The oxidation process of low-grade vanadium slag in the presence of Na2CO3 was investigated by XRD,SEM/EDS and TG-DSC techniques.The results show that the vanadium slag is oxidized in a temperature range from 273 to 7...The oxidation process of low-grade vanadium slag in the presence of Na2CO3 was investigated by XRD,SEM/EDS and TG-DSC techniques.The results show that the vanadium slag is oxidized in a temperature range from 273 to 700 °C.Olivine phases and spinel phases are completely decomposed at 500 and 600 °C,respectively.Most of water-soluble sodium vanadates are formed between 500 and 600 °C.When roasting temperature reaches above 700 °C,the vanadium-rich phases of sodium vanadates can be obviously observed.However,at temperature above 800 °C,the samples are sintered.Most of the vanadium is enwrapped by glassy phase compounds which lead to the decrease of the leaching rate of vanadium.At the same time,the effect of roasting temperature on extraction of vanadium and characterization of leach residues were discussed.展开更多
采用扫描电镜、透射电镜、金相显微镜、闪光焊接及力学性能测试,对国内某厂采用富氮钒微合金化生产的Φ40 mm HRB500抗震钢筋微合金析出强化效果、力学性能、金相显微组织、夹杂物、焊接及时效性进行了试验研究。结果表明：采用增氮降...采用扫描电镜、透射电镜、金相显微镜、闪光焊接及力学性能测试,对国内某厂采用富氮钒微合金化生产的Φ40 mm HRB500抗震钢筋微合金析出强化效果、力学性能、金相显微组织、夹杂物、焊接及时效性进行了试验研究。结果表明：采用增氮降钒工艺增加了细小弥散的钒析出相数量,析出相尺寸为10~30 nm,其中V（CN）析出物占总w（V）的79.35%,析出强化效果显著;钢中夹杂物尺寸小且数量少,A、B、D类夹杂小于1.0级,C类夹杂小于1.5级,有利于控制钢中微裂纹的萌生与扩展,改善钢筋塑韧性;钢筋强屈比（Rm实/ReL实）不小于1.27,均匀伸长率（Agt）不小于12%,抗震性能好;自然时效1个月后强度变化平缓,具有低应变时效性;焊接试样断口远离焊接接头、焊接性能良好;生产成本和钒氮微合金化工艺相比吨钢降低20元。展开更多
基金Project (2008AA031104) supported by the National High-tech Research and Development Program of China Project (2010063003) supported by the Sharing Fund of Large-scale Equipment of Chongqing University,China
文摘The oxidation process of low-grade vanadium slag in the presence of Na2CO3 was investigated by XRD,SEM/EDS and TG-DSC techniques.The results show that the vanadium slag is oxidized in a temperature range from 273 to 700 °C.Olivine phases and spinel phases are completely decomposed at 500 and 600 °C,respectively.Most of water-soluble sodium vanadates are formed between 500 and 600 °C.When roasting temperature reaches above 700 °C,the vanadium-rich phases of sodium vanadates can be obviously observed.However,at temperature above 800 °C,the samples are sintered.Most of the vanadium is enwrapped by glassy phase compounds which lead to the decrease of the leaching rate of vanadium.At the same time,the effect of roasting temperature on extraction of vanadium and characterization of leach residues were discussed.
文摘采用扫描电镜、透射电镜、金相显微镜、闪光焊接及力学性能测试,对国内某厂采用富氮钒微合金化生产的Φ40 mm HRB500抗震钢筋微合金析出强化效果、力学性能、金相显微组织、夹杂物、焊接及时效性进行了试验研究。结果表明：采用增氮降钒工艺增加了细小弥散的钒析出相数量,析出相尺寸为10~30 nm,其中V（CN）析出物占总w（V）的79.35%,析出强化效果显著;钢中夹杂物尺寸小且数量少,A、B、D类夹杂小于1.0级,C类夹杂小于1.5级,有利于控制钢中微裂纹的萌生与扩展,改善钢筋塑韧性;钢筋强屈比（Rm实/ReL实）不小于1.27,均匀伸长率（Agt）不小于12%,抗震性能好;自然时效1个月后强度变化平缓,具有低应变时效性;焊接试样断口远离焊接接头、焊接性能良好;生产成本和钒氮微合金化工艺相比吨钢降低20元。
