Valorization of Camellia oleifera oil processing byproducts to value-added chemicals and biobased materials: A critical review

The C.oleifera oil processing industry generates large amounts of solid wastes,including C.oleifera shell(COS)and C.oleifera cake(COC).Distinct from generally acknowledged lignocellulosic biomass(corn stover,bamboo,birch,etc.),Camellia wastes contain diverse bioactive substances in addition to the abundant lignocellulosic components,and thus,the biorefinery utilization of C.oleifera processing byproducts involves complicated processing technologies.This reviewfirst summarizes various technologies for extracting and converting the main components in C.oleifera oil processing byproducts into value-added chemicals and biobased materials,as well as their potential applications.Microwave,ultrasound,and Soxhlet extractions are compared for the extraction of functional bioactive components(tannin,flavonoid,saponin,etc.),while solvothermal conversion and pyrolysis are discussed for the conversion of lignocellulosic components into value-added chemicals.The application areas of these chemicals according to their properties are introduced in detail,including utilizing antioxidant and anti-in-flammatory properties of the bioactive substances for the specific application,as well as drop-in chemicals for the substitution of unrenewable fossil fuel-derived products.In addition to chemical production,biochar fabricated from COS and its applications in thefields of adsorption,supercapacitor,soil remediation and wood composites are comprehensively reviewed and discussed.Finally,based on the compositions and structural characteristics of C.oleifera byproducts,the development of full-component valorization strategies and the expansion of the appli-cationfields are proposed.

Upcycling plastic wastes into value-added products via electrocatalysis and photoelectrocatalysis

Plastic,renowned for its versatility,durability,and cost-effectiveness,is indispensable in modern society.Nevertheless,the annual production of nearly 400 million tons of plastic,coupled with a recycling rate of only 9%,has led to a monumental environmental crisis.Plastic recycling has emerged as a vital response to this crisis,offering sustainable solutions to mitigate its environmental impact.Among these recycling efforts,plastic upcycling has garnered attention,which elevates discarded plastics into higher-value products.Here,electrocatalytic and photoelectrocatalytic treatments stand at the forefront of advanced plastic upcycling.Electrocatalytic or photoelectrocatalytic treatments involve chemical reactions that facilitate electron transfer through the electrode/electrolyte interface,driven by electrical or solar energy,respectively.These methods enable precise control of chemical reactions,harnessing potential,current density,or light to yield valuable chemical products.This review explores recent progress in plastic upcycling through electrocatalytic and photoelectrocatalytic pathways,offering promising solutions to the plastic waste crisis and advancing sustainability in the plastics industry.

Coordination of Multi-leaders and Multi-followers in Supply Chain of Value-Added Telecom Services

In order to study supply chain of the telecom value-added service,a multi-leaders and multi-followers Stackelberg game model with multiple telecom operators and multiple service providers whose income is composed of information fee division and advertisement was constructed.Then a demonstration was simulated,and the results were compared with the situation of service providers' income only from information fee division.The simulated and compared results indicate that,the enterprises in the supply chain have the nature of pursuing the maximum profits in capital markets;meanwhile,first-mover advantages and some enterprise can get more profits with the information asymmetry.

Impact analysis of supplier relationship on supply chain resilience using biological cellular resilience theory

A supply chain resilience model is established based on the biological cellular resilience theory to analyze the impact of the supplier relationship on supply chain resilience. A scenario where the market demand is changed suddenly by some undesired events is considered. The results reveal that enhancing collaboration with a more resilient supplier can significantly improve supply chain resilience and reduce supply chain losses. It is also found that enhancing the supplier relationship can significantly benefit supply chain resilience if the collaborative intensity is relatively low, and it has less effect if supply chain members have already collaborated closely. Thus, enhancing the supplier relationship to a limited intensity is a relatively effective and economic method to strengthen supply chain resilience.

Artificial photosynthesis for high-value-added chemicals:Old material,new opportunity

Solar energy utilization has drawn attention due to ever-increasing environmental and energy issues.Photoelectrochemical(PEC)and photocatalytic(PC)water splitting for hydrogen production,which is the most popular and well-established solar-to-chemical conversion process,has been studied thoroughly to date but is now facing limitations related to low conversion efficiency.To resolve this issue,research in PEC cells or photocatalysts has recently aimed to produce alternative value-added chemicals by modifying their redox reactions,which potentially enables high economic reward to compensate for the low efficiency.Here,various kinds of redox reactions that decouple classic water splitting reactions to produce value-added chemicals via PEC and PC processes are introduced.Successful coupling of CO_(2) reduction,O_(2) reduction and organic synthesis with either water oxidation or water reduction is comprehensively discussed from the perspective of basic fundamental and product selectivity in terms of the band structure of materials,cocatalyst design,and thermodynamics and kinetics of the reactions.Throughout the review,future challenges and opportunities are suggested with respect to the redesigned artificial synthesis,which might be an alternative development for the commercialization of PEC or PC value-added chemical production technologies in the near future.

Food processing wastewater purification by microalgae cultivation associated with high value-added compounds production——A review

Microalgae have been considered as an efficient microorganism for wastewater treatment with simultaneously bioenergy and high value-added compounds production.However,the high energy cost associated with complicated biorefinery(e.g.microalgae cultivation,harvesting,drying,extraction,conversion,and purification)is a critical challenge that inhibits its large-scale application.Among different nutrition(e.g.carbon,nitrogen and phosphorous)sources,food processing wastewater is a relative safe and suitable one for microalgae cultivation due to its high organic content and low toxicity.In this review,the characteristic of different food wastewater is summarized and compared.The potential routes of value-added products(i.e.biofuel,pigment,polysaccharide,and amino acid)production along with wastewater purification are introduced.The existing challenges(e.g.biorefinery cost,efficiency and mechanism)of microalgal-based wastewater treatment are also discussed.The prospective of microalgae-based food processing wastewater treatment strategies(such as microalgae-bacteria consortium,poly-generation of bioenergy and value-added products)is forecasted.It can be observed that food wastewater treatment by microalgae could be a promising strategy to commercially realize waste source reduce,conversion and reutilization.

Influence of Pt/Ru anodic ratio on the valorization of ethanol by PEM electrocatalytic reforming towards value-added products

The ethanol electro-reforming process was studied over PtRu/C catalysts synthesized by the modified polyol method with different compositions.In particular,this work reports the influence of anodic Pt:Ru ratio(5:1,2:1 and 1:2)on the organic product distribution(acetaldehyde,acetic acid and ethyl acetate)and pure hydrogen generation at different current densities operation levels.Physicochemical characterization of the catalysts was made by X-ray diffraction(XRD),temperature-programmed reduction(TPR)and N_(2) adsorption-desorption measurements.XRD patterns showed that Ru is introduced into the Pt structure,forming an alloy between both metals.Also,the degree of alloy was higher by increasing the Ru amounts.From TPR profiles Pt was found to be properly reduced while Ru was both in metallic state and forming RuO2.The electrochemical behaviour of each catalyst towards ethanol electroreforming process was investigated through electrochemical techniques in a half cell and a single proton exchange membrane(PEM)cell systems.An intermediate Pt:Ru ratio was found to result in high current density and electrochemical surface area(ECSA)values along with lower amounts of adsorbed species.Also,Ru addition seems to diminish the degree of degradation of the catalyst.Based on characterization and in agreement with essays carried out in a PEM cell at mild conditions(80℃ and 1 atm),PtRu/C 2:1 anode provided the best electrocatalytic results in terms of current density(740 mA cm^(-2)),hydrogen production and selectivity toward acetic acid(up to 15%apart from acetaldehyde and ethyl acetate)while requiring the lowest energy consumption.

RESEARCH ON VALUE OF INFORMATION SHARING IN ONE SUPPLIER-MULTIPLE RETAILER SUPPLY CHAIN

Prior research has generally focused on models involving a single or multiple retailers with independent demands. The value of demand information sharing is analyzed in a two-level supply chain involving one supplier-multiple retailer model in which retailer demands may be correlated. Each member in the supply chain forecasts its demand using an AR (1) demand process. Two conditions of the information sharing are considered (1) Without the information sharing, the retailers only communicate their orders to the supplier. (2) With the information sharing, retailers communicate their orders and forecasting models to the supplier. Analyses showthat the reductions of supplier's average inventory and average costs are substantial with the information sharing. However, the retailers donot get direct benefit from the information sharing. The retailers may ask the supplier to reduce the replenishment leadtime, so that the retailers will obtain substantial cost savings and inventory reduction. Both partners may obtain benefits when information sharing and leadtime reduction are implemented together.

Supplier Selection Fuzzy Model in Supply Chain Management:Vietnamese Cafe Industry Case

Supplier selection is a vital part of the supply chain and is also a current issue that concerns businesses today as supplier quality directly affects the operations of the organization.Choosing the right supplier can help businesses increase productivity,competitiveness in the market,and profits without having to lower the quality of the products.However,choosing a supplier is not a simple matter,it requires businesses to consider many aspects about their suppliers.Therefore,the goal of this study is to propose an integrated model consisting of two models:Fuzzy Analytics Network Process(Fuzzy-ANP)model and Weighted Aggregated Sum Product Assessment(WASPAS)to solve the problem above.The Fuzzy-ANP model was developed to evaluate the weightings of the supplier selection criteria,and the WASPAS Model was used to rank the suppliers.An example of supplier selection in the coffee industry in Vietnam was studied to validate the model,namely 5 main criteria,with 16 sub-criteria,and 7 suppliers.The model test results show that the Fuzzy ANP and WASPAS integration model was suitable.In future,these developing models can apply to other industries or integrate with other models.

Pareto Optimal Solution for Supply Contracts with Multiple Suppliers

This paper analyzes an electronic procurement （e-procurement） process between a manufacturer and N-supplier in the e-market. We proof that using the general contract based on auction theory, i. e. the wholesale price contract, would not achieve the coordination of channel composed of the manufacturer and the winning supplier. The paper designs a contract mechanism, i.e. the side payment price-restricted contract based on auction theory, which not only ensures Pareto optimal solutions for both, but also coordinates the supply chain. A numerical experiment is provided to compare the performance of different auction mechanisms and to reinforce key managerial insights generated through analysis.

Brief analysis on value-added tax transformation and its influence on enterprises

From Jan. 1st, 2009, the value-added tax transformation will be performed in all industries around the country. Based on value-added tax types and retrospection of reform practices, this article analyzes the background of the national value-added tax transformation and points out the influence of full implementation of the value-added tax transformation on various enterprises.

Evolution trends and structural decomposition of China's green value-added over 40 years of reform and opening-up

China's 40-year history of reform and opening-up includes rapid economic development as well as pollution and environmental governance.Using a four-stage division,this study explores the evolution trend and structural decomposition of China's green value-added by constructing a non-competitive input-output table for environmental pollution from 1978 to 2017.The results indicate that pollution production coefficients increased continuously,and the green value-added index decreased.Additionally,the structural decomposition showed that investment and export were critical for economic growth during the period,though they were accompanied by serious pollution problems.The pollution generated by the raw material(represented by coal mining)and processing industries(represented by the textiles)were not controlled effectively.Pollution treatment for these industries should be strengthened in the future.The study has implications for government officials,policy makers,and academics.First,China should make green development a core concept for economic development,increase environmental pollution governance,develop a“green GDP,”incorporate the external costs of environmental pollution into the national economic accounting system.Second,it must change the investment and export structure as well as the traditional economic development pattern that exacerbates pollution.Specifically,the country should develop industries with low pollution and promote the export of industries producing high value-added products and increase green GDP per capita.Third,it should closely monitor the development of highly polluting industries.Upgrading technology to reduce pollution and strengthening pollution treatment will reduce the number of polluting industries and improve environmental governance efficiency.

Seismic performance evaluation of water supply pipes installed in a full-scale RC frame structure based on a shaking table test

As an important part of nonstructural components,the seismic response of indoor water supply pipes deserves much attention.This paper presents shaking table test research on water supply pipes installed in a full-scale reinforced concrete(RC)frame structure.Different material pipes and different methods for penetrating the reinforced concrete floors are combined to evaluate the difference in seismic performance.Floor response spectra and pipe acceleration amplification factors based on test data are discussed and compared with code provisions.A seismic fragility study of displacement demand is conducted based on numerical simulation.The acceleration response and displacement response of different combinations are compared.The results show that the combination of different pipe materials and different passing-through methods can cause obvious differences in the seismic response of indoor riser pipes.

Measuring the influences of supplier selection and supply chain tasks on firm performance among manufacturing firms in India

The primary objective of this research is to empirically probe the various aspects and variables that have been already addressed in the previous literature related to supplier selection criterion, supply effort management and firm performance. Further, this research aims to develop a measurement framework and pragmatically prove the framework through a measurement model. First, a factor structure for various constructs is made and the initial validity is determined from practicing managers and academicians. This research employs survey method and the data is collected from 358 supply chain professionals working in manufacturing firms in India. A measurement model is developed and proved with various tests of reliability and validity. Finally, three major latent constructs were formulated, namely, criterion of supplier selection, supply effort management and firm performance. The factor scores of these latent variables were used for further analysis. A six-stage approach was followed in the analysis of data. Firm performance was regressed against supplier selection criterion and supply effort management. The results indicate that the predictive variable has positive and significant effect on firm performance and they do not have any interaction and multicollinearity effects.

Reactive ball-milling synthesis of Co-Fe bimetallic catalyst for efficient hydrogenation of carbon dioxide to value-added hydrocarbons

Catalytic hydrogenation of CO_(2) using renewable hydrogen not only reduces greenhouse gas emissions,but also provides industrial chemicals.Herein,a Co-Fe bimetallic catalyst was developed by a facile reactive ball-milling method for highly active and selective hydrogenation of CO_(2) to value-added hydrocarbons.When reacted at 320℃,1.0 MPa and 9600 mL h^(-1) g_(cat)^(-1),the selectivity to light olefin(C_(2)^(=)-C_(4)^(=)) and C_(5)+ species achieves 57.3% and 22.3%,respectively,at a CO_(2) co nversion of 31.4%,which is superior to previous Fe-based catalysts.The CO_(2) activation can be promoted by the CoFe phase formed by reactive ball milling of the Fe-Co_(3)O_(4) mixture,and the in-situ Co_(2)C and Fe_(5)C_(2) formed during hydrogenation are beneficial for the C-C coupling reaction.The initial C-C coupling is related to the combination of CO species with the surface carbon of Fe/Co carbides,and the sustained C-C coupling is maintained by self-recovery of defective carbides.This new strategy contributes to the development of efficient catalysts for the hydrogenation of CO_(2) to value-added hydrocarbons.

PoC: An IMS-based Wireless Value-added Service

This article introduces the Push-to-talk over Cellular( PoC) service, a new mobile value-added service based on the IP Multimedia Subsystem (IMS). Its implementation scheme is discussed and its Session Initiation Protocol (SIP) signaling exchange flow is described. Target user groups are predicted based on the analysis of the strengths and weaknesses of the PoC service. The article purports that the PoC system could undoubtedly be used as a platform for new services such as multimedia messaging, instant messaging, presence, and picture receiving and sending. Just like the short message service, the PoC service will help the terminal vendors, equipment vendors, content providers and operators setup a win-for-all industrial value chain.

Optimization Agricultural Supply Chain:A Case Study of Fertilizer Supplier Selection

The 21st century is associated with the IndustrialRevolution 4.0 and the organic agriculture trend,making the utilization of high-quality fertilizers,abundant nutritional content,economical,and no affect to environment pollution.According to the new concept,clean agricultural production and organic agricultural products are not allowed to excessively use synthetic chemicals such as chemical fertilizers,and plant protection drugs,but priority is to use manure,organic fertilizers,and natural mineral fertilizers.Fertilizer must meet the balanced nutritional requirements of crops,maintain,and improve the fertility of the ground,protect the surrounding ecosystem,and leave harmful effects in agricultural products,products with high quality,safe for users and high economic efficiency for producers.To achieve the above goal,the selection of a fertilizer supplier is an important decision,supporting the supply chain’s sustainable development,fertilizer supplier selection is a multicriteria decision making model,the decision maker must assess all qualitative and quantitative factors.In this paper,the author proposed an integer decision making model including Fuzzy Analytic Hierarchy Process(FAHP)and Complex Proportional Assessment of Alternatives(COPRAS)for fertilizer supplier selection.The weightings of the criteria are calculated by using FAHP,COPRAS is then applied for ranking some potential fertilizer suppliers.The efficiency of the proposed models is proved by a case study conducted in a farm located in the south of Vietnam.This research is the first fertilizer supplier evaluation and se-lection model in Vietnam by interviewing experts and reviewing the literature.Re-search result is to provide a case study on evaluating supplier in agricultural supply chain utilizing the model proposed by the combination of FAHP and COPRAS models.

Export Value-Added of China’s Manufacturing Sector:Estimation and Mechanism Analysis

Estimation of domestic and overseas value-added of manufacturing sector is an important and difficult subject for the science-based evaluation of a country＇s trade interests under global value chain. Traditional HIY approach overestimates the domestic value- added of export. Although Koopman＇s method made certain improvements, it cannot utilize traditional I/O matrix and direct input coefficient matrix under the condition of incomplete information. By creating GAMS model, this paper addresses the above-mentioned problems and employs an improved model for the estimation of variations in domestic and overseas value-added of Chinese exports between 2002 and 2012. Our results indicate that by neglecting the export of processing trade, HIY approach overestimates the domestic value- added ratio of Chinese exports. As more imported intermediate inputs have been used in the export of processing trade, the estimation result of this paper have corrected deviations in the forecast of overseas value-added ratio and its tendencies based on HIY method Further analysis of specific factors of domestic value-added of export led to the discovery that the domestic value-added of export of processing trade and mixed trade is highly vulnerable to the impact of international capital inflow. It can be seen that the improved method for the estimation of value-added has indeed corrected the deviations in the estimation of China＇s value-added. In conclusion, China should accelerate the development of export of non- processing trade and trade in high-end services, and balance the relationship of export between local firms and foreign-funded firms, with a view to improving trade dependence and increasing the trade status of Chinese manufaeturing firms in global value chain.

Analysis of faulting destruction and water supply pipeline damage from the first mainshock of the February 6,2023 Türkiye earthquake doublet

In 2023,two consecutive earthquakes exceeding a magnitude of 7 occurred in Türkiye,causing severe casualties and economic losses.The damage to critical urban infrastructure and building structures,including highways,railroads,and water supply pipelines,was particularly severe in areas where these structures intersected the seismogenic fault.Critical infrastructure projects that traverse active faults are susceptible to the influence of fault movement,pulse velocity,and ground motions.In this study,we used a unique approach to analyze the acceleration records obtained from the seismic station array(9 strong ground motion stations)located along the East Anatolian Fault(the seismogenic fault of the MW7.8 mainshock of the 2023 Türkiye earthquake doublet).The acceleration records were filtered and integrated to obtain the velocity and displacement time histories.We used the results of an on-site investigation,jointly conducted by China Earthquake Administration and Türkiye’s AFAD,to analyze the distribution of PGA,PGV,and PGD recorded by the strong motion array of the East Anatolian Fault.We found that the maximum horizontal PGA in this earthquake was 3.0 g,and the maximum co-seismic surface displacement caused by the East Anatolian Fault rupture was 6.50 m.As the fault rupture propagated southwest,the velocity pulse caused by the directional effect of the rupture increased gradually,with the maximum PGA reaching 162.3 cm/s.We also discussed the seismic safety of critical infrastructure projects traversing active faults,using two case studies of water supply pipelines in Türkiye that were damaged by earthquakes.We used a three-dimensional finite element model of the PE(polyethylene)water pipeline at the Islahiye State Hospital and fault displacement observations obtained through on-site investigation to analyze pipeline failure mechanisms.We further investigated the effect of the fault-crossing angle on seismic safety of a pipeline,based on our analysis and the failure performance of the large-diameter Thames Water pipeline during the 1999 Kocaeli earthquake.The seismic method of buried pipelines crossing the fault was summarized.

International Competitiveness of China’s Manufacturing Sectors:Estimation Based on Trade in Value-added

Based on trade in value-added, this paper has estimated the revealed comparative advantage （RCA） of China＇s various manufacturing sectors between 1995 and 2011 and compared with the RCA indexes measured using conventional aggregate accounting approach. Results indicate that： （1） the RCA index measured using conventional aggregate accounting approach has underestimated China＇s comparative advantage of labor-intensive sectors but overestimated China＇s comparative advantage in capital, knowledge and technology-intensive manufacturing sectors, giving rise to a serious misjudgment. （2） The RCA measured using value-added approach shows that in the industry chain layout of global manufacturing sectors, China＇s comparative advantage is still concentrated in labor-intensive manufacturing sectors but has signs of weakening; in capital, knowledge and technology-intensive sectors, China is yet to develop any significant comparative advantage; there are signs that China is developing comparative advantage in capital-intensive sectors yet China＇s comparative disadvantage in knowledge and technology-intensive sectors has no significant tendency to improve. This result not only helps correct the misjudgment of China＇s competitiveness in manufacturing sectors based on conventional aggregate accounting approach but offers important policy implications for setting strategic directions and policies for China＇s manufacturing transition and upgrade.