The photoconductive properties of MBB-PPV/C_(60) composite films fabricated by the physical jet deposition(PJD)technique have been studied on the basis of the photoinduced charge transfer process.Under the photoex-cit...The photoconductive properties of MBB-PPV/C_(60) composite films fabricated by the physical jet deposition(PJD)technique have been studied on the basis of the photoinduced charge transfer process.Under the photoex-citation,the transverse photoconductivity of the composite films is greatly enhanced by 4 orders of magnitude due to the efficient excitation transfer process from MBB-PPV(as donor)to C_(60)(as acceptor)occurring at the interface,the separation of charges and the existence of in-layer free carriers.The results indicate that the conjugated polymer/fullerene composite films optimized by an appropriate configuration have potential applications in photoelectric devices and photonic fields.展开更多
基金Supported by the National Natural Science Foundation of China under Grant Nos.69687004,29890216,19774018.
文摘The photoconductive properties of MBB-PPV/C_(60) composite films fabricated by the physical jet deposition(PJD)technique have been studied on the basis of the photoinduced charge transfer process.Under the photoex-citation,the transverse photoconductivity of the composite films is greatly enhanced by 4 orders of magnitude due to the efficient excitation transfer process from MBB-PPV(as donor)to C_(60)(as acceptor)occurring at the interface,the separation of charges and the existence of in-layer free carriers.The results indicate that the conjugated polymer/fullerene composite films optimized by an appropriate configuration have potential applications in photoelectric devices and photonic fields.