Valorization of Camellia oleifera oil processing byproducts to value-added chemicals and biobased materials: A critical review

The C.oleifera oil processing industry generates large amounts of solid wastes,including C.oleifera shell(COS)and C.oleifera cake(COC).Distinct from generally acknowledged lignocellulosic biomass(corn stover,bamboo,birch,etc.),Camellia wastes contain diverse bioactive substances in addition to the abundant lignocellulosic components,and thus,the biorefinery utilization of C.oleifera processing byproducts involves complicated processing technologies.This reviewfirst summarizes various technologies for extracting and converting the main components in C.oleifera oil processing byproducts into value-added chemicals and biobased materials,as well as their potential applications.Microwave,ultrasound,and Soxhlet extractions are compared for the extraction of functional bioactive components(tannin,flavonoid,saponin,etc.),while solvothermal conversion and pyrolysis are discussed for the conversion of lignocellulosic components into value-added chemicals.The application areas of these chemicals according to their properties are introduced in detail,including utilizing antioxidant and anti-in-flammatory properties of the bioactive substances for the specific application,as well as drop-in chemicals for the substitution of unrenewable fossil fuel-derived products.In addition to chemical production,biochar fabricated from COS and its applications in thefields of adsorption,supercapacitor,soil remediation and wood composites are comprehensively reviewed and discussed.Finally,based on the compositions and structural characteristics of C.oleifera byproducts,the development of full-component valorization strategies and the expansion of the appli-cationfields are proposed.

Upcycling plastic wastes into value-added products via electrocatalysis and photoelectrocatalysis

Plastic,renowned for its versatility,durability,and cost-effectiveness,is indispensable in modern society.Nevertheless,the annual production of nearly 400 million tons of plastic,coupled with a recycling rate of only 9%,has led to a monumental environmental crisis.Plastic recycling has emerged as a vital response to this crisis,offering sustainable solutions to mitigate its environmental impact.Among these recycling efforts,plastic upcycling has garnered attention,which elevates discarded plastics into higher-value products.Here,electrocatalytic and photoelectrocatalytic treatments stand at the forefront of advanced plastic upcycling.Electrocatalytic or photoelectrocatalytic treatments involve chemical reactions that facilitate electron transfer through the electrode/electrolyte interface,driven by electrical or solar energy,respectively.These methods enable precise control of chemical reactions,harnessing potential,current density,or light to yield valuable chemical products.This review explores recent progress in plastic upcycling through electrocatalytic and photoelectrocatalytic pathways,offering promising solutions to the plastic waste crisis and advancing sustainability in the plastics industry.

Discreet investors exert greater influence on cooperation in the public goods game

This paper studies the evolutionary process of cooperative behavior in a public goods game model with heterogeneous investment strategies in square lattices.In the proposed model,players are divided into defectors,cooperators and discreet investors.Among these,defectors do not participate in investing,discreet investors make heterogeneous investments based on the investment behavior and cooperation value of their neighbors,and cooperators invest equally in each neighbor.In real life,heterogeneous investment is often accompanied by time or economic costs.The discreet investors in this paper pay a certain price to obtain their neighbors'investment behavior and cooperation value,which quantifies the time and economic costs of the heterogeneous investment process.The results of Monte Carlo simulation experiments in this study show that discreet investors can effectively resist the invasion of the defectors,form a stable cooperative group and expand the cooperative advantage in evolution.However,when discreet investors pay too high a price,they lose their strategic advantage.The results in this paper help us understand the role of heterogeneous investment in promoting and maintaining human social cooperation.

Toward inclusive list-making for trade liberalization in environmental goods to reduce carbon emissions

The Asia-Pacific Economic Cooperation(APEC)is contemplating expanding its list of environmental goods(EG)for trade liberalization to fight climate change.In support of doing so,this study proposes that a long list that retains controversies is better for carbon emission reduction than a short common list.This study examines four mechanisms of longer lists:enlarging market scales,enriching product mixes,enhancing product sophistication,and enriching trade patterns.Using China’s emerging EG trade during the 2001-2015 period as a case study,this study compares four EG lists with different EG.The results show that:(1)a longer list reduces carbon emissions from both imports and exports,making domestic regions with different advantages have better chances of improving carbon efficiencies.(2)Product sophistication reduces the emission gap between trading partners,regardless of the length of EG lists.(3)China’s EG exports contribute to carbon reduction in leading regions,while EG imports provide laggard regions with better chances of reducing carbon emissions.These findings provide three implications for future list-making:it is important to(1)seek a long and inclusive list rather than a short common list,(2)shift the focus from environmental end-use to the technological contents of products,and(3)balance the demand of laggard regions to import and the capacity of leading regions to export.

Reactive ball-milling synthesis of Co-Fe bimetallic catalyst for efficient hydrogenation of carbon dioxide to value-added hydrocarbons

Catalytic hydrogenation of CO_(2) using renewable hydrogen not only reduces greenhouse gas emissions,but also provides industrial chemicals.Herein,a Co-Fe bimetallic catalyst was developed by a facile reactive ball-milling method for highly active and selective hydrogenation of CO_(2) to value-added hydrocarbons.When reacted at 320℃,1.0 MPa and 9600 mL h^(-1) g_(cat)^(-1),the selectivity to light olefin(C_(2)^(=)-C_(4)^(=)) and C_(5)+ species achieves 57.3% and 22.3%,respectively,at a CO_(2) co nversion of 31.4%,which is superior to previous Fe-based catalysts.The CO_(2) activation can be promoted by the CoFe phase formed by reactive ball milling of the Fe-Co_(3)O_(4) mixture,and the in-situ Co_(2)C and Fe_(5)C_(2) formed during hydrogenation are beneficial for the C-C coupling reaction.The initial C-C coupling is related to the combination of CO species with the surface carbon of Fe/Co carbides,and the sustained C-C coupling is maintained by self-recovery of defective carbides.This new strategy contributes to the development of efficient catalysts for the hydrogenation of CO_(2) to value-added hydrocarbons.

Application of Dual-Energy X-Ray Image Detection of Dangerous Goods Based on YOLOv7

X-ray security equipment is currently a more commonly used dangerous goods detection tool, due to the increasing security work tasks, the use of target detection technology to assist security personnel to carry out work has become an inevitable trend. With the development of deep learning, object detection technology is becoming more and more mature, and object detection framework based on convolutional neural networks has been widely used in industrial, medical and military fields. In order to improve the efficiency of security staff, reduce the risk of dangerous goods missed detection. Based on the data collected in X-ray security equipment, this paper uses a method of inserting dangerous goods into an empty package to balance all kinds of dangerous goods data and expand the data set. The high-low energy images are combined using the high-low energy feature fusion method. Finally, the dangerous goods target detection technology based on the YOLOv7 model is used for model training. After the introduction of the above method, the detection accuracy is improved by 6% compared with the direct use of the original data set for detection, and the speed is 93FPS, which can meet the requirements of the online security system, greatly improve the work efficiency of security personnel, and eliminate the security risks caused by missed detection.

Discussion on the Supply of Child-friendly City Construction Based on the Attributes of Public Goods

Child friendliness is the need for a good life in the new era.The problems related to the construction of child-friendly cities were discussed from the perspective of the supply of public goods.Through literature research and summary,the basic concepts,construction factors,sources of supply goods,structure of the main supplies,and supply behavior of public goods supply in child-friendly cities were sorted out.Some effective suggestions were proposed,such as improving the resource conversion and integration ability of the main suppliers,establishing an effective incentive system,optimizing the structure of the main suppliers,improving multi-party collaborative efficiency,ensuring benefits for all parties,raising child-friendly awareness,innovating funding sources for projects,ensuring adequate funding supply,building urban supply system in accordance with local conditions,and ensuring the supply of public goods.

Strategy dominance mechanism of autonomous collaboration in unmanned swarm within the framework of public goods game

The key advantage of unmanned swarm operation is its autonomous cooperation. How to improve the proportion of cooperators is one of the key issues of autonomous collaboration in unmanned swarm operations. This work proposes a strategy dominance mechanism of autonomous collaboration in unmanned swarm within the framework of public goods game. It starts with the requirement analysis of autonomous collaboration in unmanned swarm;and an aspiration-driven multiplayer evolutionary game model is established based on the requirement. Then the average abundance function and strategy dominance condition of the model are constructed by theoretical derivation. Furthermore, the evolutionary mechanism of parameter adjustment in swarm cooperation is revealed via simulation,and the influences of the multiplication factor r, aspiration levelα, threshold m and other parameters on the strategy dominance conditions were simulated for both linear and threshold public goods games(PGGs) to determine the strategy dominance characteristics;Finally, deliberate proposals are suggested to provide a meaningful exploration in the actual control of unmanned swarm cooperation.

Research on Culture Goods and the Image of Mixed-blood in The Bluest Eye

The Bluest Eye is Toni Morrison’s maiden work,through which Morrison carried out independent thinking on the question of“What is beauty?”In The Bluest Eye,the image of mixed-blood is characterized as a self-satisfied beautiful girl or lady due to light skin color.However,Morrison shatters their proud aesthetic edifice through satirical techniques.Firstly,this paper starts with the analysis of Shirley Temple on the blue-and-white cup and Mary Jane on candy wrapper as culture goods,in order to reveal the aesthetic standards of the mainstream.Next,through close reading,this paper,taking the example of a high-yellow child Maureen Peal,and the graceful sugar-brown lady Geraldine,makes deep analysis on their sense of superiority and artistic characteristics,and aims to better understand Morrison’s satirical techniques and interpretation of beauty.

Globalization Under the Spells of Breakdowns in Supply Chains, Regime Change, Regime Formation, and Alliance Restructuring: How Much Is Left for Public Goods?

In a paper conceived about five years ago(“Globalization and Public Goods:Too Big to Tackle?”)roughly a dozen factors were linked to explain important causal paths from globalization to the potential output of public goods.The Russian invasion of Ukraine,the corona epidemic,and the increased hegemonic rivalry between China and the U.S.interrupted or even destroyed many of the linkages between globalization and potential public good production.About five important detrimental paths involved in the meantime.In the present article we aim at linking what is left from the previous level of globalization or emerging to form a new and simplified causal model for likely linkages between truncated or(re-)emerging globalization,and the deadly needed output of public goods.These linkages refer to rules of climate control,go to trade linkages and arbitrary tariffs and trade interventions.Regime change,regime formation,and alliance restructuring address aspects of domestic rule and international stability.Selectorate theory,regime type,and exit options for political elites provide key explanatory factors in explaining globalization and public goods productions,or their decay.Where possible we use some data and transformation experiences corroborating our arguments.In other instances need for further empirical macro research will become clear.

Application of the Industry-University-Research Education Model of“Works,Products,and Public Goods”in Design Majors Practical Courses in Colleges and Universities

One of the goals and requirements of China’s educational modernization includes prioritizing,guiding,and promoting the social service capabilities of universities.The teaching of practical courses in design majors in colleges and universities has long been plagued by problems such as being“out of touch with the market and social needs”and“ignoring the cultivation of creativity.”It fails to meet the goals and requirements of educational modernization.This article takes the“Fundamentals of Styling and Comprehensive Expression”course offered by the School of Design of Guangxi Normal University as an entry point to study the industry-university-research education method that combines“social service”with the teaching of design professional practical courses.It also attempts to improve“works,products,and public goods”through the establishment of the theoretical model of“product”and the analysis of practical application paths is carried out to solve the problems existing in the traditional teaching of the design major,enhance the social service capabilities of the design major,promote talent employment and industry and social development,and carry out teaching reform attempts.

Punishment in optional public goods games

In this work, the optional public goods games with punishment are studied. By adopting the approximate best response dynamics, a micro model is given to explain the evolutionary process. Simultaneously, the magnitude of rationality is also considered. Under the condition of bounded rationality which provides a light to interpret phenomena in human society, the model leads to two types of equilibriums. One is the equilibrium without punishers and the other is the equilibrium including only punishers and cooperators. In addition, the effects of rationality on equilibriums are briefly investigated.

Artificial photosynthesis for high-value-added chemicals:Old material,new opportunity

Solar energy utilization has drawn attention due to ever-increasing environmental and energy issues.Photoelectrochemical(PEC)and photocatalytic(PC)water splitting for hydrogen production,which is the most popular and well-established solar-to-chemical conversion process,has been studied thoroughly to date but is now facing limitations related to low conversion efficiency.To resolve this issue,research in PEC cells or photocatalysts has recently aimed to produce alternative value-added chemicals by modifying their redox reactions,which potentially enables high economic reward to compensate for the low efficiency.Here,various kinds of redox reactions that decouple classic water splitting reactions to produce value-added chemicals via PEC and PC processes are introduced.Successful coupling of CO_(2) reduction,O_(2) reduction and organic synthesis with either water oxidation or water reduction is comprehensively discussed from the perspective of basic fundamental and product selectivity in terms of the band structure of materials,cocatalyst design,and thermodynamics and kinetics of the reactions.Throughout the review,future challenges and opportunities are suggested with respect to the redesigned artificial synthesis,which might be an alternative development for the commercialization of PEC or PC value-added chemical production technologies in the near future.

Stochastic evolutionary public goods game with first and second order costly punishments in finite populations

We study the stochastic evolutionary public goods game with punishment in a finite size population. Two kinds of costly punishments are considered, i.e., first-order punishment in which only the defectors are punished, and second-order punishment in which both the defectors and the cooperators who do not punish the defective behaviors are punished. We focus on the stochastic stable equilibrium of the system. In the population, the evolutionary process of strategies is described as a finite state Markov process. The evolutionary equilibrium of the system and its stochastic stability are analyzed by the limit distribution of the Markov process. By numerical experiments, our findings are as follows.（i） The first-order costly punishment can change the evolutionary dynamics and equilibrium of the public goods game, and it can promote cooperation only when both the intensity of punishment and the return on investment parameters are large enough.（ii）Under the first-order punishment, the further imposition of the second-order punishment cannot change the evolutionary dynamics of the system dramatically, but can only change the probability of the system to select the equilibrium points in the ＂C＋P＂ states, which refer to the co-existence states of cooperation and punishment. The second-order punishment has limited roles in promoting cooperation, except for some critical combinations of parameters.（iii） When the system chooses＂C＋P＂ states with probability one, the increase of the punishment probability under second-order punishment will further increase the proportion of the ＂P＂ strategy in the ＂C＋P＂ states.

Food processing wastewater purification by microalgae cultivation associated with high value-added compounds production——A review

Microalgae have been considered as an efficient microorganism for wastewater treatment with simultaneously bioenergy and high value-added compounds production.However,the high energy cost associated with complicated biorefinery(e.g.microalgae cultivation,harvesting,drying,extraction,conversion,and purification)is a critical challenge that inhibits its large-scale application.Among different nutrition(e.g.carbon,nitrogen and phosphorous)sources,food processing wastewater is a relative safe and suitable one for microalgae cultivation due to its high organic content and low toxicity.In this review,the characteristic of different food wastewater is summarized and compared.The potential routes of value-added products(i.e.biofuel,pigment,polysaccharide,and amino acid)production along with wastewater purification are introduced.The existing challenges(e.g.biorefinery cost,efficiency and mechanism)of microalgal-based wastewater treatment are also discussed.The prospective of microalgae-based food processing wastewater treatment strategies(such as microalgae-bacteria consortium,poly-generation of bioenergy and value-added products)is forecasted.It can be observed that food wastewater treatment by microalgae could be a promising strategy to commercially realize waste source reduce,conversion and reutilization.

The Supply-Demand Analysis and Mechanism Innovation of Chinese Rural Public Goods

The connotation of rural public goods is expounded.The rural public goods refer to the products and labors that satisfy the production and living of rural residents,economic growth and social progress.The rural public goods is characterized by non-excludability,non-competitiveness and indispensability of other general public goods.The supply situation of Chinese government to rural public goods is analyzed,as well as the demand situation of rural public goods,which includes farmers' demand on training,the assistance demand of rural weak groups,farmers' demand on comfortable living conditions and farmers' demand on "soft" public goods.The paths for innovating the supply mechanism of rural public goods are put forward,which cover perfecting the decision mechanism of public goods supply;scientifically distributing the supply responsibility of rural public goods;facilitating the reform of each supporting equipment and exploring the multiple capital collecting channels of rural public goods.

The Theoretical Foundation and its Mode Transformation of Rural Public Goods Supply in the Perspective of Organizational Competition

Theoretical expositions of public goods supply by the liberalism,new institutionalism and the school of public choice are conducted in the perspective of organizational competition.And the theoretical foundation of rural public goods is put forward.Then,the changes of the supply mode of rural public goods are discussed before and after the tax reform,that is,the "Community Cooperation" supply mode of rural public goods before the tax reform and the "Organization Cooperation" supply mode of rural public goods after the tax reform.Finally,the diversification of rural public goods supply in China in future is forecasted.

Influence of Pt/Ru anodic ratio on the valorization of ethanol by PEM electrocatalytic reforming towards value-added products

The ethanol electro-reforming process was studied over PtRu/C catalysts synthesized by the modified polyol method with different compositions.In particular,this work reports the influence of anodic Pt:Ru ratio(5:1,2:1 and 1:2)on the organic product distribution(acetaldehyde,acetic acid and ethyl acetate)and pure hydrogen generation at different current densities operation levels.Physicochemical characterization of the catalysts was made by X-ray diffraction(XRD),temperature-programmed reduction(TPR)and N_(2) adsorption-desorption measurements.XRD patterns showed that Ru is introduced into the Pt structure,forming an alloy between both metals.Also,the degree of alloy was higher by increasing the Ru amounts.From TPR profiles Pt was found to be properly reduced while Ru was both in metallic state and forming RuO2.The electrochemical behaviour of each catalyst towards ethanol electroreforming process was investigated through electrochemical techniques in a half cell and a single proton exchange membrane(PEM)cell systems.An intermediate Pt:Ru ratio was found to result in high current density and electrochemical surface area(ECSA)values along with lower amounts of adsorbed species.Also,Ru addition seems to diminish the degree of degradation of the catalyst.Based on characterization and in agreement with essays carried out in a PEM cell at mild conditions(80℃ and 1 atm),PtRu/C 2:1 anode provided the best electrocatalytic results in terms of current density(740 mA cm^(-2)),hydrogen production and selectivity toward acetic acid(up to 15%apart from acetaldehyde and ethyl acetate)while requiring the lowest energy consumption.

Factors Analysis of Affecting Loading and Reinforcing Scheme of Large Goods in Railway

Large goods transported in railway are kinds of special goods and they are very important in national construction. In order to transport safely, loading and reinforcing schemes must be made first. How to design a reasonable scheme will be affected by many factors. This paper presents the characteristic of the large goods, summarizes the process of designing a loading and reinforcing scheme of large good, then probes the factors of affecting the loading and reinforcing scheme and gives a detail analysis. It’s considered that those out-of-gauge and overweight degree of goods, center-of- gravity height of a loaded wagon, position of center-of-gravity of goods, type of wagon for using, reinforcement material and reinforcement method, transport expense and transport organization could affect a scheme in the aspects of safety, economy, rapidity and convenience. This conclusion will instruct and help to make a good scheme.