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Investigation of stress-induced progressive failure of mine pillars using a Voronoi grain-based breakable block model
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作者 Shili Qiu Shirui Zhang +3 位作者 Quan Jiang Shaojun Li Hao Zhang Qiankuan Wang 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第5期713-729,共17页
The Voronoi grain-based breakable block model(VGBBM)based on the combined finite-discrete element method(FDEM)was proposed to explicitly characterize the failure mechanism and predict the deformation behavior of hard-... The Voronoi grain-based breakable block model(VGBBM)based on the combined finite-discrete element method(FDEM)was proposed to explicitly characterize the failure mechanism and predict the deformation behavior of hard-rock mine pillars.The influence of the microscopic parameters on the macroscopic mechanical behavior was investigated using laboratory-scale models.The field-scale pillar models(width-to-height,W/H=1,2 and 3)were calibrated based on the empirically predicted stress-strain curves of Creighton mine pillars.The results indicated that as the W/H ratios increased,the VGBBM effectively predicted the transition from strain-softening to pseudo-ductile behavior in pillars,and explicitly captured the separated rock slabs and the V-shaped damage zones on both sides of pillars and conjugate shear bands in core zones of pillars.The volumetric strain field revealed significant compressional deformation in core zones of pillars.While the peak strains of W/H=1 and 2 pillars were relatively consistent,there were significant differences in the strain energy storage and release mechanism.W/H was the primary factor influencing the deformation and strain energy in the pillar core.The friction coefficient of the structural plane was also an important factor affecting the pillar strength and the weakest discontinuity angle.The fracture surface was controlled by the discontinuity angle and the friction coefficient.This study demonstrated the capability of the VGBBM in predicting the strengths and deformation behavior of hard-rock pillars in deep mine design. 展开更多
关键词 pillar strength FDEM Voronoi tessellation SPALLING BULKING
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Pillar effect induced by ultrahigh phosphorous/nitrogen doping enables graphene/MXene film with excellent cycling stability for alkali metal ion storage
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作者 Meng Qin Yiwei Yao +5 位作者 Junjie Mao Chi Chen Kai Zhu Guiling Wang Dianxue Cao Jun Yan 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第6期146-156,I0004,共12页
Graphene's large theoretical surface area and high conductivity make it an attractive anode material for potassium-ion batteries(PIBs).However,its practical application is hindered by small interlayer distance and... Graphene's large theoretical surface area and high conductivity make it an attractive anode material for potassium-ion batteries(PIBs).However,its practical application is hindered by small interlayer distance and long ion transfer distance.Herein,this paper aims to address the issue by introducing MXene through a simple and scalable method for assembling graphene and realizing ultrahigh P doping content.The findings reveal that MXene and P-C bonds have a "pillar effect" on the structure of graphene,and the P-C bond plays a primary role.In addition,N/P co-doping introduces abundant defects,providing more active sites for K^(+) storage and facilitating K^(+) adsorption.As expected,the developed ultrahigh phosphorous/nitrogen co-doped flexible reduced graphene oxide/MXene(NPrGM) electrode exhibits remarkable reversible discharge capacity(554 mA hg^(-1) at 0.05 A g^(-1)),impressive rate capability(178 mA h g^(-1) at 2 A g^(-1)),and robust cyclic stability(0.0005% decay per cycle after 10,000 cycles at 2 A g^(-1)).Furthermore,the assembled activated carbon‖NPrGM potassium-ion hybrid capacitor(PIHC) can deliver an impressive energy density of 131 W h kg^(-1) and stable cycling performance with 98.1% capacitance retention after5000 cycles at 1 A g^(-1).Such a new strategy will effectively promote the practical application of graphene materials in PIBs/PIHCs and open new avenues for the scalable development of flexible films based on two-dimensional materials for potential applications in energy storage,thermal interface,and electromagnetic shielding. 展开更多
关键词 GRAPHENE MXene Phosphorous doping pillar effect Potassium-ion batteries
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Mechanical Behavior Based on Aggregates Microstructure of Ultra-high Performance Concrete
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作者 丁庆军 ZHOU Changsheng +4 位作者 张高展 GUO Hong LI Yang ZHANG Yongyuan GUO Kaizheng 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第3期673-681,共9页
We developed ultra-high performance concrete(UHPC)incorporating mullite sand and brown corundum sand(BCS),and the quartz sand UHPC was utilized to prepare for comparison.The properties of compressive strength,elastic ... We developed ultra-high performance concrete(UHPC)incorporating mullite sand and brown corundum sand(BCS),and the quartz sand UHPC was utilized to prepare for comparison.The properties of compressive strength,elastic modulus,ultrasonic pulse velocity,flexural strength,and toughness were investigated.Scanning electron microscopy and nanoindentation were also conducted to reveal the underlying mechanisms affecting macroscopic performance.Due to the superior interface bonding properties between mullite sand and matrix,the compressive strength and flexural toughness of UHPC have been significantly improved.Mullite sand and BCS aggregates have higher stiffness than quartz sand,contributing to the excellent elastic modulus exhibited by UHPC.The stiffness and volume of aggregates have a more significant impact on the elastic modulus of UHPC than interface performance,and the latter contributes more to the strength of UHPC.This study will provide a reference for developing UHPC with superior elastic modulus for structural engineering. 展开更多
关键词 ultra-high performance concrete mechanical properties fine aggregates MICROSTRUCTURE NANOINDENTATION
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Dynamic interactive bitwise meta-holography with ultra-high computational and display frame rates
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作者 Yuncheng Liu Ke Xu +4 位作者 Xuhao Fan Xinger Wang Xuan Yu Wei Xiong Hui Gao 《Opto-Electronic Advances》 SCIE EI CAS CSCD 2024年第1期36-46,共11页
Interactive holography offers unmatched levels of immersion and user engagement in the field of future display.Despite of the substantial progress has been made in dynamic meta-holography,the realization of real-time,... Interactive holography offers unmatched levels of immersion and user engagement in the field of future display.Despite of the substantial progress has been made in dynamic meta-holography,the realization of real-time,highly smooth interactive holography remains a significant challenge due to the computational and display frame rate limitations.In this study,we introduced a dynamic interactive bitwise meta-holography with ultra-high computational and display frame rates.To our knowledge,this is the first reported practical dynamic interactive metasurface holographic system.We spa-tially divided the metasurface device into multiple distinct channels,each projecting a reconstructed sub-pattern.The switching states of these channels were mapped to bitwise operations on a set of bit values,which avoids complex holo-gram computations,enabling an ultra-high computational frame rate.Our approach achieves a computational frame rate of 800 kHz and a display frame rate of 23 kHz on a low-power Raspberry Pi computational platform.According to this methodology,we demonstrated an interactive dynamic holographic Tetris game system that allows interactive gameplay,color display,and on-the-fly hologram creation.Our technology presents an inspiration for advanced dynamic meta-holography,which is promising for a broad range of applications including advanced human-computer interaction,real-time 3D visualization,and next-generation virtual and augmented reality systems. 展开更多
关键词 interactive display meta-holography bitwise operation ultra-high frame rate
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Numerical and theoretical study of load transfer behavior during cascading pillar failure
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作者 Hangyu Dong Wancheng Zhu +2 位作者 Leilei Niu Chen Hou Xige Liu 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第8期3014-3033,共20页
To further study the load transfer mechanism of roofemulti-pillarefloor system during cascading pillar failure(CPF),numerical simulation and theoretical analysis were carried out to study the three CPF modes according... To further study the load transfer mechanism of roofemulti-pillarefloor system during cascading pillar failure(CPF),numerical simulation and theoretical analysis were carried out to study the three CPF modes according to the previous experimental study on treble-pillar specimens,e.g.successive failure mode(SFM),domino failure mode(DFM)and compound failure mode(CFM).Based on the finite element code rock failure process analysis(RFPA^(2D)),numerical models of treble-pillar specimen with different mechanical properties were established to reproduce and verify the experimental results of the three CPF modes.Numerical results show that the elastic rebound of roofefloor system induced by pillar instability causes dynamic disturbance to adjacent pillars,resulting in sudden load increases and sudden jump displacement of adjacent pillars.The phenomena of load transfer in the roofemulti-pillarefloor system,as well as the induced accelerated damage behavior in adjacent pillars,were discovered and studied.In addition,based on the catastrophe theory and the proposed mechanical model of treble-pillar specimen edisc spring group system,a potential function that characterizes the evolution characteristics of roof emulti-pillarefloor system was established.The analytical expressions of sudden jump and energy release of treble-pillar specimenedisc spring group system of the three CPF modes were derived according to the potential function.The numerical and theoretical results show good agreement with the experimental results.This study further reveals the physical essence of load transfer during CPF of roof emulti-pillarefloor system,which provides references for mine design,construction and disaster prevention. 展开更多
关键词 Cascading pillar failure(CPF) Load transfer Multi-pillar Numerical simulation
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Effect of Shrinkage Reducing Agent and Steel Fiber on the Fluidity and Cracking Performance of Ultra-High Performance Concrete
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作者 Yong Wan Li Li +4 位作者 Jiaxin Zou Hucheng Xiao Mengdi Zhu Ying Su Jin Yang 《Fluid Dynamics & Materials Processing》 EI 2024年第9期1941-1956,共16页
Due to the low water-cement ratio of ultra-high-performance concrete(UHPC),fluidity and shrinkage cracking are key aspects determining the performance and durability of this type of concrete.In this study,the effects ... Due to the low water-cement ratio of ultra-high-performance concrete(UHPC),fluidity and shrinkage cracking are key aspects determining the performance and durability of this type of concrete.In this study,the effects of different types of cementitious materials,chemical shrinkage-reducing agents(SRA)and steel fiber(SF)were assessed.Compared with M2-UHPC and M3-UHPC,M1-UHPC was found to have better fluidity and shrinkage cracking performance.Moreover,different SRA incorporation methods,dosage and different SF types and aspect ratios were implemented.The incorporation of SRA and SF led to a decrease in the fluidity of UHPC.SRA internal content of 1%(NSRA-1%),SRA external content of 1%(WSRA-1%),STS-0.22 and STE-0.7 decreased the fluidity of UHPC by 3.3%,8.3%,9.2%and 25%,respectively.However,SRA and SF improved the UHPC shrinkage cracking performance.NSRA-1%and STE-0.7 reduced the shrinkage value of UHPC by 40%and 60%,respectively,and increased the crack resistance by 338%and 175%,respectively.In addition,the addition of SF was observed to make the microstructure of UHPC more compact,and the compressive strength and flexural strength of 28 d were increased by 26.9%and 19.9%,respectively. 展开更多
关键词 ultra-high performance concrete chemical shrinkage reducing agent steel fiber shrinkage cracking repair and reinforcement
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Estimating shear strength of high-level pillars supported with cemented backfilling using the HoekeBrown strength criterion
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作者 Kaizong Xia Congxin Chen +3 位作者 Xiumin Liu Yue Wang Xuanting Liu Jiahao Yuan 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第2期454-469,共16页
Deep metal mines are often mined using the high-level pillars with subsequent cementation backfilling(HLSCB)mining method.At the design stage,it is therefore important to have a reasonable method for determining the s... Deep metal mines are often mined using the high-level pillars with subsequent cementation backfilling(HLSCB)mining method.At the design stage,it is therefore important to have a reasonable method for determining the shear strength of the high-level pillars(i.e.cohesion and internal friction angle)when they are supported by cemented backfilling.In this study,a formula was derived for the upper limit of the confining pressure σ3max on a high-level pillar supported by cemented backfilling in a deep metal mine.A new method of estimating the shear strength of such pillars was then proposed based on the Hoek eBrown failure criterion.Our analysis indicates that the horizontal stress σhh acting on the cemented backfill pillar can be simplified by expressing it as a constant value.A reasonable and effective value for σ3max can then be determined.The value of s3max predicted using the proposed method is generally less than 3 MPa.Within this range,the shear strength of the high-level pillar is accurately calculated using the equivalent MohreCoulomb theory.The proposed method can effectively avoid the calculation of inaccurate shear strength values for the high-level pillars when the original HoekeBrown criterion is used in the presence of large confining pressures,i.e.the situation in which the cohesion value is too large and the friction angle is too small can effectively be avoided.The proposed method is applied to a deep metal mine in China that is being excavated using the HLSCB method.The shear strength parameters of the high-level pillars obtained using the proposed method were input in the numerical simulations.The numerical results show that the recommended level heights and sizes of the high-level pillars and rooms in the mine are rational. 展开更多
关键词 Deep metal mines High-level pillars HoekeBrown strength criterion Cemented backfilling Confining pressure Shear strength
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Remaining oil distribution characteristics in an oil reservoir with ultra-high water-cut
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作者 Hongmin Yu Youqi Wang +4 位作者 Li Zhang Qingxin Zhang Zhenhai Guo Benzhe Wang Tao Sun 《Energy Geoscience》 EI 2024年第1期219-223,共5页
An accurate mapping and understanding of remaining oil distribution is very important for water control and stabilize oil production of mature oilfields in ultra-high water-cut stage.Currently,the Tuo-21 Fault Block o... An accurate mapping and understanding of remaining oil distribution is very important for water control and stabilize oil production of mature oilfields in ultra-high water-cut stage.Currently,the Tuo-21 Fault Block of the Shengtuo Oilfield has entered the stage of ultra-high water cut(97.2%).Poor adaptability of the well pattern,ineffective water injection cycle and low efficiency of engineering measures(such as workover,re-perforation and utilization of high-capacity pumps)are the significant problems in the ultra-high water-cut reservoir.In order to accurately describe the oil and water flow characteristics,relative permeability curves at high water injection multiple(injected pore volume)and a semiquantitative method is applied to perform fine reservoir simulation of the Sand group 3e7 in the Block.An accurate reservoir model is built and history matching is performed.The distribution characteristics of remaining oil in lateral and vertical directions are quantitatively simulated and analyzed.The results show that the numerical simulation considering relative permeability at high injection multiple can reflect truly the remaining oil distribution characteristics after water flooding in an ultrahigh water-cut stage.The distribution of remaining oil saturation can be mapped more accurately and quantitatively by using the‘four-points and five-types’classification method,providing a basis for potential tapping of various remaining oil types of oil reservoirs in late-stage of development with high water-cut. 展开更多
关键词 ultra-high water-cut High water injection multiple Four-points and five-types Numerical simulation Remaining oil distribution
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A universal multifunctional dual cation doping strategy towards stabilized ultra-high nickel cobalt-free lithium layered oxide cathode
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作者 Yabin Shen Dongming Yin +2 位作者 Limin Wang Gang Huang Yong Cheng 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第8期296-305,I0007,共11页
Ultra-high nickel cobalt-free lithium layered oxides are promising cathode material for lithium-ion batteries(LIBs)because of their relatively high capacity and low cost.Nevertheless,the high nickel content would indu... Ultra-high nickel cobalt-free lithium layered oxides are promising cathode material for lithium-ion batteries(LIBs)because of their relatively high capacity and low cost.Nevertheless,the high nickel content would induce bulk structure degradation and interfacial environment deterioration,and the absence of Co element reduces the lithium diffusion kinetics,severely limiting the performance liberation of this kind of cathodes.Herein,a multifunctional Ti/Zr dual cation co-doping strategy has been employed to improve the lithium storage performance of LiNi_(0.9)Mn_(0.1)O_(2)(NM91)cathode.On the one hand,the Ti/Zr co-doping weakens the Li^(+)/Ni^(2+)mixing through magnetic interactions due to the inexistence of unpaired electrons for Ti^(4+)and Zr^(4+),increasing the lithium diffusion rate and suppressing the harmful coexistence of H1 and H2 phases.On the other hand,they enhance the lattice oxygen stability because of the strong Ti-O and Zr-O bonds,inhibiting the undesired H3 phase transition and lattice oxygen loss,improving the bulk structure and cathode-electrolyte interface stability.As a result,the Ti/Zr co-doped NM91(NMTZ)exhibits a 91.2%capacity retention rate after 100 cycles,while that of NM91 is only82.9%.Also,the NMTZ displays better rate performance than NM91 with output capacities of 115 and93 mA h g^(-1)at a high current density of 5 C,respectively.Moreover,the designed NMTZ could enable the full battery to deliver an energy density up to 263 W h kg^(-1),making the ultra-high nickel cobaltfree lithium layered oxide cathode closer to practical applications. 展开更多
关键词 Lithium-ion battery ultra-high nickel cobalt-free cathode Ti/Zr co-doping Li^(+)/Ni^(2+)mixing Lattice oxygen stability
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Amine-functionalized metal organic framework@graphene oxide as filler in PAEK-containing carboxyl group membrane for ultrafiltration with ultra-high permeability and strong fouling resistance
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作者 Zhaoli Wang Wenjing Li +6 位作者 Yi Zhang Yanyin Cheng Junjian Yu Tianming Dong Xiaoyu Chi Di Liu Zhe Wang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第6期93-103,共11页
Achieving high fouling resistance and permeability using membrane separation technology in water treatment processes remains a challenge.In this work,a novel mixed-matrix membrane(MMM)(poly(arylene ether ketone)[PAEK]... Achieving high fouling resistance and permeability using membrane separation technology in water treatment processes remains a challenge.In this work,a novel mixed-matrix membrane(MMM)(poly(arylene ether ketone)[PAEK]-containing carboxyl groups[PAEK-COOH]/UiO-66-NH_(2)@graphene oxide[GO])with superb fouling resistance and high permeability was prepared by the nonsolvent-induced phase separation method,by in-situ growth of UiO-66-NH_(2) on the GO layer,and by preparing hydrophilic PAEK-COOH.On the basis of the structure and performance analysis of the MMM,the maximum water flux reached 591.25 L·m^(-2)·h^(-1) for PAEK-COOH/UiO-66-NH_(2)@GO,whereas the retention rate for bovine serum albumin increased from 85.40%to 94.87%.As the loading gradually increased,the hydrophilicity of the MMMs increased,significantly enhancing their fouling resistance.The strongest anti-fouling ability observed was 94.74%,which was 2.02 times greater than that of the pure membrane.At the same time,the MMMs contained internal amide and hydrogen bonds during the preparation process,forming a cross-linked structure,which further enhanced the mechanical strength and chemical stability.In summary,the MMMs with high retention rate,strong permeability,and anti-fouling ability were successfully prepared. 展开更多
关键词 Poly(arylene ether ketone)-containing Carboxyl groups(PAEK-COOH) UiO-66-NH_(2)@graphene oxide Hydrophilic modification ultra-high selectivity Strong anti-fouling
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Stability prediction of hard rock pillar using support vector machine optimized by three metaheuristic algorithms 被引量:3
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作者 Chuanqi Li Jian Zhou +1 位作者 Kun Du Daniel Dias 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2023年第8期1019-1036,共18页
Hard rock pillar is one of the important structures in engineering design and excavation in underground mines.Accurate and convenient prediction of pillar stability is of great significance for underground space safet... Hard rock pillar is one of the important structures in engineering design and excavation in underground mines.Accurate and convenient prediction of pillar stability is of great significance for underground space safety.This paper aims to develop hybrid support vector machine(SVM)models improved by three metaheuristic algorithms known as grey wolf optimizer(GWO),whale optimization algorithm(WOA)and sparrow search algorithm(SSA)for predicting the hard rock pillar stability.An integrated dataset containing 306 hard rock pillars was established to generate hybrid SVM models.Five parameters including pillar height,pillar width,ratio of pillar width to height,uniaxial compressive strength and pillar stress were set as input parameters.Two global indices,three local indices and the receiver operating characteristic(ROC)curve with the area under the ROC curve(AUC)were utilized to evaluate all hybrid models’performance.The results confirmed that the SSA-SVM model is the best prediction model with the highest values of all global indices and local indices.Nevertheless,the performance of the SSASVM model for predicting the unstable pillar(AUC:0.899)is not as good as those for stable(AUC:0.975)and failed pillars(AUC:0.990).To verify the effectiveness of the proposed models,5 field cases were investigated in a metal mine and other 5 cases were collected from several published works.The validation results indicated that the SSA-SVM model obtained a considerable accuracy,which means that the combination of SVM and metaheuristic algorithms is a feasible approach to predict the pillar stability. 展开更多
关键词 Underground pillar stability Hard rock Support vector machine Metaheuristic algorithms
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Lateral abutment pressure distribution and evolution in wide pillars under the first mining effect
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作者 Zhen Zhang Zhen Li +4 位作者 Gang Xu Xiaojin Gao Qianjin Liu Zhengjie Li Jiachen Liu 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2023年第3期309-322,共14页
The wide pillars are generally popular due to the high productivity and efficiency in Northwest China.The distribution of lateral abutment pressure in coal pillars is important for mining safety.To reveal the effect o... The wide pillars are generally popular due to the high productivity and efficiency in Northwest China.The distribution of lateral abutment pressure in coal pillars is important for mining safety.To reveal the effect of the first mining on the lateral abutment pressure distribution and evolution in wide pillars,an in-situ experiment,theoretical analysis and numerical simulation were performed.First,the field monitoring of lateral abutment pressure was conducted from the perspective of time and space in the Chahasu Coal Mine,Huangling No.2 Coal Mine and Lingdong Coal Mine during the first mining.Based on the field monitoring stress,a theoretical model was proposed to reveal the lateral abutment pressure distribution.The methodology was demonstrated through a case study.Aiming at the distribution mechanism,a numerical experiment was conducted through the finite-discrete element method(FDEM).Last,field observations of borehole fractures were performed to further study the damage distribution.In addition,two types of lateral abutment pressure evolution with mining advance were discussed.Suggestions on the stress monitoring layout were proposed as well.The results could provide foundations for strata control and disaster prevention in wide pillars in underground coal mines. 展开更多
关键词 Wide pillar Lateral abutment pressure pillar stress First mining effect Field monitoring
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Mechanical behaviors of deep pillar sandwiched between strong and weak layers
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作者 Sahendra Ram Petr Waclawik +4 位作者 Jan Nemcik Radovan Kukutsch Ashok Kumar Arun Kumar Singh Libin Gong 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2023年第5期1111-1126,共16页
A variety of coal room and pillar mining methods have been efficiently practiced at depths of up to 500 m with least strata mechanics issues.However,for the first time,this method was trialled at depths of 850 e900 m ... A variety of coal room and pillar mining methods have been efficiently practiced at depths of up to 500 m with least strata mechanics issues.However,for the first time,this method was trialled at depths of 850 e900 m in CSM mine of Czech Republic.The rhomboid-shaped coal pillars with acute corners of 70,surrounded with 5.2 m wide and 3.5e4.5 m high mine roadways,were used.Pillars were developed in a staggered manner with their size variation in the Panel II from 83 m×25 m to 24 m×20 m(corner to corner)and Panel V from 35 m×30 m to 26 m×16 m.Coal seam inclined at 12was affected by the unusual slippery slickenside roof bands and sometimes in the floor levels with high vertical stress below strong and massive sandstone roof.In order to ensure safety,pillars in both the panels were continuously monitored using various geotechnical instruments measuring the induced stresses,side spalling and roof sagging.Both panels suffered high amounts of mining induced stress and pillar failure with side-spalling up to 5 m from all sides.Heavy fracturing of coal pillar sides was controlled by fully encapsulated steel bolts.Mining induced stress kept increasing with the progress of development of pillars and galleries.Instruments installed in the pillar failed to monitor actual induced stress due to fracturing of coal mass around it which created an apprehension of pillar failure up to its core due to high vertical mining induced stress.This risk was reduced by carrying out scientific studies including the three-dimensional numerical models calibrated with data from the instrumented pillar.An attempt has been made to study the behavior of coal pillars and their yielding characteristics at deeper cover based on field and simulation results. 展开更多
关键词 pillar yielding mechanisms Great depth Numerical modeling Induced stress pillar dilation Slippery slickenside layer
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Comprehensive evaluation of chemical breakers for multistage network ultra-high strength gel
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作者 Zheng Kang Hu Jia +4 位作者 Zhong-Guo Li Biao Xia Yi Wang Yong Jiang Han-Lin Peng 《Petroleum Science》 SCIE EI CSCD 2023年第5期2864-2878,共15页
Polymer gels have been accepted as a useful tool to address many sealing operations such as drilling and completion,well stimulation,wellbore integrity,water and gas shutoff,etc.Previously,we developed an ultra-high s... Polymer gels have been accepted as a useful tool to address many sealing operations such as drilling and completion,well stimulation,wellbore integrity,water and gas shutoff,etc.Previously,we developed an ultra-high strength gel(USGel)for medium to ultra-low temperature reservoirs.However,the removal of USGel is a difficult problem for most temporary plugging operations.This paper first provides new insights into the mechanism of USGel,where multistage network structure and physical entanglement are the main reasons for USGel possessing ultra-high strength.Then the effects of acid breakers,encapsulated breakers,and oxidation breakers(including H_(2)O_(2),Na_(2)S_(2)O_(8),Ca(ClO)_(2),H_(2)O_(2)+NaOH,Na_(2)S_(2)O_(8)+NaOH,and Ca(ClO)_(2)+NaOH)were evaluated.The effects of component concentration and temperature on the breaking solution were studied,and the corrosion performance,physical simulation and formation damage tests of the breaking solution were carried out.The final formulation of 2%-4%NaOH+4.5%-6%H_(2)O_(2) breaking solution was determined,which can make USGel completely turn into water at 35e105C.The combinations of“acid t breaking solution”,“acid+encapsulated breaker”and“encapsulated breaker+breaking solution”were evaluated for breaking effect.The acid gradually reduced the volume of USGel,which increased the contact area between breaking solution and USGel,and the effect of“4%acid+breaking solution”was 23 times higher than that of breaking solution alone at 35C.However,the acid significantly reduced the strength of USGel.This paper provides new insights into the breaking of high-strength gels with complex network structures. 展开更多
关键词 Gel breaking Polymer gel ultra-high strength Chemical breakers Multistage network
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Combination of a reaction cell and an ultra-high vacuum system for the in situ preparation and characterization of a model catalyst
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作者 Yi-Jing Zang Shu-Cheng Shi +5 位作者 Yong Han Hui Zhang Wei-Jia Wang Peng Liu Mao Ye Zhi Liu 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2023年第5期13-21,共9页
An in-depth understanding of the structure-activity relationship between the surface structure,chemical composition,adsorption and desorption of molecules,and their reaction activity and selectivity is necessary for t... An in-depth understanding of the structure-activity relationship between the surface structure,chemical composition,adsorption and desorption of molecules,and their reaction activity and selectivity is necessary for the rational design of high-performance catalysts.Herein,we present a method for studying catalytic mechanisms using a combination of in situ reaction cells and surface science techniques.The proposed system consists of four parts:preparation chamber,temperatureprogrammed desorption(TPD)chamber,quick load-lock chamber,and in situ reaction cell.The preparation chamber was equipped with setups based on the surface science techniques used for standard sample preparation and characterization,including an Ar+sputter gun,Auger electron spectrometer,and a low-energy electron diffractometer.After a well-defined model catalyst was prepared,the sample was transferred to a TPD chamber to investigate the adsorption and desorption of the probe molecule,or to the reaction cell,to measure the catalytic activity.A thermal desorption experiment for methanol on a clean Cu(111)surface was conducted to demonstrate the functionality of the preparation and TPD chambers.Moreover,the repeatability of the in situ reaction cell experiment was verified by CO_(2) hydrogenation on the Ni(110)surface.At a reaction pressure of 800 Torr at 673 K,turnover frequencies for the methanation reaction and reverse water-gas shift reaction were 0.15 and 7.55 Ni atom^(-1) s^(-1),respectively. 展开更多
关键词 Surface science Model catalysts ultra-high vacuum Temperature-programmed desorption In situ reaction cell
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Influence Mechanism of Curing Regimes on Interfacial Transition Zone of Lightweight Ultra-High Performance Concrete
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作者 李洋 张高展 +3 位作者 YANG Jun ZHANG Jian DING Qingjun ZHAO Mingyu 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第3期591-603,共13页
This study aims to clarify the effects of curing regimes and lightweight aggregate(LWA)on the morphology, width and mechanical properties of the interfacial transition zone(ITZ) of ultra-high performance concrete(UHPC... This study aims to clarify the effects of curing regimes and lightweight aggregate(LWA)on the morphology, width and mechanical properties of the interfacial transition zone(ITZ) of ultra-high performance concrete(UHPC), and provide reference for the selection of lightweight ultra-high performance concrete(L-UHPC) curing regimes and the pre-wetting degree LWA. The results show that, under the three curing regimes(standard curing, steam curing and autoclaved curing), LWA is tightly bound to the matrix without obvious boundaries. ITZ width increases with the water absorption of LWA and decreases with increasing curing temperature. The ITZ microhardness is the highest when water absorption is 3%, and the microhardness value is more stable with the distance from LWA. Steam and autoclaved curing increase ITZ microhardness compared to standard curing. As LWA pre-wetting and curing temperatures increase, the degree of hydration at the ITZ increases, generating high-density CSH(HD CSH) and ultra-high-density CSH(UHD CSH), and reducing unhydrated particles in ITZ. ITZ micro-mechanical properties are optimized due to hydration products being denser. 展开更多
关键词 curing regime ultra-high performance concrete lightweight aggregate interfacial transition zone meso-mechanical properties micro-mechanical properties
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Study on the disaster caused by the linkage failure of the residual coal pillar and rock stratum during multiple coal seam mining:mechanism of progressive and dynamic failure
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作者 Yunliang Tan Qing Ma +4 位作者 Xiaoli Liu Xuesheng Liu Derek Elsworth Ruipengg Qian Junlong Shang 《International Journal of Coal Science & Technology》 EI CAS CSCD 2023年第3期122-135,共14页
Multi-seam mining often leads to the retention of a significant number of coal pillars for purposes such as protection,safety,or water isolation.However,stress concentration beneath these residual coal pillars can sig... Multi-seam mining often leads to the retention of a significant number of coal pillars for purposes such as protection,safety,or water isolation.However,stress concentration beneath these residual coal pillars can significantly impact their strength and stability when mining below them,potentially leading to hydraulic support failure,surface subsidence,and rock bursting.To address this issue,the linkage between the failure and instability of residual coal pillars and rock strata during multi-seam mining is examined in this study.Key controls include residual pillar spalling,safety factor(f.),local mine stiffness(LMS),and the post-peak stiffness(k)of the residual coal pillar.Limits separating the two forms of failure,progressive versus dynamic,are defined.Progressive failure results at lower stresses when the coal pillar transitions from indefinitely stable(f,>1.5)to failing(f,<1.5)when the coal pillar can no longer remain stable for an extended duration,whereas sud-den(unstable)failure results when the strength of the pillar is further degraded and fails.The transition in mode of failure is defined by the LMS/k ratio.Failure transitions from quiescent to dynamic as LMS/k.<1,which can cause chain pillar instability propagating throughout the mine.This study provides theoretical guidance to define this limit to instability of residual coal pillars for multi-seam mining in similar mines. 展开更多
关键词 Multi-seam mining Residual coal pillars Rock stratum Linkage instability mechanism Local mine stiffness
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Ultra-high Temperature Ceramic Coatings:A Review on Preparation Technology and Development Prospect
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作者 LIU Shijie WANG Li +7 位作者 DONG Binbin XU Biao GUO Yusen MIN Yongchao GUO Yanyan WEI Haoyu ZHANG Keke YIN Chaofan 《China's Refractories》 CAS 2023年第3期42-49,共8页
Ultra-high temperature ceramic coatings have ultra-high melting points,excellent mechanical properties and high temperature ablation resistance.These unique performance combinations turn it into a promising material f... Ultra-high temperature ceramic coatings have ultra-high melting points,excellent mechanical properties and high temperature ablation resistance.These unique performance combinations turn it into a promising material for use in extreme environment structures in rockets and hypersonic vehicles,particularly nozzles,leading edges and engine components.In this paper,various preparation methods of ultra-high temperature ceramic coatings were reviewed,including plasma spraying,chemical vapor deposition,pack cementation,slurry sintering,hot pressing and their research progress.Meanwhile,some new preparation methods of high temperature coatings,such as ion beam deposition,ultrasonic spraying,metal organic frame work coating,and magnetron sputtering,were introduced.The development trend of ultra-high temperature coatings was prospected as well. 展开更多
关键词 ultra-high temperature coating preparation process development prospect
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Evaluation of Uncertainty in Determination of Ethyl Maltol in Vegetable Oil by Ultra-high Performance Liquid Chromatograph-Mass Spectrometer(UPLC-MS)
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作者 Lei ZHANG 《Agricultural Biotechnology》 CAS 2023年第3期113-115,共3页
[Objectives]This study was conducted to establish an uncertainty evaluation method for the determination of ethyl maltol by ultra-high performance liquid chromatograph-mass spectrometer(UPLC-MS).[Methods]A mathematica... [Objectives]This study was conducted to establish an uncertainty evaluation method for the determination of ethyl maltol by ultra-high performance liquid chromatograph-mass spectrometer(UPLC-MS).[Methods]A mathematical model of uncertainty was established by analyzing the method for determining ethyl maltol using UPLC-MS.The sources of uncertainty were analyzed,and the components of uncertainty were calculated to evaluate the expanded uncertainty of the method.[Results]When the content of ethyl maltol in edible vegetable oil was 1657μg/kg,the expanded uncertainty was 22.4μg/kg(K=2,P=95%).[Conclusions]The uncertainty in this evaluation model mainly came from standard solution preparation,sample weighing,dilution of sample to constant volume,standard curve fitting,and repeated measurement. 展开更多
关键词 ultra-high performance liquid chromatograph-mass spectrometer DETERMINATION Ethyl maltol Uncertainty
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Experimental study on the movement law of overlying rock non-pillar coal overhead mining
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作者 LI Yong ZHENG Jing +5 位作者 WANG Feng-nian MA Xin-gen ZHANG Rui-xue SUN Ying-ying YIN Jian-bin TAO Zhi-gang 《Journal of Mountain Science》 SCIE CSCD 2023年第6期1759-1773,共15页
Pillarless coal mining technology is a new practical technology.Based on the compensating mechanical behavior of the Negative Poisson’s Ratio(NPR)anchor cable on the roof,the roadway was successfully retained by the ... Pillarless coal mining technology is a new practical technology.Based on the compensating mechanical behavior of the Negative Poisson’s Ratio(NPR)anchor cable on the roof,the roadway was successfully retained by the top cutting and pressure relief technology.This study utilizes the Digital Speckle Monitoring(DIC monitoring),stress-strain monitoring,and infrared thermal imaging systems to conduct physical model experiment of similar materials from the displacement,stress-strain,and temperature fields to investigate in depth the fracture change law of the overlying rock.In addition,it uses FLAC3D numerical simulation to invert the surface displacement settlement.The results show that the non-pillar overhead mining under the 110 mining method has little influence on the rock crack in the middle of the coal seam,and the crack development area is mainly concentrated in the overlying rock mass of the upward coal seam.The compensatory mechanical behavior of NPR anchor cable and the dilatation characteristics of rock mass have a good effect of retaining roadway along goaf,and can also reduce surface settlement.The 110 mining method provides a scientific basis for ecological environment protection and the development of other kilometer deep soft rock high ground stress underground projects. 展开更多
关键词 No pillar mining Overhead mining NPR anchor cable Physical model of similar materials FLAC3D Numerical simulation Motion of overburden
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