A new concept of banana vibrating screen which has the same effect as traditional banana vibrating screen in a new way was put forward.The dynamic model of vibrating screen was established and its working principle wa...A new concept of banana vibrating screen which has the same effect as traditional banana vibrating screen in a new way was put forward.The dynamic model of vibrating screen was established and its working principle was analyzed when the action line of the exciting force did not act through the centroid of screen box.Moreover,the dynamic differential equations of centroid and screen surface were obtained.The motions of centroid and screen surface were simulated with actual parameters of the design example in Matlab/Simulink.The results show that not only the amplitude has a significant decrease from 9.38 to 4.10 mm,but also the throwing index and vibrating direction angle have a significant decrease from 10.49 to 4.59,and from 58.10° to 33.29°,respectively,along the screen surface,which indicates that motion characteristics of vibrating screen are consistent with those of traditional banana vibrating screen only by means of a single angle of screen surface.What's more,such banana vibrating screen of variable linear trajectory with greater processing capacity could be obtained by adjusting the relative position of force center and the centroid of screen box properly.展开更多
We have carried out a quasi-classical trajectory calculation for the reaction ofNe + H2+ (v = 0, j = 1) → NeH+ + H on the ground state (12AI) using the LZHH potential energy surface constructed by L/i et al. ...We have carried out a quasi-classical trajectory calculation for the reaction ofNe + H2+ (v = 0, j = 1) → NeH+ + H on the ground state (12AI) using the LZHH potential energy surface constructed by L/i et al. [Lu S J, Zhang P Y, Han K L and He G Z 2010 J. Chem. Phys. 132 014303]. Differential cross sections at many collision energies indicate that the reaction is dominated by forward-scattering. In addition, the Nell+ product shows rotationally hot and vibrationally cold distributions. Stereodynamical results indicate that the products are strongly polarized in the direction perpendicular to the scattering plane and that the products rotate mainly in planes parallel to the scattering plane.展开更多
This paper studies the influence of the reagent vibration on the reaction O(1D)+HF→HO+F by using a quasiclassical trajectory method on the new ab initio 1A' ground singlet potential energy surface (Gomez-Carras...This paper studies the influence of the reagent vibration on the reaction O(1D)+HF→HO+F by using a quasiclassical trajectory method on the new ab initio 1A' ground singlet potential energy surface (Gomez-Carrasco et al 2007 Chem. Phys. Lett. 435 188 193). The product angular distributions which reflect the vector correlation are calculated. Four polarization-dependent differential cross sections (PDDCSs) which are sensitive to many photoinitiated bimolecular reaction experiments are presented in the center of the mass frame, respectively. The differential cross section indicates that the OH product mainly tends to the forward scattering, and other PDDCSs are also influenced by the vibration levels of HF.展开更多
Highly excited vibrational dynamics of phosphaethyne(HCP)integrable system are investigated based on its dynamic potentials.Taking into consideration the 2:1 Fermi resonance between H–C–P bending vibrational mode an...Highly excited vibrational dynamics of phosphaethyne(HCP)integrable system are investigated based on its dynamic potentials.Taking into consideration the 2:1 Fermi resonance between H–C–P bending vibrational mode and C–P stretching vibrational mode,it is found that the effects of H–C stretching vibrational mode on vibrational dynamic features of the HCP integrable system are significant and regularly vary with Polyad numbers(P number).The geometrical profiles of the dynamic potentials and the corresponding fixed points are sensitive to the variation of H–C stretching vibrational strength when P numbers are small,but are not sensitive when P numbers become larger and the corresponding threshold values become lower.The phase space trajectories of different energy levels in a designated dynamic potential(P=28)were studied and the results indicated that the dynamic potentials govern the various dynamic environments in which the vibrational states lie.Furthermore,action integrals of the energy levels contained in dynamic potential(P=28)were quantitatively analyzed and elucidated.It was determined that the dynamic environments could be identified by the numerical values of the action integrals of trajectories of phase space,which is equivalent with dynamic potentials.展开更多
In this paper, the differential equations of flexible circular plates with initial deflection are derived. The stability of motion is investigated in phase plane. The periodical solutions of nonlinear vibration for ci...In this paper, the differential equations of flexible circular plates with initial deflection are derived. The stability of motion is investigated in phase plane. The periodical solutions of nonlinear vibration for circular plates with initial deflection are obtained by use of Galerkin method and Lindstedt-Poincare perturbation method. The effect of initial deflection on the dynamic behavior of the flexible plates are also discussed.展开更多
Quasi-classical trajectory(QCT)calculations are reported for the H+LiH(v=0-2,j=0)→Li+H2 reaction on a new ground electronic state global potential energy surface(PES)of the LiH2 system.Reaction probability and integr...Quasi-classical trajectory(QCT)calculations are reported for the H+LiH(v=0-2,j=0)→Li+H2 reaction on a new ground electronic state global potential energy surface(PES)of the LiH2 system.Reaction probability and integral cross sections(ICSs)are calculated for collision energies in the range of 0 eV-0.5 eV.Reasonable agreement is found in the comparison between present results and previous available theoretical results.We carried out statistical analyses with all the trajectories and found two main distinct reaction mechanisms in the collision process,in which the stripping mechanism(i.e.,without roaming process)is dominated over the collision energy range.The polarization dependent differential cross sections(PDDCSs)indicate that forward scattering dominates the reaction due to the dominated mechanism.Furthermore,the reactant vibration leads to a reduction of the reactivity because of the barrierless and attractive features of PES and mass combination of the system.展开更多
The stereodynamics of the abstraction reaction H^+ NeH^+(v = 1-3,j = 1,3,5) → H2^+ + Ne is studied theoretically with a quasi-classical trajectory method on a new ab initio potential energy surface [ S J,Zhang ...The stereodynamics of the abstraction reaction H^+ NeH^+(v = 1-3,j = 1,3,5) → H2^+ + Ne is studied theoretically with a quasi-classical trajectory method on a new ab initio potential energy surface [ S J,Zhang P Y,Han K L and He G Z 2012 J.Chem.Phys.132 014303].The effects of vibrational and rotational excitation of reagent molecules on the polarization of the product are investigated.The reaction cross sections,the distributions of P(θr),P(φr),and polarizationdependent differential cross sections(PDDCSs) are calculated.The obtained cross sections indicate that the title reaction is a typical barrierless atom(ion)-ion(molecule) reaction.The initial vibrational excitation and rotational excitation of reagent molecules have distinctly different influences on stereodynamics of the title reaction,and the possible reasons for the differences are presented.展开更多
The stereodynamic properties of the F + HO (v, j) reaction are explored by quasi-classical trajectory (QCT) calculations performed on the 1At and 3At potential energy surfaces (PESs). Based on the polarization-...The stereodynamic properties of the F + HO (v, j) reaction are explored by quasi-classical trajectory (QCT) calculations performed on the 1At and 3At potential energy surfaces (PESs). Based on the polarization-dependent differential cross sections (PDDCSs) and the angular distributions of the product angular momentum with the reactant at different values of initial v or j, the results show that the product scattering and product polarization have strong links with initial vibrationalrotational numbers of v and j. The significant manifestation of the normal DCSs is that the forward scattering gradually becomes predominant with the initial vibrational excitation increasing, and the scattering angle of the HF product taking place on the 3At potential energy surface is found to be more sensitive to the initial value of v. The product orientation and alignment are strongly dependent on the initial rovibrational excitation effect. With enhancement in the initial rovibrational excitation effect, there is an overall decrease in the product orientation as well as in the product alignment either perpendicular to the reagent relative velocity vector k or along the direction of the y axis, for which the initial rotational excitation effect is much more noticeable than the vibrational excitation effect. Moreover, the initial rovibrational excitation effect on the product polarization is more pronounced for the 3At potential energy surface than for the 1At potential energy surface.展开更多
The quasiclassical trajectory (QCT) method is used to study stereodynamic information about the reaction O (1D)+H2 --4OH+H on the DK (Dobbyn and Knowles) (llA;) ab initio potential energy surface (PES). A ...The quasiclassical trajectory (QCT) method is used to study stereodynamic information about the reaction O (1D)+H2 --4OH+H on the DK (Dobbyn and Knowles) (llA;) ab initio potential energy surface (PES). A wide scale of collision energy (Ec) from 0.05 eV to 0.5 eV is considered in the dynamic calculations. To reveal the rovibrational excitation effect, calculations at a collision energy of 0.52 eV are carried out for the v = 0 - 5, j = 0 and v = 0, j -- 0 - 15 initial states. The two popularly used polarization-dependent differential cross sections (PDDCSs), dtY0o/doh (0, 0) and dtra0/dtot(2, 0), and two angular distributions, P(φr) and P(φr) are calculated to obtain an insight into the alignment and the orientation of the product molecules. From the calculations, we can obtain that the alignment of the OH product is weaker at high collision energy and becomes stronger with the increase of initial vibrational level, and it is almost insensitive to the initially rotational excitation. Influences of the mass values of isotopes (HD, D2) on the stereodynamics are also shown and discussed. Comparisons between available theoretical results and experimental results are made and discussed.展开更多
The goal of this paper is to enhance a practical nominal characteristic trajectory following(NCTF) controller that is specifically designed for two-mass point-to-point positioning systems. A nominal characteristics tr...The goal of this paper is to enhance a practical nominal characteristic trajectory following(NCTF) controller that is specifically designed for two-mass point-to-point positioning systems. A nominal characteristics trajectory contained in the NCTF controller acts as movement/motion reference and a compensator is utilized to force the object to detect and follow the reference/desired trajectory. The object must follow and track closely and should be as fast as possible. The NCTF controller is designed with two different intelligent based compensator approaches which are fuzzy logic and extended minimal resource allocation network. The proposed controller which is NCTF are compared with the conventional proportional integral compensator. Then the results of simulation are discussed for the positioning performances. The inertia variations due to the effect of the design parameters are also assessed to see the robustness of controllers. The results show that the NCTF control method designed from an intelligent based compensator has a better positioning performance in terms of percentage of overshoot, settling time, and steady state error than the classical based compensator.展开更多
To investigate the effect of a reagent's rotational and vibrational excitations on the stereo-dynamics of the reaction product, the title reaction is theoretically simulated using the quasi-classical trajectory (QCT...To investigate the effect of a reagent's rotational and vibrational excitations on the stereo-dynamics of the reaction product, the title reaction is theoretically simulated using the quasi-classical trajectory (QCT) method on the 3A~ and 3Aq potentiM energy surfaces (PESs). The reaction cross section is considered as the only scalar property in this work at four different collision energies. Furthermore the vector properties including two polarization-dependent differential cross sections (PDDCSs), the angular distributions of product' rotational momentum are discussed at one fixed collision energy. Effects of reagents' rotational excitation on the reaction do exist regularly.展开更多
Based on an extended London-Eyring-Polanyi-Sato (LEPS) potential energy surface (PES), the Ba q-HF reaction has been studied by the quasi-classical trajectory (QCT) method. The reaction integral cross section as...Based on an extended London-Eyring-Polanyi-Sato (LEPS) potential energy surface (PES), the Ba q-HF reaction has been studied by the quasi-classical trajectory (QCT) method. The reaction integral cross section as a function of collision energy for the Ba q- HF --* BaF q- H reaction is presented and the influence of isotope substitution on the differential cross sections (DCSs) and alignments of the product's rotational angular momentum have also been studied. The results suggest that the integral cross sections increase with increasing collision energy, and the vibrational excitation of the reagent has great influence on the DCS. In addition, the product's rotational polarization is very strong as a result of heavy-heavy-light (HHL) mass combination, and the distinct effect of isotope substitution on the stereodynamics is also revealed.展开更多
为满足移动机械臂高精度、低抖动的作业需求,提出一种基于修正非对称组合正弦函数(modified asymmetry combined sine function,简称MACSF)的振动抑制轨迹规划方法。首先,针对传统非对称组合正弦函数(asymmetry combined sine function...为满足移动机械臂高精度、低抖动的作业需求,提出一种基于修正非对称组合正弦函数(modified asymmetry combined sine function,简称MACSF)的振动抑制轨迹规划方法。首先,针对传统非对称组合正弦函数(asymmetry combined sine function,简称ACSF)存在加速度突变、启停阶段不稳定等问题,以驱动函数加加速度连续平滑为目标,采用改进型组合正弦函数设计加加速度时间窗口中的加速阶段和减速阶段,以降低移动机械臂的关节力矩波动;其次,通过叠加组合方法求出满足约束条件的通用型驱动函数;最后,基于机器人操作系统(robot operating system,简称ROS)搭建移动机械臂抑振算法验证平台,并使用该平台在样机场景下进行了一系列实验验证。结果表明,MACSF方法能够有效抑制移动机械臂的瞬态振动和残余振动(动态作业过程中振幅优于1 mm),从而验证了该方法的有效性和实用性。展开更多
基金Projects(50574091, 50774084) supported by the National Natural Science Foundation of ChinaProject(50921001) supported by the Innovative Research Group Science Foundation,ChinaProject supported by Jiangsu Scientific Researching Fund Project ("333" Project),China
文摘A new concept of banana vibrating screen which has the same effect as traditional banana vibrating screen in a new way was put forward.The dynamic model of vibrating screen was established and its working principle was analyzed when the action line of the exciting force did not act through the centroid of screen box.Moreover,the dynamic differential equations of centroid and screen surface were obtained.The motions of centroid and screen surface were simulated with actual parameters of the design example in Matlab/Simulink.The results show that not only the amplitude has a significant decrease from 9.38 to 4.10 mm,but also the throwing index and vibrating direction angle have a significant decrease from 10.49 to 4.59,and from 58.10° to 33.29°,respectively,along the screen surface,which indicates that motion characteristics of vibrating screen are consistent with those of traditional banana vibrating screen only by means of a single angle of screen surface.What's more,such banana vibrating screen of variable linear trajectory with greater processing capacity could be obtained by adjusting the relative position of force center and the centroid of screen box properly.
基金Project supported by the National Natural Science Foundation of China (Grant No.21073110)the Independent Innovation Foundation of Shandong University of China (Grant No.10000059614011)
文摘We have carried out a quasi-classical trajectory calculation for the reaction ofNe + H2+ (v = 0, j = 1) → NeH+ + H on the ground state (12AI) using the LZHH potential energy surface constructed by L/i et al. [Lu S J, Zhang P Y, Han K L and He G Z 2010 J. Chem. Phys. 132 014303]. Differential cross sections at many collision energies indicate that the reaction is dominated by forward-scattering. In addition, the Nell+ product shows rotationally hot and vibrationally cold distributions. Stereodynamical results indicate that the products are strongly polarized in the direction perpendicular to the scattering plane and that the products rotate mainly in planes parallel to the scattering plane.
基金Project supported by the National Natural Science Foundation of China (Grant No 10574083)the Natural Science Foundation of Shandong Province of China (Grant No Y2006A23)partially by the National Basic Research Program of China (GrantNo 2006CB806000)
文摘This paper studies the influence of the reagent vibration on the reaction O(1D)+HF→HO+F by using a quasiclassical trajectory method on the new ab initio 1A' ground singlet potential energy surface (Gomez-Carrasco et al 2007 Chem. Phys. Lett. 435 188 193). The product angular distributions which reflect the vector correlation are calculated. Four polarization-dependent differential cross sections (PDDCSs) which are sensitive to many photoinitiated bimolecular reaction experiments are presented in the center of the mass frame, respectively. The differential cross section indicates that the OH product mainly tends to the forward scattering, and other PDDCSs are also influenced by the vibration levels of HF.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11505027 and 11104156)the Open Foundation of Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation(Grant No.JXMS201605)+1 种基金the Science and Technology Project of Education Department of Jiangxi Province in2016the National High Technology Research and Development Program of China(Grant No.2014AA052701)
文摘Highly excited vibrational dynamics of phosphaethyne(HCP)integrable system are investigated based on its dynamic potentials.Taking into consideration the 2:1 Fermi resonance between H–C–P bending vibrational mode and C–P stretching vibrational mode,it is found that the effects of H–C stretching vibrational mode on vibrational dynamic features of the HCP integrable system are significant and regularly vary with Polyad numbers(P number).The geometrical profiles of the dynamic potentials and the corresponding fixed points are sensitive to the variation of H–C stretching vibrational strength when P numbers are small,but are not sensitive when P numbers become larger and the corresponding threshold values become lower.The phase space trajectories of different energy levels in a designated dynamic potential(P=28)were studied and the results indicated that the dynamic potentials govern the various dynamic environments in which the vibrational states lie.Furthermore,action integrals of the energy levels contained in dynamic potential(P=28)were quantitatively analyzed and elucidated.It was determined that the dynamic environments could be identified by the numerical values of the action integrals of trajectories of phase space,which is equivalent with dynamic potentials.
文摘In this paper, the differential equations of flexible circular plates with initial deflection are derived. The stability of motion is investigated in phase plane. The periodical solutions of nonlinear vibration for circular plates with initial deflection are obtained by use of Galerkin method and Lindstedt-Poincare perturbation method. The effect of initial deflection on the dynamic behavior of the flexible plates are also discussed.
文摘Quasi-classical trajectory(QCT)calculations are reported for the H+LiH(v=0-2,j=0)→Li+H2 reaction on a new ground electronic state global potential energy surface(PES)of the LiH2 system.Reaction probability and integral cross sections(ICSs)are calculated for collision energies in the range of 0 eV-0.5 eV.Reasonable agreement is found in the comparison between present results and previous available theoretical results.We carried out statistical analyses with all the trajectories and found two main distinct reaction mechanisms in the collision process,in which the stripping mechanism(i.e.,without roaming process)is dominated over the collision energy range.The polarization dependent differential cross sections(PDDCSs)indicate that forward scattering dominates the reaction due to the dominated mechanism.Furthermore,the reactant vibration leads to a reduction of the reactivity because of the barrierless and attractive features of PES and mass combination of the system.
基金Project supported by the National Natural Science Foundation of China (Grant No. 11105022)the Fundamental Research Funds for the Central Universities,China (Grant Nos. 2012QN066 and 2011QN142)
文摘The stereodynamics of the abstraction reaction H^+ NeH^+(v = 1-3,j = 1,3,5) → H2^+ + Ne is studied theoretically with a quasi-classical trajectory method on a new ab initio potential energy surface [ S J,Zhang P Y,Han K L and He G Z 2012 J.Chem.Phys.132 014303].The effects of vibrational and rotational excitation of reagent molecules on the polarization of the product are investigated.The reaction cross sections,the distributions of P(θr),P(φr),and polarizationdependent differential cross sections(PDDCSs) are calculated.The obtained cross sections indicate that the title reaction is a typical barrierless atom(ion)-ion(molecule) reaction.The initial vibrational excitation and rotational excitation of reagent molecules have distinctly different influences on stereodynamics of the title reaction,and the possible reasons for the differences are presented.
基金supported by the National Natural Science Foundation of China (Grant Nos. 10874096 and 20633070)the Natural Science Foundation of Qingdao University,China (Grant No. 063-06300510)
文摘The stereodynamic properties of the F + HO (v, j) reaction are explored by quasi-classical trajectory (QCT) calculations performed on the 1At and 3At potential energy surfaces (PESs). Based on the polarization-dependent differential cross sections (PDDCSs) and the angular distributions of the product angular momentum with the reactant at different values of initial v or j, the results show that the product scattering and product polarization have strong links with initial vibrationalrotational numbers of v and j. The significant manifestation of the normal DCSs is that the forward scattering gradually becomes predominant with the initial vibrational excitation increasing, and the scattering angle of the HF product taking place on the 3At potential energy surface is found to be more sensitive to the initial value of v. The product orientation and alignment are strongly dependent on the initial rovibrational excitation effect. With enhancement in the initial rovibrational excitation effect, there is an overall decrease in the product orientation as well as in the product alignment either perpendicular to the reagent relative velocity vector k or along the direction of the y axis, for which the initial rotational excitation effect is much more noticeable than the vibrational excitation effect. Moreover, the initial rovibrational excitation effect on the product polarization is more pronounced for the 3At potential energy surface than for the 1At potential energy surface.
文摘The quasiclassical trajectory (QCT) method is used to study stereodynamic information about the reaction O (1D)+H2 --4OH+H on the DK (Dobbyn and Knowles) (llA;) ab initio potential energy surface (PES). A wide scale of collision energy (Ec) from 0.05 eV to 0.5 eV is considered in the dynamic calculations. To reveal the rovibrational excitation effect, calculations at a collision energy of 0.52 eV are carried out for the v = 0 - 5, j = 0 and v = 0, j -- 0 - 15 initial states. The two popularly used polarization-dependent differential cross sections (PDDCSs), dtY0o/doh (0, 0) and dtra0/dtot(2, 0), and two angular distributions, P(φr) and P(φr) are calculated to obtain an insight into the alignment and the orientation of the product molecules. From the calculations, we can obtain that the alignment of the OH product is weaker at high collision energy and becomes stronger with the increase of initial vibrational level, and it is almost insensitive to the initially rotational excitation. Influences of the mass values of isotopes (HD, D2) on the stereodynamics are also shown and discussed. Comparisons between available theoretical results and experimental results are made and discussed.
文摘The goal of this paper is to enhance a practical nominal characteristic trajectory following(NCTF) controller that is specifically designed for two-mass point-to-point positioning systems. A nominal characteristics trajectory contained in the NCTF controller acts as movement/motion reference and a compensator is utilized to force the object to detect and follow the reference/desired trajectory. The object must follow and track closely and should be as fast as possible. The NCTF controller is designed with two different intelligent based compensator approaches which are fuzzy logic and extended minimal resource allocation network. The proposed controller which is NCTF are compared with the conventional proportional integral compensator. Then the results of simulation are discussed for the positioning performances. The inertia variations due to the effect of the design parameters are also assessed to see the robustness of controllers. The results show that the NCTF control method designed from an intelligent based compensator has a better positioning performance in terms of percentage of overshoot, settling time, and steady state error than the classical based compensator.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 50972082 and 51072101)the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No.20090131120077)the Natural Science Foundation of Shandong Province, China (Grant Nos. ZR2011EMM019 and ZR2012AM007)
文摘To investigate the effect of a reagent's rotational and vibrational excitations on the stereo-dynamics of the reaction product, the title reaction is theoretically simulated using the quasi-classical trajectory (QCT) method on the 3A~ and 3Aq potentiM energy surfaces (PESs). The reaction cross section is considered as the only scalar property in this work at four different collision energies. Furthermore the vector properties including two polarization-dependent differential cross sections (PDDCSs), the angular distributions of product' rotational momentum are discussed at one fixed collision energy. Effects of reagents' rotational excitation on the reaction do exist regularly.
文摘Based on an extended London-Eyring-Polanyi-Sato (LEPS) potential energy surface (PES), the Ba q-HF reaction has been studied by the quasi-classical trajectory (QCT) method. The reaction integral cross section as a function of collision energy for the Ba q- HF --* BaF q- H reaction is presented and the influence of isotope substitution on the differential cross sections (DCSs) and alignments of the product's rotational angular momentum have also been studied. The results suggest that the integral cross sections increase with increasing collision energy, and the vibrational excitation of the reagent has great influence on the DCS. In addition, the product's rotational polarization is very strong as a result of heavy-heavy-light (HHL) mass combination, and the distinct effect of isotope substitution on the stereodynamics is also revealed.