The initial copper with large grain sizes of 60-100 μm was processed by six passes asymmetrical accumulative rolling-bond （AARB） and annealing, the ultra-fine-grained （UFG） copper with grain size of 200 nm was ob...The initial copper with large grain sizes of 60-100 μm was processed by six passes asymmetrical accumulative rolling-bond （AARB） and annealing, the ultra-fine-grained （UFG） copper with grain size of 200 nm was obtained, and the microstructures and properties were studied. The results show that there are large sub-structures and also texture component C for the UFG copper obtained by six passes AARB, possessing high strength and microhardness in company with poor elongation and conductivity. Thereafter, the UFG copper was annealed at 220 °C for 35 min, in which the sub-structures disappear, the grain boundaries are composed of big angle grain boundaries, and the textures are composed of a variety of texture components and parts of twins. Compared with the UFG copper obtained by six passes AARB, the tensile strength and yield strength for the UFG copper obtained by six passes AARB and annealing at 220 °C for 35 min are decreased slightly, the elongation and conductivity are improved obviously.展开更多
The ultra-fine-grained ferrite(UFGF) with the size of less than 1 μm is often difficult to be obtained for low-alloyed steel in practical production processing.In this study,considering the rod and wire production pr...The ultra-fine-grained ferrite(UFGF) with the size of less than 1 μm is often difficult to be obtained for low-alloyed steel in practical production processing.In this study,considering the rod and wire production process,a new method for preparing the UFGF with submicron scale is proposed by warm deformation of six passes with total strain of 2.6,followed by the cooling process in Gleeble-3500 thermo-mechanical simulator.The results show that the UFGF with an average size of 0.64 μm could be obtained via the phase transformation from austenite grains with an average size of 3.4 μm,which are achieved by the deformation-induced reversal austenization during the high strain rate warm deformation.The main driving force for the reversal transformation is the stress.And the interval between the passes also plays an important role in the reversal austenization.展开更多
Electrochemical impedance spectroscopy （EIS） and Mott-Schottky analysis were carried out to evaluate the electrochemical behavior of the passive films formed on the surface of coarse-grained （CG）, fine-grained （F...Electrochemical impedance spectroscopy （EIS） and Mott-Schottky analysis were carried out to evaluate the electrochemical behavior of the passive films formed on the surface of coarse-grained （CG）, fine-grained （FG） and ultrafine-grained （UFG） 1050 A1 alloy （AA1050） samples in alkaline media （pH value of 8.0） based on a modification of point defect model （PDM）. The EIS results revealed that the polarization resistance increased from about 22.71-120.33 kΩ cm2 for UFG sample when compared to CG sample （annealed sample）. The semiconductor properties of the passive films formed on CG, FG and UFG AA1050 samples in the test solution were investigated by employing Mott-Schottky analysis in conjunction with PDM. The results indicated that donor densities were in the range of 2.19 × 1021-0.61 × 1021 cm-3 and decreased with grain refinement. Finally, all electrochemical tests showed that the electrochemical behavior of AA1050 alloy was improved by decreasing the grain size, mainly due to the formation of thicker and less defective oxide films.展开更多
Ultra-fine-grained commercial purity aluminum was produced by severe cold rolling, annealing and then strain- ing at ultra-high rate by a single pass laser shock. Resulted microstructure was investigated by transmissi...Ultra-fine-grained commercial purity aluminum was produced by severe cold rolling, annealing and then strain- ing at ultra-high rate by a single pass laser shock. Resulted microstructure was investigated by transmission electron microscopy. Microhardness of annealed 0.6μm ultra-fine grained aluminum increased by 67% from 24 to 40 HV. Many 0.3 μm sub-grains appeared at the shock wave center after a single pass laser shock, while high density dislocation networks were observed in some grains at the shock wave edges. Accordingly, microhardness at the impact center increased by 37.5% from 40 to 55 HV. From the impact center to the edge, microhardness decreased by 22% from 55 to 45 HV.展开更多
基金Project (50804018) supported by the National Natural Science Foundation of ChinaProject (ZDS2010015C) supported by Key Lab of Advanced Materials in Rare and Precious and Non-ferrous Metals, Ministry of Education, KMUST, ChinaProject (2010DH025) supported by Yunnan Province Construction Plans of Scientific and Technological Conditions, China
文摘The initial copper with large grain sizes of 60-100 μm was processed by six passes asymmetrical accumulative rolling-bond （AARB） and annealing, the ultra-fine-grained （UFG） copper with grain size of 200 nm was obtained, and the microstructures and properties were studied. The results show that there are large sub-structures and also texture component C for the UFG copper obtained by six passes AARB, possessing high strength and microhardness in company with poor elongation and conductivity. Thereafter, the UFG copper was annealed at 220 °C for 35 min, in which the sub-structures disappear, the grain boundaries are composed of big angle grain boundaries, and the textures are composed of a variety of texture components and parts of twins. Compared with the UFG copper obtained by six passes AARB, the tensile strength and yield strength for the UFG copper obtained by six passes AARB and annealing at 220 °C for 35 min are decreased slightly, the elongation and conductivity are improved obviously.
基金financially supported by the National Natural Science Foundation of China (Grant Nos. 51574107, 51501056, 51975593)the Natural Science Foundation of Hebei Province (Grant Nos. E2015209243, E2017209048)+1 种基金the Liaoning Provincial Natural Science Foundation of China (Grant No. 2019-KF-25-01)the Research Funds from Department of Education of Hebei Province (Grant Nos. QN2019051, ZD 2019064).
文摘The ultra-fine-grained ferrite(UFGF) with the size of less than 1 μm is often difficult to be obtained for low-alloyed steel in practical production processing.In this study,considering the rod and wire production process,a new method for preparing the UFGF with submicron scale is proposed by warm deformation of six passes with total strain of 2.6,followed by the cooling process in Gleeble-3500 thermo-mechanical simulator.The results show that the UFGF with an average size of 0.64 μm could be obtained via the phase transformation from austenite grains with an average size of 3.4 μm,which are achieved by the deformation-induced reversal austenization during the high strain rate warm deformation.The main driving force for the reversal transformation is the stress.And the interval between the passes also plays an important role in the reversal austenization.
文摘Electrochemical impedance spectroscopy （EIS） and Mott-Schottky analysis were carried out to evaluate the electrochemical behavior of the passive films formed on the surface of coarse-grained （CG）, fine-grained （FG） and ultrafine-grained （UFG） 1050 A1 alloy （AA1050） samples in alkaline media （pH value of 8.0） based on a modification of point defect model （PDM）. The EIS results revealed that the polarization resistance increased from about 22.71-120.33 kΩ cm2 for UFG sample when compared to CG sample （annealed sample）. The semiconductor properties of the passive films formed on CG, FG and UFG AA1050 samples in the test solution were investigated by employing Mott-Schottky analysis in conjunction with PDM. The results indicated that donor densities were in the range of 2.19 × 1021-0.61 × 1021 cm-3 and decreased with grain refinement. Finally, all electrochemical tests showed that the electrochemical behavior of AA1050 alloy was improved by decreasing the grain size, mainly due to the formation of thicker and less defective oxide films.
基金support from the National Natural Science Foundation of China (No. 50801021)
文摘Ultra-fine-grained commercial purity aluminum was produced by severe cold rolling, annealing and then strain- ing at ultra-high rate by a single pass laser shock. Resulted microstructure was investigated by transmission electron microscopy. Microhardness of annealed 0.6μm ultra-fine grained aluminum increased by 67% from 24 to 40 HV. Many 0.3 μm sub-grains appeared at the shock wave center after a single pass laser shock, while high density dislocation networks were observed in some grains at the shock wave edges. Accordingly, microhardness at the impact center increased by 37.5% from 40 to 55 HV. From the impact center to the edge, microhardness decreased by 22% from 55 to 45 HV.
