Aiming at reducing the difficulty of cooling the interior of high-density motors,this study proposed the placement of a water cold plate cooling structure between the axial laminations of the motor stator.The effect o...Aiming at reducing the difficulty of cooling the interior of high-density motors,this study proposed the placement of a water cold plate cooling structure between the axial laminations of the motor stator.The effect of the cooling water flow,thickness of the plate,and motor loss density on the cooling effect of the water cold plate were studied.To compare the cooling performance of water cold plate and outer spiral water jacket cooling structures,a high-speed permanent magnet motor with a high loss density was used to establish two motor models with the two cooling structures.Consequently,the cooling effects of the two models were analyzed using the finite element method under the same loss density,coolant flow,and main dimensions.The results were as follows.(1)The maximum and average temperatures of the water cold plate structure were reduced by 25.5%and 30.5%,respectively,compared to that of the outer spiral water jacket motor;(2)Compared with the outer spiral water jacket structure,the water cold plate structure can reduce the overall mass and volume of the motor.Considering a 100 kW high-speed permanent magnet motor as an example,a water cold plate cooling system was designed,and the temperature distribution is analyzed,with the result indicating that the cooling structure satisfied the cooling requirements of the high loss density motor.展开更多
To maintain tight control over rheological properties of high-density water-based drilling fluids, it is essential to understand the factors influencing the theology of water-based drilling fluids. This paper examines...To maintain tight control over rheological properties of high-density water-based drilling fluids, it is essential to understand the factors influencing the theology of water-based drilling fluids. This paper examines temperature effects on the rheological properties of two types of high-density water-based drilling fluids (fresh water-based and brine-based) under high temperature and high pressure (HTHP) with a Fann 50SL rheometer. On the basis of the water-based drilling fluid systems formulated in laboratory, this paper mainly describes the influences of different types and concentration of clay, the content of a colloid stabilizer named GHJ-1 and fluid density on the rheological parameters such as viscosity and shear stress. In addition, the effects of aging temperature and aging time of the drilling fluid on these parameters were also examined. Clay content and proportions for different densities of brine-based fluids were recommended to effectively regulate the rheological properties. Four theological models, the Bingham, power law, Casson and H-B models, were employed to fit the rheological parameters. It turns out that the H-B model was the best one to describe the rheological properties of the high-density drilling fluid under HTHP conditions and power law model produced the worst fit. In addition, a new mathematical model that describes the apparent viscosity as a function of temperature and pressure was established and has been applied on site.展开更多
This work applied molecular dynamics(MD)simulation to calculate densities of natural gas mixtures at extremely high pressure(>138 MPa)and high temperature(>200℃)conditions(x HPHT)to bridge the knowledge and tec...This work applied molecular dynamics(MD)simulation to calculate densities of natural gas mixtures at extremely high pressure(>138 MPa)and high temperature(>200℃)conditions(x HPHT)to bridge the knowledge and technical gaps between experiments and classical theories.The experimental data are scarce at these conditions which are also out of assumptions for classical predictive correlations,such as the Dranchuk&Abou-Kassem(DAK)equation of state(EOS).Force fields of natural gas components were carefully chosen from literatures and the simulation results are validated with experimental data.The largest relative error is 2.67%for pure hydrocarbons,2.99%for C1/C3 mixture,7.85%for C1/C4 mixture,and 8.47%for pure H2S.These satisfactory predictions demonstrate that the MD simulation approach is reliable to predict natural-and acid-gases thermodynamic properties.The validated model is further used to generate data for the study of the EOS with pressure up to 276 MPa and temperature up to 573 K.Our results also reveal that the Dranchuk&Abou-Kassem(DAK)EOS is capable of predicting natural gas compressibility to a satisfactory accuracy at x HPHT conditions,which extends the confidence range of the DAK EOS.展开更多
The castings defects are affected by the melting volume change rate of material. The change rate has an important effect on running safety of the high temperature thermal storage chamber, too. But the characteristics ...The castings defects are affected by the melting volume change rate of material. The change rate has an important effect on running safety of the high temperature thermal storage chamber, too. But the characteristics of existing measuring installations are complex structure, troublesome operation and low precision. In order to measure the melting volume change rate of material accurately and conveniently, a self-designed measuring instrument, self-heating probe instrument, and measuring method are described. Temperature in heating cavity is controlled by PID temperature controller; melting volume change rate υ and molten density are calculated based on the melt volume which is measured by the instrument. Positive and negative υ represent expansion and shrinkage of the sample volume after melting, respectively. Taking eutectic LiF+CaF2 for example, its melting volume change rate and melting density at 1 123 K are -20.6% and 2 651 kg/m–3 measured by this instrument, which is only 0.71% smaller than literature value. Density and melting volume change rate of industry pure aluminum at 973 K and analysis pure NaCl at 1 123 K are detected by the instrument too. The measure results are agreed with report values. Measuring error sources are analyzed and several improving measures are proposed. In theory, the measuring errors of the change rate and molten density which are measured by the self-designed instrument is nearly 1/20-1/50 of that measured by the refitted mandril thermal expansion instrument. The self-designed instrument and method have the advantages of simple structure, being easy to operate, extensive applicability for material, relatively high accuracy, and most importantly, temperature and sample vapor pressure have little effect on the measurement accuracy. The presented instrument and method solve the problems of complicated structure and procedures, and large measuring errors for the samples with high vapor pressure by existing installations.展开更多
P-wave velocities in the rocks of Dabieshan, central China were measured at pressures up to 5.0 GPa and temperatures up to 1 300℃. The ultrahigh pressure eclogites have the highest density and P-wave velocity (Vp) an...P-wave velocities in the rocks of Dabieshan, central China were measured at pressures up to 5.0 GPa and temperatures up to 1 300℃. The ultrahigh pressure eclogites have the highest density and P-wave velocity (Vp) and lower anisotropy. Pressure derivatives of the eclogites range from 0. 22 to 0. 33 km. s-1 GPa-1. Average temperature derivative of the eclogites is - 3. 41×10-4 km. s-1. °C -1. The density and VP of the eclogites imply that there will be two united possibilities related to crust-mantle recycling after the eclogite formed in the deep lithosphere. One is that some eclogites in the deep lithosphere were detached and sunk into deeper mantle due to their denser density. Another is that some eclogites returned to the crust and exposed to the surface.Small amounts (<12%) of eclogites may be still exist in the deep crust beneath Dabieshan based on our calculation.展开更多
The effect of high density pulse electric current (HDPEC) on the solidification structure of the low temperature melt(LTM) of commercial A356 alloy was investigated. In the experiments, the HDPEC was discharged in the...The effect of high density pulse electric current (HDPEC) on the solidification structure of the low temperature melt(LTM) of commercial A356 alloy was investigated. In the experiments, the HDPEC was discharged in the LTM (953?K, 903?K and 873?K). By the control experiments, the results showed that the solidification structure of the LTM of A356 alloy is refined apparently when the HDPEC is discharged in low temperature melt. However, the holding time of melt treated has an adverse effect on the solidification structure. The longer the holding time of the melt treated with HDPEC, the coarser the microstructure. With the same discharge voltage, the lower the temperature of LTM, the more obscure the refinement of solidification structure. Finally, the mechanism of microstructure refining by HDPEC was analyzed.展开更多
Laboratory-scale carbon anodes were produced by a new method of high temperature mould pressing, and their physico-chemical properties were studied. The influence of mould pressing conditions and coal pitch addition o...Laboratory-scale carbon anodes were produced by a new method of high temperature mould pressing, and their physico-chemical properties were studied. The influence of mould pressing conditions and coal pitch addition on the bulk density, crushing strength, and oxidation resistance was analyzed. The mierostructure of carbon anodes was investigated by scanning electron microscopy (SEM), and the mechanism of producing carbon anodes by high-temperature mould pressing was analyzed. The results show that when the anodes are produced by high-temperature mould pressing, coal pitch can expand into the coke particles and fill the pores inside the particles, which is beneficial for improving the quality of prebaked anodes. The bulk density of carbon anodes is 1.64-1.66 g/cm3, which is 0.08-0.12 g/cm3 higher than that of industrial anodes, and the oxidation resistance of carbon anodes is also significantly improved.展开更多
Developing a simple scalable method to fabricate electrodes with high capacity and wide voltage range is desired for the real use of electrochemical supercapacitors.Herein,we synthesized amorphous NiCo-LDH nanosheets ...Developing a simple scalable method to fabricate electrodes with high capacity and wide voltage range is desired for the real use of electrochemical supercapacitors.Herein,we synthesized amorphous NiCo-LDH nanosheets vertically aligned on activated carbon cloth substrate,which was in situ transformed from Co-metal-organic framework materials nano-columns by a simple ion exchange process at room temperature.Due to the amorphous and vertically aligned ultrathin structure of NiCo-LDH,the NiCo-LDH/activated carbon cloth composites present high areal capacities of 3770 and 1480 mF cm^(-2)as cathode and anode at 2 mA cm^(-2),and 79.5%and 80%capacity have been preserved at 50 mA cm^(-2).In the meantime,they all showed excellent cycling performance with negligible change after>10000 cycles.By fabricating them into an asymmetric supercapacitor,the device achieves high energy densities(5.61 mWh cm^(-2)and 0.352 mW cm^(-3)).This work provides an innovative strategy for simplifying the design of supercapacitors as well as providing a new understanding of improving the rate capabilities/cycling stability of NiCo-LDH materials.展开更多
Lithium-sulfur batteries(LSBs)can work at high temperatures,but they suffer from poor cycle life stability due to the“shuttle effect”of polysulfides.In this study,pollen-derived porous carbon/cuprous phosphide(PC/Cu...Lithium-sulfur batteries(LSBs)can work at high temperatures,but they suffer from poor cycle life stability due to the“shuttle effect”of polysulfides.In this study,pollen-derived porous carbon/cuprous phosphide(PC/Cu_(3)P)hybrids were rationally synthesized using a one-step carbonization method using pollen as the source material,acting as the sulfur host for LSBs.In the hybrid,polar Cu_(3)P can markedly inhibit the“shuttle effect”by regulating the adsorption ability toward polysulfides,as confirmed by theoretical calculations and experimental tests.As an example,the camellia pollen porous carbon(CPC)/Cu_(3)P/S electrode shows a high capacity of 1205.6 mAh g^(−1) at 0.1 C,an ultralow capacity decay rate of 0.038%per cycle after 1000 cycles at 1 C,and a rather high initial Coulombic efficiency of 98.5%.The CPC/Cu_(3)P LSBs can work well at high temperatures,having a high capacity of 545.9 mAh g^(−1) at 1 C even at 150℃.The strategy of the PC/Cu_(3)P hybrid proposed in this study is expected to be an ideal cathode for ultrastable high-temperature LSBs.We believe that this strategy is universal and worthy of in-depth development for the next generation energy storage devices.展开更多
Powder in tube process(PIT) was adopted for the fabrication of single filament Bi-2223 tapes, and a heat treatment process including the first heat treatment(HT1), intermediate rolling(IR), and second heat treat...Powder in tube process(PIT) was adopted for the fabrication of single filament Bi-2223 tapes, and a heat treatment process including the first heat treatment(HT1), intermediate rolling(IR), and second heat treatment(HT2) was performed. The phase evolution mechanism and microstructure changes during these heat treatment processes were systematically discussed. The influences of HT1 parameters on the phase evolution process of Bi-2223 tapes were discussed. With the optimized HT1 process, a proper Bi-2223 content of about 90% was achieved. HT2 process was also optimized by adding a post annealing process. An obvious increase of current capacity was obtained due to the enhancement of intergrain connections. Single filament Bi-2223 tapes with the critical current of Ic-90 A were fabricated with the optimized sintering process.展开更多
With low temperature solution based processes and excellent mechanical flexibility,the organic field effect transistor(OFET)technology is promising for creating a wide range of emerging flexible electronics towards ap...With low temperature solution based processes and excellent mechanical flexibility,the organic field effect transistor(OFET)technology is promising for creating a wide range of emerging flexible electronics towards applications of internet of everything.However,despite of remarkable progress in developing high performance organic semiconductor materials.展开更多
The description of experimentally observed phenomenon of abnormally high electrical conductivity—'superconductivity' (SC) at the room and higher temperatures is represented. The effect was observed in metalli...The description of experimentally observed phenomenon of abnormally high electrical conductivity—'superconductivity' (SC) at the room and higher temperatures is represented. The effect was observed in metallic monospirals of small radius curvature with high density and regular distribution of dislocations. Transition into state of SC has been observed experimentally in the range from –50 up to 3000°C at the density of transmitting current up to 2·109 A/cm2. The experimental data confirming the watched phenomenon are represented. The explanations of this phenomenon are being proposed in the framework of the dislocation model.展开更多
Polymer dielectrics which possess excellent dielectric properties such as high breakdown strength,flexibility,and facile processability are considered as promising materials for advanced electrostatic capacitors.Howev...Polymer dielectrics which possess excellent dielectric properties such as high breakdown strength,flexibility,and facile processability are considered as promising materials for advanced electrostatic capacitors.However,most dielectric polymers have unsatisfactory energy storage performances at high-temperature environments.Here,polyetherimide(PEI) nanocomposite films contained with electrospun Ba(Zr_(0.79)Ti_(0.21))O_(3) nanofibers(BZTNFs) are fabricated by common solution casting method.The dielectric properties,especially the breakdown strength of the BZTNFs/PEI nanocomposites,are characterized,yet improvement is only in the small loading ones.The energy storage performance of the 0.5 vol% and1.0 vol% BZTNFs content nanocomposite is further investigated from 25 to 150℃.With the introduction of small loading BZTNFs,the dielectric permittivity and electric displacement of the nanocomposite are improved at all evaluated temperatures.The 1.0 vol% BZTNFs/PEI possesses a maximal discharged energy density of6.05 J·cm^(-3) with high efficiency of 94.9% at 25℃,then falls to 3.34 J·cm^(-3) with efficiency of 54.6% at 150℃ for the larger remnant displacement.Apparently,the relaxation ferroelectric nanofller of BZTNFs is much effective in increasing the dielectric permittivity of nanocomposite,but its capacity to restrict the migration of the charge carriers at high temperatures is weaker than that of the nanofillers with wider bandgap.The complementation of both kinds of the nanofillers probably provides an approach to available high-temperature dielectric films.展开更多
The large-scale disturbance of the spatial structure of the daytime high-latitude F-region ionosphere, caused by powerful high-frequency radio waves, pumped into the ionosphere by a groundbased ionospheric heater, is ...The large-scale disturbance of the spatial structure of the daytime high-latitude F-region ionosphere, caused by powerful high-frequency radio waves, pumped into the ionosphere by a groundbased ionospheric heater, is studied with the help of the numerical simulation. The mathematical model of the high-latitude ionosphere, developed earlier in the Polar Geophysical Institute, is utilized. The mathematical model takes into account the drift of the ionospheric plasma, strong magnetization of the plasma at F-layer altitudes, geomagnetic field declination, and effect of powerful high-frequency radio waves. The distributions of the ionospheric parameters were calculated on condition that an ionospheric heater, situated at the point with geographic coordinates of the HF heating facility near Tromso, Scandinavia, has been operated, with the ionospheric heater being located on the day side of the Earth. The results of the numerical simulation indicate that artificial heating of the ionosphere by powerful high-frequency waves ought to influence noticeably on the spatial structure of the daytime high-latitude F-region ionosphere in the vicinity of the ionospheric heater.展开更多
By means of critical behaviors of the dynamical fermion mass in four-fermion interaction models, we show by explicit calculations that when T = 0 the particle density will have a discontinuous jumping across the criti...By means of critical behaviors of the dynamical fermion mass in four-fermion interaction models, we show by explicit calculations that when T = 0 the particle density will have a discontinuous jumping across the critical chemical potential μ<SUB>c</SUB> in 2D and 3D Gross-Neveu (GN) model and these physically explain the first-order feature of the corresponding symmetry restoring phase transitions. For the second-order phase transitions in the 3D GN model when T → 0 and in 4D Nambu–Jona–Lasinio (NJL) model when T = 0, it is proven that the particle density itself will be continuous across μ<SUB>c</SUB> but its derivative over the chemical potential μ will have a discontinuous jumping. The results give a physical explanation of implications of the tricritical point in the 3D GN model. The discussions also show effectiveness of the critical analysis approach of phase transitions.展开更多
Geomagnetic storm is a kind of severe disturbance that lasts for more than ten hours to several tens of hours in the entire Earth’s magnetosphere. This paper uses the NRLMSISE-00 model to calculate the temperature an...Geomagnetic storm is a kind of severe disturbance that lasts for more than ten hours to several tens of hours in the entire Earth’s magnetosphere. This paper uses the NRLMSISE-00 model to calculate the temperature and density data. According to the surveyed medium magnetic storm events, the characteristics of daily average density and temperature in the occurrence of magnetic storms in 2010 were studied. At the same time, high latitude meridians were taken as research objects. Divide the temperature and density characteristics at different heights. Results showed that the annual trend of density is the same for different heights, and there is an average of the average density every day on the six medium magnetic storm mountains. For the average daily temperature, each medium magnetic storm event corresponds to a temperature peak. The peak temperature on April 5 was the highest temperature throughout the year, consistent with the annual average density distribution. Due to the intensity of the magnetic storm, the temperature of a large area of bright areas rose sharply on April 12, which is also the highest in the year. At 18:00 on May 2, it was the peak time of the moderate magnetic storm event caused by CIR, but May 3 was the date of the peak temperature. This peak delay is reasonable.展开更多
基金supported by the National Natural Science Foundation of China(51920105011)Natural Science Foundation of Liaoning Province(2021-YQ-09)Liaoning Bai Qian Wan Talents Program,China.
文摘Aiming at reducing the difficulty of cooling the interior of high-density motors,this study proposed the placement of a water cold plate cooling structure between the axial laminations of the motor stator.The effect of the cooling water flow,thickness of the plate,and motor loss density on the cooling effect of the water cold plate were studied.To compare the cooling performance of water cold plate and outer spiral water jacket cooling structures,a high-speed permanent magnet motor with a high loss density was used to establish two motor models with the two cooling structures.Consequently,the cooling effects of the two models were analyzed using the finite element method under the same loss density,coolant flow,and main dimensions.The results were as follows.(1)The maximum and average temperatures of the water cold plate structure were reduced by 25.5%and 30.5%,respectively,compared to that of the outer spiral water jacket motor;(2)Compared with the outer spiral water jacket structure,the water cold plate structure can reduce the overall mass and volume of the motor.Considering a 100 kW high-speed permanent magnet motor as an example,a water cold plate cooling system was designed,and the temperature distribution is analyzed,with the result indicating that the cooling structure satisfied the cooling requirements of the high loss density motor.
文摘To maintain tight control over rheological properties of high-density water-based drilling fluids, it is essential to understand the factors influencing the theology of water-based drilling fluids. This paper examines temperature effects on the rheological properties of two types of high-density water-based drilling fluids (fresh water-based and brine-based) under high temperature and high pressure (HTHP) with a Fann 50SL rheometer. On the basis of the water-based drilling fluid systems formulated in laboratory, this paper mainly describes the influences of different types and concentration of clay, the content of a colloid stabilizer named GHJ-1 and fluid density on the rheological parameters such as viscosity and shear stress. In addition, the effects of aging temperature and aging time of the drilling fluid on these parameters were also examined. Clay content and proportions for different densities of brine-based fluids were recommended to effectively regulate the rheological properties. Four theological models, the Bingham, power law, Casson and H-B models, were employed to fit the rheological parameters. It turns out that the H-B model was the best one to describe the rheological properties of the high-density drilling fluid under HTHP conditions and power law model produced the worst fit. In addition, a new mathematical model that describes the apparent viscosity as a function of temperature and pressure was established and has been applied on site.
基金partial financial support from Ballard Petroleum Holdings and Yangtze Universitythe Schooner Supercomputing from the University of Oklahomathe startup support from the University of Oklahoma。
文摘This work applied molecular dynamics(MD)simulation to calculate densities of natural gas mixtures at extremely high pressure(>138 MPa)and high temperature(>200℃)conditions(x HPHT)to bridge the knowledge and technical gaps between experiments and classical theories.The experimental data are scarce at these conditions which are also out of assumptions for classical predictive correlations,such as the Dranchuk&Abou-Kassem(DAK)equation of state(EOS).Force fields of natural gas components were carefully chosen from literatures and the simulation results are validated with experimental data.The largest relative error is 2.67%for pure hydrocarbons,2.99%for C1/C3 mixture,7.85%for C1/C4 mixture,and 8.47%for pure H2S.These satisfactory predictions demonstrate that the MD simulation approach is reliable to predict natural-and acid-gases thermodynamic properties.The validated model is further used to generate data for the study of the EOS with pressure up to 276 MPa and temperature up to 573 K.Our results also reveal that the Dranchuk&Abou-Kassem(DAK)EOS is capable of predicting natural gas compressibility to a satisfactory accuracy at x HPHT conditions,which extends the confidence range of the DAK EOS.
基金supported by Gansu Provincial Critical Patented Projects of China(Grant No. 1101ZSB117)Gansu Provincial Science and Technology Pillar Program of China(Grant No. 1002ZSB018)
文摘The castings defects are affected by the melting volume change rate of material. The change rate has an important effect on running safety of the high temperature thermal storage chamber, too. But the characteristics of existing measuring installations are complex structure, troublesome operation and low precision. In order to measure the melting volume change rate of material accurately and conveniently, a self-designed measuring instrument, self-heating probe instrument, and measuring method are described. Temperature in heating cavity is controlled by PID temperature controller; melting volume change rate υ and molten density are calculated based on the melt volume which is measured by the instrument. Positive and negative υ represent expansion and shrinkage of the sample volume after melting, respectively. Taking eutectic LiF+CaF2 for example, its melting volume change rate and melting density at 1 123 K are -20.6% and 2 651 kg/m–3 measured by this instrument, which is only 0.71% smaller than literature value. Density and melting volume change rate of industry pure aluminum at 973 K and analysis pure NaCl at 1 123 K are detected by the instrument too. The measure results are agreed with report values. Measuring error sources are analyzed and several improving measures are proposed. In theory, the measuring errors of the change rate and molten density which are measured by the self-designed instrument is nearly 1/20-1/50 of that measured by the refitted mandril thermal expansion instrument. The self-designed instrument and method have the advantages of simple structure, being easy to operate, extensive applicability for material, relatively high accuracy, and most importantly, temperature and sample vapor pressure have little effect on the measurement accuracy. The presented instrument and method solve the problems of complicated structure and procedures, and large measuring errors for the samples with high vapor pressure by existing installations.
文摘P-wave velocities in the rocks of Dabieshan, central China were measured at pressures up to 5.0 GPa and temperatures up to 1 300℃. The ultrahigh pressure eclogites have the highest density and P-wave velocity (Vp) and lower anisotropy. Pressure derivatives of the eclogites range from 0. 22 to 0. 33 km. s-1 GPa-1. Average temperature derivative of the eclogites is - 3. 41×10-4 km. s-1. °C -1. The density and VP of the eclogites imply that there will be two united possibilities related to crust-mantle recycling after the eclogite formed in the deep lithosphere. One is that some eclogites in the deep lithosphere were detached and sunk into deeper mantle due to their denser density. Another is that some eclogites returned to the crust and exposed to the surface.Small amounts (<12%) of eclogites may be still exist in the deep crust beneath Dabieshan based on our calculation.
文摘The effect of high density pulse electric current (HDPEC) on the solidification structure of the low temperature melt(LTM) of commercial A356 alloy was investigated. In the experiments, the HDPEC was discharged in the LTM (953?K, 903?K and 873?K). By the control experiments, the results showed that the solidification structure of the LTM of A356 alloy is refined apparently when the HDPEC is discharged in low temperature melt. However, the holding time of melt treated has an adverse effect on the solidification structure. The longer the holding time of the melt treated with HDPEC, the coarser the microstructure. With the same discharge voltage, the lower the temperature of LTM, the more obscure the refinement of solidification structure. Finally, the mechanism of microstructure refining by HDPEC was analyzed.
基金Project(090302012)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(50934005)supported by the National Natural Science Foundation of China
文摘Laboratory-scale carbon anodes were produced by a new method of high temperature mould pressing, and their physico-chemical properties were studied. The influence of mould pressing conditions and coal pitch addition on the bulk density, crushing strength, and oxidation resistance was analyzed. The mierostructure of carbon anodes was investigated by scanning electron microscopy (SEM), and the mechanism of producing carbon anodes by high-temperature mould pressing was analyzed. The results show that when the anodes are produced by high-temperature mould pressing, coal pitch can expand into the coke particles and fill the pores inside the particles, which is beneficial for improving the quality of prebaked anodes. The bulk density of carbon anodes is 1.64-1.66 g/cm3, which is 0.08-0.12 g/cm3 higher than that of industrial anodes, and the oxidation resistance of carbon anodes is also significantly improved.
基金the funding from Natural Science Foundation of China(No.52003163)Guangdong Basic and Applied Basic Research Foundation(No.2022A1515010670)+1 种基金Science and Technology Innovation Commission of Shenzhen(Nos.KQTD20170810105439418 and 20200812112006001)NTUT-SZU Joint Research Program(Nos.2022005 and 2022015)
文摘Developing a simple scalable method to fabricate electrodes with high capacity and wide voltage range is desired for the real use of electrochemical supercapacitors.Herein,we synthesized amorphous NiCo-LDH nanosheets vertically aligned on activated carbon cloth substrate,which was in situ transformed from Co-metal-organic framework materials nano-columns by a simple ion exchange process at room temperature.Due to the amorphous and vertically aligned ultrathin structure of NiCo-LDH,the NiCo-LDH/activated carbon cloth composites present high areal capacities of 3770 and 1480 mF cm^(-2)as cathode and anode at 2 mA cm^(-2),and 79.5%and 80%capacity have been preserved at 50 mA cm^(-2).In the meantime,they all showed excellent cycling performance with negligible change after>10000 cycles.By fabricating them into an asymmetric supercapacitor,the device achieves high energy densities(5.61 mWh cm^(-2)and 0.352 mW cm^(-3)).This work provides an innovative strategy for simplifying the design of supercapacitors as well as providing a new understanding of improving the rate capabilities/cycling stability of NiCo-LDH materials.
基金supported by the Innovation Platform of Energy Storage Engineering and New Material in Zhejiang University(No.K19-534202-002)the National Natural Science Foundation of China(No.21978261)the Zhejiang Provincial Key Research and Development Program of China(No.2021C01030).
文摘Lithium-sulfur batteries(LSBs)can work at high temperatures,but they suffer from poor cycle life stability due to the“shuttle effect”of polysulfides.In this study,pollen-derived porous carbon/cuprous phosphide(PC/Cu_(3)P)hybrids were rationally synthesized using a one-step carbonization method using pollen as the source material,acting as the sulfur host for LSBs.In the hybrid,polar Cu_(3)P can markedly inhibit the“shuttle effect”by regulating the adsorption ability toward polysulfides,as confirmed by theoretical calculations and experimental tests.As an example,the camellia pollen porous carbon(CPC)/Cu_(3)P/S electrode shows a high capacity of 1205.6 mAh g^(−1) at 0.1 C,an ultralow capacity decay rate of 0.038%per cycle after 1000 cycles at 1 C,and a rather high initial Coulombic efficiency of 98.5%.The CPC/Cu_(3)P LSBs can work well at high temperatures,having a high capacity of 545.9 mAh g^(−1) at 1 C even at 150℃.The strategy of the PC/Cu_(3)P hybrid proposed in this study is expected to be an ideal cathode for ultrastable high-temperature LSBs.We believe that this strategy is universal and worthy of in-depth development for the next generation energy storage devices.
基金Funded by the National Natural Science Foundation of China(No.51472206)the National ITER Program of China(2015GB115001)the Program for Innovative Research Team in Shaanxi Province(No.2013KCT-07)
文摘Powder in tube process(PIT) was adopted for the fabrication of single filament Bi-2223 tapes, and a heat treatment process including the first heat treatment(HT1), intermediate rolling(IR), and second heat treatment(HT2) was performed. The phase evolution mechanism and microstructure changes during these heat treatment processes were systematically discussed. The influences of HT1 parameters on the phase evolution process of Bi-2223 tapes were discussed. With the optimized HT1 process, a proper Bi-2223 content of about 90% was achieved. HT2 process was also optimized by adding a post annealing process. An obvious increase of current capacity was obtained due to the enhancement of intergrain connections. Single filament Bi-2223 tapes with the critical current of Ic-90 A were fabricated with the optimized sintering process.
文摘With low temperature solution based processes and excellent mechanical flexibility,the organic field effect transistor(OFET)technology is promising for creating a wide range of emerging flexible electronics towards applications of internet of everything.However,despite of remarkable progress in developing high performance organic semiconductor materials.
文摘The description of experimentally observed phenomenon of abnormally high electrical conductivity—'superconductivity' (SC) at the room and higher temperatures is represented. The effect was observed in metallic monospirals of small radius curvature with high density and regular distribution of dislocations. Transition into state of SC has been observed experimentally in the range from –50 up to 3000°C at the density of transmitting current up to 2·109 A/cm2. The experimental data confirming the watched phenomenon are represented. The explanations of this phenomenon are being proposed in the framework of the dislocation model.
基金financially supported by Guangdong Basic and Applied Basic Research Foundation (No. 2020B1515120074)。
文摘Polymer dielectrics which possess excellent dielectric properties such as high breakdown strength,flexibility,and facile processability are considered as promising materials for advanced electrostatic capacitors.However,most dielectric polymers have unsatisfactory energy storage performances at high-temperature environments.Here,polyetherimide(PEI) nanocomposite films contained with electrospun Ba(Zr_(0.79)Ti_(0.21))O_(3) nanofibers(BZTNFs) are fabricated by common solution casting method.The dielectric properties,especially the breakdown strength of the BZTNFs/PEI nanocomposites,are characterized,yet improvement is only in the small loading ones.The energy storage performance of the 0.5 vol% and1.0 vol% BZTNFs content nanocomposite is further investigated from 25 to 150℃.With the introduction of small loading BZTNFs,the dielectric permittivity and electric displacement of the nanocomposite are improved at all evaluated temperatures.The 1.0 vol% BZTNFs/PEI possesses a maximal discharged energy density of6.05 J·cm^(-3) with high efficiency of 94.9% at 25℃,then falls to 3.34 J·cm^(-3) with efficiency of 54.6% at 150℃ for the larger remnant displacement.Apparently,the relaxation ferroelectric nanofller of BZTNFs is much effective in increasing the dielectric permittivity of nanocomposite,but its capacity to restrict the migration of the charge carriers at high temperatures is weaker than that of the nanofillers with wider bandgap.The complementation of both kinds of the nanofillers probably provides an approach to available high-temperature dielectric films.
文摘The large-scale disturbance of the spatial structure of the daytime high-latitude F-region ionosphere, caused by powerful high-frequency radio waves, pumped into the ionosphere by a groundbased ionospheric heater, is studied with the help of the numerical simulation. The mathematical model of the high-latitude ionosphere, developed earlier in the Polar Geophysical Institute, is utilized. The mathematical model takes into account the drift of the ionospheric plasma, strong magnetization of the plasma at F-layer altitudes, geomagnetic field declination, and effect of powerful high-frequency radio waves. The distributions of the ionospheric parameters were calculated on condition that an ionospheric heater, situated at the point with geographic coordinates of the HF heating facility near Tromso, Scandinavia, has been operated, with the ionospheric heater being located on the day side of the Earth. The results of the numerical simulation indicate that artificial heating of the ionosphere by powerful high-frequency waves ought to influence noticeably on the spatial structure of the daytime high-latitude F-region ionosphere in the vicinity of the ionospheric heater.
基金The project supported by National Natural Science Foundation ot China
文摘By means of critical behaviors of the dynamical fermion mass in four-fermion interaction models, we show by explicit calculations that when T = 0 the particle density will have a discontinuous jumping across the critical chemical potential μ<SUB>c</SUB> in 2D and 3D Gross-Neveu (GN) model and these physically explain the first-order feature of the corresponding symmetry restoring phase transitions. For the second-order phase transitions in the 3D GN model when T → 0 and in 4D Nambu–Jona–Lasinio (NJL) model when T = 0, it is proven that the particle density itself will be continuous across μ<SUB>c</SUB> but its derivative over the chemical potential μ will have a discontinuous jumping. The results give a physical explanation of implications of the tricritical point in the 3D GN model. The discussions also show effectiveness of the critical analysis approach of phase transitions.
文摘Geomagnetic storm is a kind of severe disturbance that lasts for more than ten hours to several tens of hours in the entire Earth’s magnetosphere. This paper uses the NRLMSISE-00 model to calculate the temperature and density data. According to the surveyed medium magnetic storm events, the characteristics of daily average density and temperature in the occurrence of magnetic storms in 2010 were studied. At the same time, high latitude meridians were taken as research objects. Divide the temperature and density characteristics at different heights. Results showed that the annual trend of density is the same for different heights, and there is an average of the average density every day on the six medium magnetic storm mountains. For the average daily temperature, each medium magnetic storm event corresponds to a temperature peak. The peak temperature on April 5 was the highest temperature throughout the year, consistent with the annual average density distribution. Due to the intensity of the magnetic storm, the temperature of a large area of bright areas rose sharply on April 12, which is also the highest in the year. At 18:00 on May 2, it was the peak time of the moderate magnetic storm event caused by CIR, but May 3 was the date of the peak temperature. This peak delay is reasonable.