The massive stacking of the coal gangue (CG) in the coal mining process, discarded industrial zeolite waste (IZW) and agricultural corn straw (CS) has caused serious environmental pollution and resource waste. To achi...The massive stacking of the coal gangue (CG) in the coal mining process, discarded industrial zeolite waste (IZW) and agricultural corn straw (CS) has caused serious environmental pollution and resource waste. To achieve the recycling of solid waste, an economical method for synthesizing ultramarine blue pigment using a two-step calcination process of the CG/IZW/Na_(2)CO_(3)/S/CS with the mass rates of 1.50: 0.50: 2.50: 3.50: 1.00 (the first stage at 400℃ for 0.50 h and the second stage at 900℃ for 2.00 h) is proposed in this paper. The structure and composition of the synthesis ultramarine blue pigment were characterized by XRD, FT-IR, Raman, as well as SEM technologies, and results showed it had a sodalite structure containing S_(3)^(−) and S_(2)^(−) radicals. Furthermore, SiO2 (1.20 mL of tetraethyl orthosilicate (TEOS) as the precursor and 4.50 mL of NH_(3)·H_(2)O as the catalyst) coated the synthesis ultramarine blue pigment (1.00 g) was successfully synthesized by sol-gel technique to improve the acid resistance of the pigment (pH=2.50-3.00). This new method of preparing ultramarine blue pigments not only achieves resource reuse at a low cost but also improves the acid rain resistance of the pigments.展开更多
A standard ultramarine pigment was used to produce phase change material composites, by adsorbing n-hexadecane paraffin around the pigment surface with the aim of obtaining a pigment providing thermal storage capacity...A standard ultramarine pigment was used to produce phase change material composites, by adsorbing n-hexadecane paraffin around the pigment surface with the aim of obtaining a pigment providing thermal storage capacity apart from color. Vacuum impregnation method was employed optimizing the process variables to maximize the latent heat of the hexadecane/pigment composite. In addition to the process optimization, the stability of the composite having the maximum latent heat was investigated. The hexadecane/pigment composite providing the highest latent heat has a Latent heat of fusion of 44 J/g (around a 20%wt. hexadecane adsorbed in the pigment). Durability of the material was tested by thermo-diffractometric measurements. The results indicate slow reduction of the area intensity up to 6.5% after the 100 cycles.展开更多
基金supported by the National Key Research and Development Program of China(2017YFD0800301)Liaoning Province Education Administration(No.LJ2020008,LQ2020023,and LQ2020027)Program for Liaoning Innovative Research Team in University(LT2020016).
文摘The massive stacking of the coal gangue (CG) in the coal mining process, discarded industrial zeolite waste (IZW) and agricultural corn straw (CS) has caused serious environmental pollution and resource waste. To achieve the recycling of solid waste, an economical method for synthesizing ultramarine blue pigment using a two-step calcination process of the CG/IZW/Na_(2)CO_(3)/S/CS with the mass rates of 1.50: 0.50: 2.50: 3.50: 1.00 (the first stage at 400℃ for 0.50 h and the second stage at 900℃ for 2.00 h) is proposed in this paper. The structure and composition of the synthesis ultramarine blue pigment were characterized by XRD, FT-IR, Raman, as well as SEM technologies, and results showed it had a sodalite structure containing S_(3)^(−) and S_(2)^(−) radicals. Furthermore, SiO2 (1.20 mL of tetraethyl orthosilicate (TEOS) as the precursor and 4.50 mL of NH_(3)·H_(2)O as the catalyst) coated the synthesis ultramarine blue pigment (1.00 g) was successfully synthesized by sol-gel technique to improve the acid resistance of the pigment (pH=2.50-3.00). This new method of preparing ultramarine blue pigments not only achieves resource reuse at a low cost but also improves the acid rain resistance of the pigments.
基金founding from the European Union Seventh Framework Programme(FP7-NMP-2010-Small-5)under grant agreement n°280393from the Dpto.Educacion,Politica Linguistica y Cultura of the Basque Goverment(IT-630-13),Ministerio de Ciencia e Innovacion(MAT2013-42092-R)Engineering and Physical Sciences Research Council(EP/I003932).
文摘A standard ultramarine pigment was used to produce phase change material composites, by adsorbing n-hexadecane paraffin around the pigment surface with the aim of obtaining a pigment providing thermal storage capacity apart from color. Vacuum impregnation method was employed optimizing the process variables to maximize the latent heat of the hexadecane/pigment composite. In addition to the process optimization, the stability of the composite having the maximum latent heat was investigated. The hexadecane/pigment composite providing the highest latent heat has a Latent heat of fusion of 44 J/g (around a 20%wt. hexadecane adsorbed in the pigment). Durability of the material was tested by thermo-diffractometric measurements. The results indicate slow reduction of the area intensity up to 6.5% after the 100 cycles.
