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Ultraviolet and visible upconversion dynamics in Er^3+:YAlO3 under ^2H11/2 excitation
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作者 杨海贵 戴振文 孙志伟 《Chinese Physics B》 SCIE EI CAS CSCD 2006年第6期1273-1277,共5页
The luminescence of Er^3+:YAlO3 in ultraviolet visible and infrared ranges under the 518 nm excitation of the multiples ^2H11/2 have been investigated. Ultraviolet (275 nm and 318 nm), violet (405 nm and 413 nm)... The luminescence of Er^3+:YAlO3 in ultraviolet visible and infrared ranges under the 518 nm excitation of the multiples ^2H11/2 have been investigated. Ultraviolet (275 nm and 318 nm), violet (405 nm and 413 nm) and blue (474 nm) upconversion and infrared downconversion luminescence has been observed. By means of measuring the fluorescence decay curves and using the theory of rate equations, the luminescence kinetics was studied in detail and the processes of energy transfer upconversion (ETU) and excitation state absorption (ESA) were proposed to explain the upconversion phenomena. 展开更多
关键词 ultraviolet upconversion dynamics Er^3+:yalo3
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UV and visible upconversion luminescence in Er^3+:YAG under red laser excitation 被引量:2
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作者 杨海贵 戴振文 祖宁宁 《Chinese Physics B》 SCIE EI CAS CSCD 2007年第6期1650-1654,共5页
This paper reports that the ultraviolet and visible upconversion luminescence from the ^4S3/2, ^2G9/2 and ^2P3/2 levels have been observed in Er^3+:YAG following 647.2 nm excitation of the ^4F9/2 multiple. Upconvers... This paper reports that the ultraviolet and visible upconversion luminescence from the ^4S3/2, ^2G9/2 and ^2P3/2 levels have been observed in Er^3+:YAG following 647.2 nm excitation of the ^4F9/2 multiple. Upconversion luminescence intensity dependence on pump power was recorded. The measured decay profiles were theoretically fitted by kinetics theory and the basically good agreements were achieved. The results indicate that some energy transfer processes proposed to explain the observed upconversion phenomena are reasonable. 展开更多
关键词 upconversion luminescence dynamics Er^3+:YAG
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980nm激发下Tm^(3+)诱导的Gd^(3+)上转换发光性质研究
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作者 曹春燕 余晓光 +1 位作者 秦伟平 张继森 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2010年第3期616-620,共5页
通过简单温和水热法,制备了系列Tm3+/Yb3+共掺GdF3粉末。用X射线衍射仪和场发射扫描电镜对样品进行了结构和形貌表征。在980 nm半导体连续激光二极管激发下,用荧光光谱仪对氩气保护下退火后的粉末样品进行了上转换发射光谱表征。粉末上... 通过简单温和水热法,制备了系列Tm3+/Yb3+共掺GdF3粉末。用X射线衍射仪和场发射扫描电镜对样品进行了结构和形貌表征。在980 nm半导体连续激光二极管激发下,用荧光光谱仪对氩气保护下退火后的粉末样品进行了上转换发射光谱表征。粉末上转换发光动力学过程是在脉冲(脉宽10 ns,重复频率10 Hz)YAG∶Nd激光器激发光参量振荡器至980 nm激发下研究的,发光信号由单色仪和示波器记录。文章主要讨论了Gd3+的311.6 nm(6P7/2→8S7/2)的发光动力学行为。发光动力学分析结果表明:在980 nm激发下,Gd3+,作为一种基质离子,其发光是由Yb3+作为一级敏化离子通过多步能量传递把能量传递给Tm3+使其布居至3P2能级;然后Tm3+作为二级敏化离子通过能量传递过程3P2→3H6(Tm3+):8S7/2→6IJ(Gd3+)把能量传给Gd3+;进一步,Gd3+与Yb3+或Tm3+之间通过能量传递过程布居至高激发多重态6DJ能级;最后,可观察到Gd3+的激发态6D9/2,6IJ,6P5/2及6P7/2至基态8S7/2的发射。同时,Tm3+在其自身发光过程中也充当激活剂,除了3P2及1I6至3H6的发射外,其他发射不作研究。文章还研究了基质Gd3+依赖于Yb3+浓度、Tm3+浓度、退火温度及激发功率密度的紫外上转换发光性质。 展开更多
关键词 Tm3+/Yb3+共掺GdF3 紫外上转换发射 发光动力学
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