In this work,we reported a series of monolithic 3D-printed Ni-Mo alloy electrodes for highly efficient water splitting at high current density(1500 mA cm^(-2))with excellent stability,which provides a solution to scal...In this work,we reported a series of monolithic 3D-printed Ni-Mo alloy electrodes for highly efficient water splitting at high current density(1500 mA cm^(-2))with excellent stability,which provides a solution to scale up Ni-Mo catalysts for HER to industry use.All possible Ni-Mo metal/alloy phases were achieved by tuning the atomic composition and heat treatment procedure,and they were investigated through both experiment and simulation,and the optimal NiMo phase shows the best performance.Density functional theory(DFT)calculations elucidate that the NiMo phase has the lowest H2O dissociation energy,which further explains the exceptional performance of NiMo.In addition,the microporosity was modulated via controlled thermal treatment,indicating that the 1100℃sintered sample has the best catalytic performance,which is attributed to the high electrochemically active surface area(ECSA).Finally,the four different macrostructures were achieved by 3D printing,and they further improved the catalytic performance.The gyroid structure exhibits the best catalytic performance of driving 500 mA cm^(-2)at a low overpotential of 228 mV and 1500 mA cm^(-2)at 325 mV,as it maximizes the efficient bubble removal from the electrode surface,which offers the great potential for high current density water splitting.展开更多
提出了在等电位工作状态下校准多元感应分流器(multiple inductive current divider,MICD)的1种方法。在校准装置中加入由跟随器和电阻组成的I/V变换器,以使MICD各支路间的电流比例与其工作状态保持一致;用参考电流互感器(CT)提供独立...提出了在等电位工作状态下校准多元感应分流器(multiple inductive current divider,MICD)的1种方法。在校准装置中加入由跟随器和电阻组成的I/V变换器,以使MICD各支路间的电流比例与其工作状态保持一致;用参考电流互感器(CT)提供独立的参考电流,以避免影响支路电流的比例关系。在20、55、400 Hz及1 kHz下对11支路MICD校准所得10:1电流比例的比值差合成标准不确定度优于0.2μA/A,相位差合成标准不确定度优于1.5μrad。展开更多
Although Zn metal has been regarded as the most promising anode for aqueous batteries,its practical application is still restricted by side reactions and dendrite growth.Herein,an in-situ solid electrolyte interphase(...Although Zn metal has been regarded as the most promising anode for aqueous batteries,its practical application is still restricted by side reactions and dendrite growth.Herein,an in-situ solid electrolyte interphase(SEI)film formed on the interface of electrode/electrolyte during the plating/stripping of zinc anodes by introducing trace amounts of multidentate ligand sodium diethyldithiocarbamate(DDTC)additive into 1 M ZnSO_(4).The synergistic effect of in-situ solid electrolyte interphase forming and chelate effect endows Zn^(2+)with uniform and rapid interface-diffusion kinetics against dendrite growth and surface side reactions.As a result,the Zn anode in 1 M ZnSO_(4)+DDTC electrolytes displays an ultra-high coulombic efficiency of 99.5%and cycling stability(more than 2000 h),especially at high current density(more than 600 cycles at 40 mA cm^(-2)).Moreover,the Zn//MnO_(2)full cells in the ZnSO_(4)+DDTC electrolyte exhibit outstanding cyclic stability(with 98.6%capacity retention after 2000 cycles at 10 C).This electrode/electrolyte interfacial chemistry modulated strategy provides new insight into enhancing zinc anode stability for high-performance aqueous zinc batteries.展开更多
面向工业、国防及重大科学研究领域超大电流在线计量的迫切需求,提出基于光纤电流传感器量程自扩展特性实现超大电流计量标准的量值传递。基于微分琼斯矩阵方法,建立了光纤敏感环路的数学模型,揭示了线性双折射对传感器量程自扩展特性...面向工业、国防及重大科学研究领域超大电流在线计量的迫切需求,提出基于光纤电流传感器量程自扩展特性实现超大电流计量标准的量值传递。基于微分琼斯矩阵方法,建立了光纤敏感环路的数学模型,揭示了线性双折射对传感器量程自扩展特性的影响机理,并证明了采用椭圆双折射光纤的电流传感器具有良好的量程自扩展能力,可通过光纤圈数对Faraday效应的比例放大作用,利用小电流实现传感器在超大电流下的等效校准。研制了干涉式数字闭环柔性光纤电流传感器,可在不断开载流母线的情况下直接形成敏感环路,实现在线计量。样机性能测试结果表明:在直流等效10~210 k A范围内,样机的测量准确度优于±0.1%;在工频额定等效25 k A条件下,样机的比差准确度满足IEC60044-8 0.2 S级要求;样机的带宽大于10 k Hz。展开更多
文摘In this work,we reported a series of monolithic 3D-printed Ni-Mo alloy electrodes for highly efficient water splitting at high current density(1500 mA cm^(-2))with excellent stability,which provides a solution to scale up Ni-Mo catalysts for HER to industry use.All possible Ni-Mo metal/alloy phases were achieved by tuning the atomic composition and heat treatment procedure,and they were investigated through both experiment and simulation,and the optimal NiMo phase shows the best performance.Density functional theory(DFT)calculations elucidate that the NiMo phase has the lowest H2O dissociation energy,which further explains the exceptional performance of NiMo.In addition,the microporosity was modulated via controlled thermal treatment,indicating that the 1100℃sintered sample has the best catalytic performance,which is attributed to the high electrochemically active surface area(ECSA).Finally,the four different macrostructures were achieved by 3D printing,and they further improved the catalytic performance.The gyroid structure exhibits the best catalytic performance of driving 500 mA cm^(-2)at a low overpotential of 228 mV and 1500 mA cm^(-2)at 325 mV,as it maximizes the efficient bubble removal from the electrode surface,which offers the great potential for high current density water splitting.
基金supported by the Joint Funds of the National Natural Science Foundation of China(No.U22A20140)the Independent Cultivation Program of Innovation Team of Ji'nan City(No.2019GXRC011)the National Natural Science Foundation of China(No.62001189)
文摘Although Zn metal has been regarded as the most promising anode for aqueous batteries,its practical application is still restricted by side reactions and dendrite growth.Herein,an in-situ solid electrolyte interphase(SEI)film formed on the interface of electrode/electrolyte during the plating/stripping of zinc anodes by introducing trace amounts of multidentate ligand sodium diethyldithiocarbamate(DDTC)additive into 1 M ZnSO_(4).The synergistic effect of in-situ solid electrolyte interphase forming and chelate effect endows Zn^(2+)with uniform and rapid interface-diffusion kinetics against dendrite growth and surface side reactions.As a result,the Zn anode in 1 M ZnSO_(4)+DDTC electrolytes displays an ultra-high coulombic efficiency of 99.5%and cycling stability(more than 2000 h),especially at high current density(more than 600 cycles at 40 mA cm^(-2)).Moreover,the Zn//MnO_(2)full cells in the ZnSO_(4)+DDTC electrolyte exhibit outstanding cyclic stability(with 98.6%capacity retention after 2000 cycles at 10 C).This electrode/electrolyte interfacial chemistry modulated strategy provides new insight into enhancing zinc anode stability for high-performance aqueous zinc batteries.
文摘面向工业、国防及重大科学研究领域超大电流在线计量的迫切需求,提出基于光纤电流传感器量程自扩展特性实现超大电流计量标准的量值传递。基于微分琼斯矩阵方法,建立了光纤敏感环路的数学模型,揭示了线性双折射对传感器量程自扩展特性的影响机理,并证明了采用椭圆双折射光纤的电流传感器具有良好的量程自扩展能力,可通过光纤圈数对Faraday效应的比例放大作用,利用小电流实现传感器在超大电流下的等效校准。研制了干涉式数字闭环柔性光纤电流传感器,可在不断开载流母线的情况下直接形成敏感环路,实现在线计量。样机性能测试结果表明:在直流等效10~210 k A范围内,样机的测量准确度优于±0.1%;在工频额定等效25 k A条件下,样机的比差准确度满足IEC60044-8 0.2 S级要求;样机的带宽大于10 k Hz。
