研究采用真空感应气雾化(Vacuum Induction Gas Atomization,VIGA)技术制备GH4169合金粉末,系统探究气体温度对粉末特性的影响规律。结果表明,随着气体温度从100℃升高到600℃,粉末的粒度分布明显向左移动,D50由75μm减小到42μm。扫描...研究采用真空感应气雾化(Vacuum Induction Gas Atomization,VIGA)技术制备GH4169合金粉末,系统探究气体温度对粉末特性的影响规律。结果表明,随着气体温度从100℃升高到600℃,粉末的粒度分布明显向左移动,D50由75μm减小到42μm。扫描电子显微镜(Scanning Electron Microscope,SEM)分析表明,较高气体温度有助于提高粉末的球形度,减少卫星粉的生成。X射线衍射(X-Ray Diffraction,XRD)分析揭示,气体温度对粉末的物相组成影响不大,但是较高温度下粉末具有更高的结晶度和更大的晶粒尺寸。此外,粉末的流动性随气体温度的升高而显著改善。展开更多
A simple and feasible method for the production of high nitrogen austenitic stainless steels involves nitrogen gas alloying and adding nitrided ferroalloys under normal atmospheric conditions. Alloying by nitrogen gas...A simple and feasible method for the production of high nitrogen austenitic stainless steels involves nitrogen gas alloying and adding nitrided ferroalloys under normal atmospheric conditions. Alloying by nitrogen gas bubbling in Fe-Cr-Mn-Mo series alloys was carried out in MoSi2 resistance furnace and air induction furnace under normal atmospheric conditions. The results showed that nitrogen alloying could be accelerated by increasing nitrogen gas flow rate, prolonging residence time of bubbles, increasing gas/molten steel interfaces, and decreasing the sulphur and oxygen contents in molten steel. Nitrogen content of 0.69% in 18Crl8Mn was obtained using air induction furnace by bubbling of nitrogen gas from porous plug. In addition, the nickel-free, high nitrogen austenitic stainless steels with sound and compact macrostructure had been produced in the laboratory using vacuum induction furnace and electroslag remelting furnace under nitrogen atmosphere by the addition of nitrided alloy with the maximum nitrogen content of 0.81%. Pores were observed in the ingots obtained by melting and casting in vacuum induction furnace with the addition of nitrided ferroalloys and under nitrogen atmosphere. After electroslag remelting of the cast ingots, they were all sound and were free of pores. The yield of nitrogen increased with the decrease of melting rate in the ESR process. Due to electroslag remelting under nitrogen atmosphere and the consequential addition of aluminum as deoxidizer to the slag, the loss of manganese decreased obviously. There existed mainly irregular Al2O3 inclusions and MnS inclusions in ESR ingots, and the size of most of the inclusions was less than 5 um. After homogenization of the hot rolled plate at 1 150℃ × 1 h followed by water quenching, the microstructure consisted of homogeneous austenite.展开更多
文摘研究采用真空感应气雾化(Vacuum Induction Gas Atomization,VIGA)技术制备GH4169合金粉末,系统探究气体温度对粉末特性的影响规律。结果表明,随着气体温度从100℃升高到600℃,粉末的粒度分布明显向左移动,D50由75μm减小到42μm。扫描电子显微镜(Scanning Electron Microscope,SEM)分析表明,较高气体温度有助于提高粉末的球形度,减少卫星粉的生成。X射线衍射(X-Ray Diffraction,XRD)分析揭示,气体温度对粉末的物相组成影响不大,但是较高温度下粉末具有更高的结晶度和更大的晶粒尺寸。此外,粉末的流动性随气体温度的升高而显著改善。
基金Item Sponsored by National Natural Science Foundation of China(50534010)
文摘A simple and feasible method for the production of high nitrogen austenitic stainless steels involves nitrogen gas alloying and adding nitrided ferroalloys under normal atmospheric conditions. Alloying by nitrogen gas bubbling in Fe-Cr-Mn-Mo series alloys was carried out in MoSi2 resistance furnace and air induction furnace under normal atmospheric conditions. The results showed that nitrogen alloying could be accelerated by increasing nitrogen gas flow rate, prolonging residence time of bubbles, increasing gas/molten steel interfaces, and decreasing the sulphur and oxygen contents in molten steel. Nitrogen content of 0.69% in 18Crl8Mn was obtained using air induction furnace by bubbling of nitrogen gas from porous plug. In addition, the nickel-free, high nitrogen austenitic stainless steels with sound and compact macrostructure had been produced in the laboratory using vacuum induction furnace and electroslag remelting furnace under nitrogen atmosphere by the addition of nitrided alloy with the maximum nitrogen content of 0.81%. Pores were observed in the ingots obtained by melting and casting in vacuum induction furnace with the addition of nitrided ferroalloys and under nitrogen atmosphere. After electroslag remelting of the cast ingots, they were all sound and were free of pores. The yield of nitrogen increased with the decrease of melting rate in the ESR process. Due to electroslag remelting under nitrogen atmosphere and the consequential addition of aluminum as deoxidizer to the slag, the loss of manganese decreased obviously. There existed mainly irregular Al2O3 inclusions and MnS inclusions in ESR ingots, and the size of most of the inclusions was less than 5 um. After homogenization of the hot rolled plate at 1 150℃ × 1 h followed by water quenching, the microstructure consisted of homogeneous austenite.
