The luminescence of Er^3+:YAlO3 in ultraviolet visible and infrared ranges under the 518 nm excitation of the multiples ^2H11/2 have been investigated. Ultraviolet (275 nm and 318 nm), violet (405 nm and 413 nm)...The luminescence of Er^3+:YAlO3 in ultraviolet visible and infrared ranges under the 518 nm excitation of the multiples ^2H11/2 have been investigated. Ultraviolet (275 nm and 318 nm), violet (405 nm and 413 nm) and blue (474 nm) upconversion and infrared downconversion luminescence has been observed. By means of measuring the fluorescence decay curves and using the theory of rate equations, the luminescence kinetics was studied in detail and the processes of energy transfer upconversion (ETU) and excitation state absorption (ESA) were proposed to explain the upconversion phenomena.展开更多
This paper reports that the ultraviolet and visible upconversion luminescence from the ^4S3/2, ^2G9/2 and ^2P3/2 levels have been observed in Er^3+:YAG following 647.2 nm excitation of the ^4F9/2 multiple. Upconvers...This paper reports that the ultraviolet and visible upconversion luminescence from the ^4S3/2, ^2G9/2 and ^2P3/2 levels have been observed in Er^3+:YAG following 647.2 nm excitation of the ^4F9/2 multiple. Upconversion luminescence intensity dependence on pump power was recorded. The measured decay profiles were theoretically fitted by kinetics theory and the basically good agreements were achieved. The results indicate that some energy transfer processes proposed to explain the observed upconversion phenomena are reasonable.展开更多
基金Project supported by the National Natural Science Foundation of China (Grant No 10074020).
文摘The luminescence of Er^3+:YAlO3 in ultraviolet visible and infrared ranges under the 518 nm excitation of the multiples ^2H11/2 have been investigated. Ultraviolet (275 nm and 318 nm), violet (405 nm and 413 nm) and blue (474 nm) upconversion and infrared downconversion luminescence has been observed. By means of measuring the fluorescence decay curves and using the theory of rate equations, the luminescence kinetics was studied in detail and the processes of energy transfer upconversion (ETU) and excitation state absorption (ESA) were proposed to explain the upconversion phenomena.
基金Project supported by the National Natural Science Foundation of China (Grant No 10074020).Acknowledgement The authors would like to thank Professor Siyuan Zhang for providing Er^3+:YAG crystal.
文摘This paper reports that the ultraviolet and visible upconversion luminescence from the ^4S3/2, ^2G9/2 and ^2P3/2 levels have been observed in Er^3+:YAG following 647.2 nm excitation of the ^4F9/2 multiple. Upconversion luminescence intensity dependence on pump power was recorded. The measured decay profiles were theoretically fitted by kinetics theory and the basically good agreements were achieved. The results indicate that some energy transfer processes proposed to explain the observed upconversion phenomena are reasonable.