Based on Schaaff＇s collision factor theory （CFT） in liquids, the equations for nonlinear ultrasonic parameters in both organic liquid and binary organic liquid mixtures are deduced. The nonlinear ultrasonic paramet...Based on Schaaff＇s collision factor theory （CFT） in liquids, the equations for nonlinear ultrasonic parameters in both organic liquid and binary organic liquid mixtures are deduced. The nonlinear ultrasonic parameters, including pressure coefficient, temperature coefficients of ultrasonic velocity, and nonlinear acoustic parameter B/A in both organic liquid and binary organic liquid mixtures, are evaluated for comparison with the measured results and data from other sources. The equations show that the coefficient of ultrasonic velocity and nonlinear acoustic parameter B/A are closely related to molecular interactions. These nonlinear ultrasonic parameters reflect some information of internal structure and outside status of the medium or mixtures. From the exponent of repulsive forces of the molecules, several thermodynamic parameters, pressure and temperature of the medium, the nonlinear ultrasonic parameters and ultrasonic nature of the medium can be evaluated. When evaluating and studying nonlinear acoustic parameter B/A of binary organic liquid mixtures, there is no need to know the nonlinear acoustic parameter B/A of the components. Obviously, the equation reveals the connection between the nonlinear ultrasonic nature and internal structure and outside status of the mixtures more directly and distinctly than traditional mixture law for B/A, e.g. Apfel＇s and Sehgal＇s laws for liquid binary mixtures.展开更多
The accurate measurement method of ultrasonic velocity by the pulse interference method with eliminating the diffraction effect has been investigated in VHF range experimentally. Two silicate glasses were taken as the...The accurate measurement method of ultrasonic velocity by the pulse interference method with eliminating the diffraction effect has been investigated in VHF range experimentally. Two silicate glasses were taken as the specimens, their frequency dependences of longitudinal velocities were measured in the frequency range 50-350 MHz, and the phase advances of ultrasonic signals caused by diffraction effect were calculated using A. O. Williams' theoretical expression. For the frequency dependences of longitudinal velocities, the measurement results were in good agreement with the simulation ones in which the phase advances were included. It has been shown that the velocity error due to diffraction effect can be corrected very well by this method.展开更多
The measurement errors due to nonparallelness of specimen faces in the ultrasonic velocity and attenuation coefficient measured by the pulse reflection method in VHF range have been investigated theoretically, and the...The measurement errors due to nonparallelness of specimen faces in the ultrasonic velocity and attenuation coefficient measured by the pulse reflection method in VHF range have been investigated theoretically, and the theoretical expressions for estimating these measurement errors are given. It has also been shown that, the attenuation coefficient error is depending on both the nonparallelness angle of specimen faces and the ultrasonic frequency, but the velocity error is only depending on the former. Furthermore, for pure silica glass specimen it is estimated that, in VHF range in order to insure that the attenuation coefficient and velocity errors due to nonparallelness of specimen faces are less than 10% and 0.01%, respectively, the nonparallelness angle of specimen faces must be less than 10 s and 40 s correspondingly.展开更多
On the basis of Jacobson's free length theory and the theory of pressure coefficient and temperature coefficient of free length in liquids, the relationship between the pressure coefficient of ultrasonic velocity...On the basis of Jacobson's free length theory and the theory of pressure coefficient and temperature coefficient of free length in liquids, the relationship between the pressure coefficient of ultrasonic velocity and the pressure coefficient of free length, and the relationship between the temperature coefficient of ultrasonic velocity and the temperature coefficient of free length were studied. Relevant equations were given, and the pressure coefficient and temperature coefficient of ultrasonic velocity were calculated, which are in agreement with the measured values.展开更多
文摘Based on Schaaff＇s collision factor theory （CFT） in liquids, the equations for nonlinear ultrasonic parameters in both organic liquid and binary organic liquid mixtures are deduced. The nonlinear ultrasonic parameters, including pressure coefficient, temperature coefficients of ultrasonic velocity, and nonlinear acoustic parameter B/A in both organic liquid and binary organic liquid mixtures, are evaluated for comparison with the measured results and data from other sources. The equations show that the coefficient of ultrasonic velocity and nonlinear acoustic parameter B/A are closely related to molecular interactions. These nonlinear ultrasonic parameters reflect some information of internal structure and outside status of the medium or mixtures. From the exponent of repulsive forces of the molecules, several thermodynamic parameters, pressure and temperature of the medium, the nonlinear ultrasonic parameters and ultrasonic nature of the medium can be evaluated. When evaluating and studying nonlinear acoustic parameter B/A of binary organic liquid mixtures, there is no need to know the nonlinear acoustic parameter B/A of the components. Obviously, the equation reveals the connection between the nonlinear ultrasonic nature and internal structure and outside status of the mixtures more directly and distinctly than traditional mixture law for B/A, e.g. Apfel＇s and Sehgal＇s laws for liquid binary mixtures.
文摘The accurate measurement method of ultrasonic velocity by the pulse interference method with eliminating the diffraction effect has been investigated in VHF range experimentally. Two silicate glasses were taken as the specimens, their frequency dependences of longitudinal velocities were measured in the frequency range 50-350 MHz, and the phase advances of ultrasonic signals caused by diffraction effect were calculated using A. O. Williams' theoretical expression. For the frequency dependences of longitudinal velocities, the measurement results were in good agreement with the simulation ones in which the phase advances were included. It has been shown that the velocity error due to diffraction effect can be corrected very well by this method.
文摘The measurement errors due to nonparallelness of specimen faces in the ultrasonic velocity and attenuation coefficient measured by the pulse reflection method in VHF range have been investigated theoretically, and the theoretical expressions for estimating these measurement errors are given. It has also been shown that, the attenuation coefficient error is depending on both the nonparallelness angle of specimen faces and the ultrasonic frequency, but the velocity error is only depending on the former. Furthermore, for pure silica glass specimen it is estimated that, in VHF range in order to insure that the attenuation coefficient and velocity errors due to nonparallelness of specimen faces are less than 10% and 0.01%, respectively, the nonparallelness angle of specimen faces must be less than 10 s and 40 s correspondingly.
文摘On the basis of Jacobson's free length theory and the theory of pressure coefficient and temperature coefficient of free length in liquids, the relationship between the pressure coefficient of ultrasonic velocity and the pressure coefficient of free length, and the relationship between the temperature coefficient of ultrasonic velocity and the temperature coefficient of free length were studied. Relevant equations were given, and the pressure coefficient and temperature coefficient of ultrasonic velocity were calculated, which are in agreement with the measured values.
