A three-dimensional mathematical model was established to predict the multiphase flow,motion and dispersion of desulfurizer particles,and desulfurization of hot metal during the Kanbara reactor(KR)process.The turbulen...A three-dimensional mathematical model was established to predict the multiphase flow,motion and dispersion of desulfurizer particles,and desulfurization of hot metal during the Kanbara reactor(KR)process.The turbulent kinetic energy-turbulent dissipation rate(k-ε)turbulence model,volume-of-fluid multiphase model,discrete-phase model,and unreacted core model for the reaction between the hot metal and particles were coupled.The measured sulfur content of the hot metal with time during the actual KR process was employed to validate the current mathematical model.The distance from the lowest point of the liquid level to the bottom of the ladle decreased from 3170 to2191 mm when the rotation speed increased from 30 to 110 r/min,which had a great effect on the dispersion of desulfurizer particles.The critical rotation speed for the vortex to reach the upper edge of the stirring impeller was 70 r/min when the immersion depth was 1500 mm.The desulfurization rate increased with the increase in the impeller rotation speed,whereas the influence of the immersion depth was relatively small.Formulas for different rotation parameters on the desulfurization rate constant and turbulent energy dissipation rate were proposed to evaluate the variation in sulfur content over time.展开更多
Controlling inclusion composition, from the point of view of thermodynamics, only explains the probability and limit of reaction. However, kinetics makes the nucleation and the velocity of growth of inclusions clear, ...Controlling inclusion composition, from the point of view of thermodynamics, only explains the probability and limit of reaction. However, kinetics makes the nucleation and the velocity of growth of inclusions clear, and these kinetic factors are very important to the quality of slab. The basic kinetic theory of unreacted core model was used to build the mathematical model for the growth of inclusions and the concerned software was developed through Visual Basic 6.0. The time that different radius inclusions attain saturation was calculated to determine the controlling step of reaction between steel and inclusions. The time for the growth of inclusion obtained from the model was in good agreement with the data measured by Japanese Okuyama G, which indicated that the model is reasonable.展开更多
基金financially supported by the National Science Foundation China(No.52104343)the Natural Science Foundation of Hebei Province,China(No.E2021203222)+1 种基金support from the High Steel Center(HSC)at Yanshan UniversityNorth China University of Technology,China。
文摘A three-dimensional mathematical model was established to predict the multiphase flow,motion and dispersion of desulfurizer particles,and desulfurization of hot metal during the Kanbara reactor(KR)process.The turbulent kinetic energy-turbulent dissipation rate(k-ε)turbulence model,volume-of-fluid multiphase model,discrete-phase model,and unreacted core model for the reaction between the hot metal and particles were coupled.The measured sulfur content of the hot metal with time during the actual KR process was employed to validate the current mathematical model.The distance from the lowest point of the liquid level to the bottom of the ladle decreased from 3170 to2191 mm when the rotation speed increased from 30 to 110 r/min,which had a great effect on the dispersion of desulfurizer particles.The critical rotation speed for the vortex to reach the upper edge of the stirring impeller was 70 r/min when the immersion depth was 1500 mm.The desulfurization rate increased with the increase in the impeller rotation speed,whereas the influence of the immersion depth was relatively small.Formulas for different rotation parameters on the desulfurization rate constant and turbulent energy dissipation rate were proposed to evaluate the variation in sulfur content over time.
基金Item Sponsored by National Natural Science Foundation of China and Shanghai Baoshan Steel Group(50674013)
文摘Controlling inclusion composition, from the point of view of thermodynamics, only explains the probability and limit of reaction. However, kinetics makes the nucleation and the velocity of growth of inclusions clear, and these kinetic factors are very important to the quality of slab. The basic kinetic theory of unreacted core model was used to build the mathematical model for the growth of inclusions and the concerned software was developed through Visual Basic 6.0. The time that different radius inclusions attain saturation was calculated to determine the controlling step of reaction between steel and inclusions. The time for the growth of inclusion obtained from the model was in good agreement with the data measured by Japanese Okuyama G, which indicated that the model is reasonable.
基金Project(51276074)supported by the National Natural Science Foundation of ChinaProject(2014NY008)supported by Innovation Research Foundation of Huazhong University of Science and Technology,China