Single-molecule magnets(SMMs),which can exhibit slow magnetization relaxation and bulk-magnet-like hysteresis of purely molecular origin,are promising candidates for high-density information storage,molecular spintron...Single-molecule magnets(SMMs),which can exhibit slow magnetization relaxation and bulk-magnet-like hysteresis of purely molecular origin,are promising candidates for high-density information storage,molecular spintronics,and quantum computing.To realize their applications,it is crucial to improve the blocking temperature(TB)and the effective relaxation barrier(Ueff).Three decades of multidisciplinary research have yielded distinct SMMs with a state-of-the-art Ueff of up to 2,000 K and a TB of up to the liquid nitrogen region.Several strategies have been investigated and summarized,which revealed that enhancing the uniaxiality of magnetic anisotropy is critical for constructing high-performance SMMs.Therefore,magnetic anisotropy,a key property that connects the molecular structure symmetry and performance of SMMs,plays a fundamental role in dictating magneto-structural correlations.Understanding and employing magnetic anisotropy would be significantly beneficial for rationally designing high-performance SMMs.This review focuses on the magnetic anisotropy of SMMs.We illustrate the origin and manifestation of magnetic anisotropy in mononuclear 3d-and 4f-block metal complexes.We then introduce developed approaches to investigate magnetic anisotropy both theoretically and experimentally.Typical SMMs by optimizing uniaxial magnetic anisotropy through lanthanide metallocene,symmetry controlling,and low-coordination approaches are represented.Furthermore,the remaining challenges and opportunities in this field will be discussed.展开更多
Thermal damage and thermal fracture of rocks are two important indicators in geothermal mining projects.This paper investigates the effects of heating and water-cooling on granite specimens at various temperatures.The...Thermal damage and thermal fracture of rocks are two important indicators in geothermal mining projects.This paper investigates the effects of heating and water-cooling on granite specimens at various temperatures.The laboratory uniaxial compression experiments were also conducted.Then,a coupled thermo-mechanical ordinary state-based peridynamic(OSB-PD)model and corresponding numerical scheme were developed to simulate the damage of rocks after the heating and cooling processes,and the change of crack evolution process was predicted.The results demonstrate that elevated heating temperatures exacerbate the thermal damage to the specimens,resulting in a decrease in peak strength and an increase in ductility of granite.The escalating occurrence of thermal-induced cracks significantly affects the crack evolution process during the loading phase.The numerical results accurately reproduce the damage and fracture characteristics of the granite under different final heating temperatures(FHTs),which are consistent with the test results in terms of strength,crack evolution process,and failure mode.展开更多
To better understand the failure behaviours and strength of bolt-reinforced blocky rocks,large scale extensive laboratory experiments are carried out on blocky rock-like specimens with and without rockbolt reinforceme...To better understand the failure behaviours and strength of bolt-reinforced blocky rocks,large scale extensive laboratory experiments are carried out on blocky rock-like specimens with and without rockbolt reinforcement.The results show that both shear failure and tensile failure along joint surfaces are observed but the shear failure is a main controlling factor for the peak strength of the rock mass with and without rockbolts.The rockbolts are necked and shear deformation simultaneously happens in bolt reinforced rock specimens.As the joint dip angle increases,the joint shear failure becomes more dominant.The number of rockbolts has a significant impact on the peak strain and uniaxial compressive strength(UCS),but little influence on the deformation modulus of the rock mass.Using the Winkler beam model to represent the rockbolt behaviours,an analytical model for the prediction of the strength of boltreinforced blocky rocks is proposed.Good agreement between the UCS values predicted by proposed model and obtained from experiments suggest an encouraging performance of the proposed model.In addition,the performance of the proposed model is further assessed using published results in the literature,indicating the proposed model can be used effectively in the prediction of UCS of bolt-reinforced blocky rocks.展开更多
Granitic veins(GVs)have a significant influence on the mechanical responses of tunnels excavated in granitic strata.Distinguishing the mechanical properties of host granites(HGs),GVs and vein-granite interfaces(VGIs)i...Granitic veins(GVs)have a significant influence on the mechanical responses of tunnels excavated in granitic strata.Distinguishing the mechanical properties of host granites(HGs),GVs and vein-granite interfaces(VGIs)is critical.For this,this paper analyzed the mechanical behaviors and rupture processes of typical HG,GV,and VGI samples under uniaxial compression condition.For the rocks studied,although the linear axial stress‒strain relation can be identified and the deformation modulus can be determined,the transverse deformation developed nonlinearly with axial stress.As a result,the instantaneous Poisson’s ratio increases continuously and may even exceed 0.5,making it extremely difficult to accurately determine the Poisson’s ratio.In addition,the studied GV samples were found to be significantly brittle,indicating that large-scale GVs cannot be ignored when assessing rockburst hazards in granitic strata with brittle GVs.In terms of the rupture process,the HG and GV samples were gradually damaged by the formation of small-scale cracks and then ruptured by large cracks formed from smallscale cracks,whereas the VGI samples ruptured along large cracks with significant energy release.By examining the characteristic stress thresholds of these three granites,it is noted that the crack closure stress scc exceeds both the crack initiation stress sci and the crack damage stress scd for the HG and VGI samples.The transverse damage to a tested sample appears to be significantly greater than the axial damage,which is essentially related to the rock grain size and grain size distribution.展开更多
In northeastern Sicily(Italy),sandstone rock masses widely crop out as cover deposits over crystalline terrains belonging to the orogenic belt.Despite being part of the same geological formation,these sandstones are c...In northeastern Sicily(Italy),sandstone rock masses widely crop out as cover deposits over crystalline terrains belonging to the orogenic belt.Despite being part of the same geological formation,these sandstones are characterized by highly different features in terms of texture and physico-mechanical properties.This poses a scientific question on the possibility of tracing these rocks to a single statistical model,which could be representative of their main engineering geological properties.Therefore,it is worth investigating on the possible reasons of such differences,that should be searched either in the current geographical sandstone distribution or in the rock texture.For this study,sandstone samples were collected from different sites and were analyzed at both the hand and thin section scales.Three sandstone types were recognized,characterized by a different texture.Then,the laboratory characterization allowed estimating their main physico-mechanical and ultrasonic properties,such as porosity,density,mechanical strength,deformability,and ultrasonic velocities.The rock mechanical strength proved linked to the rock compactness and to the presence of lithic fragments,while pores and a pseudo-matrix between grains represent weakening features.Rock data were also statistically analyzed by grouping the specimens according to a geographical criterion,with respect to their sampling area,but no link was found between location and rock properties.Finally,with the aim of achieving mathematical laws that could be used to predict some rock properties from others,useful for practical purposes when dealing with such a high property variability,single and multiple regression analyses were carried out.Results show that the Uniaxial Compressive Strength,porosity,and P-wave velocity are the best predictors for a quick,indirect estimation of the main physico-mechanical parameters.The methodological approach developed for this research can be taken as reference to study other worldwide cases,involving rocks characterized by a wide range of physico-mechanical properties and covering large regional territories.展开更多
Ignimbrites have been widely used as building materials in many historical and touristic structures in the Kayseri region of Türkiye. Their diverse colours and textures make them a popular choice for modern const...Ignimbrites have been widely used as building materials in many historical and touristic structures in the Kayseri region of Türkiye. Their diverse colours and textures make them a popular choice for modern construction as well. However, ignimbrites are particularly vulnerable to atmospheric conditions, such as freeze-thaw cycles, due to their high porosity, which is a result of their formation process. When water enters the pores of the ignimbrites, it can freeze during cold weather. As the water freezes and expands, it generates internal stress within the stone, causing micro-cracks to develop. Over time, repeated freeze-thaw (F-T) cycles lead to the growth of these micro-cracks into larger cracks, compromising the structural integrity of the ignimbrites and eventually making them unsuitable for use as building materials. The determination of the long-term F-T performance of ignimbrites can be established after long F-T experimental processes. Determining the long-term F-T performance of ignimbrites typically requires extensive experimental testing over prolonged freeze-thaw cycles. To streamline this process, developing accurate predictive equations becomes crucial. In this study, such equations were formulated using classical regression analyses and artificial neural networks (ANN) based on data obtained from these experiments, allowing for the prediction of the F-T performance of ignimbrites and other similar building stones without the need for lengthy testing. In this study, uniaxial compressive strength, ultrasonic propagation velocity, apparent porosity and mass loss of ignimbrites after long-term F-T were determined. Following the F-T cycles, the disintegration rate was evaluated using decay function approaches, while uniaxial compressive strength (UCS) values were predicted with minimal input parameters through both regression and ANN analyses. The ANN and regression models created for this purpose were first started with a single input value and then developed with two and three combinations. The predictive performance of the models was assessed by comparing them to regression models using the coefficient of determination (R2) as the evaluation criterion. As a result of the study, higher R2 values (0.87) were obtained in models built with artificial neural network. The results of the study indicate that ANN usage can produce results close to experimental outcomes in predicting the long-term F-T performance of ignimbrite samples.展开更多
Bedding structural planes significantly influence the mechanical properties and stability of engineering rock masses.This study conducts uniaxial compression tests on layered sandstone with various bedding angles(0...Bedding structural planes significantly influence the mechanical properties and stability of engineering rock masses.This study conducts uniaxial compression tests on layered sandstone with various bedding angles(0°,15°,30°,45°,60°,75°and 90°)to explore the impact of bedding angle on the deformational mechanical response,failure mode,and damage evolution processes of rocks.It develops a damage model based on the Logistic equation derived from the modulus’s degradation considering the combined effect of the sandstone bedding dip angle and load.This model is employed to study the damage accumulation state and its evolution within the layered rock mass.This research also introduces a piecewise constitutive model that considers the initial compaction characteristics to simulate the whole deformation process of layered sandstone under uniaxial compression.The results revealed that as the bedding angle increases from 0°to 90°,the uniaxial compressive strength and elastic modulus of layered sandstone significantly decrease,slightly increase,and then decline again.The corresponding failure modes transition from splitting tensile failure to slipping shear failure and back to splitting tensile failure.As indicated by the modulus’s degradation,the damage characteristics can be categorized into four stages:initial no damage,damage initiation,damage acceleration,and damage deceleration termination.The theoretical damage model based on the Logistic equation effectively simulates and predicts the entire damage evolution process.Moreover,the theoretical constitutive model curves closely align with the actual stress−strain curves of layered sandstone under uniaxial compression.The introduced constitutive model is concise,with fewer parameters,a straightforward parameter determination process,and a clear physical interpretation.This study offers valuable insights into the theory of layered rock mechanics and holds implications for ensuring the safety of rock engineering.展开更多
Pillar is closely related to the stability and reliability of underground spaces in closed/abandoned mines.The present research introduced a new technique to strengthen square cement mortar columns via fiber-reinforce...Pillar is closely related to the stability and reliability of underground spaces in closed/abandoned mines.The present research introduced a new technique to strengthen square cement mortar columns via fiber-reinforced polymer(FRP)strips to verify the strengthening effect of FRP on pillars.Compared to a fully wrapped FRP jacket,the advantages of FRP strip are cost-effective and easy-to-construct.A series of compression tests as well as theoretical analysis were carried out to explore the mechanical behavior of square cement mortar specimens partially strengthened with FRP strips.The results verified the effectiveness of FRP strips in enhancing the stress and strain of cement mortar.Different from unconfined cement mortar specimens,these FRP-strengthened cement mortar specimens are featured with the double-peaked behaviors,mainly attributed to the stress state transformation from a one-dimensional to a three-dimensional stress state.It also indicated that the enhancement of stress increased with the FRP strip width.Moreover,the brittle-ductile transition ductile failure characteristics were also observed in FRP-confined cement mortar specimens.The ultimate ductility of the cement mortar specimen decreases gradually with the growth of the FRP strip width.The main contribution of this research is to enrich the strengthening techniques for residual pillars.展开更多
We report a study of the electronic structure of BaFe_(2)As_(2) under uniaxial strains using angle-resolved photoemission spectroscopy and transport measurements. Two electron bands at the MY point, with an energy spl...We report a study of the electronic structure of BaFe_(2)As_(2) under uniaxial strains using angle-resolved photoemission spectroscopy and transport measurements. Two electron bands at the MY point, with an energy splitting of 50 meV in the strain-free sample, shift downward and merge into each other under a large uniaxial strain, while three hole bands at theГ point shift downward together. However, we also observed an enhancement of the resistance anisotropy under uniaxial strains by electrical transport measurements, implying that the applied strains strengthen the electronic nematic order in BaFe_(2)As_(2). These observations suggest that the splitting of these two electron bands at the MY point is not caused by the nematic order in BaFe_(2)As_(2).展开更多
Due to the uneven seabed and heaving of soil during pumping,incomplete soil plugs may occur during the installation of bucket foundations,and the impacts on the bearing capacities of bucket foundations need to be eval...Due to the uneven seabed and heaving of soil during pumping,incomplete soil plugs may occur during the installation of bucket foundations,and the impacts on the bearing capacities of bucket foundations need to be evaluated.In this paper,the contact ratio(the ratio of the top diameter of the soil plug to the diameter of the bucket)and the soil plug ratio(the ratio of the soil heave height to the skirt height)are defined to describe the shape and size of the incomplete soil plug.Then,finite element models are established to investigate the bearing capacities of bucket foundations with incomplete soil plugs and the influences of the contact ratios,and the soil plug ratios on the bearing capacities are analyzed.The results show that the vertical bearing capacity of bucket foundations in homogeneous soil continuously improves with the increase of the contact ratio.However,in normally consolidated soil,the vertical bearing capacity barely changes when the contact ratio is smaller than 0.75,while the bearing capacity suddenly increases when the contact ratio increases to 1 due to the change of failure mode.The contact ratio hardly affects the horizontal bearing capacity of bucket foundations.Moreover,the moment bearing capacity improves with the increase of the contact ratio for small aspect ratios,but hardly varies with increasing contact ratio for aspect ratios larger than 0.5.Consequently,the reduction coefficient method is proposed based on this analysis to calculate the bearing capacities of bucket foundations considering the influence of incomplete soil plugs.The comparison results show that the proposed reduction coefficient method can be used to evaluate the influences of incomplete soil plug on the bearing capacities of bucket foundations.展开更多
Geological exploration cores obtained from shale gas wells several kilometers deep often show different height-diameter ratios(H/D)because of complex geological conditions(core disking or developed fractures),which ma...Geological exploration cores obtained from shale gas wells several kilometers deep often show different height-diameter ratios(H/D)because of complex geological conditions(core disking or developed fractures),which makes further standard specimen preparation for mechanical evaluation of reservoirs difficult.In multi-cluster hydraulic fracturing,shale reservoirs between planes of hydraulic fractures with different lengths could be simplified to have different H/D ratios.Discovering the effect of H/D on the mechanical characteristics of shale specimens with different bedding orientations will support mechanical evaluation tests of reservoirs based on disked geological cores and help to optimize multicluster fracturing programs.In this study,we performed uniaxial compression tests and acoustic emission(AE)monitoring on cylindrical Longmaxi shale specimens under five bedding orientations and four H/D ratios.The experimental results showed that both the H/D-dependent mechanical properties and AE parameters demonstrated significant anisotropy.Increasing H/D did not change the uniaxial compressive strength(UCS)evolution versus bedding orientation,demonstrating a V-shaped relationship,but enhanced the curve shape.The stress level of crack damage for the specimens significantly increased with increasing H/D,excluding the specimens with a bedding orientation of 0°.With increasing H/D,the cumulative AE counts of the specimens with each bedding orientation tended to exhibit a stepped jump against the loading time.The proportion of low-average-frequency AE signals(below 100 kHz)in specimens with bedding orientations of 45°and 60°increased to over 70%by increasing H/D,but it only increased to 40%in specimens with bedding orientations of 0°,30°,and 90°.Finally,an empirical model that can reveal the effect of H/D on anisotropic UCS of shale reservoir was proposed,the anisotropic proportion of tensile and shear failure cracks in specimens under four H/D ratios was classified based on the AE data,and the effect of H/D on the anisotropic crack growth of specimens was discussed.展开更多
Many rock engineering projects show that the growth of tensile cracks is often an important cause of engineering disasters,and the mechanical behavior of rocks is essentially the transmission,storage,dissipation and r...Many rock engineering projects show that the growth of tensile cracks is often an important cause of engineering disasters,and the mechanical behavior of rocks is essentially the transmission,storage,dissipation and release of energy.To investigate the tensile behavior of rock from the perspective of energy,uniaxial tension tests(UTTs)and uniaxial compression tests(UCTs)were carried out on three typical rocks(granite,sandstone and marble).Different unloading points were set before the peak stress to separate elastic energy and dissipated energy.The input energy density ut,elastic energy density ue,and dissipated energy density ud at each unloading point were calculated by integrating stress-strain curves.The results show that there is a strong linear relationship between the three energy parameters and the square of the unloading stress in UCT,but this linear relationship is weaker in UTT.The ue and ud increase linearly with the increase in ut in UCT and UTT.Based on the phenomenon that ue and ud increase linearly with ut,the applicability of W_(et)^(p) index in UTT was proved and the relative energy storage capacity and absolute energy distribution characteristics of three rocks in UCT and UTT were evaluated.The tensile behavior of marble and sandstone in UTT can be divided into two stages vaguely according to the energy distribution,but granite is not the case.In addition,based on dissipated energy,the damage evolution of three types of rocks in UCT and UTT was discussed.This study provides some new insights for understanding the tensile behavior of rock.展开更多
Based on the Landau-Lifshitz-Gilbert(LLG)equation,the precession relaxation of magnetization is studied when the external field H is parallel to the uniaxial anisotropic field H_(k).The evolution of three-component ma...Based on the Landau-Lifshitz-Gilbert(LLG)equation,the precession relaxation of magnetization is studied when the external field H is parallel to the uniaxial anisotropic field H_(k).The evolution of three-component magnetization is solved analytically under the condition of H=nH_(k)(n=3,1 and 0).It is found that with an increase of H or a decrease of the initial polar angle of magnetization,the relaxation time decreases and the angular frequency of magnetization increases.For comparison,the analytical solution for H_(k)=0 is also given.When the magnetization becomes stable,the angular frequency is proportional to the total effective field acting on the magnetization.The analytical solutions are not only conducive to the understanding of the precession relaxation of magnetization,but also can be used as a standard model to test the numerical calculation of LLG equation.展开更多
Gauge length influences the biomechanical properties of herbaceous roots such as tensile resistance,tensile strength and Young’s modulus.However,the extent to which and how these biomechanical properties of herbaceou...Gauge length influences the biomechanical properties of herbaceous roots such as tensile resistance,tensile strength and Young’s modulus.However,the extent to which and how these biomechanical properties of herbaceous roots are influenced remain unknown.To better understand the behavior of roots in tension under different conditions and to illustrate these behaviors,uniaxial tensile tests were conducted on the Poa araratica roots as the gauge length increased from 20 mm to 80 mm.Subsequently,ANOVA was used to test the impact of the significant influences of gauge length on the biomechanical properties,nonlinear regression was applied to establish the variation in the biomechanical properties with gauge length to answer the question of the extent to which the biomechanical properties are influenced,and Weibull models were subsequently introduced to illustrate how the biomechanical properties are influenced by gauge length.The results reveal that(1)the variation in biomechanical properties with root diameter depends on both the gauge length and the properties themselves;(2)the gauge length significantly impacts most of the biomechanical properties;(3)the tensile resistance,tensile strength,and tensile strain at cracks decrease as the gauge length increases,with values decreasing by 20%-300%,while Young’s modulus exhibits the opposite trend,with a corresponding increase of 30%;and(4)the Weibull distribution is suitable for describing the probability distribution of these biomechanical properties;the Weibull modulus for both tensile resistance and tensile strain at cracks linearly decrease with gauge length,whereas those for tensile strength and Young’s modulus exhibit the opposite trend.The tensile resistance,tensile strength,and tensile strain at the cracks linearly decrease with increasing gauge length,while the tensile strength and Young’s modulus linearly increase with increasing gauge length.展开更多
Deformation can change the transition pathway of materials under high pressure,thus significantly affects physical and chemical properties of matters.However,accurate pressure calibration under deformation is challeng...Deformation can change the transition pathway of materials under high pressure,thus significantly affects physical and chemical properties of matters.However,accurate pressure calibration under deformation is challenging and thereby causes relatively large pressure uncertainties in deformation experiments,resulting in the synthesis of complex multiphase materials.Here,pressure generations of three types of deformation assemblies were well calibrated in a Walker-type largevolume press(LVP)by electrical resistance measurements combined with finite element simulations(FESs).Hard Al_(2)O_(3) or diamond pistons in shear and uniaxial deformation assemblies significantly increase the efficiency of pressure generation compared with the conventional quasi-hydrostatic assembly.The uniaxial deformation assembly using flat diamond pistons possesses the highest efficiency in these deformation assemblies.This finding is further confirmed by stress distribution analysis based on FESs.With this deformation assembly,we found shear can effectively promote the transformation of C60 into diamond under high pressure and realized the synthesis of phase-pure diamond at relatively moderate pressure and temperature conditions.The present developed techniques will help improve pressure efficiencies in LVP and explore the new physical and chemical properties of materials under deformation in both science and technology.展开更多
The objective of this research was to determine the mechanical parameter from EVA foam and also investigate its behavior by using Blatz-Ko,Neo-Hookean,Mooney model and experimental test.The physical characteristic of ...The objective of this research was to determine the mechanical parameter from EVA foam and also investigate its behavior by using Blatz-Ko,Neo-Hookean,Mooney model and experimental test.The physical characteristic of EVA foam was also evaluated by scanning electron microscopy(SEM).The results show that Blatz-Ko and Neo-Hookean model can fit the curve at 5%and 8%strain,respectively.The Mooney model can fit the curve at 50%strain.The modulus of rigidity evaluated from Mooney model is 0.0814±0.0027 MPa.The structure of EVA foam from SEM image shows that EVA structure is a closed cell with homogeneous porous structure.From the result,it is found that Mooney model can adjust the data better than other models.This model can be applied for mechanical response prediction of EVA foam and also for reference value in engineering application.展开更多
Traditional laboratory tests for measuring rock uniaxial compressive strength(UCS)are tedious and timeconsuming.There is a pressing need for more effective methods to determine rock UCS,especially in deep mining envir...Traditional laboratory tests for measuring rock uniaxial compressive strength(UCS)are tedious and timeconsuming.There is a pressing need for more effective methods to determine rock UCS,especially in deep mining environments under high in-situ stress.Thus,this study aims to develop an advanced model for predicting the UCS of rockmaterial in deepmining environments by combining three boosting-basedmachine learning methods with four optimization algorithms.For this purpose,the Lead-Zinc mine in Southwest China is considered as the case study.Rock density,P-wave velocity,and point load strength index are used as input variables,and UCS is regarded as the output.Subsequently,twelve hybrid predictive models are obtained.Root mean square error(RMSE),mean absolute error(MAE),coefficient of determination(R2),and the proportion of the mean absolute percentage error less than 20%(A-20)are selected as the evaluation metrics.Experimental results showed that the hybridmodel consisting of the extreme gradient boostingmethod and the artificial bee colony algorithm(XGBoost-ABC)achieved satisfactory results on the training dataset and exhibited the best generalization performance on the testing dataset.The values of R2,A-20,RMSE,and MAE on the training dataset are 0.98,1.0,3.11 MPa,and 2.23MPa,respectively.The highest values of R2 and A-20(0.93 and 0.96),and the smallest RMSE and MAE values of 4.78 MPa and 3.76MPa,are observed on the testing dataset.The proposed hybrid model can be considered a reliable and effective method for predicting rock UCS in deep mines.展开更多
The mechanical characteristics and acoustic behavior of rock masses are greatly influenced by stochastic joints.In this study,numerical models of rock masses incorporating intermittent joints with different numbers an...The mechanical characteristics and acoustic behavior of rock masses are greatly influenced by stochastic joints.In this study,numerical models of rock masses incorporating intermittent joints with different numbers and dip angles were produced using the finite element method(FEM)with the intrinsic cohesive zone model(ICZM).Then,the uniaxial compressive and wave propagation simulations were performed.The results indicate that the joint number and dip angle can affect the mechanical and acoustic properties of the models.The uniaxial compressive strength(UCS)and wave velocity of rock masses decrease monotonically as the joint number increases.However,the wave velocity grows monotonically as the joint dip angle increases.When the joint dip angle is 45°–60°,the UCS of the rock mass is lower than that of other dip angles.The wave velocity parallel to the joints is greater than that perpendicular to the joints.When the dip angle of joints remains unchanged,the UCS and wave velocity are positively related.When the joint dip angle increases,the variation amplitude of the UCS regarding the wave velocity increases.To reveal the effect of the joint distribution on the velocity,a theoretical model was also proposed.According to the theoretical wave velocity,the change in wave velocity of models with various joint numbers and dip angles was consistent with the simulation results.Furthermore,a theoretical indicator(i.e.fabric tensor)was adopted to analyze the variation of the wave velocity and UCS.展开更多
The geometry of joints has a significant influence on the mechanical properties of rocks.To simplify the curved joint shapes in rocks,the joint shape is usually treated as straight lines or planes in most laboratory e...The geometry of joints has a significant influence on the mechanical properties of rocks.To simplify the curved joint shapes in rocks,the joint shape is usually treated as straight lines or planes in most laboratory experiments and numerical simulations.In this study,the computerized tomography (CT) scanning and photogrammetry were employed to obtain the internal and surface joint structures of a limestone sample,respectively.To describe the joint geometry,the edge detection algorithms and a three-dimensional (3D) matrix mapping method were applied to reconstruct CT-based and photogrammetry-based jointed rock models.For comparison tests,the numerical uniaxial compression tests were conducted on an intact rock sample and a sample with a joint simplified to a plane using the parallel computing method.The results indicate that the mechanical characteristics and failure process of jointed rocks are significantly affected by the geometry of joints.The presence of joints reduces the uniaxial compressive strength (UCS),elastic modulus,and released acoustic emission (AE) energy of rocks by 37%–67%,21%–24%,and 52%–90%,respectively.Compared to the simplified joint sample,the proposed photogrammetry-based numerical model makes the most of the limited geometry information of joints.The UCS,accumulative released AE energy,and elastic modulus of the photogrammetry-based sample were found to be very close to those of the CT-based sample.The UCS value of the simplified joint sample (i.e.38.5 MPa) is much lower than that of the CT-based sample (i.e.72.3 MPa).Additionally,the accumulative released AE energy observed in the simplified joint sample is 3.899 times lower than that observed in the CT-based sample.CT scanning provides a reliable means to visualize the joints in rocks,which can be used to verify the reliability of photogrammetry techniques.The application of the photogrammetry-based sample enables detailed analysis for estimating the mechanical properties of jointed rocks.展开更多
This study compares the strength characteristics of rocks anchored by NPR bolts and ordinary bolts with varied preloads,based on the mechanical properties of NPR bolts(with a negative Poisson’s ratio).The results sho...This study compares the strength characteristics of rocks anchored by NPR bolts and ordinary bolts with varied preloads,based on the mechanical properties of NPR bolts(with a negative Poisson’s ratio).The results show that the uniaxial compressive stress-strain curve of ordinary anchored rocks exhibits noticeable abrupt changes.After reaching peak strength,the bolt breaks,whereas the stress-strain curve of NPR-anchored rocks is smoother.The NPR bolt enters the stage of continuous resistance after reaching maximal strength and does not break.As the preload increases,the strength of the anchored rock grows linearly.A calculation equation for the strength of the anchored rock is proposed based on the preload.The theoretical equation fits the test results well,and the fitted parameters show that NPR bolts can better increase the strength of the rock.The concept of dynamic toughness UC of anchored rock is proposed to reflect the comprehensive mechanical properties of anchored rock,including strength and plasticity.As the preload increases,the UC of ordinary anchored rock first decreases and then increases,while the UC of the NPR anchored rock does not change significantly with the preload when the strain is small,and the UC increases with the increase of the preload when the strain is large.展开更多
基金supported by the National Natural Science Foundation of China(21971006,21801037,22101220)the National Key R&D Program of China(2018YFA0306003,2017YFA0206301,2017YFA0204903)the Fundamental Research Funds for the Central Universities(WUT:2021IVA073).
文摘Single-molecule magnets(SMMs),which can exhibit slow magnetization relaxation and bulk-magnet-like hysteresis of purely molecular origin,are promising candidates for high-density information storage,molecular spintronics,and quantum computing.To realize their applications,it is crucial to improve the blocking temperature(TB)and the effective relaxation barrier(Ueff).Three decades of multidisciplinary research have yielded distinct SMMs with a state-of-the-art Ueff of up to 2,000 K and a TB of up to the liquid nitrogen region.Several strategies have been investigated and summarized,which revealed that enhancing the uniaxiality of magnetic anisotropy is critical for constructing high-performance SMMs.Therefore,magnetic anisotropy,a key property that connects the molecular structure symmetry and performance of SMMs,plays a fundamental role in dictating magneto-structural correlations.Understanding and employing magnetic anisotropy would be significantly beneficial for rationally designing high-performance SMMs.This review focuses on the magnetic anisotropy of SMMs.We illustrate the origin and manifestation of magnetic anisotropy in mononuclear 3d-and 4f-block metal complexes.We then introduce developed approaches to investigate magnetic anisotropy both theoretically and experimentally.Typical SMMs by optimizing uniaxial magnetic anisotropy through lanthanide metallocene,symmetry controlling,and low-coordination approaches are represented.Furthermore,the remaining challenges and opportunities in this field will be discussed.
基金funded by the Postgraduate Research&Practice Innovation Program of Jiangsu Province(Grant No.KYCX22_0613)the National Natural Science Foundation of China(Grant Nos.41831278 and 51878249).
文摘Thermal damage and thermal fracture of rocks are two important indicators in geothermal mining projects.This paper investigates the effects of heating and water-cooling on granite specimens at various temperatures.The laboratory uniaxial compression experiments were also conducted.Then,a coupled thermo-mechanical ordinary state-based peridynamic(OSB-PD)model and corresponding numerical scheme were developed to simulate the damage of rocks after the heating and cooling processes,and the change of crack evolution process was predicted.The results demonstrate that elevated heating temperatures exacerbate the thermal damage to the specimens,resulting in a decrease in peak strength and an increase in ductility of granite.The escalating occurrence of thermal-induced cracks significantly affects the crack evolution process during the loading phase.The numerical results accurately reproduce the damage and fracture characteristics of the granite under different final heating temperatures(FHTs),which are consistent with the test results in terms of strength,crack evolution process,and failure mode.
基金supported by the National Key Research and Development Projects of China(No.2021YFB2600402)National Natural Science Foundation of China(Nos.52209148 and 52374119)+1 种基金the opening fund of State Key Laboratory of Geomechanics and Geotechnical Engineering,Institute of Rock and Soil Mechanics,Chinese Academy of Sciences(No.SKLGME023023)the opening fund of Key Laboratory of Water Management and Water Security for Yellow River Basin,Ministry of Water Resources(No.2023-SYSJJ-02)。
文摘To better understand the failure behaviours and strength of bolt-reinforced blocky rocks,large scale extensive laboratory experiments are carried out on blocky rock-like specimens with and without rockbolt reinforcement.The results show that both shear failure and tensile failure along joint surfaces are observed but the shear failure is a main controlling factor for the peak strength of the rock mass with and without rockbolts.The rockbolts are necked and shear deformation simultaneously happens in bolt reinforced rock specimens.As the joint dip angle increases,the joint shear failure becomes more dominant.The number of rockbolts has a significant impact on the peak strain and uniaxial compressive strength(UCS),but little influence on the deformation modulus of the rock mass.Using the Winkler beam model to represent the rockbolt behaviours,an analytical model for the prediction of the strength of boltreinforced blocky rocks is proposed.Good agreement between the UCS values predicted by proposed model and obtained from experiments suggest an encouraging performance of the proposed model.In addition,the performance of the proposed model is further assessed using published results in the literature,indicating the proposed model can be used effectively in the prediction of UCS of bolt-reinforced blocky rocks.
基金Additionally,the authors appreciate Dr.Zhaopeng Zhang’s assistance in conducting the experiments.This research was funded by the Science and Technology Department of Tibet(Grant No.XZ202201ZY0021G).
文摘Granitic veins(GVs)have a significant influence on the mechanical responses of tunnels excavated in granitic strata.Distinguishing the mechanical properties of host granites(HGs),GVs and vein-granite interfaces(VGIs)is critical.For this,this paper analyzed the mechanical behaviors and rupture processes of typical HG,GV,and VGI samples under uniaxial compression condition.For the rocks studied,although the linear axial stress‒strain relation can be identified and the deformation modulus can be determined,the transverse deformation developed nonlinearly with axial stress.As a result,the instantaneous Poisson’s ratio increases continuously and may even exceed 0.5,making it extremely difficult to accurately determine the Poisson’s ratio.In addition,the studied GV samples were found to be significantly brittle,indicating that large-scale GVs cannot be ignored when assessing rockburst hazards in granitic strata with brittle GVs.In terms of the rupture process,the HG and GV samples were gradually damaged by the formation of small-scale cracks and then ruptured by large cracks formed from smallscale cracks,whereas the VGI samples ruptured along large cracks with significant energy release.By examining the characteristic stress thresholds of these three granites,it is noted that the crack closure stress scc exceeds both the crack initiation stress sci and the crack damage stress scd for the HG and VGI samples.The transverse damage to a tested sample appears to be significantly greater than the axial damage,which is essentially related to the rock grain size and grain size distribution.
文摘In northeastern Sicily(Italy),sandstone rock masses widely crop out as cover deposits over crystalline terrains belonging to the orogenic belt.Despite being part of the same geological formation,these sandstones are characterized by highly different features in terms of texture and physico-mechanical properties.This poses a scientific question on the possibility of tracing these rocks to a single statistical model,which could be representative of their main engineering geological properties.Therefore,it is worth investigating on the possible reasons of such differences,that should be searched either in the current geographical sandstone distribution or in the rock texture.For this study,sandstone samples were collected from different sites and were analyzed at both the hand and thin section scales.Three sandstone types were recognized,characterized by a different texture.Then,the laboratory characterization allowed estimating their main physico-mechanical and ultrasonic properties,such as porosity,density,mechanical strength,deformability,and ultrasonic velocities.The rock mechanical strength proved linked to the rock compactness and to the presence of lithic fragments,while pores and a pseudo-matrix between grains represent weakening features.Rock data were also statistically analyzed by grouping the specimens according to a geographical criterion,with respect to their sampling area,but no link was found between location and rock properties.Finally,with the aim of achieving mathematical laws that could be used to predict some rock properties from others,useful for practical purposes when dealing with such a high property variability,single and multiple regression analyses were carried out.Results show that the Uniaxial Compressive Strength,porosity,and P-wave velocity are the best predictors for a quick,indirect estimation of the main physico-mechanical parameters.The methodological approach developed for this research can be taken as reference to study other worldwide cases,involving rocks characterized by a wide range of physico-mechanical properties and covering large regional territories.
文摘Ignimbrites have been widely used as building materials in many historical and touristic structures in the Kayseri region of Türkiye. Their diverse colours and textures make them a popular choice for modern construction as well. However, ignimbrites are particularly vulnerable to atmospheric conditions, such as freeze-thaw cycles, due to their high porosity, which is a result of their formation process. When water enters the pores of the ignimbrites, it can freeze during cold weather. As the water freezes and expands, it generates internal stress within the stone, causing micro-cracks to develop. Over time, repeated freeze-thaw (F-T) cycles lead to the growth of these micro-cracks into larger cracks, compromising the structural integrity of the ignimbrites and eventually making them unsuitable for use as building materials. The determination of the long-term F-T performance of ignimbrites can be established after long F-T experimental processes. Determining the long-term F-T performance of ignimbrites typically requires extensive experimental testing over prolonged freeze-thaw cycles. To streamline this process, developing accurate predictive equations becomes crucial. In this study, such equations were formulated using classical regression analyses and artificial neural networks (ANN) based on data obtained from these experiments, allowing for the prediction of the F-T performance of ignimbrites and other similar building stones without the need for lengthy testing. In this study, uniaxial compressive strength, ultrasonic propagation velocity, apparent porosity and mass loss of ignimbrites after long-term F-T were determined. Following the F-T cycles, the disintegration rate was evaluated using decay function approaches, while uniaxial compressive strength (UCS) values were predicted with minimal input parameters through both regression and ANN analyses. The ANN and regression models created for this purpose were first started with a single input value and then developed with two and three combinations. The predictive performance of the models was assessed by comparing them to regression models using the coefficient of determination (R2) as the evaluation criterion. As a result of the study, higher R2 values (0.87) were obtained in models built with artificial neural network. The results of the study indicate that ANN usage can produce results close to experimental outcomes in predicting the long-term F-T performance of ignimbrite samples.
基金Projects(52074299,41941018)supported by the National Natural Science Foundation of ChinaProject(2023JCCXSB02)supported by the Fundamental Research Funds for the Central Universities,China。
文摘Bedding structural planes significantly influence the mechanical properties and stability of engineering rock masses.This study conducts uniaxial compression tests on layered sandstone with various bedding angles(0°,15°,30°,45°,60°,75°and 90°)to explore the impact of bedding angle on the deformational mechanical response,failure mode,and damage evolution processes of rocks.It develops a damage model based on the Logistic equation derived from the modulus’s degradation considering the combined effect of the sandstone bedding dip angle and load.This model is employed to study the damage accumulation state and its evolution within the layered rock mass.This research also introduces a piecewise constitutive model that considers the initial compaction characteristics to simulate the whole deformation process of layered sandstone under uniaxial compression.The results revealed that as the bedding angle increases from 0°to 90°,the uniaxial compressive strength and elastic modulus of layered sandstone significantly decrease,slightly increase,and then decline again.The corresponding failure modes transition from splitting tensile failure to slipping shear failure and back to splitting tensile failure.As indicated by the modulus’s degradation,the damage characteristics can be categorized into four stages:initial no damage,damage initiation,damage acceleration,and damage deceleration termination.The theoretical damage model based on the Logistic equation effectively simulates and predicts the entire damage evolution process.Moreover,the theoretical constitutive model curves closely align with the actual stress−strain curves of layered sandstone under uniaxial compression.The introduced constitutive model is concise,with fewer parameters,a straightforward parameter determination process,and a clear physical interpretation.This study offers valuable insights into the theory of layered rock mechanics and holds implications for ensuring the safety of rock engineering.
基金Project(51925402)supported by the National Science Fund for Distinguished Young Scholars,ChinaProject supported by the New Cornerstone Science Foundation through the XPLORER PRIZE,China+2 种基金Project(202103021222008)supported by the Outstanding Youth Cultivation Project in Shanxi Province,ChinaProject(2022SX-TD010)supported by Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering,ChinaProject(20201102004)supported by Shanxi Science and Technology Major Project,China。
文摘Pillar is closely related to the stability and reliability of underground spaces in closed/abandoned mines.The present research introduced a new technique to strengthen square cement mortar columns via fiber-reinforced polymer(FRP)strips to verify the strengthening effect of FRP on pillars.Compared to a fully wrapped FRP jacket,the advantages of FRP strip are cost-effective and easy-to-construct.A series of compression tests as well as theoretical analysis were carried out to explore the mechanical behavior of square cement mortar specimens partially strengthened with FRP strips.The results verified the effectiveness of FRP strips in enhancing the stress and strain of cement mortar.Different from unconfined cement mortar specimens,these FRP-strengthened cement mortar specimens are featured with the double-peaked behaviors,mainly attributed to the stress state transformation from a one-dimensional to a three-dimensional stress state.It also indicated that the enhancement of stress increased with the FRP strip width.Moreover,the brittle-ductile transition ductile failure characteristics were also observed in FRP-confined cement mortar specimens.The ultimate ductility of the cement mortar specimen decreases gradually with the growth of the FRP strip width.The main contribution of this research is to enrich the strengthening techniques for residual pillars.
基金Project supported by the National Natural Science Foundation of China (Grant Nos.11888101 and U1832202)the Chinese Academy of Sciences (Grant Nos.QYZDB-SSWSLH043,XDB28000000,and XDB33000000)+1 种基金the K.C.Wong Education Foundation (Grant No.GJTD-2018-01)the Informatization Plan of Chinese Academy of Sciences (Grant No.CAS-WX2021SF-0102)。
文摘We report a study of the electronic structure of BaFe_(2)As_(2) under uniaxial strains using angle-resolved photoemission spectroscopy and transport measurements. Two electron bands at the MY point, with an energy splitting of 50 meV in the strain-free sample, shift downward and merge into each other under a large uniaxial strain, while three hole bands at theГ point shift downward together. However, we also observed an enhancement of the resistance anisotropy under uniaxial strains by electrical transport measurements, implying that the applied strains strengthen the electronic nematic order in BaFe_(2)As_(2). These observations suggest that the splitting of these two electron bands at the MY point is not caused by the nematic order in BaFe_(2)As_(2).
基金financially supported by the National Science Fund for Distinguished Young Scholars of China(Grant No.51825904)the Research on the Form,Design Method and Weathering Resistance of Key Components of Novel Floating Support Structures for Offshore Photovoltaics(Grant No.2022YFB4200701).
文摘Due to the uneven seabed and heaving of soil during pumping,incomplete soil plugs may occur during the installation of bucket foundations,and the impacts on the bearing capacities of bucket foundations need to be evaluated.In this paper,the contact ratio(the ratio of the top diameter of the soil plug to the diameter of the bucket)and the soil plug ratio(the ratio of the soil heave height to the skirt height)are defined to describe the shape and size of the incomplete soil plug.Then,finite element models are established to investigate the bearing capacities of bucket foundations with incomplete soil plugs and the influences of the contact ratios,and the soil plug ratios on the bearing capacities are analyzed.The results show that the vertical bearing capacity of bucket foundations in homogeneous soil continuously improves with the increase of the contact ratio.However,in normally consolidated soil,the vertical bearing capacity barely changes when the contact ratio is smaller than 0.75,while the bearing capacity suddenly increases when the contact ratio increases to 1 due to the change of failure mode.The contact ratio hardly affects the horizontal bearing capacity of bucket foundations.Moreover,the moment bearing capacity improves with the increase of the contact ratio for small aspect ratios,but hardly varies with increasing contact ratio for aspect ratios larger than 0.5.Consequently,the reduction coefficient method is proposed based on this analysis to calculate the bearing capacities of bucket foundations considering the influence of incomplete soil plugs.The comparison results show that the proposed reduction coefficient method can be used to evaluate the influences of incomplete soil plug on the bearing capacities of bucket foundations.
基金funded by the National Natural Science Foundation of China(Grant Nos.51927808,52174098 and 52374151).
文摘Geological exploration cores obtained from shale gas wells several kilometers deep often show different height-diameter ratios(H/D)because of complex geological conditions(core disking or developed fractures),which makes further standard specimen preparation for mechanical evaluation of reservoirs difficult.In multi-cluster hydraulic fracturing,shale reservoirs between planes of hydraulic fractures with different lengths could be simplified to have different H/D ratios.Discovering the effect of H/D on the mechanical characteristics of shale specimens with different bedding orientations will support mechanical evaluation tests of reservoirs based on disked geological cores and help to optimize multicluster fracturing programs.In this study,we performed uniaxial compression tests and acoustic emission(AE)monitoring on cylindrical Longmaxi shale specimens under five bedding orientations and four H/D ratios.The experimental results showed that both the H/D-dependent mechanical properties and AE parameters demonstrated significant anisotropy.Increasing H/D did not change the uniaxial compressive strength(UCS)evolution versus bedding orientation,demonstrating a V-shaped relationship,but enhanced the curve shape.The stress level of crack damage for the specimens significantly increased with increasing H/D,excluding the specimens with a bedding orientation of 0°.With increasing H/D,the cumulative AE counts of the specimens with each bedding orientation tended to exhibit a stepped jump against the loading time.The proportion of low-average-frequency AE signals(below 100 kHz)in specimens with bedding orientations of 45°and 60°increased to over 70%by increasing H/D,but it only increased to 40%in specimens with bedding orientations of 0°,30°,and 90°.Finally,an empirical model that can reveal the effect of H/D on anisotropic UCS of shale reservoir was proposed,the anisotropic proportion of tensile and shear failure cracks in specimens under four H/D ratios was classified based on the AE data,and the effect of H/D on the anisotropic crack growth of specimens was discussed.
基金supported by the National Natural Science Foundation of China(Grant No.52074352)the National Natural Science Foundation of Hunan Province of China(Grant No.2023JJ30680)the Fundamental Research Funds for the Central Universities of Central South University(Grant No.2024ZZTS0423).
文摘Many rock engineering projects show that the growth of tensile cracks is often an important cause of engineering disasters,and the mechanical behavior of rocks is essentially the transmission,storage,dissipation and release of energy.To investigate the tensile behavior of rock from the perspective of energy,uniaxial tension tests(UTTs)and uniaxial compression tests(UCTs)were carried out on three typical rocks(granite,sandstone and marble).Different unloading points were set before the peak stress to separate elastic energy and dissipated energy.The input energy density ut,elastic energy density ue,and dissipated energy density ud at each unloading point were calculated by integrating stress-strain curves.The results show that there is a strong linear relationship between the three energy parameters and the square of the unloading stress in UCT,but this linear relationship is weaker in UTT.The ue and ud increase linearly with the increase in ut in UCT and UTT.Based on the phenomenon that ue and ud increase linearly with ut,the applicability of W_(et)^(p) index in UTT was proved and the relative energy storage capacity and absolute energy distribution characteristics of three rocks in UCT and UTT were evaluated.The tensile behavior of marble and sandstone in UTT can be divided into two stages vaguely according to the energy distribution,but granite is not the case.In addition,based on dissipated energy,the damage evolution of three types of rocks in UCT and UTT was discussed.This study provides some new insights for understanding the tensile behavior of rock.
基金Project supported by the National Key R&D Program of China (Grant No.2021YFB3501300)the National Natural Science Foundation of China (Grant Nos.91963201 and 12174163)the 111 Project (Grant No.B20063)。
文摘Based on the Landau-Lifshitz-Gilbert(LLG)equation,the precession relaxation of magnetization is studied when the external field H is parallel to the uniaxial anisotropic field H_(k).The evolution of three-component magnetization is solved analytically under the condition of H=nH_(k)(n=3,1 and 0).It is found that with an increase of H or a decrease of the initial polar angle of magnetization,the relaxation time decreases and the angular frequency of magnetization increases.For comparison,the analytical solution for H_(k)=0 is also given.When the magnetization becomes stable,the angular frequency is proportional to the total effective field acting on the magnetization.The analytical solutions are not only conducive to the understanding of the precession relaxation of magnetization,but also can be used as a standard model to test the numerical calculation of LLG equation.
基金financially supported by the Key R&D Program of Shaanxi Province(2023-YBSF-324)Shaanxi Provincial Department of Education Services Local Special Plan Project(23JC019)National Natural Science of Foundation of China(42267024).
文摘Gauge length influences the biomechanical properties of herbaceous roots such as tensile resistance,tensile strength and Young’s modulus.However,the extent to which and how these biomechanical properties of herbaceous roots are influenced remain unknown.To better understand the behavior of roots in tension under different conditions and to illustrate these behaviors,uniaxial tensile tests were conducted on the Poa araratica roots as the gauge length increased from 20 mm to 80 mm.Subsequently,ANOVA was used to test the impact of the significant influences of gauge length on the biomechanical properties,nonlinear regression was applied to establish the variation in the biomechanical properties with gauge length to answer the question of the extent to which the biomechanical properties are influenced,and Weibull models were subsequently introduced to illustrate how the biomechanical properties are influenced by gauge length.The results reveal that(1)the variation in biomechanical properties with root diameter depends on both the gauge length and the properties themselves;(2)the gauge length significantly impacts most of the biomechanical properties;(3)the tensile resistance,tensile strength,and tensile strain at cracks decrease as the gauge length increases,with values decreasing by 20%-300%,while Young’s modulus exhibits the opposite trend,with a corresponding increase of 30%;and(4)the Weibull distribution is suitable for describing the probability distribution of these biomechanical properties;the Weibull modulus for both tensile resistance and tensile strain at cracks linearly decrease with gauge length,whereas those for tensile strength and Young’s modulus exhibit the opposite trend.The tensile resistance,tensile strength,and tensile strain at the cracks linearly decrease with increasing gauge length,while the tensile strength and Young’s modulus linearly increase with increasing gauge length.
基金the National Natural Science Foundation of China(Grant Nos.42272041,41902034,52302043,12304015,52302043,and 12011530063)the National Major Science Facility Synergetic Extreme Condition User Facility Achievement Transformation Platform Construction(Grant No.2021FGWCXNLJSKJ01)+2 种基金the China Postdoctoral Science Foundation(Grant Nos.2022M720054 and 2023T160257)the National Key Research and Development Program of China(Grant No.2022YFB3706602)the Jilin Univer-sity High-level Innovation Team Foundation,China(Grant No.2021TD-05).
文摘Deformation can change the transition pathway of materials under high pressure,thus significantly affects physical and chemical properties of matters.However,accurate pressure calibration under deformation is challenging and thereby causes relatively large pressure uncertainties in deformation experiments,resulting in the synthesis of complex multiphase materials.Here,pressure generations of three types of deformation assemblies were well calibrated in a Walker-type largevolume press(LVP)by electrical resistance measurements combined with finite element simulations(FESs).Hard Al_(2)O_(3) or diamond pistons in shear and uniaxial deformation assemblies significantly increase the efficiency of pressure generation compared with the conventional quasi-hydrostatic assembly.The uniaxial deformation assembly using flat diamond pistons possesses the highest efficiency in these deformation assemblies.This finding is further confirmed by stress distribution analysis based on FESs.With this deformation assembly,we found shear can effectively promote the transformation of C60 into diamond under high pressure and realized the synthesis of phase-pure diamond at relatively moderate pressure and temperature conditions.The present developed techniques will help improve pressure efficiencies in LVP and explore the new physical and chemical properties of materials under deformation in both science and technology.
基金supported by grants funded by Department of Mechanical Engineering,Faculty of Engineering,Chiang Mai University and the Graduate School of Chiang Mai University.
文摘The objective of this research was to determine the mechanical parameter from EVA foam and also investigate its behavior by using Blatz-Ko,Neo-Hookean,Mooney model and experimental test.The physical characteristic of EVA foam was also evaluated by scanning electron microscopy(SEM).The results show that Blatz-Ko and Neo-Hookean model can fit the curve at 5%and 8%strain,respectively.The Mooney model can fit the curve at 50%strain.The modulus of rigidity evaluated from Mooney model is 0.0814±0.0027 MPa.The structure of EVA foam from SEM image shows that EVA structure is a closed cell with homogeneous porous structure.From the result,it is found that Mooney model can adjust the data better than other models.This model can be applied for mechanical response prediction of EVA foam and also for reference value in engineering application.
基金supported by the National Natural Science Foundation of China(Grant No.52374153).
文摘Traditional laboratory tests for measuring rock uniaxial compressive strength(UCS)are tedious and timeconsuming.There is a pressing need for more effective methods to determine rock UCS,especially in deep mining environments under high in-situ stress.Thus,this study aims to develop an advanced model for predicting the UCS of rockmaterial in deepmining environments by combining three boosting-basedmachine learning methods with four optimization algorithms.For this purpose,the Lead-Zinc mine in Southwest China is considered as the case study.Rock density,P-wave velocity,and point load strength index are used as input variables,and UCS is regarded as the output.Subsequently,twelve hybrid predictive models are obtained.Root mean square error(RMSE),mean absolute error(MAE),coefficient of determination(R2),and the proportion of the mean absolute percentage error less than 20%(A-20)are selected as the evaluation metrics.Experimental results showed that the hybridmodel consisting of the extreme gradient boostingmethod and the artificial bee colony algorithm(XGBoost-ABC)achieved satisfactory results on the training dataset and exhibited the best generalization performance on the testing dataset.The values of R2,A-20,RMSE,and MAE on the training dataset are 0.98,1.0,3.11 MPa,and 2.23MPa,respectively.The highest values of R2 and A-20(0.93 and 0.96),and the smallest RMSE and MAE values of 4.78 MPa and 3.76MPa,are observed on the testing dataset.The proposed hybrid model can be considered a reliable and effective method for predicting rock UCS in deep mines.
基金financial support from the National Key R&D Program of China(Grant No.2020YFA0711802).
文摘The mechanical characteristics and acoustic behavior of rock masses are greatly influenced by stochastic joints.In this study,numerical models of rock masses incorporating intermittent joints with different numbers and dip angles were produced using the finite element method(FEM)with the intrinsic cohesive zone model(ICZM).Then,the uniaxial compressive and wave propagation simulations were performed.The results indicate that the joint number and dip angle can affect the mechanical and acoustic properties of the models.The uniaxial compressive strength(UCS)and wave velocity of rock masses decrease monotonically as the joint number increases.However,the wave velocity grows monotonically as the joint dip angle increases.When the joint dip angle is 45°–60°,the UCS of the rock mass is lower than that of other dip angles.The wave velocity parallel to the joints is greater than that perpendicular to the joints.When the dip angle of joints remains unchanged,the UCS and wave velocity are positively related.When the joint dip angle increases,the variation amplitude of the UCS regarding the wave velocity increases.To reveal the effect of the joint distribution on the velocity,a theoretical model was also proposed.According to the theoretical wave velocity,the change in wave velocity of models with various joint numbers and dip angles was consistent with the simulation results.Furthermore,a theoretical indicator(i.e.fabric tensor)was adopted to analyze the variation of the wave velocity and UCS.
基金supported by the National Natural Science Foundation of China(Grant Nos.42277150,41977219)Henan Provincial Science and Technology Research Project(Grant No.222102320271).
文摘The geometry of joints has a significant influence on the mechanical properties of rocks.To simplify the curved joint shapes in rocks,the joint shape is usually treated as straight lines or planes in most laboratory experiments and numerical simulations.In this study,the computerized tomography (CT) scanning and photogrammetry were employed to obtain the internal and surface joint structures of a limestone sample,respectively.To describe the joint geometry,the edge detection algorithms and a three-dimensional (3D) matrix mapping method were applied to reconstruct CT-based and photogrammetry-based jointed rock models.For comparison tests,the numerical uniaxial compression tests were conducted on an intact rock sample and a sample with a joint simplified to a plane using the parallel computing method.The results indicate that the mechanical characteristics and failure process of jointed rocks are significantly affected by the geometry of joints.The presence of joints reduces the uniaxial compressive strength (UCS),elastic modulus,and released acoustic emission (AE) energy of rocks by 37%–67%,21%–24%,and 52%–90%,respectively.Compared to the simplified joint sample,the proposed photogrammetry-based numerical model makes the most of the limited geometry information of joints.The UCS,accumulative released AE energy,and elastic modulus of the photogrammetry-based sample were found to be very close to those of the CT-based sample.The UCS value of the simplified joint sample (i.e.38.5 MPa) is much lower than that of the CT-based sample (i.e.72.3 MPa).Additionally,the accumulative released AE energy observed in the simplified joint sample is 3.899 times lower than that observed in the CT-based sample.CT scanning provides a reliable means to visualize the joints in rocks,which can be used to verify the reliability of photogrammetry techniques.The application of the photogrammetry-based sample enables detailed analysis for estimating the mechanical properties of jointed rocks.
基金supported by the National Natural Science Foundation of China(Grant Nos.52174096 and 51874311)。
文摘This study compares the strength characteristics of rocks anchored by NPR bolts and ordinary bolts with varied preloads,based on the mechanical properties of NPR bolts(with a negative Poisson’s ratio).The results show that the uniaxial compressive stress-strain curve of ordinary anchored rocks exhibits noticeable abrupt changes.After reaching peak strength,the bolt breaks,whereas the stress-strain curve of NPR-anchored rocks is smoother.The NPR bolt enters the stage of continuous resistance after reaching maximal strength and does not break.As the preload increases,the strength of the anchored rock grows linearly.A calculation equation for the strength of the anchored rock is proposed based on the preload.The theoretical equation fits the test results well,and the fitted parameters show that NPR bolts can better increase the strength of the rock.The concept of dynamic toughness UC of anchored rock is proposed to reflect the comprehensive mechanical properties of anchored rock,including strength and plasticity.As the preload increases,the UC of ordinary anchored rock first decreases and then increases,while the UC of the NPR anchored rock does not change significantly with the preload when the strain is small,and the UC increases with the increase of the preload when the strain is large.