Mechanical Behavior Based on Aggregates Microstructure of Ultra-high Performance Concrete

We developed ultra-high performance concrete(UHPC)incorporating mullite sand and brown corundum sand(BCS),and the quartz sand UHPC was utilized to prepare for comparison.The properties of compressive strength,elastic modulus,ultrasonic pulse velocity,flexural strength,and toughness were investigated.Scanning electron microscopy and nanoindentation were also conducted to reveal the underlying mechanisms affecting macroscopic performance.Due to the superior interface bonding properties between mullite sand and matrix,the compressive strength and flexural toughness of UHPC have been significantly improved.Mullite sand and BCS aggregates have higher stiffness than quartz sand,contributing to the excellent elastic modulus exhibited by UHPC.The stiffness and volume of aggregates have a more significant impact on the elastic modulus of UHPC than interface performance,and the latter contributes more to the strength of UHPC.This study will provide a reference for developing UHPC with superior elastic modulus for structural engineering.

Dynamic interactive bitwise meta-holography with ultra-high computational and display frame rates

Interactive holography offers unmatched levels of immersion and user engagement in the field of future display.Despite of the substantial progress has been made in dynamic meta-holography,the realization of real-time,highly smooth interactive holography remains a significant challenge due to the computational and display frame rate limitations.In this study,we introduced a dynamic interactive bitwise meta-holography with ultra-high computational and display frame rates.To our knowledge,this is the first reported practical dynamic interactive metasurface holographic system.We spa-tially divided the metasurface device into multiple distinct channels,each projecting a reconstructed sub-pattern.The switching states of these channels were mapped to bitwise operations on a set of bit values,which avoids complex holo-gram computations,enabling an ultra-high computational frame rate.Our approach achieves a computational frame rate of 800 kHz and a display frame rate of 23 kHz on a low-power Raspberry Pi computational platform.According to this methodology,we demonstrated an interactive dynamic holographic Tetris game system that allows interactive gameplay,color display,and on-the-fly hologram creation.Our technology presents an inspiration for advanced dynamic meta-holography,which is promising for a broad range of applications including advanced human-computer interaction,real-time 3D visualization,and next-generation virtual and augmented reality systems.

Effect of Shrinkage Reducing Agent and Steel Fiber on the Fluidity and Cracking Performance of Ultra-High Performance Concrete

Due to the low water-cement ratio of ultra-high-performance concrete(UHPC),fluidity and shrinkage cracking are key aspects determining the performance and durability of this type of concrete.In this study,the effects of different types of cementitious materials,chemical shrinkage-reducing agents(SRA)and steel fiber(SF)were assessed.Compared with M2-UHPC and M3-UHPC,M1-UHPC was found to have better fluidity and shrinkage cracking performance.Moreover,different SRA incorporation methods,dosage and different SF types and aspect ratios were implemented.The incorporation of SRA and SF led to a decrease in the fluidity of UHPC.SRA internal content of 1%(NSRA-1%),SRA external content of 1%(WSRA-1%),STS-0.22 and STE-0.7 decreased the fluidity of UHPC by 3.3%,8.3%,9.2%and 25%,respectively.However,SRA and SF improved the UHPC shrinkage cracking performance.NSRA-1%and STE-0.7 reduced the shrinkage value of UHPC by 40%and 60%,respectively,and increased the crack resistance by 338%and 175%,respectively.In addition,the addition of SF was observed to make the microstructure of UHPC more compact,and the compressive strength and flexural strength of 28 d were increased by 26.9%and 19.9%,respectively.

Remaining oil distribution characteristics in an oil reservoir with ultra-high water-cut

An accurate mapping and understanding of remaining oil distribution is very important for water control and stabilize oil production of mature oilfields in ultra-high water-cut stage.Currently,the Tuo-21 Fault Block of the Shengtuo Oilfield has entered the stage of ultra-high water cut(97.2%).Poor adaptability of the well pattern,ineffective water injection cycle and low efficiency of engineering measures(such as workover,re-perforation and utilization of high-capacity pumps)are the significant problems in the ultra-high water-cut reservoir.In order to accurately describe the oil and water flow characteristics,relative permeability curves at high water injection multiple(injected pore volume)and a semiquantitative method is applied to perform fine reservoir simulation of the Sand group 3e7 in the Block.An accurate reservoir model is built and history matching is performed.The distribution characteristics of remaining oil in lateral and vertical directions are quantitatively simulated and analyzed.The results show that the numerical simulation considering relative permeability at high injection multiple can reflect truly the remaining oil distribution characteristics after water flooding in an ultrahigh water-cut stage.The distribution of remaining oil saturation can be mapped more accurately and quantitatively by using the‘four-points and five-types’classification method,providing a basis for potential tapping of various remaining oil types of oil reservoirs in late-stage of development with high water-cut.

A universal multifunctional dual cation doping strategy towards stabilized ultra-high nickel cobalt-free lithium layered oxide cathode

Ultra-high nickel cobalt-free lithium layered oxides are promising cathode material for lithium-ion batteries(LIBs)because of their relatively high capacity and low cost.Nevertheless,the high nickel content would induce bulk structure degradation and interfacial environment deterioration,and the absence of Co element reduces the lithium diffusion kinetics,severely limiting the performance liberation of this kind of cathodes.Herein,a multifunctional Ti/Zr dual cation co-doping strategy has been employed to improve the lithium storage performance of LiNi_(0.9)Mn_(0.1)O_(2)(NM91)cathode.On the one hand,the Ti/Zr co-doping weakens the Li^(+)/Ni^(2+)mixing through magnetic interactions due to the inexistence of unpaired electrons for Ti^(4+)and Zr^(4+),increasing the lithium diffusion rate and suppressing the harmful coexistence of H1 and H2 phases.On the other hand,they enhance the lattice oxygen stability because of the strong Ti-O and Zr-O bonds,inhibiting the undesired H3 phase transition and lattice oxygen loss,improving the bulk structure and cathode-electrolyte interface stability.As a result,the Ti/Zr co-doped NM91(NMTZ)exhibits a 91.2%capacity retention rate after 100 cycles,while that of NM91 is only82.9%.Also,the NMTZ displays better rate performance than NM91 with output capacities of 115 and93 mA h g^(-1)at a high current density of 5 C,respectively.Moreover,the designed NMTZ could enable the full battery to deliver an energy density up to 263 W h kg^(-1),making the ultra-high nickel cobaltfree lithium layered oxide cathode closer to practical applications.

Amine-functionalized metal organic framework@graphene oxide as filler in PAEK-containing carboxyl group membrane for ultrafiltration with ultra-high permeability and strong fouling resistance

Achieving high fouling resistance and permeability using membrane separation technology in water treatment processes remains a challenge.In this work,a novel mixed-matrix membrane(MMM)(poly(arylene ether ketone)[PAEK]-containing carboxyl groups[PAEK-COOH]/UiO-66-NH_(2)@graphene oxide[GO])with superb fouling resistance and high permeability was prepared by the nonsolvent-induced phase separation method,by in-situ growth of UiO-66-NH_(2) on the GO layer,and by preparing hydrophilic PAEK-COOH.On the basis of the structure and performance analysis of the MMM,the maximum water flux reached 591.25 L·m^(-2)·h^(-1) for PAEK-COOH/UiO-66-NH_(2)@GO,whereas the retention rate for bovine serum albumin increased from 85.40%to 94.87%.As the loading gradually increased,the hydrophilicity of the MMMs increased,significantly enhancing their fouling resistance.The strongest anti-fouling ability observed was 94.74%,which was 2.02 times greater than that of the pure membrane.At the same time,the MMMs contained internal amide and hydrogen bonds during the preparation process,forming a cross-linked structure,which further enhanced the mechanical strength and chemical stability.In summary,the MMMs with high retention rate,strong permeability,and anti-fouling ability were successfully prepared.

Comprehensive evaluation of chemical breakers for multistage network ultra-high strength gel

Polymer gels have been accepted as a useful tool to address many sealing operations such as drilling and completion,well stimulation,wellbore integrity,water and gas shutoff,etc.Previously,we developed an ultra-high strength gel(USGel)for medium to ultra-low temperature reservoirs.However,the removal of USGel is a difficult problem for most temporary plugging operations.This paper first provides new insights into the mechanism of USGel,where multistage network structure and physical entanglement are the main reasons for USGel possessing ultra-high strength.Then the effects of acid breakers,encapsulated breakers,and oxidation breakers(including H_(2)O_(2),Na_(2)S_(2)O_(8),Ca(ClO)_(2),H_(2)O_(2)+NaOH,Na_(2)S_(2)O_(8)+NaOH,and Ca(ClO)_(2)+NaOH)were evaluated.The effects of component concentration and temperature on the breaking solution were studied,and the corrosion performance,physical simulation and formation damage tests of the breaking solution were carried out.The final formulation of 2%-4%NaOH+4.5%-6%H_(2)O_(2) breaking solution was determined,which can make USGel completely turn into water at 35e105C.The combinations of“acid t breaking solution”,“acid+encapsulated breaker”and“encapsulated breaker+breaking solution”were evaluated for breaking effect.The acid gradually reduced the volume of USGel,which increased the contact area between breaking solution and USGel,and the effect of“4%acid+breaking solution”was 23 times higher than that of breaking solution alone at 35C.However,the acid significantly reduced the strength of USGel.This paper provides new insights into the breaking of high-strength gels with complex network structures.

Combination of a reaction cell and an ultra-high vacuum system for the in situ preparation and characterization of a model catalyst

An in-depth understanding of the structure-activity relationship between the surface structure,chemical composition,adsorption and desorption of molecules,and their reaction activity and selectivity is necessary for the rational design of high-performance catalysts.Herein,we present a method for studying catalytic mechanisms using a combination of in situ reaction cells and surface science techniques.The proposed system consists of four parts:preparation chamber,temperatureprogrammed desorption(TPD)chamber,quick load-lock chamber,and in situ reaction cell.The preparation chamber was equipped with setups based on the surface science techniques used for standard sample preparation and characterization,including an Ar+sputter gun,Auger electron spectrometer,and a low-energy electron diffractometer.After a well-defined model catalyst was prepared,the sample was transferred to a TPD chamber to investigate the adsorption and desorption of the probe molecule,or to the reaction cell,to measure the catalytic activity.A thermal desorption experiment for methanol on a clean Cu(111)surface was conducted to demonstrate the functionality of the preparation and TPD chambers.Moreover,the repeatability of the in situ reaction cell experiment was verified by CO_(2) hydrogenation on the Ni(110)surface.At a reaction pressure of 800 Torr at 673 K,turnover frequencies for the methanation reaction and reverse water-gas shift reaction were 0.15 and 7.55 Ni atom^(-1) s^(-1),respectively.

Influence Mechanism of Curing Regimes on Interfacial Transition Zone of Lightweight Ultra-High Performance Concrete

This study aims to clarify the effects of curing regimes and lightweight aggregate(LWA)on the morphology, width and mechanical properties of the interfacial transition zone(ITZ) of ultra-high performance concrete(UHPC), and provide reference for the selection of lightweight ultra-high performance concrete(L-UHPC) curing regimes and the pre-wetting degree LWA. The results show that, under the three curing regimes(standard curing, steam curing and autoclaved curing), LWA is tightly bound to the matrix without obvious boundaries. ITZ width increases with the water absorption of LWA and decreases with increasing curing temperature. The ITZ microhardness is the highest when water absorption is 3%, and the microhardness value is more stable with the distance from LWA. Steam and autoclaved curing increase ITZ microhardness compared to standard curing. As LWA pre-wetting and curing temperatures increase, the degree of hydration at the ITZ increases, generating high-density CSH(HD CSH) and ultra-high-density CSH(UHD CSH), and reducing unhydrated particles in ITZ. ITZ micro-mechanical properties are optimized due to hydration products being denser.

Ultra-high Temperature Ceramic Coatings:A Review on Preparation Technology and Development Prospect

Ultra-high temperature ceramic coatings have ultra-high melting points,excellent mechanical properties and high temperature ablation resistance.These unique performance combinations turn it into a promising material for use in extreme environment structures in rockets and hypersonic vehicles,particularly nozzles,leading edges and engine components.In this paper,various preparation methods of ultra-high temperature ceramic coatings were reviewed,including plasma spraying,chemical vapor deposition,pack cementation,slurry sintering,hot pressing and their research progress.Meanwhile,some new preparation methods of high temperature coatings,such as ion beam deposition,ultrasonic spraying,metal organic frame work coating,and magnetron sputtering,were introduced.The development trend of ultra-high temperature coatings was prospected as well.

Evaluation of Uncertainty in Determination of Ethyl Maltol in Vegetable Oil by Ultra-high Performance Liquid Chromatograph-Mass Spectrometer(UPLC-MS)

[Objectives]This study was conducted to establish an uncertainty evaluation method for the determination of ethyl maltol by ultra-high performance liquid chromatograph-mass spectrometer(UPLC-MS).[Methods]A mathematical model of uncertainty was established by analyzing the method for determining ethyl maltol using UPLC-MS.The sources of uncertainty were analyzed,and the components of uncertainty were calculated to evaluate the expanded uncertainty of the method.[Results]When the content of ethyl maltol in edible vegetable oil was 1657μg/kg,the expanded uncertainty was 22.4μg/kg(K=2,P=95%).[Conclusions]The uncertainty in this evaluation model mainly came from standard solution preparation,sample weighing,dilution of sample to constant volume,standard curve fitting,and repeated measurement.

基于多轴强度准则的混凝土面板应力安全评价方法研究

混凝土面板作为面板堆石坝的关键防渗结构,其应力变形安全对保障工程安全运行至关重要。目前工程中普遍采用混凝土单轴标准强度评价面板应力安全,该方法忽略了面板应力状态对其强度的影响,会对面板破坏范围作出不合理的判断,因此,提出了基于多轴强度准则的混凝土面板应力安全评价方法,该方法通过确定混凝土强度调整系数及多轴强度应力水平指标评价面板应力安全。联合基于位移多点约束法的面板精细化计算方法及改进黏弹性方法全面考虑动位移和永久变形对面板动应力的影响,细致模拟地震过程中面板破坏发展过程。以强震区狭窄河谷上240 m级特高面板坝为例,对比分析了文中提出的多轴强度方法与当前单轴强度方法判断面板破坏范围的差异,结果表明:正常蓄水期,坝肩两侧面板位于“抗压强度削减区”、河床面板均位于“抗压强度增强区”,其中河床底部面板强度增加尤为明显,两种方法判断的面板受拉破坏区基本一致,但受压破坏区存在较大差异;遭遇地震情况下,多轴强度方法判断的面板受拉破坏区略小,而两种方法受压破坏区的位置和大小均存在显著差异。鉴于单轴强度方法无法考虑面板应力分布对其强度的影响,建议采用多轴强度准则指导特高面板坝混凝土面板设计和施工。

集中配筋连接预制剪力墙抗震性能试验研究

针对现有预制混凝土剪力墙接缝施工容错率低、混凝土现场浇筑作业量大和钢筋锚固过长等不足,提出一种使用超高性能混凝土(UHPC)的集中配筋连接预制剪力墙。通过对比1片现浇剪力墙试件、3片不同接缝形式的集中配筋连接预制剪力墙试件的拟静力试验结果,揭示该类预制剪力墙的破坏规律和抗震性能、竖缝对墙体抗震性能的影响和连接钢筋的受力特点。采用ABAQUS软件对试件进行有限元模拟,分析轴压比和集中配筋率对试件抗震性能的影响。研究结果表明:预制试件与现浇试件具有相同的破坏规律,均为弯剪破坏;这2类试件的滞回曲线均较饱满,骨架曲线走势基本一致,耗能能力接近,且预制试件的最小承载力仅比现浇试件低5.6%,表明预制试件的抗震性能与现浇试件的抗震性能基本相同;竖缝对剪力墙承载力的影响较小,使剪力墙的延性和耗能能力有一定的削弱;不同竖缝形式预制墙的抗震性能相近但各有特点,竖缝形式预制墙采用UHPC出筋搭接具有更好的整体性,采用U形键槽的预制墙具有更大的刚度和更强的耗能能力;连接钢筋的应力分布具有典型受弯构件的特征;随着轴压比增加,模型的刚度和承载力不断增加,在轴压比从0.05增加到0.30时,最大的峰值荷载增幅发生在轴压比从0.05到0.10时,从承载力的提高、刚度、耗能和墙角抬高等方面考虑,试件的集中配筋率保持在90%~110%为宜。

峡谷区深厚覆盖层上面板堆石坝结构安全研究

趾板直接建在覆盖层上的面板堆石坝,通过防渗墙、连接板、混凝土面板以及接缝止水构成完整的防渗体系,由于覆盖层的大变形以及岸坡区以及河床覆盖层区较大的差异变形使得整体防渗体结构安全面临严峻考验。依托新疆某电站面板堆石坝工程,室内试验与现场旁压试验相结合确定合理的覆盖层和筑坝料力学参数,采用数值计算方法优化分析了连接板宽度、防渗墙施工次序、混凝土面板宽度、面板柔性缝设置方式等措施对改善防渗体系应力变形的效果。结果表明:合理的连接板长度与分缝型式可减小连接板应力和接缝变位;防渗墙后期施工能显著改善墙体应力,减小面板分缝宽度和设置柔性缝均能较好控制面板的应力性态;对于覆盖层上的新疆某电站面板堆石坝,防渗墙与连接板接缝以及陡峭左岸周边缝剪切变形是控制该工程运行安全的重要因素,研究结果可为同类型土石坝设计建设提供借鉴。

Microstructure and Oxidation Behavior of ZrB_(2)-SiC Ceramics Fabricated by Tape Casting and Reactive Melt Infiltration

ZrB_(2)-based ceramics typically necessitate high temperature and pressure for sintering,whereas ZrB_(2)-SiC ceramics can be fabricated at 1500℃using the process of reactive melt infiltration with Si.In comparison to the conventional preparation method,reactive synthesis allows for the more facile production of ultra-high temperature ceramics with fine particle size and homogeneous composition.In this work,ZrSi_(2),B4C,and C were used as raw materials to prepare ZrB_(2)-SiC via combination of tape casting and reactive melt infiltration herein referred to as ZBC ceramics.Control sample of ZrB_(2)-SiC was also prepared using ZrB_(2) and SiC as raw materials through an identical process designated as ZS ceramics.Microscopic analysis of both ceramic groups revealed smaller and more uniformly distributed particles of the ZrB_(2) phase in ZBC ceramics compared to the larger particles in ZS ceramics.Both sets of ceramics underwent cyclic oxidation testing in the air at 1600℃for a cumulative duration of 5 cycles,each cycle lasting 2 h.Analysis of the oxidation behavior showed that both ZBC ceramics and ZS ceramics developed a glassy SiO_(2)-ZrO_(2) oxide layer on their surfaces during the oxidation.This layer severed as a barrier against oxygen.In ZBC ceramics,ZrO_(2) is finely distributed in SiO_(2),whereas in ZS ceramics,larger ZrO_(2) particles coexist with glassy SiO_(2).The surface oxide layer of ZBC ceramics maintains a dense structure because the well-dispersed ZrO_(2) increases the viscosity of glassy SiO_(2),preventing its crystallization during the cooling.Conversely,some SiO_(2) in the oxide layer of ZS ceramics may crystallize and form a eutectic with ZrO_(2),leading to the formation of ZrSiO_(4).This leads to cracking of the oxide layer due to differences in thermal expansion coefficients,weakening its barrier effect.An analysis of the oxidation resistance shows that ZBC ceramics exhibit less increase in oxide layer thickness and mass compared to ZS ceramics,suggesting superior oxidation resistance of ZBC ceramics.

高混凝土面板堆石坝接缝止水设计综述

接缝止水是高混凝土面板堆石坝设计的关键技术问题之一。对国内外高混凝土面板堆石坝接缝止水设计研究进展进行了综述,主要包括止水变形控制标准与止水结构设计两大方面,对目前中国高混凝土面板堆石坝接缝止水结构设计的基本思路及工程实践进行了回顾。研究认为采用数值计算结合工程经验确定接缝止水变形控制标准是合适的。目前接缝止水的新技术集中在表层填料止水及其保护盖板、垂直缝柔性嵌缝材料等方面。混凝土面板堆石坝接缝止水后续研究的重点为表层止水结构创新、止水结构简化设计、防挤压破坏措施、止水耐久性提高方法和修复技术。

Determination of Ten Kinds of Alpha-2 Agonists Residues in Animal Derived Food by UHPLC-Triple Quadrupole/Composite Linear Ion Trap Mass Spectrometry

[Objectives]The paper was to establish an ultra high performance liquid chromatography-quadrupole/linear ion trap complex mass spectrometry for the determination of 10 kinds ofα2-receptor agonists in animal derived food.[Methods]The samples were extracted with sodium carbonate buffer solution and ethyl acetate,and analyzed by mass spectrometry after solid phase extraction and high performance liquid chromatography separation.[Results]Ten kinds ofα2-receptor agonists showed a good linear relationship in the range of 1-100μg/mL,with the average recovery of over 69%and the relative standard deviation less than 8.32%.The detection limit of 10 kinds of α_(2)-receptor agonists was up to 1μg/kg.[Conclusions]The method has good selectivity and strong anti-interference ability,and can meet the requirements of 10 kinds ofα2-receptor agonists residues in animal derived food.

Analysis and Prediction Model Reinforced UHPC Shrinkage Property

This paper explores the shrinkage of reinforced UHPC under high-temperature steam curing and natural curing conditions.The results are compared with the existing shrinkage prediction models.The results show that the maximum shrinkage strain of reinforced UHPC after steam curing is 164μεand gradually becomes zero.As for natural curing,the maximum shrinkage strain is 173μεand the value stabilizes on the 10th day after pouring.This indicated that steam curing can significantly reduce shrinkage time.Compared with the plain UHPC tested in the previous literature,the structural reinforcement can significantly inhibit the UHPC shrinkage and greatly reduce the risk of cracking due to shrinkage.By comparing the results in this paper with the existing models for predicting the shrinkage strain development,it is found that the formula recommended in the French UHPC structural and technical specification is suitable for the shrinkage curve in the present paper.

非洲某水电站项目坝型选择

依托非洲某水电站项目,结合地形、地质、填筑材料、气候等实际条件,从坝体稳定、施工组织设计、工程投资等方面对各坝型(混凝土面板堆石坝、沥青混凝土心墙堆石坝、复合土工膜面板堆石坝、粘土心墙堆石坝及碾压混凝土坝)进行了综合比选。笔者分析了各坝型的优缺点,以期能给类似工程提供经验,使其因地制宜,选择最合适的坝型。

寒冷强震地区250 m级特高混凝土面板堆石坝接缝止水设计

寒冷强震地区的250 m级特高混凝土面板堆石坝变形控制难度大、抗震安全问题突出、耐久性要求高,这些难题对面板坝接缝止水设计提出了更高的要求。以233.5 m高的玉龙喀什混凝土面板堆石坝为例,利用三维静动力有限元计算成果,结合国内外类似高面板坝的工程经验,定量提出其接缝变形控制标准,针对性地开展了不同部位接缝的止水尺寸设计。基于工程特点和大坝变形特性,考虑面板不同区域受力的差异、水位变动区冰冻的影响、防挤压破坏和板块间约束等因素,采用多道冗余设计、聚脲涂覆盖板、垂直缝均设嵌缝材料、压性缝局部加强等措施,对周边缝、垂直缝、防浪墙水平缝和沉降缝的止水开展了个性化设计,可供类似工程参考。