Morphology and Precipitation Kinetics of MnS in Low-Carbon Steel During Thin Slab Continuous Casting Process

The morphology of manganese sulfide formed during thin slab continuous casting process in low-carbon steel produced by compact strip production （CSP） technique was investigated. Using transmission electron microscopy analysis, it was seen that a majority of manganese sulfides precipitated at austenite grain boundaries, the morphologies of which were spherical or close to the spherical shape and the size of MnS precipitates ranged from 30 nm to 100 nm. A mathematical model of the manganese sulfide precipitation in this process was developed based on classical nucleation theory. Under the given conditions, the starting and finishing precipitation temperatures of MnS in the continuous casting thin slab of the studied low-carbon steel are 1 189 ℃ and 1 171 ℃, respectively, and the average diameter of MnS precipitates is about 48 nm within this precipitation temperature range. The influences of chemical components and thermo-mechanical processing conditions on the precipitation behavior of MnS in the same process were also discussed.

Temperature distribution and dynamic control of secondary cooling in slab continuous casting

To predict and optimize the temperature distribution of slab continuous casting in steady operational state, a three-dimensional model （named ＂offline model＂） based on the heat transfer and solidification theories was developed. Both heat transfer and flux distribution characteristics of the nozzle sprays on the slab were considered, and the complicated boundary conditions, such as spray cooling, natural convection, thermal radiation as well as contact cooling of individual rolls were involved in the model. By using the calibrated caster dependent model factors, the calculated temperature and shell thickness accorded well with the measured. Furthermore, a dynamic secondary water cooling control system was also developed on the basis of a two-dimensional transient heat transfer model （named ＂online model＂） and incremental PID control algorithm to reduce slab surface temperature fluctuation in unsteady state. Compared with the traditional spray table control method, the present online model and dynamic PID control demonstrate a higher capability and flexibility to adjust cooling water flowrate and reduce slab surface temperature fluctuation when the casting speed is changed.

Physical modeling of gas-liquid interfacial fluctuation in a thick slab continuous casting mold with argon blowing

Combining with the physical model of level fluctuation in a thick slab continuous casting mold with the cross-section of 1500 mm×280 mm and argon blowing, the rationalities of estimating the level fluctuation by three traditional quantitative approaches were discussed, and the effects of gas flowrate, casting speed, and the immersion depth of submerged entry nozzle （SEN） on the level fluctuation were also investigated. As a result, it seems that three traditional quantitative approaches are not very suitable for estimating the level fluctuation in a mold with argon blowing, so a new approach for estimating level fluctuation in the mold with argon blowing was presented. The experimental results show that the level fluctuation is mainly in the region around the nozzle wall. When the casting speeds are larger than a certain value, there is the escape of large bubbles near the nozzle wall, which causes an obvious increase of level fluctuation. Furthermore, optimal process parameters, viz., the gas flowrate of 6 NL/min, the casting speed of 1.1 m/min, and the immersion depth of 170 mm, are presented to restrain the level fluctuation by a physical model.

Water modeling of mold powder entrapment in slab continuous casting mold

The optimal parameters were determined by the water modeling of slab casting. It was found that there are mainly three types of mold powder entrapment in slab continuous casting, i.e., the entrapment caused by the shearing flow near the narrow face of mold, the entrapment caused by vortexes around the submerged entry nozzle （SEN）, and the entrapment caused by the Ar bubbling. Both the velocity of the surface flow and the level fluctuation of the liquids are enlarged with increasing the casting speed, reducing the submersion depth of SEN, decreasing the downward angles of the nozzle outlets, and increasing the Ar flowrate, all of which increase the tendency of mold powder entrapment. Among the four above-mentioned factors, casting speed has the largest effect.

Characteristics of shell thickness in a slab continuous casting mold

The key to reduce shell breakout in the continuous casting process is to control shell thickness in the mold. A numerical simulation on the turbulent flow and heat transfer coupled with solidification in the slab mold using the volume of fluid （VOF） model and the enthalpy-porosity scheme was conducted and the emphasis was put upon the flow effect on the shell thickness profiles in longitudinal and transverse directions. The results show that the jet acts a stronger impingement on the shell of narrow face, which causes a zero-increase of shell thickness in a certain range near the impingement point. The thinnest shell on the slab cross-section locates primarily in the center of the narrow face, and secondly near the comer of the wide face. Nozzle optimization can obviously increase the shell thickness and make it more uniform.

Strain in solidifying shell of continuous casting slabs

Two-dimension unsteady heat transfer model was applied to obtain the surfacetemperature and the shell thickness of continuous casting slabs during the process ofsolidification. On the basis of which, the mathematical model of strain at the interface of solidand liquid steel was set up. Through which, the strain in the solidifying shell under normal andabnormal operation conditions was gained. The results indicate that the strain is small under thenormal operation conditions and the internal crack never happens. However, when the variation of theroll gap is above 2 mm, the strain caused by which is greater than that caused by bulging.Furthermore, the total strain exceeds the critical one and the internal crack is the result. So itis of great importance to maintain the fine state of continuous casting machine to avoid theappearance of internal crack.

INVESTIGATION ON HOT DUCTILITY AND STRENGTH OF CONTINUOUS CASTING SLAB FOR AH32 STEEL

By means of Gleeble-1500 testing machine, the simulation of continuous casting process forAH32 steel was carried out and hot ductility and strength were determined. The cracking sensitivity was studied under the different temperatures and strain rates. The Precipitations of AIN at different temperatures and the fractures of high-temperature tensile samples were observed by using TEM （transmission electron microscope） and SEM （scanning electron microscope）. The factors affecting the brittle temperature zone were discussed.

Longitudinal crack on slab surface at straightening stage during continuous casting using finite element method

Deformation behavior of slab at the straightening stage during continuous casting was simulated by the explicit dynamic finite element method,and the stress distribution along the width direction of the slab and its change regularity at slab center during continuous casting were obtained.The influence of distribution and change of stress on the propagation of longitudinal cracks on slab surface was discussed.The results show that the tensional stress appears on slab surface at the inner arc side and the compressive stress appears on slab surface at the outer arc side at stages 6-8 in straightening zone during continuous casting.Longitudinal cracks generally appear on slab top surface and do not appear on slab bottom surface,which are also observed in industry.

Flow and Temperature Fields in Slab Continuous Casting Molds

In order to develop super-board and super-thick slabs, the flow and temperatur fields were studied in slab continuous casting molds under different practical conditions, such as slab dimensions, with-drawing slab speed, design of nozzles, and superheat tempera-ture. The results showed that it is preferred to incline nozzle bores downwards and the submerged depth of the nozzles is best kept be-tween 250-300 mm. In addition, the solidified shell is thicker at the wide face than that at the narrow face, while the thin points alongthe wide face ekist both in the center and in the some area toward each respective end.

Heat-transfer model on the improvement of continuous casting slab temperature

A heat transfer model on the solidification process has been established onthe basis of the technical conditions of the slab caster in No.3 steel works of Wuhan Iron & SteelCorporation, and the temperature field in the solidifying slab was calculated which was verified bythe measured slab surface temperature. The influences of the main operating factors includingcasting speed, spray cooling patterns, superheat of melt and slab size on the solidification processwere analyzed and the means of enhancing the slab temperature was brought forward. Raising thecasting speed to 1.3 m/min, controlling the flowrate of secondary cooling water and improving thecooling pattern at the lower segments of secondary cooling zone could improve the slab temperatureeffectively. And the increasing the superheat is adverse to the production of high temperature slab.

Modeling of unsteadiness of fluid flows and level fluctuations in thin slab continuous casting moulds

Unsteady fluid flows and level fluctuations in a thin slab continuous casting mould have significant influence on product quality. In this study, the phenomena concerning transient flow features and free surface motions were analyzed by means of the large eddy simulation （LES） software with the smagorinsky SGS model--VisualCast （VCast） II, where the Simpler algorithm on a body-fitted mesh was used to resolve governing equations. A series of water analog experiments on the fluid flow and the surface wave in the moulds of thin slab continuous casting were also performed. The results of fluid regions, middle of vortex and level fluctuation from digital simulations were identical with the results of the water analog experiments.

Effect of cooling structure on thermal behavior of copper plates of slab continuous casting mold

A three-dimensional finite-element model of slab continuous casting mold was conducted to clarify the effect of cooling structure on thermal behavior of copper plates. The results show that temperature distribution of hot surface is mainly governed by cooling structure and heat-transfer conditions. For hot surface centricity, maximum surface temperature promotions are 30℃ and 15℃ with thickness increments of copper plates of 5 mm and nickel layers of 1 mm, respectively. The surface temperature without nickel layers is depressed by 10℃ when the depth increment of water slots is 2 mm and that with nickel layers adjacent to and away from mold outlet is depressed by 7℃ and 5℃, respectively. The specific trend of temperature distribution of transverse sections of copper plates is nearly free of cooling structure, but temperature is changed and its law is similar to the corresponding surface temperature.

Slab Storage Calculation Method for Continuous Casting-Hot Rolling

Based on load-oriented manufacturing control theory,different combining modes and slab storage calculation method for continuous casting and hot rolling were discussed.The buffer capacity index of continuous casting-rolling was introduced,and the reasonable slab storage under different combining modes was calculated with buffer capacity index of 120.00 hfor CCR,79.20 hfor HCR,19.68 hfor DHCR and 3.84 hfor DR.Thin slab is 1.20 h,and the strip is zero.Theory gist was provided for steel enterprise to decrease storage.

Study Segregation of Alloying Elements in Continuous Casting Slab with Valence Electron Structure

By calculating the electron structures of the phases that phosphor, sulfur and alloying elements dissolving inγ-Fe, the reason why alloying elements can bring centerline segregation in continuous casting slab (CCS) with nA, the number of electrons on the strongest covalent bonds, and the structure formation factor S were investigated, and an electron structural criterion to control and to eliminate the centerline segregation was advanced. Basing on this, the electron structures of a part of rare earth phosphides and sulfides are calculated, the physical mechanism that rare earth elements can control the segregation of phosphor and sulfur is analyzed, and the criterion is well verified.

Technological Investigation on the Continuous Casting of Mid-Width Thin Slabs

Continuous casting of thin slabs is a key state project for 7th and sth five -year plans. On thebasis of foundamental works , CISRI condueted the tests of 102 heats in Lanzhou Steel Works in the periodof January 1991- June 1992. Three slab assortments of 50× 900 mm . 70 × 900 mm , 70 × 500 mm were ex-amined. In June of 1992, 412 t steel of 46 heats were cast with the efficiency of 91. 3 %. This. result meetsthe requiremeni of the state in this period. The mould, hedt transfer . casting technology and factors influ-encing slab’s qualities are investigated as well.

Numerical simulation of fluid flows in a slab continuous casting mold under electromagnetic stirring

This study established a three-dimensional mathematical model to determine the fluid flow in a slab continuous casting mold under an electromagnetic stirring force. The flow structure and distribution were studied with respect to different continuous casting parameters and stirring current. Based on the calculation results, the mold flux entrapment index in free surface and velocity uniformity index were used to evaluate the flow field in the mold. The theoretical basis for the optimization of the flow field structure was provided. The study also suggested an optimization method for electromagnetic stirring parameters.

Research on the trajectory of non-metal inclusions with the flow in the mold during the solidification of continuous casting slabs

By means of the numerical simulation method,the mathematical model of inclusions movement in the mold is established under the condition of austenitic and fen-itic stainless steel slab production. According to the simulation results, the main zones for inclusion particles accumulation were found and many factors that affected floating-up probability of inclusion particles were identified. These factors include the inclusion particle size, the casting speed and the slab width, etc. It is believed that the inclusion particle size is the key one among these factors.

Evaluation of the performance of mold powder for continuous casting of plate slabs

The No. 3 slab caster,which mainly provides slabs to the 5000 mm plate mill at Baosteel, was put into production in December,2004. The size of the biggest slab produced by this caster is 2300 mm in width and 300 mm in thickness. The designed output of the caster is 2.3 Mt/a. Slab surface longitudinal crack defects,which were related to the heat flux of the mold, frequently occurred in the early stage of the startup of the caster. As mild cooling powder is beneficial to the uniformity of the shell of initial slabs ,the concentration of stress is reduced, and the longitudinal cracking on the surface is avoided. This study evaluates the performance of several kinds of powder, and the results show that mold powder of high basicity, high crystallization proportion and low heat flux is to the benefit of the reduction of the longitudinal cracks on the surface and the defects of slabs.

Simulation of thermal behavior during peritectic steel solidification in slab continuous casting mold

Thermal behavior of the solidifying shell in continuous casting mold is very important to final steel products.In the present work,one two-dimension transient thermal-mechanical finite element model was developed to simulate the thermal behavior of peritectic steel solidifying in slab continuous casting mold by using the sequential coupling method.In this model,the steel physical properties at high temperature was gotten from the micro-segregation model withδ/γtransformation in mushy zone,and the heat flux was obtained according to the displacement between the surface of solidifying shell and the hot face of mold as solidification contraction,the liquid-solid structure and distribution of mold flux,and the temperature distribution of slab surface and mold hot face,in addition,the rate-dependent elastic-viscoplastic constitutive equation was applied to account for the evolution of shell stress in the mold.With this model,the variation characteristics of surface temperature,heat flux, and growth of the solidifying shell corner,as well as the thickness distribution of the liquid flux,solidified flux,air gap and the corresponding thermal resistance were described.