Provenance of colorless and brown volcanic glass in late Pleistocene tephra layers in the Western Philippine Sea

Tephra layers in the western Philippine Sea,characterized by abundant volcanic glass shards,may provide crucial evidence on the eruption history of volcanoes and tectonic evolution of the western Pacific.A 220-ka sediment core from the Benham Rise in the western Philippine Sea offers new insights into the provenance of four intercalated tephra layers(T1–T4,in chronological order)containing either colorless or brown glass shards.Relative to primitive mantle,all glass shards are enriched in large-ion lithophile elements,such as Rb,Cs,and Pb,and depleted in high field-strength elements,such as Th,Nb,and Ta,indicating a subduction-related origin.The colorless glass shards are characterized by high SiO_(2)(>78%)and light rare earth element(LREE)contents as well as high La/Sm ratios(>9),low FeO and MgO contents(<1%),low Sr/Y(<15)and high Ba/Th ratios(>100),pointing to a rhyolitic composition and a medium-K calc-alkaline serial affinity.In contrast,the brown glass shards are characterized by lower SiO_(2)(<63%)and LREE contents,higher FeO,MgO,and CaO contents,lower La/Sm(<6)and Ba/Th(<75),and similar Sr/Y ratios(<15),indicating derivation from medium to high-K calc-alkaline andesite magma.Brown glass shards from layers T3(152 ka)and T4(172 ka)were correlated with volcanic deposits from the Taal and Laguna Caldera in the Maccolod Corridor,respectively,while the colorless glass shards from layers T1(36.5 ka)and T2(61.2 ka)were likely sourced from the Irosin Caldera in the Bicol Arc.Establishing the provenance of late Pleistocene tephra layers in the western Philippine Sea is helpful to complement a Philippine volcanic history and establish a regional tephrochronostratigraphy.

Geochemistry of volcanic glass from Mahanadi offshore region,eastern continental margin of India:Constraints on the contribution of latest Toba super-eruption

The tephra layers in multiple sediment cores from the offshore region of the Mahanadi basin in the northern Bay of Bengal were investigated for possible volcanic sources. The glass shards from those tephra layers were studied for size distribution, texture, and elemental geochemistry to establish chronostratigraphic markers for regional and global Quaternary correlation. The textural features of fine-grained(silty) volcanic glasses suggest the distal source of these tephra deposits. Major element composition with elevated SiO_(2) contents ranging between75%–76% and dominance of K_(2)O(> 4.5%) over CaO(< 0.9%) suggest ashes have originated from siliceous rhyolitic melts, similar to the petrographic composition of tephra from the Toba volcano. The bulk trace element compositions of the same glass shards were comparable with those reported in the youngest Toba tephra reported elsewhere. Likewise, the LREE-dominated chondrite normalized REE profiles of tephra from the Mahanadi basin closely resemble the characteristic REE patterns in Toba ash from other parts of the Indian Ocean and thus confirmed the contribution of the youngest Toba super-eruption for this ash layers.

Petrogenesis of the Lunar volcanic glasses and Mg-suite:constraints on a post-magma-ocean cumulate overturn

The lunar volcanic glasses and Mg-suite rocks represent the early enigmatic episodes of lunar magmatism.Due to the gravitational instability of the Fe-Ti enriched(±KREEP)layer,which is formed at the later stage of fractional crystallization,a post-magma-ocean cumulate overturn occurred contemporaneously or near-contemporaneously with the lunar magma ocean(LMO)solidification.The radioactive elements within the KREEP layer were transferred downward and provided continuous energy for the partial melting of the Moon’s interior.The melt from the Moon’s interior and those from decompression melting,in turn,provide source magma for the origin of lunar volcanic glasses and Mg-suite.However,experimental and theoretical studies on the formation process of lunar volcanic glasses and Mg-suite show that the origin of their parental magma is poorly constrained,which largely depends on the initial depth and composition of the LMO.This review examines the mineralogy,petrogenesis,and distribution of lunar volcanic glasses and Mg-suite.Combining with existing models,we constrain the degree,distribution,and timescale of lunar mantle overturn and explore their relationship with later stages of LMO differentiation.We propose an updated chemical composition of the lunar interior,which provides a useful reference for estimating the bulk composition and early differentiation of the Moon and the early Earth.

Principle of Hydrogen Isotope Geochemistry Paleo-altimeter and its Potential in Reconstructing Paleo-elevation of the Southeastern Tibetan Plateau

The reconstruction of paleo-elevation serves a dual purpose to enhance our comprehension of geodynamic processes affecting terrestrial landforms and to contribute significantly to the interpretation of atmospheric circulation and biodiversity.The oxygen(δ~(18)O_w)and deuterium(δD_w)isotopes in atmospheric precipitation are systematically depleted with the increase of altitude,which are typical and widely applicated paleo-altimeters.The utilization of hydrogen isotope of hydrous silicate minerals within the shear zone system,volcanic glass,and plant leaf wax alkanes offers valuable insights for addressing evaporation and diagenesis.In this paper,we review the principle,application conditions,and influencing factors of the hydrogen isotope paleo-altimeter.In addition,we discuss the feasibility of utilizing this technique for quantitatively estimating the paleo-elevation of the southeastern Tibetan Plateau,where multiple shear zones extend over hundred kilometers parallel to the topographic gradient.

Nature, Source and Composition of Volcanic Ash in Surficial Sediments Around the Zhongsha Islands

Volcanic detrital sediments are a unique indicator for reconstructing the petrogenetic evolution of submarine volcanic terrains. Volcanic ash in surficial sediments around the Zhongsha Islands includes three kinds of volcanogenic detritus, i.e., brown volcanic glass, colorless volcanic glass and volcanic scoria. The major element characteristics show that bimodal volcanic activity may have taken place in the northern margin of the South China Sea, with brown volcanic glass and colorless volcanic glass repre- senting the mafic end-member and felsic end-member, respectively. Fractional crystallization is the main process for magma evolu- tion. The nature of the volcanic activity implies that the origin of volcanic activity was related to extensional tectonic settings, which is corresponding to an extensional geodynamic setting in the Xisha Trench, and supports the notion, which is based on geophysical data and petrology, that there may exist a mantle plume around the Hainan Island.

Phillipsite in deep-sea sediments

A phillipsite as one of oceanic authigenic zeolites gradually forms from alteration of volcanic glass under low temperature and pressure. In this paper physical property and chemical and mineralogical compositions ofsome zeolite grains collected from the study area in the North Pacific Ocean are first comprehensively studied, andthey are defined as phillipsite. Then, statistics of grain percentage of the phillipsite widely-distributed at 35 sitesin the study area in the deep-sea sediments were made ; it has been found that they mainly occur in the two sediments: red clay and calcareous ooze, and are rich in the former. Finally, the authors preliminarily discuss the formation process of the phillipsite on the basis of this study results, together with the view points of predecessors.

Zeolite diagenesis and its control on petroleum reservoir quality of Permian in northwestern margin of Junggar Basin,China

Recently, silicate diagenesis has been the focus of many studies because of its impact on porosity and permeability in sedimentary rocks. In the process of diagenetic evolution, the crystallization, cementation, and corrosion of zeolite （as a diagenetic mineral） have different effects on properties of Permian reservoirs in the study area. In the Permian sediments in the no,inwestern margin of the Junggar Basin, Zeolite minerals have formed during diagenesis in an open hydrologic system, related to the hydration of abundant volcanic glass. Chemical property of groundwater, pH of pore water, cation property and ratios have directly influenced the transformation among various zeolites and the dissolution of zeolite mineral. The main species of zeolite include analcime, heulandite, and laumontite. Transformations of these minerals during diagenesis are： volcanic glass→ clinoptilolite→analcime→heulandite→laumontite. Corrosion of analcime obviously improved reservoir quality. Extensive heulandite cementation developed and intensively reduced reservoir pore spaces. Early zeolite cementation protected pore structure against compaction and provided substance for late dissolution. The dissolution of analcime was closely related with the organic acid recharged by hydrocarbon source rocks and the NaHCO3 type formation water in the Permian, and was sensitive to permeability of rocks. Within the CaCl2 type formation water, heulandite and laumontite were hardly dissolved. In the study area, the belt with dissolved analcime is the area for the development of secondary pores and favorable reservoirs.