Almost 30 years has passed since the publication of materials on vacuum carburizing technology, and is attracting a great deal of attention as a technology capable of being used as a substitute for gas carburizing tec...Almost 30 years has passed since the publication of materials on vacuum carburizing technology, and is attracting a great deal of attention as a technology capable of being used as a substitute for gas carburizing technology. However, the technology was not popular except in specific fields. The main reason for this is due to a variety of harmful influences accompanying the sooting problems caused by CH4 or C3H8. We have succeeded in that the occurrence of sooting was suppressed by utilizing acetylene, at extremely low pressure for carburizing (below 1 kPa). This process is now showing the excellent quality and prospects for this technology in terms of quality, economy and safety. At present almost 70 practical mass production furnaces are used in production lines, in Japan and abroad. At this time, we will report summary of the present acetylene vacuum carburizing process and the actual results obtained by these acetylene vacuum carburizing furnaces for mass production.展开更多
For pulsed power devices, surface flashover phenomena across solid insulators greatly restrict their overall performance. In recent decades, much attention has been paid on enhancing the surface electric withstanding ...For pulsed power devices, surface flashover phenomena across solid insulators greatly restrict their overall performance. In recent decades, much attention has been paid on enhancing the surface electric withstanding strength of insulators, and it is found that surface treatment of material is useful to improve the surface flashover voltage. The carburization treatment is employed to modify the surface components of newly-developed machinable ceramics （MC） materials. A series of MC samples with different glucose solution concentration （0%, 10%, 20%, 30% and 40%） are prepared by chemical reactions for surface carburization modification, and their surface fiashover characteristics are investigated under pulsed voltage in vacuum. It is found that the surface carburization treatment greatly modifies the surface resistivity of MCs and hence the flashover behaviors. Based on the reduction of surface resistivity and the secondary electron emission avalanche （SEEA） theory, the adjustment of flashover withstanding ability can be reasonably explained.展开更多
Compared with the traditional atm ospheric carburization, low-pressure carburization has the benefits of producing no surface oxidation and leaving fine, uniformly dispersed carbides in the carburized layer. However, ...Compared with the traditional atm ospheric carburization, low-pressure carburization has the benefits of producing no surface oxidation and leaving fine, uniformly dispersed carbides in the carburized layer. However, the process param eters for low-pressure carburization of 16Cr3NiWMoVNbE steel have yet to be optimized. Thus, we use the saturation-value method to optimize these parameters for aviation-gear materials. Toward this end, the m icrostructure and properties of 16Cr3NiWMoVNbE steel after different carburization processes are studied by optical microscopy, scanning electron microscopy, transm ission electron microscopy, and electron probe microanalysis. Considering the saturated austenite carbon concentration, we propose a model of carbon flux and an alloy coefficient for low -pressure carburization to reduce the carbon concentration in austenite and avoid the surface carbide network. At the early stage of carburization (30 s), the gas-solid interface has a higher concentration gradient. The averaging method is not ideal in practical applications, but the carbon flux measured by using the segm ented average m ethod is 2.5 times that measured by the overall average method, which is ideal in practical applications. The corresponding carburization tim e is reduced by 60%. By using the integral average method, the actual carburization time increases, which leads to the rapid form ation of carbide on the surface and affects the entire carburization process. Nb and Wcombine with C to form carbides, which hinders carbon diffusion and consumes carbon, resulting in a sharp decrease in the rate of C diffusion in austenite (the diffusion rate is reduced by 52% for 16Cr3NiWMoVNbE steel). By changing the diffusion coefficient model and comparing the hardness gradient of different processes, the depth of the actual layer is found to be very similar to the design depth.展开更多
IN the past five years the process combination of vacuum hardening, respectively vacuum carburizing with high-pressure gas quenching was successfully introduced to the market, especially in the manufacture of gears. I...IN the past five years the process combination of vacuum hardening, respectively vacuum carburizing with high-pressure gas quenching was successfully introduced to the market, especially in the manufacture of gears. In the meantime furnace concepts for various applications are available to the industry. In the following report three plant varieties are introduced, which differ in process flexibility and throughput. This report also explains criteria for the selection of a furnace in view of the existing application requirements. Besides this a short introduction is given into the vacuum carburizing process and the high-pressure gas quenching technology.展开更多
文摘Almost 30 years has passed since the publication of materials on vacuum carburizing technology, and is attracting a great deal of attention as a technology capable of being used as a substitute for gas carburizing technology. However, the technology was not popular except in specific fields. The main reason for this is due to a variety of harmful influences accompanying the sooting problems caused by CH4 or C3H8. We have succeeded in that the occurrence of sooting was suppressed by utilizing acetylene, at extremely low pressure for carburizing (below 1 kPa). This process is now showing the excellent quality and prospects for this technology in terms of quality, economy and safety. At present almost 70 practical mass production furnaces are used in production lines, in Japan and abroad. At this time, we will report summary of the present acetylene vacuum carburizing process and the actual results obtained by these acetylene vacuum carburizing furnaces for mass production.
基金supported in part by National Natural Science Foundation of China(Nos.50937004,50777051)NSFC-JSPS Joint Project(50911140103)
文摘For pulsed power devices, surface flashover phenomena across solid insulators greatly restrict their overall performance. In recent decades, much attention has been paid on enhancing the surface electric withstanding strength of insulators, and it is found that surface treatment of material is useful to improve the surface flashover voltage. The carburization treatment is employed to modify the surface components of newly-developed machinable ceramics （MC） materials. A series of MC samples with different glucose solution concentration （0%, 10%, 20%, 30% and 40%） are prepared by chemical reactions for surface carburization modification, and their surface fiashover characteristics are investigated under pulsed voltage in vacuum. It is found that the surface carburization treatment greatly modifies the surface resistivity of MCs and hence the flashover behaviors. Based on the reduction of surface resistivity and the secondary electron emission avalanche （SEEA） theory, the adjustment of flashover withstanding ability can be reasonably explained.
基金financially supported by the National Key R&D Program of China (Grant No. 2016YFB0300600)the National Natural Science Foundation of China (Grant No. 51604074)
文摘Compared with the traditional atm ospheric carburization, low-pressure carburization has the benefits of producing no surface oxidation and leaving fine, uniformly dispersed carbides in the carburized layer. However, the process param eters for low-pressure carburization of 16Cr3NiWMoVNbE steel have yet to be optimized. Thus, we use the saturation-value method to optimize these parameters for aviation-gear materials. Toward this end, the m icrostructure and properties of 16Cr3NiWMoVNbE steel after different carburization processes are studied by optical microscopy, scanning electron microscopy, transm ission electron microscopy, and electron probe microanalysis. Considering the saturated austenite carbon concentration, we propose a model of carbon flux and an alloy coefficient for low -pressure carburization to reduce the carbon concentration in austenite and avoid the surface carbide network. At the early stage of carburization (30 s), the gas-solid interface has a higher concentration gradient. The averaging method is not ideal in practical applications, but the carbon flux measured by using the segm ented average m ethod is 2.5 times that measured by the overall average method, which is ideal in practical applications. The corresponding carburization tim e is reduced by 60%. By using the integral average method, the actual carburization time increases, which leads to the rapid form ation of carbide on the surface and affects the entire carburization process. Nb and Wcombine with C to form carbides, which hinders carbon diffusion and consumes carbon, resulting in a sharp decrease in the rate of C diffusion in austenite (the diffusion rate is reduced by 52% for 16Cr3NiWMoVNbE steel). By changing the diffusion coefficient model and comparing the hardness gradient of different processes, the depth of the actual layer is found to be very similar to the design depth.
文摘IN the past five years the process combination of vacuum hardening, respectively vacuum carburizing with high-pressure gas quenching was successfully introduced to the market, especially in the manufacture of gears. In the meantime furnace concepts for various applications are available to the industry. In the following report three plant varieties are introduced, which differ in process flexibility and throughput. This report also explains criteria for the selection of a furnace in view of the existing application requirements. Besides this a short introduction is given into the vacuum carburizing process and the high-pressure gas quenching technology.
