The vanadium species were contaminated on FCC catalysts by using the Mitchell method. After the hydrothermal deactivation of the FCC catalysts, the cracking reaction was performed on these catalyst samples. The test r...The vanadium species were contaminated on FCC catalysts by using the Mitchell method. After the hydrothermal deactivation of the FCC catalysts, the cracking reaction was performed on these catalyst samples. The test results revealed that the conversion of feedstock and the gasoline yield obtained over the FCC catalysts with vanadium trapping components were obviously higher than those without addition of vanadium trapping components. The results also showed that the dry gas and coke selectivity on the FCC catalysts containing vanadium trapping components was improved. The X-Ray diffraction results proved that the zeolite crystal structure was well protected by the vanadium trapping components during its hydrothermal deactivation step. The results of SEM-EDX mapping disclosed that the vanadium was enriched on the vanadium trapping components which verified the positive function of vanadium trapping components.展开更多
基金supported by the National Basic Research Development Program "973" Project of China(2010CB732301)the SINOPEC Research and Development Program(No.112034)
文摘The vanadium species were contaminated on FCC catalysts by using the Mitchell method. After the hydrothermal deactivation of the FCC catalysts, the cracking reaction was performed on these catalyst samples. The test results revealed that the conversion of feedstock and the gasoline yield obtained over the FCC catalysts with vanadium trapping components were obviously higher than those without addition of vanadium trapping components. The results also showed that the dry gas and coke selectivity on the FCC catalysts containing vanadium trapping components was improved. The X-Ray diffraction results proved that the zeolite crystal structure was well protected by the vanadium trapping components during its hydrothermal deactivation step. The results of SEM-EDX mapping disclosed that the vanadium was enriched on the vanadium trapping components which verified the positive function of vanadium trapping components.
