Ultra-high molecular weight polyacrylonitrile (UHMW PAN ) was prepared by aqueous suspension polymerization, and the effect of molecular weight on its rheological behaviors in dimethylsulfoxide (DMSO) and the spinning...Ultra-high molecular weight polyacrylonitrile (UHMW PAN ) was prepared by aqueous suspension polymerization, and the effect of molecular weight on its rheological behaviors in dimethylsulfoxide (DMSO) and the spinning stability were investigated. It shows that,compared with common polyacrylonitrile (C-PAN),UHMW- PAN/DMS0 solution has smaller non- Newtonian index, larger structural viscosity index, much longer maximum relaxation time, and no first- Newtonian region appears in the flow curves under the same experimental conditions. The explanations for these phenomena are given in the view of chain- entanglements. The optimal technology of preparing UHMW-PAN fibers and hollow fiber membranes could be obtained based on the theological study.展开更多
UHMW-PAN is an important polymer material used to make high strength and high modules fiber as well as hollow fiber membrane with high mechanical strength to resist the backwash process.In this paper, the effect of te...UHMW-PAN is an important polymer material used to make high strength and high modules fiber as well as hollow fiber membrane with high mechanical strength to resist the backwash process.In this paper, the effect of temperature on non-Newtonian flow index, structural viscosity index,maximum relaxation time and zero shear viscosity of the UHMW-PAN solution has been studied.The relationship between parameters and spinnability has been discussed. On the basis of above works, the suitable temperature of spinning solution by gel-spinning has been found.展开更多
基金This work was supported by Shanghai Natural Science Foundation(98ZF14001)
文摘Ultra-high molecular weight polyacrylonitrile (UHMW PAN ) was prepared by aqueous suspension polymerization, and the effect of molecular weight on its rheological behaviors in dimethylsulfoxide (DMSO) and the spinning stability were investigated. It shows that,compared with common polyacrylonitrile (C-PAN),UHMW- PAN/DMS0 solution has smaller non- Newtonian index, larger structural viscosity index, much longer maximum relaxation time, and no first- Newtonian region appears in the flow curves under the same experimental conditions. The explanations for these phenomena are given in the view of chain- entanglements. The optimal technology of preparing UHMW-PAN fibers and hollow fiber membranes could be obtained based on the theological study.
文摘UHMW-PAN is an important polymer material used to make high strength and high modules fiber as well as hollow fiber membrane with high mechanical strength to resist the backwash process.In this paper, the effect of temperature on non-Newtonian flow index, structural viscosity index,maximum relaxation time and zero shear viscosity of the UHMW-PAN solution has been studied.The relationship between parameters and spinnability has been discussed. On the basis of above works, the suitable temperature of spinning solution by gel-spinning has been found.
