CPs with PA66 molar fraction of 50%possess a high saturated water absorption rate of 17.6%,compared to 11.6%for pure PA56 and 7.8%for pure PA66.

The Effect of Water Absorption on Mechanical Properties of Wood Flour/Wheat Husk Polypropylene Hybrid Composites

The main objectives of this research were to study the effect of water absorption on mechanical properties of hybrid fiber reinforcement for polypropylene composites. The poor resistance towards water absorption is one of the draw- backs of natural fibers. Hybrid filler-polypropylene composites are subjected to water immersion tests in order to study the effects of water absorption on the mechanical properties. Composites specimens containing 30 phr and 40 phr fiber weight were prepared by melt blending process. Water absorption tests were conducted by immersion specimens in distilled water at room temperature for different time durations (24, 48, 72, 96, 120, 144, 168, 192 hours). The tensile, flexural and impact properties were investigated before and after water absorption. The percentage of moisture uptake increased as the increasing order of the filler loading due to the high cellulose content. The phase morphology of wood flour/wheat husk polypropylene hybrid composites were investigated by SEM, the dynamic mechanical properties of the composite are analyzed by DMA & wheat, wood filler interaction are analyzed by FT-IR.

Water Absorption and Chloride Ion Penetrability of Concrete Damaged by Freeze-thawing and Loading

In order to investigate water and chloride ion transport in damaged concrete, three types of concrete were prepared, freeze-thawing（F-T） cycling and compressive loading were adopted to induce damage to concrete. Ultrasonic pulse velocity technique was used for evaluating the damage degree of concrete, and the defects of damaged concrete were also detected by X-CT. Water absorption and chloride ion penetrability were used for describing the transport properties of damaged concrete. Effects of damage degree on the water absorption rate and chloride ion penetrability were investigated in detail and the relationships were also established. The results show that the water absorption of concrete makes various responses to damage degree due to the difference of concrete type and damage method. For same concrete with similar damage degree, the water absorption rate of F-T damaged concrete is usually larger than that of concrete damaged by loading. The chloride ion penetrability of damaged concrete increases linearly with increasing damage degree, which is more sensitive to damage degree if the original penetrability of sound concrete is higher.

Application of Air-cooled Blast Furnace Slag Aggregates as Replacement of Natural Aggregates in Cement-based Materials：A Study on Water Absorption Property

The influence of air-cooled blast furnace slag aggregates as replacement of natural aggregates on the water absorption of concrete and mortar was studied, and the mechanism was analyzed. The interface between aggregate and matrix in concrete was analyzed by using a micro-hardness tester, a laser confocal microscope and a scanning electron microscope with backscattered electron image mode. The pore structure of mortar matrixes under different curing conditions was investigated by mercury intrusion porosimetry. The results showed that when natural aggregates were replaced with air-cooled blast furnace slag aggregates in mortar or concrete, the content of the capillary pore in the mortar matrix was reduced and the interfacial structure between aggregate and matrix was improved, resulting in the lower water absorption of mortar or concrete. Compared to the concrete made with crushed limestone and natural river sand, the initial absorption coefficient, the secondary absorption coefficient and the water absorption capacity through the surface for 7 d of the concrete made from crushed air-cooled blast furnace slag and air-cooled blast furnace slag sand were reduced by 48.9%, 52.8%, and 46.5%, respectively.

Self-water-absorption-type two-dimensional composite photocatalyst with high-efficiency water absorption and overall water-splitting performance

Photocatalytic overall water splitting is an interesting research topic in the field of energy and outer space exploration.Here,we designed a P/MoS_(2) composite photocatalyst with self-water-absorption performance by compositing MoS_(2) nanosheets and polycrystalline black phosphorus nanosheets.The composite photocatalyst produced a sufficient amount of hydrogen in the absence of any precious metal.This also demonstrated photocatalytic overall water-splitting ability in the absence of any sacrificial agent.More interestingly,it effectively absorbed water and demonstrated good overall water-splitting performance under the simulated Mars conditions;the average hydrogen production rate was 17.68μmol h^(-1) g^(-1),and the oxygen production rate was 7.61μmol h^(-1) g^(-1) over a period of 70 h.A comprehensive investigation of the ability of the composite photocatalyst to absorb water and produce hydrogen was performed.

MASS TRANSFER IN MEMBRANE ABSORPTIONDESORPTION OF AMMONIA FROM AMMONIA WATER

Hydrophobic membrane can provide fast mass transfer for absorption-desorption of gasesform liquid to absorbent.The removal of ammonia from ammonia water and absorption with dilutesulphuric acid was studied in a pilot plant with polypropylene hollow fiber column,The removalrate and influences of operation temperature,flow rate and concentration on mass transferperformances were discussed mathematically.Experimental results and computer calculation show thatthe ammonia removal rate is not affected by the feed concentration for a given system.Both partialand overall mass transfer coefficients vary along the axis of the fiber,and the mass transfer for themembrane process is controlled by membrane resistance.

Water Absorption Capcapability and Moisture Content Seasonal Changing of Salt-Crust in Lop Nur Dry Lake

The Lop Nur dry salt lake,Xinjiang province,is charactered by typical physiognomy salt-crust,located in39.6-41.3N.latitude and 89.6-91.4E.longitude.The thickness of salt-crust is about from 20 cm to 100 cm,and