Phytoremediation of industrial effluent containing azo dye by model up-flow constructed wetland

This study assessed the treatment of azo dye Acid Orange 7 （AO7） containing wastewater by laboratory-scale up-flow constructed wetland （UFCW） with and without supplementary aeration. The supplementary aeration could effectively control the ratio of anaerobic and aerobic zones in the UFCW reactor. The results clearly show the supplementary aeration boosted the biodegradation of organic pollutants and mineralization of intermediate aromatic amines formed by AO7 degradation.

Performance and Modeling of an Up-flow Anaerobic Sludge Blanket(UASB) Reactor for Treating High Salinity Wastewater from Heavy Oil Production

In this study,an up-flow anaerobic sludge blanket(UASB) reactor was applied to treat the high salinity wastewater from heavy oil production process.At a HRT of ≥24 h,the COD removal reached as high as 65.08% at an influent COD ranging from 350mg/L to 640mg/L.An average of 74.33% oil reduction was also achieved in the UASB reactor at an initial oil concentration between 112mg/L and 205mg/L.These results indicated that this heavy oil production related wastewater could be degraded efficiently in the UASB reactor.Granular sludge was formed in this reactor.In addition,two models,built on the back propagation neural network(BPNN) theory and linear regression techniques were developed for the simulation of the UASB system performance in the oily wastewater biodegradation.The average error of COD and oil removal was-0.65% and 0.84%,respectively.The results indicated that the models built on the BPNN theory were wellfitted to the detected data,and were able to simulate and predict the removal of COD and oil by the UASB reactor.

基质质量浓度对不同载体UAFB-Anammox反应器脱氮性能的影响

为了研究厌氧氨氧化膜生物反应器运行的稳定性,利用3个分别以组合填料、聚氨酯泡绵和立体弹性纤维作为填料的上流式固定床(up-flow anaerobic fixed bed,UAFB)生物膜反应器,以人工配水为研究对象,考察了进水基质(NH_4^+-N、NO_2^--N)质量浓度对不同生物载体反应器脱氮效能及挂膜效果的影响.结果表明:与聚氨酯泡绵和立体弹性纤维相比,添加组合填料的反应器耐基质质量浓度冲击能力最强.随着基质质量浓度的增加,其对NH_4^+-N及NO_2^--N的去除率呈先降低后上升的趋势.当基质质量浓度均达226 mg/L时,两者的去除率分别为76.37%和77.53%,氮去除负荷为1.32kg·N/(m^3·d).含聚氨酯泡绵填料的反应器在最大基质质量浓度下NH_4^+-N和NO_2^--N去除率仅为44.90%和41.41%.添加立体弹性纤维填料的反应器的脱氮稳定性介于前两者之间.组合填料具有较高的比表面积和较好的亲水性,易于微生物附着生长且不易脱落;而聚氨酯泡绵填料比表面积及表面粗糙度均低于组合填料,且微生物截留能力较低,导致其受到冲击后生物膜易脱落,故其耐基质质量浓度冲击能力最差;立体弹性纤维表面粗糙度高利于微生物附着,但亲水性差且对微生物亲和性低,易发生膜损失.

Nitrogen removal via nitrite from municipal landfill leachate

A system consisting of a two-stage up-flow anaerobic sludge blanket （UASB）, an anoxic/aerobic （A/O） reactor and a sequencing batch reactor （SBR）, was used to treat landfill leachate. During operation, denitrification and methanogenesis took place simultaneously in the first stage UASB, and the effluent chemical oxygen demand （COD） was further removed in the second stage UASB. Then the denitrification of nitrite and nitrate in the returned sludge by using the residual COD was accomplished in the A/O reactor, and ammonia was removed via nitrite in it. Last but not least, the residual ammonia was removed in SBR as well as nitrite and nitrate which were produced by nitrification. The results over 120 d （60 d for phase I and 60 d for phase II） were as follows： when the total nitrogen （TN） concentration of influent leachate was about 2500 mg/L and the ammonia nitrogen concentration was about 2000 mg/L, the shortcut nitrification with 85%-90% nitrite accumulation was achieved stably in the A/O reactor. The TN and ammonia nitrogen removal efficiencies of the system were 98% and 97%, respectively. The residual ammonia, nitrite and nitrate produced during nitrification in the A/O reactor could be washed out almost completely in SBR. The TN and ammonia nitrogen concentrations of final effluent were about 39 mg/L and 12 mg/L, respectively.

Effect of Sodium Ion Concentration on Hydrogen Production from Sucrose by Anaerobic Hydrogen-producing Granular Sludge

This work evaluated the effects of sodium ion concentration, ranging from 0 to 16000mg·L^-1（Na^＋）, on the conversion of sucrose to hydrogen by a high-activity anaerobic hydrogen-producing granular sludge. At the optimum sodium ion concentration [1000-2000mg·L^-1（Na^＋）] for hydrogen production at 37℃, the maximum sucrose degradation rate, the specific hydrogen production yield and the specific hydrogen production rate were 393.6-413.1mg·L^-1.h^-1, 28.04-28.97ml·g^-1, 7.52-7.83ml·g^-1.h^-1, respectively. The specific production yields of propionate, butyrate and valerate decreased with increasing sodium ion concentration, whereas the specific acetate production yield increased, meanwhile the specific production yields of ethanol and caproate were less than 55.3 and 12.6mg·g^-1, respectively. The hybrid fermentation composition gradually developed from acetate, propionate and butyrate to acetate with the increase in sodium ion concentration.

Effect of Flow Directions on Multiphase Flow Boiling Heat Transfer Enhanced by Suspending Particles in a Circulating Evaporation System

A circulating fluidized bed evaporator(including down-flow, horizontal, and up-flow beds) was constructed to study the effect of flow directions on multiphase flow boiling heat transfer. A range of experimental investigations were carried out by varying amount of added particles(0-2%), circulation flow rate(2.15-5.16 m^3/h) and heat flux(8-16 kW/m^2). The comparison of heat transfer performance in different vertical heights of the horizontal bed was also discussed. Results reveal that the glass bead particle can enhance heat transfer compared with vapor-liquid two-phase flow for all beds. At a low heat flux(q = 8 kW/m), the heat-transfer-enhancing factor of the horizontal bed is obviously greater than those of the up-flow and down-flow beds. With the increase in the amount of added particles, the heat-transfer-enhancing factors of the up-flow and down-flow beds increase, whereas that of the horizontal bed initially increases and then decreases. However, at a high heat flux(q=16 kW/m), the heat-transfer-enhancing factors of the three beds show an increasing tendency with the increase in the amount of added particles and become closer than those at a low heat flux. For all beds, the heat-transfer-enhancing factor generally increases with the circulation flow rate but decreases with the increase in heat flux.

Water-recycled Cassava Bioethanol Production Integrated with Two-stage UASB Treatment

Considering limited success in target-hitting discharge from alcohol industry, our attention was directed toward a recycling use of distillery spentwash (DS) in cassava bioethanol production by using a two-stage up-flow anaerobic sludge blanket bioremediation (TS-UASBB). With the TS-UASBB, 2 4 SO , COD, N and P in the effluent from the DS degraded significantly and their concentrations were kept at 0.2 g·L -1 , 2.0 g·L -1 , 1.0 g·L -1 and 15 mg·L -1 , respectively, in 13 batch processes for water-recycled ethanol fermentation. With the effluent used directly as dilution water, no heat-resistant bacteria were found alive. The thirteen-batch ethanol production individually achieved 10% after 48 h fermentation. The starch utilization ratio and total sugar consumption were 90% and 99.5%, respectively. The novel water-recycled bioethanol production process with ethanol fermentation and TS-UASBB has a considerable potential in other starchy and cellulosic ethanol production.

Useful predictions ahead of large earthquakes and lessons learned for future progress

A significant basis for this article is the outcome of 4 multinational research projects which were carried out in South-West Iceland from 1988-2006,focusing on crustal processes that preceded two magnitude-6.6 earthquakes in June 2000.The seismic activity that preceded a magnitude 6.3 double-earthquake in the same seismic zone in 2008 is also significant,as well as other research work which helps to understand how observable crustal processes lead to earthquakes.A significant outcome is that it cannot be assumed that any two earthquakes have the same precursory processes.Therefore,statistical analysis of precursors of past earthquakes is of limited value for predicting future earthquakes.On the other hand,with highly sensitive seismic monitoring it is possible to observe the nucleation process for each specific large earthquake for long enough time for earth-realistic modeling of it and extrapolating towards the earthquake in time and space.In the Iceland crust,with its fluid-rock interactions,pre-earthquake activity on a scale of years is expected.This allows a long-term approach to prediction.We apply historical information and sensor-based data to find probable sources of earthquake nucleation.We monitor the nucleation process for a possibly impending earthquake at these sources,and then model the process to find its governing factors and extrapolate those in time and space,aiming towards finding hypocenter,fault-size,impact,and time of the impending earthquake.We refine our models by predicting frequent medium-sized earthquakes and compare the predictions with measurements.We predict how the possibly impending large earthquake would trigger earthquakes at other locations.Given the complexity of the crust,we must take all observed changes into account when developing models of pre-earthquake processes.The development of a continuously operating geo-watching system is discussed to link scientific evaluations to warnings that can be used by emergency authorities.

Kinetics of municipal sewage degradation in EGSB and UASB reactors at 10 ℃

Kinetics of municipal sewage degradation in Expanded Granular Sludge Bed(EGSB)and Up-flow Anaerobic Sludge Blanket(UASB)reactors at 10℃ were investigated via continuous experimental equipments.The results indicated that the whole reaction process can be simulated by the first-order dynamic equation model.Dynamic parameters such as k,Vmax and Ks of UASB in hydrolysis acidification stage were 1.08 d-1,2.8 d-1 and 372 mg/L comparing to those of 1.18 d-1,3.5 d-1 and 112 mg/L in the methanogenesis stage respectively.The EGSB’s k,Vmax and Ks were 2.91 d-1,14.3 d-1 and 470 mg/L in the hydrolysis acidification stage comparing to those of 1.68 d-1,6.6 d-1 and 103 mg/L in the methanogenesis stage respectively.Comparison of k values of the two stages in UASB and EGSB indicates that hydrolysis acidification stage is the controlling step for the whole reaction process of UASB,while methanogenesis stage is the controlling step in EGSB.Compared with UASB,municipal sewage treatment by EGSB at 10 ℃ can reach the same effluent requirement with lower retention time due to its effluent recirculation.

Effect of Sodium Ion Concentration on Hydrogen Production from Sucrose by Anaerobic Hydrogen-producing Granular Sludge

This work evaluated the effects of sodium ion concentration, ranging from 0 to 16000mg·L-1(Na+), on the conversion of sucrose to hydrogen by a high-activity anaerobic hydrogen-producing granular sludge. At the opti- mum sodium ion concentration [1000—2000mg·L-1(Na+)] for hydrogen production at 37℃, the maximum sucrose degradation rate, the specific hydrogen production yield and the specific hydrogen production rate were 393.6— 413.1mg·L-1·h-1, 28.04—28.97ml·g-1, 7.52—7.83ml·g-1·h-1, respectively. The specific production yields of propionate, butyrate and valerate decreased with increasing sodium ion concentration, whereas the specific acetate production yield increased, meanwhile the specific production yields of ethanol and caproate were less than 55.3 and 12.6mg·g-1, respectively. The hybrid fermentation composition gradually developed from acetate, propionate and butyrate to acetate with the increase in sodium ion concentration.

Optimizing Conditions of Enhancing Granule Sludge Concentration and Performance

An expanded granular sludge bed （EGSB） reactor was adopted to study the influence factors and rule of enhancing granular sludge concentration and performance. The experiment was performed at 33 ℃, pH 6.0-8.0 with continuous flow by adding proper quantity of nutritional trace elements. The results show that SLR was the key of steady operation of EGSB reactor. The increment of the granular sludge was influenced by volume loading rate （VLR）, liquid up-flow velocity and sludge loading rate （SLR）. Concentration of granular sludge increased rapidly when liquid up-flow velocity was over 0.94 m · h^-1 with SLR being at 1.0-2.0 d ^-1. With the propriety parameters： liquid up-flow velocity 2.52 m · h^-1, SLR 1.0-2.2 d^-1 and VLR 8.2-13.1 kg · m ^3 · d^-1, 23 days＇ continuous operation resulted in an increment by over 80% of granular sludge concentration in the EGSB reactor, plus good granular sludge property.

Feasibility assessment of up-flow anaerobic sludge blanket treatment of sulfamethoxazole pharmaceutical wastewater

Treatment of sulfamethoxazole pharmaceutical wastewater is a big challenge.In this study,a series of anaerobic evaluation tests on pharmaceutical wastewater from different operating units was conducted to evaluate the feasibility of using anaerobic digestion,and the results indicated that the key refractory factor for anaerobic treatment of this wastewater was the high sulfate concentration.A laboratory-scale up-flow anaerobic sludge blanket(UASB)reactor was operated for 195 days to investigate the effects of the influent chemical oxygen demand(COD),organic loading rate(OLR),and COD/SO_(4)^(2-) ratio on the biodegradation of sulfamethoxazole in pharmaceutical wastewater and the process performance.The electron flow indicated that methanogenesis was still the dominant reaction although sulfidogenesis was enhanced with a stepwise decrease in the influent COD/SO_(4)^(2-) ratio.For the treated sulfamethoxazole pharmaceutical wastewater,a COD of 4983 mg/L(diluted by 50%),OLR of 2.5 kg COD/(m^(3)·d),and COD/SO_(4)^(2-) ratio of more than 5 were suitable for practical applications.The recovery performance indicated that the system could resume operation quickly even if production was halted for a few days.

Anaerobic treatment of wastewater containing methanol in up-flow anaerobic sludge bed (UASB) reactor

The direct conversion of methanol into methane is the main process in anaerobic treatment of methanol containing wastewater.However,acetic acid can also be produced from methanol theoretically,which may probably result in an abrupt pH drop and deteriorate the anaerobic process.Therefore,it is interesting to know what would really happen in an anaerobic reactor treating methanol wastewater.In this study,an up-flow anaerobic sludge bed(UASB)reactor treating methanol wastewater was operated.The chemical oxygen demand(COD),acetic acid and pH of the effluent were monitored at different loadings and influent alkalinity.The results showed that the anaerobic reactor could be operated steadily at as low as 119 mg/L of influent alkalinity and high organic loading rate with no obvious pH drops.Volatile fatty acids accumulation was not observed even at strong shock loadings.The microorganisms in the sludge at the end of the test became homogeneous in morphology,which were mainly spherical or spheroidal in shape.

Deciphering the effect of sodium dodecylbenzene sulfonate on up-flow anaerobic sludge blanket treatment of synthetic sulfate-containing wastewater

In this study,the effects of organic sulfur on anaerobic biological processes were investigated by operating two up-flow anaerobic sludge blanket(UASB)reactors with sodium dodecylbenzene sulfonate(SDBS)as a representative of organic sulfur.The results indicated that the specific methanogenic activity(SMA)and chemical oxygen demand(COD)removal efficiency of R2(with SDBS added)were higher than those of R1(without SDBS)when the COD/SO_(4)^(2−)ratio was above 5.0.However,when the COD/SO_(4)^(2−)ratio was lower than 5.0,the sulfate reduction efficiency of R2 was higher than that of R1.These results and the observed SDBS transformation efficiency in anaerobic reactors indicate that low concentrations of SDBS accelerate methane production and the continuous accumulation of SDBS does not weaken the reduction of sulfate.Similarly,the calculated electron flux for a COD/SO_(4)^(2−)ratio of 1.0 indicates that the utilization intensity of electrons by sulfate-reducing bacteria(SRB)in R2 was 36.48%higher than that of SRB in R1 and exceeded that of methane-producing archaea(MPA)under identical working conditions.Moreover,the addition of SDBS in R2 made sulfidogenesis the dominant reaction at low COD/SO_(4)^(2−),and Methanobacterium and Methanobrevibacter with H_(2)/CO_(2)as the substrate and Desulfomicrobium were the dominant MPA and SRB,respectively.However,methanogenesis was still the dominant reaction in R1,and Methanosaeta with acetic acid as the substrate and Desulfovibrio were the dominant MPA and SRB,respectively.

Sustainable green technology on wastewater treatment:The evaluation of enhanced single chambered up-flow membrane-less microbial fuel cell

This study demonstrated the potential of single chamber up-flow membrane-less microbial fuel cell（UFML-MFC） in wastewater treatment and power generation. The purpose of this study was to evaluate and enhance the performance under different operational conditions which affect the chemical oxygen demand（COD） reduction and power generation,including the increase of KCl concentration（MFC1） and COD concentration（MFC2）. The results showed that the increase of KCl concentration is an important factor in up-flow membrane-less MFC to enhance the ease of electron transfer from anode to cathode. The increase of COD concentration in MFC2 could led to the drop of voltage output due to the prompt of biofilm growth in MFC2 cathode which could increase the internal resistance. It also showed that the COD concentration is a vital issue in up-flow membrane-less MFC.Despite the COD reduction was up to 96%, the power output remained constrained.

Insights into a novel nitrogen removal process based on simultaneous anammox and denitrification(SAD) following nitritation with in-situ NOB elimination

Simultaneous anammox and denitrification(SAD) is an efficient approach to treat wastewater having a low C/N ratio;however, few studies have investigated a combination of SAD and partial nitritation(PN). In this study, a lab-scale up-flow blanket filter(UBF) and zeolite sequence batch reactor(ZSBR) were continuously operated to implement SAD and PN advantages, respectively. The UBF achieved a high total nitrogen(TN) removal efficiency of over 70% during the start-up stage(days 1–50), and reached a TN removal efficiency of 96%in the following 90 days(days 51–140) at COD/NH_(4)^(+)-N ratio of 2.5. The absolute abundance of anammox bateria increased to the highest value of 1.58 × 107copies/μL DNA;Comamonadaceae was predominant in the UBF at the optimal ratio. Meanwhile, ZSBR was initiated on day 115 as fast nitritation process to satisfy the influent requirement for the UBF. The combined process was started on day 140 and then lasted for 30 days, during the combined process, between the two reactors, the UBF was the main contributor for TN(66.5% ± 4.5%)and COD(71.8% ± 4.9%) removal. These results demonstrated that strong SAD occurred in the UBF when following a ZSBR with in-situ NOB elimination. This research presents insights into a novel biological nitrogen removal process for low C/N ratio wastewater treatment.

Enhanced removal of organic matter and typical disinfection byproduct precursors in combined iron–carbon micro electrolysis-UBAF process for drinking water pre-treatment

The organic matter and two types of disinfection byproduct(DBP) precursors in micropolluted source water were removed using an iron–carbon micro-electrolysis(ICME)combined with up-flow biological aerated filter(UBAF) process. Two pilot-scale experiments(ICME-UBAF and UBAF alone) were used to investigate the effect of the ICME system on the removal of organic matter and DBP precursors. The results showed that ICME pretreatment removed 15.6% of dissolved organic matter(DOM)and significantly improved the removal rate in the subsequent UBAF process. The ICME system removed 31% of trichloromethane(TCM) precursors and 20% of dichloroacetonitrile(DCAN) precursors. The results of measurements of the molecular weight distribution and hydrophilic fractions of DOM and DBP precursors showed that ICME pretreatment played a key role in breaking large-molecular-weight organic matter into low-molecular-weight components, and the hydrophobic fraction into hydrophilic compounds, which was favorable for subsequent biodegradation by UBAF.Three-dimensional fluorescence spectroscopy(3D-EEM) further indicated that the ICME system improved the removal of TCM and DCAN precursors. The biomass analysis indicated the presence of a larger and more diverse microbial community in the ICME-UBAF system than for the UBAF alone. The high-throughput sequencing results revealed that domination of the genera Sphingomonas, Brevundimonas and Sphingorhabdus contributed to the better removal of organic matter and two types of DBP precursors. Also, Nitrosomonas and Pseudomonas were beneficial for ammonia removal.

Effect of upward ion on field-aligned currents in the near-earth magnetotail

A 3-dimensional resistive MHD simulation was carried out to study the effect of the upward ions on the field-aligned currents (FACs) in the near-earth magnetotail. The simulation results show that the up-flow ions originating from the nightside auroral oval would drift into the center plasma sheet along the magnetic field lines in the plasma sheet boundary, and have an important effect on the field-aligned currents. The main conclusions include that: 1) the upward-ions mainly affect the field- aligned currents in the near-earth magnetotail (inside 15 Re); 2) the generated FACs in the near-earth region have two types, i.e., Region 1 FAC in the high-latitude and Region 2 FAC in the low-latitude; 3) FACs increase with the enhancement of the upward ion flux; 4) with the same flux of the upward ions, FACs enhance with the increase of the velocity of the up-flow ions; 5) the intensification of FACs is also closely related with the latitude of the upward ions, and the ions from the closed field line region generate larger FACs; 6) the generation of FACs is closely related with By created by the upward ions.

Solids flow diagram of a CFB riser using Geldart B-type powders

Riser operating modes are vital to designing a circulating fluidized bed （CFB） reactor for a required process of either a gas-solid or a gas-catalytic nature. Different operating modes provide different solids＇ residence times and mixing behaviors, which define the reactions＇ efficiency and yield. The literature demonstrates distinct operating modes resulting from observed differences in slip factors and the range of particle velocities and their associated residence time distribution. The present research uses positron emission particle tracking （PEPT） in a riser of B-type bed material to determine the different operating modes by measuring （i） particle velocities and residence time distribution, （ii） population densities of these particles in the cross-sectional area of the riser, and （iii） solids flow pattern at the bottom of the riser, Data treatment defines four distinct solids hold-up regimes in the riser and proposes a ＂phase diagram＂ depicting the existence of the different operating modes （dilute, dense, core-annulus and combined） as a function of the superficial gas velocity and solids circulation flux in the riser. The delineated regimes have good agreement with available literature data and known industrial operations. Comparison with literature data for risers using A-type powders is also fair. The diagram enables CFB designers to better delineate operating characteristics.

CFD modeling and experiment of heat transfer in a tubular photo-bioreactor for photo-fermentation bio-hydrogen production

Temperature is one of the most important parameters that need to be controlled in photo-fermentation bio-hydrogen production(PFHP)system.Since the high temperature and big temperature fluctuation have adverse impacts on bio-hydrogen yield,the system numerical simulation based on the operating conditions and environmental factors is desirable.This research focused on the investigation of heat transfer properties of the PFHP system.Enzymatic hydrolysate from agricultural residues was taken as substrate,and up-flow tubular photo-bioreactor was adopted for PFHP.Temperatures inside the photo-bioreactor were monitored.The experimental design and computational modeling for the determination of the heat transfer behavior in tubular photo-bioreactor was presented.Energy balance analysis was conducted to determine the energy efficiency,and optimize the operation parameters in order to obtain higher energy efficiency.The commercial software FLUENT was also adopted in order to predict the transient temperature distribution in the photo-bioreactor.The results showed that mathematical and computational modeling method has a clear potential for improving the performance of photo-bioreactor in the process of PFHP.Up-flow tubular bioreactor has tiny temperature fluctuant,and is suitable for PFHP.