Geochemistry of Alkaline-Ultrabasic Rocks in the Jijie Complex, Lufeng, Yunnan

This paper is concerned with the geochemical features of major elements, transitionmetal elements, large ion lithophile elements, rare-earth elements and Sr isotopes in alkaline-ul-trabasic rocks in the Jijie complex of Lufeng, Yunnan Province, which is located in southernSichuan-Yunnan rift zone, one of Luoci alkaline-ultrabasic complexes in central Ynnnan.Moreover, its origin pertaining primary magma, magma soure region, fractional crystallization,etc. are also discussed in the present paper.

THE STUDY OF META-BASIC-ULTRABASIC ROCKS IN THEPROTEROZOIC DANZHOU GROUP,NORTHERN GUANGXI:A NEW VIEW

Recent geological study and survey on the scale of 1: 50000 in northern Guangxi have made some advancements: meta-basic-ultrabasic rocks which occured as bedding injection sheets in the Sanrnenjie formation of the Proterozoic Danzhou group and caused contact metamorphism or hydrothermal alteration in adjacent wallrocks, were originated in extensional environment. Basic rocks belong to deep-sea tholeiite. TLe meta-basic -ultrabasic rocks sufferred intense deformation partitioning, resulting in lenticular network which was composed of mylonite zones in highly de formed field and lensoids in less- or non-deformed field. This structural pattern was explained as "melange" or "non-rooted cool intrusion " by previous workers. The deformation partitioning was mainly pure shearing in the early stage plus simple shearing in the later stage. This evolution was closely related to progressive deformation of the Guangxi orogeny.

Geochemical Characteristics of the Jinjiazhuang Ultrabasic Rock-Type Gold Deposit in Chicheng County, Hebei Province

The Jinjiazhuang gold deposit occurs in the Zhangjiakou gold field, Northwest Hebei. The ore bodies are mostly hosted in Xiaozhangjiakou ultrabasic rocks dominated by diopsidite. Electron microprobe analyses indicate that the deposit is characterized by the enrichment of some platinum group elements in principal metallic minerals such as chalcopyrite, galena, sphalerite and pyrite, and the presence of millerite. Stable isotope studies show that carbon, sulfur and most of the metallogenic elements were probably derived largely from the host Xiaozhangjiakou ultrabasic rocks and that it is possible that the ore\|forming fluid was predominated by meteoric water.

Geological characteristics and metallogenic significance of the Devonian intermediate-basic volcanic rocks in the Dachang deposit, Guangxi Zhuang Autonomous Region

Recently discovered intermediate-basic volcanic rocks in the Devonian strata at Dachang, Guangxi Zhuang Autonomous Region are dominated by basalts and andesites. Most of them belong to the calc-alkali and alkali series. Petrology and geochemistry data indicate that the volcanic rocks may be formed in a continental rift environment. The volcanic rocks are in conformable contact with the overlying and underlying wall rocks, with such typical sedimentary structures as laminated and striped ones, and the host rocks of the volcanic rocks contain lots of marine fossils such as tentaculite. Many pieces of evidence indicate that the eruption environment of the volcanic rocks is a sea-facies one. The volcanic rocks are of the LREE-enrichment type, with high ratios of light rare-earth elements to heavy rare-earth elements. In addition, they display moderately negative δEu anomalies and moderately negative δCe anomalies with a higher degree of LREE and HREE fractionation. Through the Q-cluster analysis of the REE samples, it is indicated that the ores have a closer relation with the layered volcanic rocks, and also possess a certain inheritance-consistency relationship with the layered volcanic rocks. The source of ore-forming materials may be related with volcanism. It is proposed that the ore deposit in the study area should be genetically explained as the result of marine volcano-sedimentary exhalation of hot water and late superposition-reworking.

Geochemical and Geochronological Constraints on the Origin of the Meta-basic Volcanic Rocks in the Tengtiaohe Zone, Southeast Yunnan

The meta-basic volcanic rocks in the Tengtiaohe Zone yield zircon U–Pb ages of 258.8±2.5 Ma and 259.2±1.8 Ma, respectively which agree with the ages of flood basalts of ELIP and are similar to the basaltic rocks and komatiites from the Song Da Zone in northern Vietnam. The results suggest that the age of meta-basic volcanic rocks is Late Permian, rather than the Early Permian or Early Carboniferous ages as previously inferred. Most meta-basic volcanic rocks are strongly enriched in LREEs relative to HREEs and display trace element patterns similar to the ELIP high-Ti basalts, and are enriched in LILEs with negative Sr anomalies. Their initial 87^Sr/86^Sr ratios range from 0.705974 to 0.706188 and εNd（t） from-0.82 to-2.11. Their magmas were derived from an enriched and deep mantle source without significant crustal contamination. These meta-basic volcanic rocks formed in ELIP. Therefore, the Tengtiaohe Zone is not an ophiolite zone and can link to the Song Da Zone in northern Vietnam.

Control of Melt Structures on Cu-Au Mineralization in Basic-Ultrabasic Complexes of Northern China

Based on systematic analyses of 72 samples of different basic-ultrabasic rocks, the present paper discusses the relationship between melt structure and Cu and Au mineralization. It is found that if the NBO/T, NBO, M2+, FeO and MgO values are relatively high and the T, M3+, Fe2O3 and CaO values are low the basic-ultrabasic melt will be favourable to Cu (Ni) mineralization, but if the former are low and the latter are high it is favourable to Au metallization. Cu ions occupy dominantly octahedra in basic-ultrabasic melt and the higher the NBO/T, NBO and M2+ values, the more the octahedra in the melt. Au element mainly takes the form of Au+ ions in basic-ultrabasic melt and the Au+ ions constitute tetrahedral sites together with Fe3+ ions. Therefore, low M2+ and high Fe3+, i.e. high oxygen fu-gacity, can promote the enrichment of Au+ ions and Au mineralization. Components NT (other than Au+), Al2O3 and SiO2 in basic-ultrabasic melt have no effect on metallogenetic species. As mentioned above, in relevant diagrams distribution areas of the characteristic values of ore-free melt and those of ore-forming melt are overlapped in different degrees, which possibly indicates that not all the magmas have mineralizing ability. It can be well distinguished whether basic-ultrabasic rocks are favourable to Cu or Au mineralization or they are just ore-free rocks by analysing integrated diagrams of the characteristic values of the magmatic melt structure.

Thermal simulation of basic volcanic fluid influence on different source rocks

Based on thermal simulation experiment, interactions between volcanic fluids and source rocks were studied. Gas generations in the dry system and fluid system under different temperatures were analyzed. The results showed that the various types of source rocks are similar in composition, containing gaseous C1-C5 hydrocarbons, H2 and CO2 whose gas yields increase with increasing temperature. The gas yield of source rocks of type is Ⅰ the highest, followed by type Ⅱ, and that of source rocks of type is Ⅲ the lowest, indicating that the yield of hydrocarbon gases is related to their hydrocarbon generating potential. Although the generating potential of type is Ⅲ the lowest, it can still be regarded as a useful gas source when it is buried deeply enough. The basic volcanic fluid restrains the generation of gaseous hydrocarbons in different types of source rocks, but promotes the generation of inorganic gases.

MODELLING OF COMPOSITION OF MANTLE SOURCE FOR THE JIJIE ALKALINE-ULTRABASIC INTRUSIVE COMPLEX, LUFENG, YUNNAN

Based on the data on petrology and geochemisty for the Jijie alkaline-ultrabasic intrusive rock complex, this paper, by means of correlation, suggested that the average composition of melteigites with 10% olivine added (Fo=86) can be considered as the composition of the primary magma of the Jijie complex. This magma, whose composition is estimated from the incompatible element P2O5, was produced by 3%±partial melting of pyrolites. The results of Petrological Mixing Calculating showed that the mantle-source rocks of the Jijie complex are obviously depleted in incompatible elements.

Geochemistry of the Caledonian Basic Volcanic Rocks at the South Margin of the Qinling Orogenic Belt, and Its Tectonic Implications

The geochemistry of the basic volcanic rocks at the south margin of the Qinling orogenic belt (SMQOB) suggests that they were formed in an intraplate tectonic setting. The REE distribution patterns show these rocks are strongly enriched in LREE with high ΣREE, and their trace elements geochemistry is similar to that of continental flood basalt. All the above evidence suggests that the Caledonian basic volcanic rocks in the SMQOB were tholeiitic basalts formed in an intraplate spreading initial rift tectonic setting. The characteristics of regional geology and geochemistry indicate that there was an intraplate spreading rift tectonic setting between the South Qinling block and the Yangtze block in the Caledonian epoch. The dynamic spreading in this district began in the Early Caledonian and then the intraplate spreading initial rifts were formed in the Late Caledonian. As a result of spreading of the Tethys and geodynamic processes in deep mantle, the Mianlue Huashan oceanic basin was formed between the Qinling block and the Yangtze block in Devonian, and the Qinling microplate was separated from the northern part of the Yangtze plate.

Geochemical and Sr-Nd-Pb isotopic compositions of volcanic rocks from the Iheya Ridge,the middle Okinawa Trough：implications for petrogenesis and a mantle source

As an active back-arc basin, the Okinawa Trough is located in the southeastern region of the East China Sea shelf and is strongly influenced by the subduction of the Philippine Sea Plate. Major element, trace element and Sr-NdPb isotopic composition data are presented for volcanic rocks from the Iheya Ridge（IR）, the middle Okinawa Trough. The IR rocks record large variations in major elements and range from basalts to rhyolites. Similar trace element distribution characteristics together with small variations in ^87Sr/^86Sr（0.703 862–0.704 884）, ^144Nd/^143Nd（0.512 763–0.512 880） and Pb isotopic ratios, demonstrate that the IR rocks are derived from a similar magma source. The fractional crystallization of olivine, clinopyroxene, plagioclase, and amphibole, as well as accessory minerals, can reasonably explain the compositional variations of these IR rocks. The simulations suggest that approximately 60% and 75% fractionation of an evolved basaltic magma can produce trace element compositions similar to those of the intermediate rocks and acid rocks, respectively. The analysis of their Sr-Nd-Pb isotopic content ratios suggest that the source of the rocks from the IR is close to the depleted mantle（DM） but extends to the enriched mantle（EMII）, indicating that the mantle source of these rocks is a mixture between the DM and EMII end members. The simulations show that the source of the IR volcanic rocks can be best interpreted as the result of the mixing of approximately 0.8%–2.0% subduction sediment components and 98.0%–99.2% mantlederived melts.

LA-ICP-MS U-Pb Zircon Geochronology of Basic Dikes within Maxianshan Rock Group in the Central Qilian Orogenic Belt and Its Tectonic Implications

A large number of basic dikes, which indicate an important tectonic-magmatic event in the eastern part of the Central Qilian （祁连） orogenic belt, were found from Maxianshan （马衔山） rock group, Yongjing （永靖） county, Gansu （甘肃） Province, China. According to the research on the characteristics of geology and petrology, the basic dike swarms, widely intruded in Maxianshan rock group, are divided into two phases by the authors. U-Pb isotope of zircons from the basic dikes above two phases is separately determined by LA-ICP-MS in the Key Laboratory of Continental Dynamics of Northwest University, China and the causes of formation of the zircons are studied using CL images. The formation age of the earlier phase of metagabbro dikes is （441.1±1.4） Ma （corresponding to the early stage of Early Silurian）, and the age of the main metamorphic period is （414.3±1.2） Ma （corresponding to the early stage of Early Devonian）. The formation age of the later phase of diabase dike swarms is （434±1.0） Ma （corresponding to the late stage of Early Silurian）. The cap- tured-zircons from diabase dike swarms saved some information of material interfusion by Maxianshan rock group （^207pb/206pb apparent ages are （2 325±3）-（2 573 ±6） Ma）, and some zircons from diabase dike swarms also saved impacted information by tectonic thermal event during the late period of Caledonian movement （^206pb/^238U apparent ages are （400±2）-（429±2） Ma）. By combining the results of the related studies, the basic dikes within Maxianshan rock group were considered to be formed in the transfer period, from subductional orogeny towards collisional orogeny, which represents geological records of NW-SE extension during regional NE-SW towards intense compression in the Central Qilian block.

Cu-Ni-PGES MINERALIZATION OF MELANOCRATIC ROCKS IN SOUTHEAST MARGIN OF THE QINGHAI-XIZANG(TIBET) PLATEAU, HKT

The Panxi Rift Zone is a famous metallogenic province in Southwest China. Continental rifting developed in Hercynian period (P 2, 260～250Ma) accompany with a series of basic\|ultrabasic rocks. Various in lithologies, such as layered intrusions (V\|Ti\|Fe formation), small\|sized mafic\|ultramafic bodies (stocks) and large\|scale basalt (Emeishan Basalt) are constituted of a complete melanocratic rock system.Most of Cu\|Ni\|PGE sulfide deposits are related to small\|sized ultramafic rock bodies. It is a perfect possibility for them to be an affinity of basic eruptive lava and for the neck facies. But in ① Panzhihua\|Center Yunnan Province, the Gaojiacun, also Jinbaoshan, as large stratiform basic\|ultrabasic complex used to be thought that is older one intruded to basement rocks in Precambrian. However, new evidences suggest it is similar with the small\|sized ultramafic rock bodies containing Cu\|Ni\|PGE, and also the both are affinity of the Emeishan Basalt; ② Miyi district, Cu\|Pt mineralization was discovered in the Xinjie bedded basic complex, and in where ophitic olivine\|pyroxenite\|peridotite facies are exactly Pt\|bearing layers; ③ Longzhoushan district, we have recently researched basic\|ultrabasic clusters which intruded into fracture zones, and Cu\|Ni\|Pt, Pd mineralization developed at the salbands.Generally, the basalt is poor in PGE and rich in Cu. It is suggested as the result of PGE dispersion\|concentration processing in the melanocratic rock system when rifting happened.

Source Rock Classification and the Basic Structure of Coal and Kerogen

In accordance with the confusion on classification of source rocks, the authors raised a source rock classification for its enriched and dispersed organic matter types based on both Alpern’s idea and maceral genesis/composition. The determined rock type is roughly similar to palynofacies of Combaz , whereas it is "rock maceral facies (for coal viz. coal facies)" in strictly speaking. Therefore, it is necessary to use the organic ingredients classification proposed by the authors so that it can be used for both maceral analysis and environment research . This source rock classification not only shows sedimentology and diagenetic changes but also acquires organic matter type even if hydrocarbon potential derived from maceral’s geochemical parameters. So, it is considered as genetic classification. The "rock maceral facies" may be transformed to sedimentary organic facies , which is used as quantitative evaluation means if research being perfect.Now, there are many models in terms of structure either for coal or for kerogen. In our opinion, whatever coal or kerogen ought be polymer, then we follow Combaz’s thought and study structure of amorphous kerogens which are accordance with genetic mechanism showing biochemical and geochemical process perfectly. Here, we use the time of flight secondary ion mass spectrometry (TOFSIMS) to expand Combaz’s models from three to five. They are also models for coal.

松辽盆地深层中-基性火山岩有利相带及储层“甜点”逐级识别

松辽盆地深层下白垩统火石岭组中-基性火山岩广泛发育,岩性-岩相复杂,储层横向非均质性强,储层“甜点”识别难,制约了油气勘探和开发。以查干花地区为例,研究了松辽盆地深层中-基性火山岩岩相及储层特征,提出了火山通道、有利岩相、有利岩性及储层甜点识别方法。研究表明:①火山岩岩相主要为3相6亚相,优质储层岩性主要为粗粒、细粒凝灰岩和凝灰质砂岩,在近-中源相带中火山爆发相储层最为发育,相带控制了有利岩性凝灰岩的分布区域,物性和含气性是火山岩“甜点”的主要控制因素。②通过分析每个喷发期次的裂缝密度,结合蚂蚁体与地震数据的叠合剖面,识别出了不同喷发期次的火山通道,以判断火山近源相带,再结合火山机构厚度和能量半衰时属性划分中源与远源相带的边界,实现储层“甜点”发育区的定性刻画。③为降低地震反演定量预测中-基性火山岩储层的多解性,优选出低波阻抗表征沉凝灰岩,低密度表征高核磁孔隙度储层,低拉梅常数表征气层,基于此,在叠前反演密度预测孔隙度数据体的基础上,逐级剔除干扰沉凝灰岩、低孔隙度层及非气层,得到较为可靠的火山岩储层“甜点”空间分布预测结果。经验证,预测结果符合有利相带分布规律,且与已钻井气层解释结论吻合。应用有利相带定性认识及逐级定量刻画“甜点”空间分布,部署井取得较好效果,该方法可在深层火山岩“甜点”分布地震预测中广泛推广。

新疆哈密市黑石山一带铜矿成矿预测

根据多位地质工作者的研究和分析,由成矿地质背景、矿床成因等方面的因素出发,很多研究也得到了突破性的成就。2012年在新疆哈密黑石山一带开展矿山普查地质工作,开展工作的同时在区内发现大量孔雀石化的地表信息。根据地表孔雀石矿化信息,结合区内地、物、化成果及其他热液脉状铜矿床的成矿规律进行综合研究,对区内铜矿成矿可能性进行预测。

Classification and rating of disintegrated dolomite strata for slope stability analysis

Although disintegrated dolomite,widely distributed across the globe,has conventionally been a focus of research in underground engineering,the issue of slope stability issues in disintegrated dolomite strata is gaining increasing prominence.This is primarily due to their unique properties,including low strength and loose structure.Current methods for evaluating slope stability,such as basic quality(BQ)and slope stability probability classification(SSPC),do not adequately account for the poor integrity and structural fragmentation characteristic of disintegrated dolomite.To address this challenge,an analysis of the applicability of the limit equilibrium method(LEM),BQ,and SSPC methods was conducted on eight disintegrated dolomite slopes located in Baoshan,Southwest China.However,conflicting results were obtained.Therefore,this paper introduces a novel method,SMRDDS,to provide rapid and accurate assessment of disintegrated dolomite slope stability.This method incorporates parameters such as disintegrated grade,joint state,groundwater conditions,and excavation methods.The findings reveal that six slopes exhibit stability,while two are considered partially unstable.Notably,the proposed method demonstrates a closer match with the actual conditions and is more time-efficient compared with the BQ and SSPC methods.However,due to the limited research on disintegrated dolomite slopes,the results of the SMRDDS method tend to be conservative as a safety precaution.In conclusion,the SMRDDS method can quickly evaluate the current situation of disintegrated dolomite slopes in the field.This contributes significantly to disaster risk reduction for disintegrated dolomite slopes.

X射线荧光光谱法测定超基性岩中14种主次量元素

本论文确定了X射线荧光熔片法测定超基性岩中Si、Ca、Fe、Ni、Co、V等14种主次量元素的方法。样品与助溶剂比例为1∶10,样品在700℃预氧化,1050℃预熔2 min,旋转、摇摆10 min,铂-黄金坩埚自然冷却制备玻璃样片。用国家一级标准物质和人工混合标样制备校准标准样片,建立校准曲线,用熔片法大大降低了矿物效应和粒度效应,用经验系数法补偿基体效应,检测元素除Co相关系数r=0.99665外,其他元素相关系数均大于0.999,本方精密度、准确度法满足化学分析要求。

岩溶场地岩土体发育特征及地基评价分析

贵州属碳酸盐岩广泛分布地区,在进行岩溶场地勘察时需详细掌握场地的岩土体发育特征,了解其特性发育规律。解决岩溶场地勘察工作时场地数据的不足,造成勘察数据失真,造成设计资源浪费和基础设计缺陷的问题。通过查明岩溶场地岩土工程地质条件,分析岩土体发育特征,为设计、施工提供基础地质资料。以仁怀市南部新城大健康服务工程建设项目地岩土工程勘察项目为例,根据岩土体发育特征确定基础型式、基础埋深,对地基基础进行评价分析,最终选择合理的基础施工方案,为类似项目提供借鉴。

焦作矿区煤系含气系统基本要素研究

煤系气是重要的天然气资源,明确煤系含气系统的基本要素对于煤系气勘探开发至关重要。以焦作矿区石炭—二叠系海陆过渡相含煤岩系为例,基于区内煤系气勘探资料,从生、储、盖及上覆岩层4方面,探讨了研究区煤系含气系统的基本要素及其特征。研究表明,焦作矿区石炭—二叠系烃源岩以煤和暗色泥岩为主,马厂1井太原组、山西组和下石盒子组泥岩的TOC含量分别为1.68%、0.905%和4.35%,二1煤顶底板泥岩的S_(1)+S_(2)含量分别为0.452、0.576 mg/g,达到了较好—好烃源岩级别;从镜质组含量、类型指数等方面,判定烃源岩为Ⅲ型有机质类型;烃源岩热演化程度整体处于成熟—过成熟阶段,处于主生气期。储集层以煤为主,其次为泥岩和部分砂岩,其含气量分为11.54~23.16、1~3、0.18~1.47 m^(3)/t,储集层矿物组成主要为石英和黏土矿物,主要发育植物胞腔孔和气孔,孔隙度介于0.80%~11.08%,渗透率介于0.004×10^(-3)~0.012×10^(-3)μm^(2),具有低孔低渗的物性特征;太原组、山西组和下石盒子组泥岩的饱和气突破压力为5.88~9.80 MPa,饱和煤油突破压力为13.72~14.11 MPa,具有很好的封闭能力。研究认为,焦作矿区石炭—二叠系煤系含气系统基本要素的组合关系为,烃源岩发育于太原组至下石盒子组,优势储集层为山西组,上石盒子组为区域盖层,第四系及新近系为研究区上覆岩层。

岩体基本质量指标BQ与岩石坚固性系数f之间的关系研究

为了建立岩石坚固性系数f与岩体基本质量指标BQ、岩体各力学参数指标之间的关系,采用下列方法进行研究:(1)已知岩石单轴抗压强度R_C和BQ、f都存在相关关系,以R_C作为中间量,建立BQ与f的关系式;(2)已知岩体体积节理数J_V和岩石质量指标D_(RQD)、完整性指数K_V都存在相关关系,以J_V作为中间量,建立D_(RQD)与K_V的关系式,再经推导可得出BQ、f、D_(RQD)之间的关系式;(3)根据BQ、f、D_(RQD)之间的关系式,建立岩体各力学参数与f之间的关系方程;(4)将得到的研究结果用于吉尔吉斯斯坦南北路隧道工程的岩体分级及岩体各力学参数估计,据此确定施工方案,沉降变形监测结果表明,该工程施工效果良好。