The effect and mechanism of ultrasound and CaF_(2) on vanadium leaching from vanadium-bearing shale were investigated systematically.In consideration of the enhancement for vanadium recovery,the combination of ultraso...The effect and mechanism of ultrasound and CaF_(2) on vanadium leaching from vanadium-bearing shale were investigated systematically.In consideration of the enhancement for vanadium recovery,the combination of ultrasound and CaF_(2)(66.28%) exerts more evident effects than ultrasound(26.97%) and CaF_(2)(60.35%) alone,demonstrating the synergetic effect of ultrasound and CaF_(2).Kinetic analysis manifests that the product layer diffusion controls vanadium leaching in ultrasound system without CaF_(2),however product layer diffusion and interfacial reaction is the rate-controlling step for vanadium leaching in other three leaching systems.The combination of ultrasound and CaF_(2) notably decreases the activation energy(E_(a)) from 62.03 to 27.61 kJ/mol,nevertheless individual CaF_(2) only reduces the E_(a) to 50.70 kj/mol.X-ray diffraction and fourier transform infrared spectrometer analyses show that the decomposition degree of the vanadium-bearing mica structure is the most significant in ultrasound and CaF_(2) system,proving the highest release degree of vanadium.Specific surface area and pore distribution combined with scanning electron microscope analyses reveal that the action of ultrasound and CaF_(2) would provide higher specific surface area,more abundant pores structure and cracks for the particles,which further prompts the rapid diffusion of H^(+),F^(-)and HF,and achieves the conspicuous improvement of vanadium leaching recovery.展开更多
Carbonaceous shale is a sedimentary rock containing a large amount of dispersed carbonaceous organic material.It is easy to crack and soften when exposed to water.In the present work,the stability of such a rock and i...Carbonaceous shale is a sedimentary rock containing a large amount of dispersed carbonaceous organic material.It is easy to crack and soften when exposed to water.In the present work,the stability of such a rock and its sensitivity to the formation of infiltrations due to rainfall are analyzed numerically using the GeoStudio software.The slope stability coefficient is calculated and verified using the landslide thrust calculation method.The results show that under the action of heavy rainfall,water infiltrates into the slope layer by layer,and,accordingly,the soil volume water content is different with respect to that typical of a homogeneous soil.It is also shown that,although in an initial stage,rainfall infiltration leads to the decline of the slope stability coefficient,with the progress of rainfall,this coefficient can temporarily increase,that is,these phenomena can display a lag phase.展开更多
基金supported by the National Natural Science Foundation of China (51874222 and 52074204)the Fundamental Research Funds for the Central Universities (No. 2020-YB029)。
文摘The effect and mechanism of ultrasound and CaF_(2) on vanadium leaching from vanadium-bearing shale were investigated systematically.In consideration of the enhancement for vanadium recovery,the combination of ultrasound and CaF_(2)(66.28%) exerts more evident effects than ultrasound(26.97%) and CaF_(2)(60.35%) alone,demonstrating the synergetic effect of ultrasound and CaF_(2).Kinetic analysis manifests that the product layer diffusion controls vanadium leaching in ultrasound system without CaF_(2),however product layer diffusion and interfacial reaction is the rate-controlling step for vanadium leaching in other three leaching systems.The combination of ultrasound and CaF_(2) notably decreases the activation energy(E_(a)) from 62.03 to 27.61 kJ/mol,nevertheless individual CaF_(2) only reduces the E_(a) to 50.70 kj/mol.X-ray diffraction and fourier transform infrared spectrometer analyses show that the decomposition degree of the vanadium-bearing mica structure is the most significant in ultrasound and CaF_(2) system,proving the highest release degree of vanadium.Specific surface area and pore distribution combined with scanning electron microscope analyses reveal that the action of ultrasound and CaF_(2) would provide higher specific surface area,more abundant pores structure and cracks for the particles,which further prompts the rapid diffusion of H^(+),F^(-)and HF,and achieves the conspicuous improvement of vanadium leaching recovery.
基金This study was supported by the“Reinforcement Theory and Technology of Multipoint Restraint Anchor Cable and Monitoring Warning for Highway High Slope”(Grant:2020-MS3-082)the“Research and Application of Ecological Slope Protection Technology in Carbonaceous Rock Slopes”(Grant:AD19110124).
文摘Carbonaceous shale is a sedimentary rock containing a large amount of dispersed carbonaceous organic material.It is easy to crack and soften when exposed to water.In the present work,the stability of such a rock and its sensitivity to the formation of infiltrations due to rainfall are analyzed numerically using the GeoStudio software.The slope stability coefficient is calculated and verified using the landslide thrust calculation method.The results show that under the action of heavy rainfall,water infiltrates into the slope layer by layer,and,accordingly,the soil volume water content is different with respect to that typical of a homogeneous soil.It is also shown that,although in an initial stage,rainfall infiltration leads to the decline of the slope stability coefficient,with the progress of rainfall,this coefficient can temporarily increase,that is,these phenomena can display a lag phase.
