Aiming to analyze the damage mechanism of UTAO from the perspective of meso-mechanical mechanism using discrete element method(DEM),we conducted study of diseases problems of UTAO in several provinces in China,and fou...Aiming to analyze the damage mechanism of UTAO from the perspective of meso-mechanical mechanism using discrete element method(DEM),we conducted study of diseases problems of UTAO in several provinces in China,and found that aggregate spalling was one of the main disease types of UTAO.A discrete element model of UTAO pavement structure was constructed to explore the meso-mechanical mechanism of UTAO damage under the influence of layer thickness,gradation,and bonding modulus.The experimental results show that,as the thickness of UTAO decreasing,the maximum value and the mean value of the contact force between all aggregate particles gradually increase,which leads to aggregates more prone to spalling.Compared with OGFC-5 UTAO,AC-5 UTAO presents smaller maximum and average values of all contact forces,and the loading pressure in AC-5 UTAO is fully diffused in the lateral direction.In addition,the increment of pavement modulus strengthens the overall force of aggregate particles inside UTAO,resulting in aggregate particles peeling off more easily.The increase of bonding modulus changes the position where the maximum value of the tangential force appears,whereas has no effect on the normal force.展开更多
The electrocatalytic N_(2)reduction reaction(NRR)is expected to supersede the traditional Haber-Bosch technology for NH3 production under ambient conditions.The activity and selectivity of electrochemical NRR are rest...The electrocatalytic N_(2)reduction reaction(NRR)is expected to supersede the traditional Haber-Bosch technology for NH3 production under ambient conditions.The activity and selectivity of electrochemical NRR are restricted to a strong polarized electric field induced by the catalyst,correct electron transfer direction,and electron tunneling distance between bare electrode and active sites.By coupling the chemical vapor deposition method with the poly(methyl methacylate)-transfer method,an ultrathin sandwich catalyst,i.e.,Fe atoms(polarized electric field layer)sandwiched between ultrathin(within electron tunneling distance)BN(catalyst layer)and graphene film(conducting layer),is fabricated for electrocatalytic NRR.The sandwich catalyst not only controls the transfer of electrons to the BN surface in the correct direction under applied voltage but also suppresses hydrogen evolution reaction by constructing a neutral polarization electric field without metal exposure.The sandwich electrocatalyst NRR system achieve NH3 yield of 8.9μg h^(−1)cm^(−2)and Faradaic Efficiency of 21.7%.The N_(2)adsorption,activation,and polarization electric field changes of three sandwich catalysts(BN-Fe-G,BN-Fe-BN,and G-Fe-G)during the electrocatalytic NRR are investigated by experiments and density functional theory simulations.Driven by applied voltage,the neutral polarized electric field induced by BN-Fe-G leads to the high activity of electrocatalytic NRR.展开更多
For the application of carbon capture by membrane process,it is crucial to develop a highly permeable CO_(2)-selective membrane.In this work,we reported an ultra-thin polyether-block-amide(Pebax)mixedmatrix membranes(...For the application of carbon capture by membrane process,it is crucial to develop a highly permeable CO_(2)-selective membrane.In this work,we reported an ultra-thin polyether-block-amide(Pebax)mixedmatrix membranes(MMMs)incorporated by graphene oxide(GO),in which the interlayer channels were regulated to optimize the CO_(2)/N_(2) separation performance.Various membrane preparation conditions were systematically investigated on the influence of the membrane structure and separation performance,including the lateral size of GO nanosheets,GO loading,thermal reduction temperature,and time.The results demonstrated that the precisely regulated interlayer channel of GO nanosheets can rapidly provide CO_(2)-selective transport channels due to the synergetic effects of size sieving and preferential adsorption.The GO/Pebax ultra-thin MMMs exhibited CO_(2)/N_(2) selectivity of 72 and CO_(2) permeance of 400 GPU(1 GPU=106 cm^(3)(STP)·cm^(2)·s^(-1)·cmHg^(-1)),providing a promising candidate for CO_(2) capture.展开更多
Many industrial sectors exploit fossil sources to develop useful and necessary materials for our needs,such as bituminous paving materials.Bitumen,a key component of asphalt mixtures,is derived from oil refining and i...Many industrial sectors exploit fossil sources to develop useful and necessary materials for our needs,such as bituminous paving materials.Bitumen,a key component of asphalt mixtures,is derived from oil refining and its properties are influenced by the crude oil source and refining process,resulting in a significant carbon footprint.With growing awareness of resource depletion and environmental concerns,pavement researchers are exploring sustainable alternatives to reduce dependence on fossil sources.This includes a rising trend in using renewable materials like biomasses to produce bio-based binders as substitutes for bitumen,aiming for a more sustainable approach.Biomasses,including vegetal and animal wastes,and waste cooking oils,as substitutes for crude oil in the production of bio-binders.Through thermochemical conversion(TCC),such as pyrolysis,biomasses can be converted into bio-char and bio-oils,which can replace fossil-based components in binders.Researchers have utilized these bio-products to reduce the dependency on fossil fuels in binders.However,there are no set minimum requirements for bio-components in bio-based binders.As the percentage of replaced bitumen increases,various types of binders are produced,including modified bitumen,extended bitumen,and alternative binders,where the fossil replacement is gradual.Overall rheological tests on bio-binders,reveal that those containing biochar exhibit increased viscosity,stiffness,rutting resistance,and sometimes antioxidant properties.Conversely,bio-binders with bio-oils as bitumen substitutes show poorer performance at high temperatures but improved behavior at low temperatures.These results suggest that bio-binders could provide versatile solutions for various climatic and loading conditions in road construction.However,the development of pavement mixtures based on bio-binders has not been studied in depth and requires further attention to unlock its full potential.As sustainability considerations,including life cycle assessments(LCA)and life cycle cost analyses(LCC),are crucial aspects for future studies.It is essential not only to collect data on the performance characteristics of bio-binders but also to understand their environmental impact and recyclability.In-depth evaluations using methods such as LCA and LCC will provide valuable insights into the overall sustainability and long-term viability of these products.展开更多
Tactile paving is a professional road facility to ensure the safe travel of people with visual impairment.However,there are many problems with tactile paving travel in practice.For one,some tactile paving is seriously...Tactile paving is a professional road facility to ensure the safe travel of people with visual impairment.However,there are many problems with tactile paving travel in practice.For one,some tactile paving is seriously damaged,and the other is the accumulation of obstacles.How to help visually impaired people recognize and locate obstacles in tactile paving is a problem worth studying.In this paper,image recognition technology is used to recognize the tactile paving pictures with obstacles,and an attention mechanism is used to optimize samples to improve recognition accuracy.展开更多
The stability of roads in cities directly affects the safety of traffic and transportation.In the process of pavement laying,relevant personnel should use permeable paving materials in the process of construction.Base...The stability of roads in cities directly affects the safety of traffic and transportation.In the process of pavement laying,relevant personnel should use permeable paving materials in the process of construction.Based on the analysis of road drainage requirements,traditional paving materials have relatively poor water permeability,which leads to ponding problems during road use[1].Within this frame of reference,beginning with the characteristics of permeable paving materials,this paper makes an in-depth exploration on practical application measures.展开更多
The important parameters that influence the mechanical property of the pavinglayer on an orthotropic steel bridge deck are the paving layer thickness and modulus of the asphaltconcrete surfacing. Three important indic...The important parameters that influence the mechanical property of the pavinglayer on an orthotropic steel bridge deck are the paving layer thickness and modulus of the asphaltconcrete surfacing. Three important indices that control the typical failures of the paving layerare the maximum tensile stress of paving layer, the maximum shear stress between the steel deck andthe paving layer, and the maximum deflection on the paving surface. In this paper, the analyticalmodel of paving systems on orthotropic steel bridge deck is established, and the finite elementmethod is adopted to study the stress and strain of paving system. With the variation of asphaltconcrete modulus in high or low temperature season, the influences of paving layer thickness onthree control indices are researched. The results provide a theoretical basis for the determinationof thickness of the paving layer on the steel bridge deck.展开更多
Many specifications of paving asphalts are closely related to their colloidal stability, which is, however, determined by their exact chemical compositions. The Yumen vacuum residue (YVR), the bottoms of a paraffinic...Many specifications of paving asphalts are closely related to their colloidal stability, which is, however, determined by their exact chemical compositions. The Yumen vacuum residue (YVR), the bottoms of a paraffinic crude oil is unfit for the production of highway paving asphalts directly, Neither are the de-oiled asphalts of the YVR. In this research a blending method and an optimal process of solvent de-asphalts are adopted to investigate the feasibility of formulating highway-paving asphalts from YVR. Results show that highway paving asphalts are formulated by blending solvent de-oiled asphalts with one or more of the materials including YVR, decanted oil from FCC process, and furfural extracts from lubricating base stocks. Further investigations indicate that adding oil decanted from FCC process to the solvent de-asphalting process can increase the de-asphalted oil production, improve the de-oiled asphalts quality, and thus optimize the refinery processes. The methodology of this research can be extended even to refineries processing non-paraffinic crude oils.展开更多
Highway maintenance mileage reached 5.25 million kilometers in China by 2021.Ultra-thin overlay is one of the most commonly used maintenance technologies,which can significantly enhance the economic and environmental ...Highway maintenance mileage reached 5.25 million kilometers in China by 2021.Ultra-thin overlay is one of the most commonly used maintenance technologies,which can significantly enhance the economic and environmental benefits of pavements.To promote the low-carbon development of ultrathin overlays,this paper mainly studied the mechanism and influencing factors of several ultra-thin overlay functions.Firstly,the skid resistance,noise reduction,rutting resistance,and crack resistance of ultrathin overlays were evaluated.The results indicated that the high-quality aggregates improved the skid and rutting resistance of ultra-thin overlay by 5%-20%.The optimized gradations and modified binders reduced noise of ultra-thin overlay by 0.4-6.0 dB.The high viscosity modified binders improved the rutting resistance of ultra-thin overlay by about 10%-130%.Basalt fiber improved the cracking resistance of ultra-thin overlay by more than 20%.Due to the thinner thickness and better road performance,the performance-based engineering cost of ultra-thin overlay was reduced by about 30%-40%compared with conventional overlays.Secondly,several environmentally friendly functions of ultra-thin overlay were investigated,including snow melting and deicing,exhaust gas purification and pavement cooling.The lower thickness of ultra-thin overlay was conducive to the diffusion of chloride-based materials to the pavement surface.Therefore,the snow melting effect of self-ice-melting was better.In addition,the ultra-thin overlay mixture containing photocatalytic materials could decompose 20%-50%of the exhaust gas.The colored ultra-thin overlay was able to reduce the temperature of the pavement by up to 8.1℃.The temperature difference between the upper and lower surfaces of the ultra-thin overlay containing thermal resistance materials could reach up to 12.8℃.In addition,numerous typical global engineering applications of functional ultra-thin overlay were summarized.This review can help better understand the functionality of ultra-thin overlays and promote the realization of future multi-functional and low-carbon road maintenance.展开更多
A novel mesa ultra-thin base AlGaAs/GaAs HBT is designed and fabricated with wet chemical selective etch technique and monitor electrode technique. It has a particular and obvious voltage-controlled NDR whose PVCR is ...A novel mesa ultra-thin base AlGaAs/GaAs HBT is designed and fabricated with wet chemical selective etch technique and monitor electrode technique. It has a particular and obvious voltage-controlled NDR whose PVCR is larger than 120. By use of device simulation,the cause of NDR is that increasing collector voltage makes the ultrathin base reach through and the device transforms from a bipolar state to a bulk barrier state. In addition, the simulated cutoff frequency is about 60-80GHz.展开更多
文摘Aiming to analyze the damage mechanism of UTAO from the perspective of meso-mechanical mechanism using discrete element method(DEM),we conducted study of diseases problems of UTAO in several provinces in China,and found that aggregate spalling was one of the main disease types of UTAO.A discrete element model of UTAO pavement structure was constructed to explore the meso-mechanical mechanism of UTAO damage under the influence of layer thickness,gradation,and bonding modulus.The experimental results show that,as the thickness of UTAO decreasing,the maximum value and the mean value of the contact force between all aggregate particles gradually increase,which leads to aggregates more prone to spalling.Compared with OGFC-5 UTAO,AC-5 UTAO presents smaller maximum and average values of all contact forces,and the loading pressure in AC-5 UTAO is fully diffused in the lateral direction.In addition,the increment of pavement modulus strengthens the overall force of aggregate particles inside UTAO,resulting in aggregate particles peeling off more easily.The increase of bonding modulus changes the position where the maximum value of the tangential force appears,whereas has no effect on the normal force.
文摘The electrocatalytic N_(2)reduction reaction(NRR)is expected to supersede the traditional Haber-Bosch technology for NH3 production under ambient conditions.The activity and selectivity of electrochemical NRR are restricted to a strong polarized electric field induced by the catalyst,correct electron transfer direction,and electron tunneling distance between bare electrode and active sites.By coupling the chemical vapor deposition method with the poly(methyl methacylate)-transfer method,an ultrathin sandwich catalyst,i.e.,Fe atoms(polarized electric field layer)sandwiched between ultrathin(within electron tunneling distance)BN(catalyst layer)and graphene film(conducting layer),is fabricated for electrocatalytic NRR.The sandwich catalyst not only controls the transfer of electrons to the BN surface in the correct direction under applied voltage but also suppresses hydrogen evolution reaction by constructing a neutral polarization electric field without metal exposure.The sandwich electrocatalyst NRR system achieve NH3 yield of 8.9μg h^(−1)cm^(−2)and Faradaic Efficiency of 21.7%.The N_(2)adsorption,activation,and polarization electric field changes of three sandwich catalysts(BN-Fe-G,BN-Fe-BN,and G-Fe-G)during the electrocatalytic NRR are investigated by experiments and density functional theory simulations.Driven by applied voltage,the neutral polarized electric field induced by BN-Fe-G leads to the high activity of electrocatalytic NRR.
基金financially supported by The Natural Science Foundation of the Jiangsu Higher Education Institutions of China(22KJB530007,22KJA530001)National Natural Science Foundation of China(22208151)+1 种基金the Natural Science Foundation of Jiangsu Province(BK20220002)the State Key Laboratory of MaterialsOriented Chemical Engineering(SKL-MCE-22B07).
文摘For the application of carbon capture by membrane process,it is crucial to develop a highly permeable CO_(2)-selective membrane.In this work,we reported an ultra-thin polyether-block-amide(Pebax)mixedmatrix membranes(MMMs)incorporated by graphene oxide(GO),in which the interlayer channels were regulated to optimize the CO_(2)/N_(2) separation performance.Various membrane preparation conditions were systematically investigated on the influence of the membrane structure and separation performance,including the lateral size of GO nanosheets,GO loading,thermal reduction temperature,and time.The results demonstrated that the precisely regulated interlayer channel of GO nanosheets can rapidly provide CO_(2)-selective transport channels due to the synergetic effects of size sieving and preferential adsorption.The GO/Pebax ultra-thin MMMs exhibited CO_(2)/N_(2) selectivity of 72 and CO_(2) permeance of 400 GPU(1 GPU=106 cm^(3)(STP)·cm^(2)·s^(-1)·cmHg^(-1)),providing a promising candidate for CO_(2) capture.
基金The research is funded by the NEXT GENERATION EU–PNRR project ex D.M.352/2022.The authors would like to thank ENI S.p.A for supporting this research.
文摘Many industrial sectors exploit fossil sources to develop useful and necessary materials for our needs,such as bituminous paving materials.Bitumen,a key component of asphalt mixtures,is derived from oil refining and its properties are influenced by the crude oil source and refining process,resulting in a significant carbon footprint.With growing awareness of resource depletion and environmental concerns,pavement researchers are exploring sustainable alternatives to reduce dependence on fossil sources.This includes a rising trend in using renewable materials like biomasses to produce bio-based binders as substitutes for bitumen,aiming for a more sustainable approach.Biomasses,including vegetal and animal wastes,and waste cooking oils,as substitutes for crude oil in the production of bio-binders.Through thermochemical conversion(TCC),such as pyrolysis,biomasses can be converted into bio-char and bio-oils,which can replace fossil-based components in binders.Researchers have utilized these bio-products to reduce the dependency on fossil fuels in binders.However,there are no set minimum requirements for bio-components in bio-based binders.As the percentage of replaced bitumen increases,various types of binders are produced,including modified bitumen,extended bitumen,and alternative binders,where the fossil replacement is gradual.Overall rheological tests on bio-binders,reveal that those containing biochar exhibit increased viscosity,stiffness,rutting resistance,and sometimes antioxidant properties.Conversely,bio-binders with bio-oils as bitumen substitutes show poorer performance at high temperatures but improved behavior at low temperatures.These results suggest that bio-binders could provide versatile solutions for various climatic and loading conditions in road construction.However,the development of pavement mixtures based on bio-binders has not been studied in depth and requires further attention to unlock its full potential.As sustainability considerations,including life cycle assessments(LCA)and life cycle cost analyses(LCC),are crucial aspects for future studies.It is essential not only to collect data on the performance characteristics of bio-binders but also to understand their environmental impact and recyclability.In-depth evaluations using methods such as LCA and LCC will provide valuable insights into the overall sustainability and long-term viability of these products.
基金supported by the Jiangsu Province College Student Innovation Training Program(Project No.20221127684Y)the Talent Startup project of Nanjing Institute of Technology(Project No.YKJ202117)。
文摘Tactile paving is a professional road facility to ensure the safe travel of people with visual impairment.However,there are many problems with tactile paving travel in practice.For one,some tactile paving is seriously damaged,and the other is the accumulation of obstacles.How to help visually impaired people recognize and locate obstacles in tactile paving is a problem worth studying.In this paper,image recognition technology is used to recognize the tactile paving pictures with obstacles,and an attention mechanism is used to optimize samples to improve recognition accuracy.
文摘The stability of roads in cities directly affects the safety of traffic and transportation.In the process of pavement laying,relevant personnel should use permeable paving materials in the process of construction.Based on the analysis of road drainage requirements,traditional paving materials have relatively poor water permeability,which leads to ponding problems during road use[1].Within this frame of reference,beginning with the characteristics of permeable paving materials,this paper makes an in-depth exploration on practical application measures.
文摘The important parameters that influence the mechanical property of the pavinglayer on an orthotropic steel bridge deck are the paving layer thickness and modulus of the asphaltconcrete surfacing. Three important indices that control the typical failures of the paving layerare the maximum tensile stress of paving layer, the maximum shear stress between the steel deck andthe paving layer, and the maximum deflection on the paving surface. In this paper, the analyticalmodel of paving systems on orthotropic steel bridge deck is established, and the finite elementmethod is adopted to study the stress and strain of paving system. With the variation of asphaltconcrete modulus in high or low temperature season, the influences of paving layer thickness onthree control indices are researched. The results provide a theoretical basis for the determinationof thickness of the paving layer on the steel bridge deck.
文摘Many specifications of paving asphalts are closely related to their colloidal stability, which is, however, determined by their exact chemical compositions. The Yumen vacuum residue (YVR), the bottoms of a paraffinic crude oil is unfit for the production of highway paving asphalts directly, Neither are the de-oiled asphalts of the YVR. In this research a blending method and an optimal process of solvent de-asphalts are adopted to investigate the feasibility of formulating highway-paving asphalts from YVR. Results show that highway paving asphalts are formulated by blending solvent de-oiled asphalts with one or more of the materials including YVR, decanted oil from FCC process, and furfural extracts from lubricating base stocks. Further investigations indicate that adding oil decanted from FCC process to the solvent de-asphalting process can increase the de-asphalted oil production, improve the de-oiled asphalts quality, and thus optimize the refinery processes. The methodology of this research can be extended even to refineries processing non-paraffinic crude oils.
基金the National Key Research and Development Program of China(2022YFE0137300)the National Natural Science Foundation of China(52078018)the German Research Foundation(SFB/TRR 339 and 453596084).
文摘Highway maintenance mileage reached 5.25 million kilometers in China by 2021.Ultra-thin overlay is one of the most commonly used maintenance technologies,which can significantly enhance the economic and environmental benefits of pavements.To promote the low-carbon development of ultrathin overlays,this paper mainly studied the mechanism and influencing factors of several ultra-thin overlay functions.Firstly,the skid resistance,noise reduction,rutting resistance,and crack resistance of ultrathin overlays were evaluated.The results indicated that the high-quality aggregates improved the skid and rutting resistance of ultra-thin overlay by 5%-20%.The optimized gradations and modified binders reduced noise of ultra-thin overlay by 0.4-6.0 dB.The high viscosity modified binders improved the rutting resistance of ultra-thin overlay by about 10%-130%.Basalt fiber improved the cracking resistance of ultra-thin overlay by more than 20%.Due to the thinner thickness and better road performance,the performance-based engineering cost of ultra-thin overlay was reduced by about 30%-40%compared with conventional overlays.Secondly,several environmentally friendly functions of ultra-thin overlay were investigated,including snow melting and deicing,exhaust gas purification and pavement cooling.The lower thickness of ultra-thin overlay was conducive to the diffusion of chloride-based materials to the pavement surface.Therefore,the snow melting effect of self-ice-melting was better.In addition,the ultra-thin overlay mixture containing photocatalytic materials could decompose 20%-50%of the exhaust gas.The colored ultra-thin overlay was able to reduce the temperature of the pavement by up to 8.1℃.The temperature difference between the upper and lower surfaces of the ultra-thin overlay containing thermal resistance materials could reach up to 12.8℃.In addition,numerous typical global engineering applications of functional ultra-thin overlay were summarized.This review can help better understand the functionality of ultra-thin overlays and promote the realization of future multi-functional and low-carbon road maintenance.
文摘A novel mesa ultra-thin base AlGaAs/GaAs HBT is designed and fabricated with wet chemical selective etch technique and monitor electrode technique. It has a particular and obvious voltage-controlled NDR whose PVCR is larger than 120. By use of device simulation,the cause of NDR is that increasing collector voltage makes the ultrathin base reach through and the device transforms from a bipolar state to a bulk barrier state. In addition, the simulated cutoff frequency is about 60-80GHz.