The superlarge continental volcanic rock\|type uranium deposits, which were discovered abroad long ago, have not yet been reported up to now in China. This is an important problem that needs to be urgently solved by u...The superlarge continental volcanic rock\|type uranium deposits, which were discovered abroad long ago, have not yet been reported up to now in China. This is an important problem that needs to be urgently solved by uranium geologists at present. In this paper, on the basis of analyzing the metallogenic settings and geological conditions of the superlarge continental volcanic rock\|type uranium deposits discovered in the world along with the metallogenic characteristics of those of the same type in China, the space\|time distribution patterns of continental volcanics and the metallogenic potential of main tectono\|volcanic belts in China are discussed, and a synthetic conclusion has been drawn that there is a possibility to discover the superlarge continental volcanic rock\|type uranium deposits in China. Moreover, it is evidenced that the Ganhang, Nanling, Yanliao, Da Hinggan Ling and other tectono\|volcanic belts possess favorable geological conditions for the formation of ssuperlarge ore deposits of the continental volcanic rock type. The intersecting and overlapping locations of the aforementioned main belts with other tectono\|volcanic (\|intrusive) belts are the most potential areas where the superlarge continental volcanic rock\|type uranium deposits would be found.展开更多
Deep-water gravity depositional processes and evolution in arc systems have become topics of intense research focus in recent years.This study discusses the co-evolution of volcanism and deep-water gravity flow deposi...Deep-water gravity depositional processes and evolution in arc systems have become topics of intense research focus in recent years.This study discusses the co-evolution of volcanism and deep-water gravity flow deposits at the southern margin of the Junggar Basin,based on petrology,geochronology and geochemical analyses.The results show that a massive collapse of unstable sediments from the slope was triggered by volcanism,resulting in the formation of slumping gravity flows.The occurrence of volcanic beds in the slump deposits confirm that synchronous volcanism likely affected sediment instability,triggering gravity flows.The Th/Yb,Ta/Yb and Th/Ta elemental ratios,U-Pb ages of detrital zircons and paleocurrent directions indicate that the North Tianshan(NTS)island arc represents the provenance of the Qianxia Formation.Moreover,statistical data on the pyroclastic components in the gravity flow deposits reveal an intensity index of volcanism,indicating that volcanism is strongly related to gravity flow deposits,especially in terms of the type and distribution of the deposits.A model for volcanically-triggered deep-water gravity flow deposits is established,in order to provide a more in-depth understanding of the co-evolution of volcanism and gravity flow deposits within the depositional setting of the late Paleozoic NTS oceanic subduction margin in the Junggar Basin.展开更多
Long-standing controversy persists over the presence and role of iron-rich melts in the formation of volcanic rock-hosted iron deposits. Conjugate iron-rich and silica-rich melt inclusions observed in thin-sections ar...Long-standing controversy persists over the presence and role of iron-rich melts in the formation of volcanic rock-hosted iron deposits. Conjugate iron-rich and silica-rich melt inclusions observed in thin-sections are considered as direct evidence for the presence of iron-rich melt, yet unequivocal outcrop-scale evidence of iron-rich melts are still lacking in volcanic rock-hosted iron deposits. Submarine volcanic rock-hosted iron deposits, which are mainly distributed in the western and eastern Tianshan Mountains in Xinjiang, are important resources of iron ores in China, but it remains unclear whether iron-rich melts have played a role in the mineralization of such iron ores. In this study, we observed abundant iron-rich agglomerates in the brecciated andesite lava of the Heijianshan submarine volcanic rock-hosted iron deposit, Eastern Tianshan, China. The iron-rich agglomerates occur as irregular and angular masses filling fractures of the host brecciated andesite lava. They show concentric potassic alteration with silicification or epidotization rims, indicative of their formation after the wall rocks. The iron-rich agglomerates have porphyritic and hyalopilitic textures, and locally display chilled margins in the contact zone with the host rocks. These features cannot be explained by hydrothermal replacement of wall rocks (brecciated andesite lava) which is free of vesicle and amygdale, rather they indicate direct crystallization of the iron-rich agglomerates from iron-rich melts. We propose that the iron-rich agglomerates were formed by open-space filling of volatile-rich iron-rich melt in fractures of the brecciated andesite lava. The iron-rich agglomerates are compositionally similar to the wall-rock brecciated andesite lava, but have much larger variation. Based on mineral assemblages, the iron-rich agglomerates are subdivided into five types, i.e., albite-magnetite type, albite-K-feldspar- magnetite type, K-feldspar-magnetite type, epidote-magnetite type and quartz-magnetite type, representing that products formed at different stages during the evolution of a magmatic-hydrothermal system. The albite-magnetite type represents the earliest crystallization product from a residual iron- rich melt; the albite-K-feldspar-magnetite and K-feldspar-magnetite types show features of magmatic- hydrothermal transition, whereas the epidote-magnetite and quartz-magnetite types represent products of hydrothermal alteration. The occurrence of iron-rich agglomerates provides macroscopic evidence for the presence of iron-rich melts in the mineralization of the Heijianshan iron deposit. It also indicates that iron mineralization of submarine volcanic rock-hosted iron deposits is genetically related to hydrothermal fluids derived from iron-rich melts.展开更多
Precise in situ zircon U-Pb dating and Lu-Hf isotopic measurement using an LA-ICP-MS system, whole-rock major and trace element geochemistry and Sr-Nd isotope geochemistry were conducted on the volcanic host rocks of ...Precise in situ zircon U-Pb dating and Lu-Hf isotopic measurement using an LA-ICP-MS system, whole-rock major and trace element geochemistry and Sr-Nd isotope geochemistry were conducted on the volcanic host rocks of the Tongyu copper deposit on the basis of further understanding of its geological characteristics. Three zircon samples from the volcanic host rocks yielded 206Pb/238 U weighted average ages ranging from 436±4 Ma to 440±5 Ma, which are statistically indistinguishable and coeval with the ca. 440 Ma northward subduction event of the Paleo-Qinling oceanic slab. The volcanic host rocks were products of magmatic differentiation that evolved from basalt to andesite to dacite to rhyolite, forming an integrated tholeiitic island arc volcanic rock suite. The primitive mantle-normalized trace element patterns for most samples show characteristics of island arc volcanic rocks, such as relative enrichment of LILE(e.g. Th, U, Pb and La) and depletion of HFSE(e.g. Nb, Ta, Ti, Zr and Hf). Discrimination diagrams of Ta/Yb vs Th/Yb, Ta vs Th, Yb vs Th/Ta, Ta/Hf vs Th/Hf, Hf/3 vs Th vs Nb/16, La vs La/Nb and Nb vs Nb/Th all suggest that both the volcanic host rocks from the Tongyu copper deposit and the volcanic rocks from the regional Xieyuguan Group were formed in an island arc environment related to subduction of an oceanic slab. Values of ISr(0.703457 to 0.708218) and εNd(t)(-2 to 5.8) indicate that the source materials of volcanic rocks from the Tongyu copper deposit and the Xieyuguan Group originated from the metasomatised mantle wedge with possible crustal material assimilation. Most of the volcanic rock samples show good agreement with the values of typical island arc volcanic rocks in the ISr-εNd(t) diagram. The involvement of crustal-derived material in the magma of the volcanic rocks from the Tongyu copper deposit was also reflected in the zircon εHf(t) values, which range from-3.08 to 10.7, and the existence of inherited ancient xenocrystic zircon cores(2616±39 Ma and 1297±22 Ma). The mineralization of the Tongyu copper deposit shows syn-volcanic characteristics such as layered orebodies interbedded with the volcanic rock strata, thus, the zircon U-Pb age of the volcanic host rocks can approximately represent the mineralization age of the Tongyu copper deposit. Both the Meigou pluton and the volcanic host rocks were formed during the ca. 440 Ma northward subduction of the Paleo-Qinling Ocean when high oxygen fugacity aqueous hydrothermal fluid released by dehydration of the slab and the overlying sediments fluxed into the mantle wedge, triggered partial melting of the mantle wedge, and activated and extracted Cu and other ore-forming elements. The magma and ore-bearing fluid upwelled and erupted, and consequently formed the island arc volcanic rock suite and the Tongyu VHMS-type copper deposit.展开更多
Deposits of 10 volcanic events of 6 stages have been discovered by the authors after detailed field and lab studies of the Benxi and Taiyuan Formations in Shandong Province and its adjacent regions. They show certain ...Deposits of 10 volcanic events of 6 stages have been discovered by the authors after detailed field and lab studies of the Benxi and Taiyuan Formations in Shandong Province and its adjacent regions. They show certain temporal-spatial distribution characteristics. Volcanic fragments were probably derived from two different volcanic sources north and south of the North China Platform, while the magma of the two volcanic sources was probably derived from the lower crust. A new stratigraphic correlation scheme is put forward for the Benxi and Taiyuan Formations in this region on the basis of previous biostratigraphic work with the regionally widespread volcanic event layers as the marker bed for the isochronous stratigraphic correlation on a super-regional scale and in conjunction with the maximum transgressive event layers.展开更多
Recently discovered intermediate-basic volcanic rocks in the Devonian strata at Dachang, Guangxi Zhuang Autonomous Region are dominated by basalts and andesites. Most of them belong to the calc-alkali and alkali serie...Recently discovered intermediate-basic volcanic rocks in the Devonian strata at Dachang, Guangxi Zhuang Autonomous Region are dominated by basalts and andesites. Most of them belong to the calc-alkali and alkali series. Petrology and geochemistry data indicate that the volcanic rocks may be formed in a continental rift environment. The volcanic rocks are in conformable contact with the overlying and underlying wall rocks, with such typical sedimentary structures as laminated and striped ones, and the host rocks of the volcanic rocks contain lots of marine fossils such as tentaculite. Many pieces of evidence indicate that the eruption environment of the volcanic rocks is a sea-facies one. The volcanic rocks are of the LREE-enrichment type, with high ratios of light rare-earth elements to heavy rare-earth elements. In addition, they display moderately negative δEu anomalies and moderately negative δCe anomalies with a higher degree of LREE and HREE fractionation. Through the Q-cluster analysis of the REE samples, it is indicated that the ores have a closer relation with the layered volcanic rocks, and also possess a certain inheritance-consistency relationship with the layered volcanic rocks. The source of ore-forming materials may be related with volcanism. It is proposed that the ore deposit in the study area should be genetically explained as the result of marine volcano-sedimentary exhalation of hot water and late superposition-reworking.展开更多
In 2011, petroleum exploration of shallow marine deposits Carboniferous and volcanic tuff reservoir re- alized breakthroughs at Chepaizi slope in the western margin of Junggar Basin. Pal 61 well, with 855.7 949.6 m se...In 2011, petroleum exploration of shallow marine deposits Carboniferous and volcanic tuff reservoir re- alized breakthroughs at Chepaizi slope in the western margin of Junggar Basin. Pal 61 well, with 855.7 949.6 m section, in the conventional test oil obtained 6 t/d industrial oil flow. The surface viscosity is 390 mPa. s (50 ℃). The marine deposit of Carboniferous are deep oil source rocks and high-quality reservoir. Magma volcanic activity provides the basis for volcanic reservoir development and distribution. The weathering crust and secondary cracks developed volcanic tuff by strong rock weathering and dissolution of organic acids which has become top quality reservoir. Deep Permian oil-gas migrated and accumulated to high parts along Hong-Che fault belt and stratigraphic unconformity stripping. Permian and Triassic volcanic rocks or dense mudstone sedimentary cover as a regional seal for the late Carboniferous oil-gas to save critically. The seismic pre-stack time migration processing technologies for the problem of poor inner structures of Carboniferous were developed. Response of volcanic rock seismic and logging are obvious. The application imaging logging and nuclear magnetic technology achieved the qualitative identification and quantification of fracture description.展开更多
The Katelixi Cu-Zn deposit is a marine volcanic rock-type copper deposit discovered for the first time in the Tokuzidaban Group in eastern Kunlun Mountains area. It is hosted in the Lower Carboniferous Tokuzidaban Gro...The Katelixi Cu-Zn deposit is a marine volcanic rock-type copper deposit discovered for the first time in the Tokuzidaban Group in eastern Kunlun Mountains area. It is hosted in the Lower Carboniferous Tokuzidaban Group volcanic strata. The orebodies are obviously controlled by the strata and their ore-bearing rocks are a suite of greyish-green mafic tuffs, generally parallel-stratiform, stratoid and lenticular in form, occurring in limestone as well as in the contact between limestone and carbon-bearing siltstone. This ore deposit possesses distinct characteristics of marine volcanic rock sedimentaion. The geological, petrochemical and REE characteristics of its occurrence pro-vide strong evidence suggesting that this deposit is of marine volcanic rock sedimention origin, basically identical to those of some typical marine volcanic rock-type copper deposits in Xinjiang and other parts of China. Marine vol-canic rocks are well developed in the Lower Carboniferous Tokuzidaban strata in eastern Kunlun Mountains area. In addition to this deposit, we have also found a number of copper polymetallic ore deposits or occurrences in associa-tion with marine volcanc activities in many places where there is a good metallogenic prospect. A breakthrough in the understanding of ore prospecting and genesis has not only filled up the gap in prospecting this type of ore depos-its in this area, but also is of great significance in directing exploration of this type of ore deposits in this area.展开更多
Radon(Rn)and helium(He)gases from uranium decay form distinct anomalies related to buried uranium deposits.In order to trace the geochemical anomalous sources from the volcanic-related uranium deposits in deeply burie...Radon(Rn)and helium(He)gases from uranium decay form distinct anomalies related to buried uranium deposits.In order to trace the geochemical anomalous sources from the volcanic-related uranium deposits in deeply buried areas,systematical Rn contents and He isotope ratios were analyzed from the Daguanchang uranium deposit.The soil gas Rn concentrations above the deep uranium are ten times higher than those in barren areas,indicating that instantaneous Rn content measurements can be used to detect deeply buried uranium.The helium isotope ratios(^(3)He/^(4)He)of the unmineralized samples from the mineralized drill hole(ZK1)are relatively lower and uniform compared to those of the samples from no-mineral drill hole(ZK2).However,the Th and U contents of the drill core samples from ZK1 are slightly lower than those of the samples from ZK2,indicating that the lower 3He/4He ratios in ZK1 are most likely due to the addition of 4He from underlying uranium intervals.The differences in the instantaneous Rn contents are consistent with the variations in the He isotope ratios of the drill core samples.These results demonstrate that soil gas Rn and ^(3)He/^(4)He ratios are useful tracers and can indicate the existence of deeply buried volcanic-related hydrothermal uranium ores.展开更多
The sorption of the uranium(VI) ions from aqueous solutions by diethylethanolammonium organovolcanics(Kula-TURKEY) was investigated under different experimental conditions. DEEA was used to modify the surface of basal...The sorption of the uranium(VI) ions from aqueous solutions by diethylethanolammonium organovolcanics(Kula-TURKEY) was investigated under different experimental conditions. DEEA was used to modify the surface of basaltic volcanics. The characteristic of basaltic volcanic was analyzed by XRF, SEM–EDS, FTIR, and XRD. The BET surface areas of unmodified volcanics and DEEA-modified volcanics were found as 2.265 and3.689 m^2/g, respectively. The volcanic samples were treated by using different concentrations of DEEA. The adsorption of U(VI) on natural and modified volcanics was examined as a function of the contact time, initial p H of the solution, initial U(VI) concentration, and temperature.Langmuir, Freundlich, and D–R adsorption isotherms were used to describe the adsorption. While examining the adsorption percentage and distribution coefficient, these values for unmodified volcanics were found to be25% ± 0.76 and 10.08 m L/g, while the values for the DEEA-modified volcanics were 88% ± 1.04 and 220 m L/g, respectively. The pseudo-first-order and pseudo-secondorder kinetic models were used to describe the kinetic data.In this study, it can be seen that the adsorption process is suitable for the pseudo-second-order kinetic model. Various thermodynamic parameters(ΔG°, ΔH°, and ΔS°) were calculated with the thermodynamic distribution coefficients obtained at different temperatures. The sorption process was a chemical adsorption process. The results indicated that the processes are spontaneous and endothermic.展开更多
The 300±20 Ma anomalously radioactive trachytes of Wadi El Kareim, central Eastern Desert, are a significant example of U-mineralization related to the alkaline volcanics in Egypt. Extensive portable gamma-ray sp...The 300±20 Ma anomalously radioactive trachytes of Wadi El Kareim, central Eastern Desert, are a significant example of U-mineralization related to the alkaline volcanics in Egypt. Extensive portable gamma-ray spectrometric data has been utilized to identify geological factors controlling uranium mobility in the geological units along the three detailed study locations of Kab Al-Abyad, South Wadi(W) Al-Tarafawy and W. Al-Farkhah; their eT h/eU ratios averaging around 4.1, 3.7 and 5.6 respectively. Quantitative analysis with the integration of mobility maps and geological studies suggest two systems controlling U-migration within the geological units(confined system and unconfined system). In the confined system, the syngenetically formed U have experienced mobility after leaching and are redistributed in the presence of an incorporation carrier during transportation(probably as carbonate complexes). Then the retardant for uranium is achieved by sorption or by coprecipitation with the aid of Fe oxy-hydroxide, and finally the formation of immobile secondary U-bearing minerals takes place along a lithogeochemical trap. In contrast to the confined system, the unconfined one is basically lacking the lithogeochemical trap which influences the final accumulation of U-bearing minerals. The radioactivity of the trachyte rocks arises from the radioactive minerals uranophane and betauranophane with U-and/or Th-bearing minerals samarskite, Th-rich REE silicates, monazite and allanite.展开更多
The present work deals with the detailed geology,mineralogy,geochemistry,and spectrometric prospection of the felsic volcanic rocks at the Eastern Desert,Egypt of the Arabian-Nubian Shield.Felsic volcanic rocks are an...The present work deals with the detailed geology,mineralogy,geochemistry,and spectrometric prospection of the felsic volcanic rocks at the Eastern Desert,Egypt of the Arabian-Nubian Shield.Felsic volcanic rocks are an essential source for rare earth elements(REEs)and uranium occurrences in this area.They are compositionally uniform with tholeiitic to calc-alkaline affinities,peraluminous and belong to the series of rhyolite with high-K melt.They exhibit more enrichment in high field strength elements(HFSE,e.g.Zr,Ta,Nd,Th,and U)and large-ion lithophile elements(LILE,e.g.Pb and Rb)compared to the country rocks of the studied area,with REE ranging from 188.20 to 442.70 ppm and strong depletion in Ti,Sr,P with deep negative Eu oddities.The felsic volcanic rocks were mostly generated from the partial melting of quartz-amphibolite facies accreted during the Neoproterozoic.Positive oddities of Zr-U-Th for the felsic volcanic rocks determine the involvement of crustal materials.Felsic volcanic rocks are found in A-type suites of magma and represent highly fractionated rocks derived from rhyolitic magma,with insignificant interaction with continental crust in the low-pressure environment and during fractional crystallization.Felsic volcanic rocks have higher values of radioactivity in which eU range from 0.5 to 121 ppm and eTh from 1.0 to 415.10 ppm.The high values of eU and eTh can be ascribed to the mineralization of uranium and the presence of accessory minerals of radiogenic nature such as uranophane,uranothorite,zircon,and monazite.Uranophane is considered as the mineral with most enriched uranium contents in the studied felsic volcanic rocks in which(UO2=87.30 wt%).Also,they are enriched with REE-bearing accessory minerals comprising allanite,titanite,and apatite.The geological investigations of the felsic volcanic rocks in the studied areas are inappropriate to clear the feasible economic potentialities of rare earth elements and U occurrences;itemized and invaluable explorational work is as yet needed.Whilst,the environmental impact of mineralization,owing to U and Th and their radiogenic daughter products,is observed and must be elaborated minutely.展开更多
Ningwu porphyrite-type iron deposits are located in Ningwu Mesozoic volcanic basin,which belongs to the middle and lower reaches of the Yangtze River metallogenic province.The volcanic rocks can be divided into Longwa...Ningwu porphyrite-type iron deposits are located in Ningwu Mesozoic volcanic basin,which belongs to the middle and lower reaches of the Yangtze River metallogenic province.The volcanic rocks can be divided into Longwangshan,Dawangshan,Gushan and Niangniangshan Formations from early to late.All these volcanic rocks are rich in alkali,and show the similar patterns in rare earth element(REE) distribution.However,some differences can be found in the trace elements and REE patterns.The study of petrology and REE geochemical characteristics shows that these rocks are derived from the underplating of the lithospheric mantle and are contaminated by crustal materials,undergo AFC process during the magmatic evolution.展开更多
A gravity and magnetic study has been carried out along the continental part of the Cameroon Volcanic Line (CVL), with the aim to explore the possibility of ore’s presence into the basement of this region. Different ...A gravity and magnetic study has been carried out along the continental part of the Cameroon Volcanic Line (CVL), with the aim to explore the possibility of ore’s presence into the basement of this region. Different processing techniques have been applied, including the isostatic residual, the analytic signal and the Euler deconvolution to compute the Bouguer and magnetic anomalies. Following Euler solutions (result of Euler deconvolution) and the analytic signal results, four profiles crossing main structures on the isostatic residual have been used to enhance the structure of intrusions in the studied area. Despite the lack of constraints in the studied region, the results show that the basement is intruded by bodies of different density (2.57<span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">g/cm</span><sup><span style="font-family:Verdana;">3</span></sup><span style="font-family:Verdana;"> to 2.87</span></span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">g/cm</span><sup><span style="font-family:Verdana;">3</span></sup><span style="font-family:Verdana;">), different size and shape, with depths between 1 and 10 kilometers. These bodies have been interpreted as old rocks then as potential reservoirs of rare ores. In addition, volcanic rocks modeled have constituted potential reserves of other ores like graphite, sulfur, copper, iron.</span></span>展开更多
In terms of major element, trace element and REE geochemical characteristics of volcanic rocks in the area studied and by making use of the TiO\-2\|K\-2O\|P\-2O\-5, Th\|Hf\|Ta and Zr\|Nb\|Y trianglar diagrams and the ...In terms of major element, trace element and REE geochemical characteristics of volcanic rocks in the area studied and by making use of the TiO\-2\|K\-2O\|P\-2O\-5, Th\|Hf\|Ta and Zr\|Nb\|Y trianglar diagrams and the environmental discrimination diagrams of incompatible element distribution patterns, the authors have drawn some conclusions that are different from those by previous workers. It is concluded that volcanic rocks in the Laochang Ag polymetallic deposit at Lancang, Yunnan belong to continental within\|plate alkali basalts, and that their geotectonic setting seems to be at the northeastern margin of East Gondwana Land.展开更多
Large amounts of volcanic debris-avalanche deposits, which take the shape of hummocks, are distributed around the peripheries of the Laoheishan volcano and Huoshaoshan volcano in Wudalianchi World Geopark. In earlier ...Large amounts of volcanic debris-avalanche deposits, which take the shape of hummocks, are distributed around the peripheries of the Laoheishan volcano and Huoshaoshan volcano in Wudalianchi World Geopark. In earlier times, they were called "satellite volcanoes", namely, freestanding volcanoes. This paper points out that these deposits actually came from the collapse of the cones of these two volcanoes. When the lava flow spilled out at the base of the slope of the cones, the slope broke up and collapsed under the action of gravity. Later, ravines were formed on the slope. Caved slope clastics, accompanying lava flow, accumulated at the rims of the volcano cones. Although some accumulations may form very large cones, they are not volcanoes, but deposits of volcanic debris avalanches.展开更多
The Sipu region of North Guangxi is located in the southwest of the "Jiangnan Ancient Land",where there are developed the oldest stratum in southern China,the Proterozoic Sipu Group,and there are also largel...The Sipu region of North Guangxi is located in the southwest of the "Jiangnan Ancient Land",where there are developed the oldest stratum in southern China,the Proterozoic Sipu Group,and there are also largely ex-posed mafic intrusive rocks,mafic volcanic rocks and copper-nickel sulfide deposits.Both mafic intrusive rocks and volcanic rocks are rich in MgO(6.52%-26.39%),but poor in K2O(0.05%-1.00%) and TiO2(0.33%-0.89%).They are also rich in trace elements such as Rb and Ba while poor in Ta,Nb and the like.Both of them have medium con-tents of rare-earth elements,30.26×10-6-126.71×10-6,in which LREEs are slightly rich with ΣLREE/ΣHREE of 1.35-2.46,δEu 0.79-1.33,displaying weak or no δEu anomaly,with the same geochemical features.The right-inclined distribution patterns and the features show that magma would be formed at the comagmatic un-diagenetic stage.All studies show that mafic intrusive rocks and volcanic rocks are the products of the same source region evolving in different stages and times.The copper-nickel sulfide deposits are characterized by liquation,crys-tallization and fractionation of mafic rocks,and have some interrelations with mafic intrusive rocks and volcanic rocks with respect to magmatic genesis.展开更多
The Longbohe Cu deposit, which is located in the southern part of the Honghe ore-forming zone, Yunnan Province, China, belongs to a typical ore field where volcanic rocks are of wide distribution and are associated wi...The Longbohe Cu deposit, which is located in the southern part of the Honghe ore-forming zone, Yunnan Province, China, belongs to a typical ore field where volcanic rocks are of wide distribution and are associated with Cu mineralization in time and space. The volcanic rocks in the ore field, which have experienced varying degree of alteration or regional metamorphism, can be divided into three types, i.e., meta-andesite, meta-subvolcanic rock and meta-basic volcanic rock in accordance with their mineral assemblages. These three types of volcanic rocks in the ore field are relatively rich in Na and the main samples plot in the area of alkali basalts in the geochemical classification diagram. With the exception of very few elements, these three types of volcanic rocks are similar in the content of trace elements. In comparison to the basalts of different tectonic settings, the meta-volcanic rocks in the ore field are rich in high field strength elements (HFSE) such as Th, Nb, etc. and depleted in large ion lithophile elements (LILE) such as Sr, Ba, etc. and their primary mantle-normalized trace element patterns show remarkable negative Th and Nb anomalies and negative Sr and Ba anomalies. These three types of volcanic rocks are similar in REE content range and chondrite-normalized REE patterns with the exception of Eu anomaly. Various lines of evidence show that these three types of volcanic rocks in the ore field have the same source but are the products of different stages of magmatic evolution, their original magma is a product of partial melting of the metasomatically enriched mantle in the tensional tectonic setting within the continent plate, and the crystallization differentiation plays an important role in the process of magmatic evolution.展开更多
Outcrop and drill hole data show that the Jurassic coal measures in the northeastern Ordos Basin are composed mainly of the Yan’an Formation and the lowstand system tract of the Zhiluo Formation, and there is a regio...Outcrop and drill hole data show that the Jurassic coal measures in the northeastern Ordos Basin are composed mainly of the Yan’an Formation and the lowstand system tract of the Zhiluo Formation, and there is a regional unconformity between them. The Dongsheng uranium deposit is associated with the Jurassic coal measures. Research data indicate that the Jurassic coal measures in the study area have a certain hydrocarbon-generating capacity, although the metamorphic grade is low (Ro=0.40%–0.58%). In the Dongsheng region alone, the accumulative amount of generated coalbed methane (CBM) is about 2028.29 × 108 –2218.72 × 108 m3; the residual amount is about 50.92 × 108 m3, and the lost amount is about 1977 × 108 m3. Analysis of the burial history of the host rocks and the evolutionary history of the Dongsheng uranium deposit suggests that the Jurassic coal measures generated hydrocarbon mainly from Middle Jurassic to Early Crataceous, which is the main mineralization phase of the Dongsheng uranium deposit. By the Late Cretaceous, a mass of CBM dissipated due to the strong tectonic uplift, and the Dongsheng uranium deposit stepped into the preservation phase. Therefore, the low-mature hydrocarbon-containing fluid in the Jurassic coal measures not only served as a reducing agent for the formation of sandstone-type uranium deposits, but also rendered the second reduction of paleo-interlayer oxidation zone and become the primary reducing agent for ore conservation. Regional strata correlation reveals that the sandstone-type uranium reservoir at the bottom of the Zhiluo Formation is in contact with the underlying industrial coal seams in the Yan’an Formation through incision or in the form of an unconformity surface. In the Dongsheng region with poorly developed fault systems, the unconformity surface and scour surface served as the main migration pathways for low-mature hydrocarbon-containing fluid migrating to the uranium reservoir.展开更多
文摘The superlarge continental volcanic rock\|type uranium deposits, which were discovered abroad long ago, have not yet been reported up to now in China. This is an important problem that needs to be urgently solved by uranium geologists at present. In this paper, on the basis of analyzing the metallogenic settings and geological conditions of the superlarge continental volcanic rock\|type uranium deposits discovered in the world along with the metallogenic characteristics of those of the same type in China, the space\|time distribution patterns of continental volcanics and the metallogenic potential of main tectono\|volcanic belts in China are discussed, and a synthetic conclusion has been drawn that there is a possibility to discover the superlarge continental volcanic rock\|type uranium deposits in China. Moreover, it is evidenced that the Ganhang, Nanling, Yanliao, Da Hinggan Ling and other tectono\|volcanic belts possess favorable geological conditions for the formation of ssuperlarge ore deposits of the continental volcanic rock type. The intersecting and overlapping locations of the aforementioned main belts with other tectono\|volcanic (\|intrusive) belts are the most potential areas where the superlarge continental volcanic rock\|type uranium deposits would be found.
基金jointly funded by the National Natural Science Foundation of China(Grant Nos.41972120,42172129)the State Key Laboratory of Paleobiology and Stratigraphy(Nanjing Institute of Geology and Paleontology,CAS)(Grant No.173131)+1 种基金the Science and Technology Cooperation Project of the CNPC-SWPU Innovation Alliance(Grant No.2020CX050103)the China Postdoctoral Science Foundation(Grant No.2021M702720)。
文摘Deep-water gravity depositional processes and evolution in arc systems have become topics of intense research focus in recent years.This study discusses the co-evolution of volcanism and deep-water gravity flow deposits at the southern margin of the Junggar Basin,based on petrology,geochronology and geochemical analyses.The results show that a massive collapse of unstable sediments from the slope was triggered by volcanism,resulting in the formation of slumping gravity flows.The occurrence of volcanic beds in the slump deposits confirm that synchronous volcanism likely affected sediment instability,triggering gravity flows.The Th/Yb,Ta/Yb and Th/Ta elemental ratios,U-Pb ages of detrital zircons and paleocurrent directions indicate that the North Tianshan(NTS)island arc represents the provenance of the Qianxia Formation.Moreover,statistical data on the pyroclastic components in the gravity flow deposits reveal an intensity index of volcanism,indicating that volcanism is strongly related to gravity flow deposits,especially in terms of the type and distribution of the deposits.A model for volcanically-triggered deep-water gravity flow deposits is established,in order to provide a more in-depth understanding of the co-evolution of volcanism and gravity flow deposits within the depositional setting of the late Paleozoic NTS oceanic subduction margin in the Junggar Basin.
基金financially supported by the Geological Survey Program of China(grants No.K1410 and DD20160346)the National Natural Foundation of China(grants No.41672078 and 41402067)
文摘Long-standing controversy persists over the presence and role of iron-rich melts in the formation of volcanic rock-hosted iron deposits. Conjugate iron-rich and silica-rich melt inclusions observed in thin-sections are considered as direct evidence for the presence of iron-rich melt, yet unequivocal outcrop-scale evidence of iron-rich melts are still lacking in volcanic rock-hosted iron deposits. Submarine volcanic rock-hosted iron deposits, which are mainly distributed in the western and eastern Tianshan Mountains in Xinjiang, are important resources of iron ores in China, but it remains unclear whether iron-rich melts have played a role in the mineralization of such iron ores. In this study, we observed abundant iron-rich agglomerates in the brecciated andesite lava of the Heijianshan submarine volcanic rock-hosted iron deposit, Eastern Tianshan, China. The iron-rich agglomerates occur as irregular and angular masses filling fractures of the host brecciated andesite lava. They show concentric potassic alteration with silicification or epidotization rims, indicative of their formation after the wall rocks. The iron-rich agglomerates have porphyritic and hyalopilitic textures, and locally display chilled margins in the contact zone with the host rocks. These features cannot be explained by hydrothermal replacement of wall rocks (brecciated andesite lava) which is free of vesicle and amygdale, rather they indicate direct crystallization of the iron-rich agglomerates from iron-rich melts. We propose that the iron-rich agglomerates were formed by open-space filling of volatile-rich iron-rich melt in fractures of the brecciated andesite lava. The iron-rich agglomerates are compositionally similar to the wall-rock brecciated andesite lava, but have much larger variation. Based on mineral assemblages, the iron-rich agglomerates are subdivided into five types, i.e., albite-magnetite type, albite-K-feldspar- magnetite type, K-feldspar-magnetite type, epidote-magnetite type and quartz-magnetite type, representing that products formed at different stages during the evolution of a magmatic-hydrothermal system. The albite-magnetite type represents the earliest crystallization product from a residual iron- rich melt; the albite-K-feldspar-magnetite and K-feldspar-magnetite types show features of magmatic- hydrothermal transition, whereas the epidote-magnetite and quartz-magnetite types represent products of hydrothermal alteration. The occurrence of iron-rich agglomerates provides macroscopic evidence for the presence of iron-rich melts in the mineralization of the Heijianshan iron deposit. It also indicates that iron mineralization of submarine volcanic rock-hosted iron deposits is genetically related to hydrothermal fluids derived from iron-rich melts.
基金jointly supported by the National Natural Science Foundation of China(Grant Nos.41272092,41421002 and 41072068)Program for Changjiang Scholars and Innovative Research Team in University(Grant IRT1281)+1 种基金Natural Science Basic Research Program of Shaanxi Province,China(Grant No.2013JZ013)Graduate Innovation Funds of Northwest University,China(Grant No.YZZ12006)
文摘Precise in situ zircon U-Pb dating and Lu-Hf isotopic measurement using an LA-ICP-MS system, whole-rock major and trace element geochemistry and Sr-Nd isotope geochemistry were conducted on the volcanic host rocks of the Tongyu copper deposit on the basis of further understanding of its geological characteristics. Three zircon samples from the volcanic host rocks yielded 206Pb/238 U weighted average ages ranging from 436±4 Ma to 440±5 Ma, which are statistically indistinguishable and coeval with the ca. 440 Ma northward subduction event of the Paleo-Qinling oceanic slab. The volcanic host rocks were products of magmatic differentiation that evolved from basalt to andesite to dacite to rhyolite, forming an integrated tholeiitic island arc volcanic rock suite. The primitive mantle-normalized trace element patterns for most samples show characteristics of island arc volcanic rocks, such as relative enrichment of LILE(e.g. Th, U, Pb and La) and depletion of HFSE(e.g. Nb, Ta, Ti, Zr and Hf). Discrimination diagrams of Ta/Yb vs Th/Yb, Ta vs Th, Yb vs Th/Ta, Ta/Hf vs Th/Hf, Hf/3 vs Th vs Nb/16, La vs La/Nb and Nb vs Nb/Th all suggest that both the volcanic host rocks from the Tongyu copper deposit and the volcanic rocks from the regional Xieyuguan Group were formed in an island arc environment related to subduction of an oceanic slab. Values of ISr(0.703457 to 0.708218) and εNd(t)(-2 to 5.8) indicate that the source materials of volcanic rocks from the Tongyu copper deposit and the Xieyuguan Group originated from the metasomatised mantle wedge with possible crustal material assimilation. Most of the volcanic rock samples show good agreement with the values of typical island arc volcanic rocks in the ISr-εNd(t) diagram. The involvement of crustal-derived material in the magma of the volcanic rocks from the Tongyu copper deposit was also reflected in the zircon εHf(t) values, which range from-3.08 to 10.7, and the existence of inherited ancient xenocrystic zircon cores(2616±39 Ma and 1297±22 Ma). The mineralization of the Tongyu copper deposit shows syn-volcanic characteristics such as layered orebodies interbedded with the volcanic rock strata, thus, the zircon U-Pb age of the volcanic host rocks can approximately represent the mineralization age of the Tongyu copper deposit. Both the Meigou pluton and the volcanic host rocks were formed during the ca. 440 Ma northward subduction of the Paleo-Qinling Ocean when high oxygen fugacity aqueous hydrothermal fluid released by dehydration of the slab and the overlying sediments fluxed into the mantle wedge, triggered partial melting of the mantle wedge, and activated and extracted Cu and other ore-forming elements. The magma and ore-bearing fluid upwelled and erupted, and consequently formed the island arc volcanic rock suite and the Tongyu VHMS-type copper deposit.
基金This study was supported by the National Natural Science Foundation of China Grant No. 4880102
文摘Deposits of 10 volcanic events of 6 stages have been discovered by the authors after detailed field and lab studies of the Benxi and Taiyuan Formations in Shandong Province and its adjacent regions. They show certain temporal-spatial distribution characteristics. Volcanic fragments were probably derived from two different volcanic sources north and south of the North China Platform, while the magma of the two volcanic sources was probably derived from the lower crust. A new stratigraphic correlation scheme is put forward for the Benxi and Taiyuan Formations in this region on the basis of previous biostratigraphic work with the regionally widespread volcanic event layers as the marker bed for the isochronous stratigraphic correlation on a super-regional scale and in conjunction with the maximum transgressive event layers.
基金financially supported by the Applied Basic Research Projects(General Program)of Yunnan Province(2011FB015)
文摘Recently discovered intermediate-basic volcanic rocks in the Devonian strata at Dachang, Guangxi Zhuang Autonomous Region are dominated by basalts and andesites. Most of them belong to the calc-alkali and alkali series. Petrology and geochemistry data indicate that the volcanic rocks may be formed in a continental rift environment. The volcanic rocks are in conformable contact with the overlying and underlying wall rocks, with such typical sedimentary structures as laminated and striped ones, and the host rocks of the volcanic rocks contain lots of marine fossils such as tentaculite. Many pieces of evidence indicate that the eruption environment of the volcanic rocks is a sea-facies one. The volcanic rocks are of the LREE-enrichment type, with high ratios of light rare-earth elements to heavy rare-earth elements. In addition, they display moderately negative δEu anomalies and moderately negative δCe anomalies with a higher degree of LREE and HREE fractionation. Through the Q-cluster analysis of the REE samples, it is indicated that the ores have a closer relation with the layered volcanic rocks, and also possess a certain inheritance-consistency relationship with the layered volcanic rocks. The source of ore-forming materials may be related with volcanism. It is proposed that the ore deposit in the study area should be genetically explained as the result of marine volcano-sedimentary exhalation of hot water and late superposition-reworking.
基金National Planed Major S&T Projects(No.2011ZX05002-002)Scientific Research Project of Sinopec(No.P03011)Key Technology Tacking Project,Shengli Oilfield Company,Sinopec(No.YKK0808)
文摘In 2011, petroleum exploration of shallow marine deposits Carboniferous and volcanic tuff reservoir re- alized breakthroughs at Chepaizi slope in the western margin of Junggar Basin. Pal 61 well, with 855.7 949.6 m section, in the conventional test oil obtained 6 t/d industrial oil flow. The surface viscosity is 390 mPa. s (50 ℃). The marine deposit of Carboniferous are deep oil source rocks and high-quality reservoir. Magma volcanic activity provides the basis for volcanic reservoir development and distribution. The weathering crust and secondary cracks developed volcanic tuff by strong rock weathering and dissolution of organic acids which has become top quality reservoir. Deep Permian oil-gas migrated and accumulated to high parts along Hong-Che fault belt and stratigraphic unconformity stripping. Permian and Triassic volcanic rocks or dense mudstone sedimentary cover as a regional seal for the late Carboniferous oil-gas to save critically. The seismic pre-stack time migration processing technologies for the problem of poor inner structures of Carboniferous were developed. Response of volcanic rock seismic and logging are obvious. The application imaging logging and nuclear magnetic technology achieved the qualitative identification and quantification of fracture description.
基金supported finantially by the National "12 nd Five-Year Plan" Supporting Grogram (No.2011BAB06B05)the Key Orientation Project under the Knowledge Innovation Program of the Chinese Academy of Sciences (No.KZCX2-YW-107-03)
文摘The Katelixi Cu-Zn deposit is a marine volcanic rock-type copper deposit discovered for the first time in the Tokuzidaban Group in eastern Kunlun Mountains area. It is hosted in the Lower Carboniferous Tokuzidaban Group volcanic strata. The orebodies are obviously controlled by the strata and their ore-bearing rocks are a suite of greyish-green mafic tuffs, generally parallel-stratiform, stratoid and lenticular in form, occurring in limestone as well as in the contact between limestone and carbon-bearing siltstone. This ore deposit possesses distinct characteristics of marine volcanic rock sedimentaion. The geological, petrochemical and REE characteristics of its occurrence pro-vide strong evidence suggesting that this deposit is of marine volcanic rock sedimention origin, basically identical to those of some typical marine volcanic rock-type copper deposits in Xinjiang and other parts of China. Marine vol-canic rocks are well developed in the Lower Carboniferous Tokuzidaban strata in eastern Kunlun Mountains area. In addition to this deposit, we have also found a number of copper polymetallic ore deposits or occurrences in associa-tion with marine volcanc activities in many places where there is a good metallogenic prospect. A breakthrough in the understanding of ore prospecting and genesis has not only filled up the gap in prospecting this type of ore depos-its in this area, but also is of great significance in directing exploration of this type of ore deposits in this area.
基金supported by the National Key Research and Development Project of the Ministry of Science and Technology of the People’s Republic of China,“Penetrating Geochemical Exploration Technology”(No.2016YFC0600604).
文摘Radon(Rn)and helium(He)gases from uranium decay form distinct anomalies related to buried uranium deposits.In order to trace the geochemical anomalous sources from the volcanic-related uranium deposits in deeply buried areas,systematical Rn contents and He isotope ratios were analyzed from the Daguanchang uranium deposit.The soil gas Rn concentrations above the deep uranium are ten times higher than those in barren areas,indicating that instantaneous Rn content measurements can be used to detect deeply buried uranium.The helium isotope ratios(^(3)He/^(4)He)of the unmineralized samples from the mineralized drill hole(ZK1)are relatively lower and uniform compared to those of the samples from no-mineral drill hole(ZK2).However,the Th and U contents of the drill core samples from ZK1 are slightly lower than those of the samples from ZK2,indicating that the lower 3He/4He ratios in ZK1 are most likely due to the addition of 4He from underlying uranium intervals.The differences in the instantaneous Rn contents are consistent with the variations in the He isotope ratios of the drill core samples.These results demonstrate that soil gas Rn and ^(3)He/^(4)He ratios are useful tracers and can indicate the existence of deeply buried volcanic-related hydrothermal uranium ores.
基金supported by the Manisa Celal Bayar University(No.BAP 2012-005)
文摘The sorption of the uranium(VI) ions from aqueous solutions by diethylethanolammonium organovolcanics(Kula-TURKEY) was investigated under different experimental conditions. DEEA was used to modify the surface of basaltic volcanics. The characteristic of basaltic volcanic was analyzed by XRF, SEM–EDS, FTIR, and XRD. The BET surface areas of unmodified volcanics and DEEA-modified volcanics were found as 2.265 and3.689 m^2/g, respectively. The volcanic samples were treated by using different concentrations of DEEA. The adsorption of U(VI) on natural and modified volcanics was examined as a function of the contact time, initial p H of the solution, initial U(VI) concentration, and temperature.Langmuir, Freundlich, and D–R adsorption isotherms were used to describe the adsorption. While examining the adsorption percentage and distribution coefficient, these values for unmodified volcanics were found to be25% ± 0.76 and 10.08 m L/g, while the values for the DEEA-modified volcanics were 88% ± 1.04 and 220 m L/g, respectively. The pseudo-first-order and pseudo-secondorder kinetic models were used to describe the kinetic data.In this study, it can be seen that the adsorption process is suitable for the pseudo-second-order kinetic model. Various thermodynamic parameters(ΔG°, ΔH°, and ΔS°) were calculated with the thermodynamic distribution coefficients obtained at different temperatures. The sorption process was a chemical adsorption process. The results indicated that the processes are spontaneous and endothermic.
文摘The 300±20 Ma anomalously radioactive trachytes of Wadi El Kareim, central Eastern Desert, are a significant example of U-mineralization related to the alkaline volcanics in Egypt. Extensive portable gamma-ray spectrometric data has been utilized to identify geological factors controlling uranium mobility in the geological units along the three detailed study locations of Kab Al-Abyad, South Wadi(W) Al-Tarafawy and W. Al-Farkhah; their eT h/eU ratios averaging around 4.1, 3.7 and 5.6 respectively. Quantitative analysis with the integration of mobility maps and geological studies suggest two systems controlling U-migration within the geological units(confined system and unconfined system). In the confined system, the syngenetically formed U have experienced mobility after leaching and are redistributed in the presence of an incorporation carrier during transportation(probably as carbonate complexes). Then the retardant for uranium is achieved by sorption or by coprecipitation with the aid of Fe oxy-hydroxide, and finally the formation of immobile secondary U-bearing minerals takes place along a lithogeochemical trap. In contrast to the confined system, the unconfined one is basically lacking the lithogeochemical trap which influences the final accumulation of U-bearing minerals. The radioactivity of the trachyte rocks arises from the radioactive minerals uranophane and betauranophane with U-and/or Th-bearing minerals samarskite, Th-rich REE silicates, monazite and allanite.
文摘The present work deals with the detailed geology,mineralogy,geochemistry,and spectrometric prospection of the felsic volcanic rocks at the Eastern Desert,Egypt of the Arabian-Nubian Shield.Felsic volcanic rocks are an essential source for rare earth elements(REEs)and uranium occurrences in this area.They are compositionally uniform with tholeiitic to calc-alkaline affinities,peraluminous and belong to the series of rhyolite with high-K melt.They exhibit more enrichment in high field strength elements(HFSE,e.g.Zr,Ta,Nd,Th,and U)and large-ion lithophile elements(LILE,e.g.Pb and Rb)compared to the country rocks of the studied area,with REE ranging from 188.20 to 442.70 ppm and strong depletion in Ti,Sr,P with deep negative Eu oddities.The felsic volcanic rocks were mostly generated from the partial melting of quartz-amphibolite facies accreted during the Neoproterozoic.Positive oddities of Zr-U-Th for the felsic volcanic rocks determine the involvement of crustal materials.Felsic volcanic rocks are found in A-type suites of magma and represent highly fractionated rocks derived from rhyolitic magma,with insignificant interaction with continental crust in the low-pressure environment and during fractional crystallization.Felsic volcanic rocks have higher values of radioactivity in which eU range from 0.5 to 121 ppm and eTh from 1.0 to 415.10 ppm.The high values of eU and eTh can be ascribed to the mineralization of uranium and the presence of accessory minerals of radiogenic nature such as uranophane,uranothorite,zircon,and monazite.Uranophane is considered as the mineral with most enriched uranium contents in the studied felsic volcanic rocks in which(UO2=87.30 wt%).Also,they are enriched with REE-bearing accessory minerals comprising allanite,titanite,and apatite.The geological investigations of the felsic volcanic rocks in the studied areas are inappropriate to clear the feasible economic potentialities of rare earth elements and U occurrences;itemized and invaluable explorational work is as yet needed.Whilst,the environmental impact of mineralization,owing to U and Th and their radiogenic daughter products,is observed and must be elaborated minutely.
基金Project(2011BAB04D01) supported by the National Science and Technology Support Program of China
文摘Ningwu porphyrite-type iron deposits are located in Ningwu Mesozoic volcanic basin,which belongs to the middle and lower reaches of the Yangtze River metallogenic province.The volcanic rocks can be divided into Longwangshan,Dawangshan,Gushan and Niangniangshan Formations from early to late.All these volcanic rocks are rich in alkali,and show the similar patterns in rare earth element(REE) distribution.However,some differences can be found in the trace elements and REE patterns.The study of petrology and REE geochemical characteristics shows that these rocks are derived from the underplating of the lithospheric mantle and are contaminated by crustal materials,undergo AFC process during the magmatic evolution.
文摘A gravity and magnetic study has been carried out along the continental part of the Cameroon Volcanic Line (CVL), with the aim to explore the possibility of ore’s presence into the basement of this region. Different processing techniques have been applied, including the isostatic residual, the analytic signal and the Euler deconvolution to compute the Bouguer and magnetic anomalies. Following Euler solutions (result of Euler deconvolution) and the analytic signal results, four profiles crossing main structures on the isostatic residual have been used to enhance the structure of intrusions in the studied area. Despite the lack of constraints in the studied region, the results show that the basement is intruded by bodies of different density (2.57<span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">g/cm</span><sup><span style="font-family:Verdana;">3</span></sup><span style="font-family:Verdana;"> to 2.87</span></span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">g/cm</span><sup><span style="font-family:Verdana;">3</span></sup><span style="font-family:Verdana;">), different size and shape, with depths between 1 and 10 kilometers. These bodies have been interpreted as old rocks then as potential reservoirs of rare ores. In addition, volcanic rocks modeled have constituted potential reserves of other ores like graphite, sulfur, copper, iron.</span></span>
基金ThisresearchprojectwasfinanciallysupportedjointlybytheNationalNaturalScienceFoundationofChina (No .96 914 0 3)andtheImportantProjectsundertheKnowledge InnovationProgramsponsoredbytheChineseAcademyofSciences (No.KZCX2 SW 117)
文摘In terms of major element, trace element and REE geochemical characteristics of volcanic rocks in the area studied and by making use of the TiO\-2\|K\-2O\|P\-2O\-5, Th\|Hf\|Ta and Zr\|Nb\|Y trianglar diagrams and the environmental discrimination diagrams of incompatible element distribution patterns, the authors have drawn some conclusions that are different from those by previous workers. It is concluded that volcanic rocks in the Laochang Ag polymetallic deposit at Lancang, Yunnan belong to continental within\|plate alkali basalts, and that their geotectonic setting seems to be at the northeastern margin of East Gondwana Land.
文摘Large amounts of volcanic debris-avalanche deposits, which take the shape of hummocks, are distributed around the peripheries of the Laoheishan volcano and Huoshaoshan volcano in Wudalianchi World Geopark. In earlier times, they were called "satellite volcanoes", namely, freestanding volcanoes. This paper points out that these deposits actually came from the collapse of the cones of these two volcanoes. When the lava flow spilled out at the base of the slope of the cones, the slope broke up and collapsed under the action of gravity. Later, ravines were formed on the slope. Caved slope clastics, accompanying lava flow, accumulated at the rims of the volcano cones. Although some accumulations may form very large cones, they are not volcanoes, but deposits of volcanic debris avalanches.
文摘The Sipu region of North Guangxi is located in the southwest of the "Jiangnan Ancient Land",where there are developed the oldest stratum in southern China,the Proterozoic Sipu Group,and there are also largely ex-posed mafic intrusive rocks,mafic volcanic rocks and copper-nickel sulfide deposits.Both mafic intrusive rocks and volcanic rocks are rich in MgO(6.52%-26.39%),but poor in K2O(0.05%-1.00%) and TiO2(0.33%-0.89%).They are also rich in trace elements such as Rb and Ba while poor in Ta,Nb and the like.Both of them have medium con-tents of rare-earth elements,30.26×10-6-126.71×10-6,in which LREEs are slightly rich with ΣLREE/ΣHREE of 1.35-2.46,δEu 0.79-1.33,displaying weak or no δEu anomaly,with the same geochemical features.The right-inclined distribution patterns and the features show that magma would be formed at the comagmatic un-diagenetic stage.All studies show that mafic intrusive rocks and volcanic rocks are the products of the same source region evolving in different stages and times.The copper-nickel sulfide deposits are characterized by liquation,crys-tallization and fractionation of mafic rocks,and have some interrelations with mafic intrusive rocks and volcanic rocks with respect to magmatic genesis.
文摘The Longbohe Cu deposit, which is located in the southern part of the Honghe ore-forming zone, Yunnan Province, China, belongs to a typical ore field where volcanic rocks are of wide distribution and are associated with Cu mineralization in time and space. The volcanic rocks in the ore field, which have experienced varying degree of alteration or regional metamorphism, can be divided into three types, i.e., meta-andesite, meta-subvolcanic rock and meta-basic volcanic rock in accordance with their mineral assemblages. These three types of volcanic rocks in the ore field are relatively rich in Na and the main samples plot in the area of alkali basalts in the geochemical classification diagram. With the exception of very few elements, these three types of volcanic rocks are similar in the content of trace elements. In comparison to the basalts of different tectonic settings, the meta-volcanic rocks in the ore field are rich in high field strength elements (HFSE) such as Th, Nb, etc. and depleted in large ion lithophile elements (LILE) such as Sr, Ba, etc. and their primary mantle-normalized trace element patterns show remarkable negative Th and Nb anomalies and negative Sr and Ba anomalies. These three types of volcanic rocks are similar in REE content range and chondrite-normalized REE patterns with the exception of Eu anomaly. Various lines of evidence show that these three types of volcanic rocks in the ore field have the same source but are the products of different stages of magmatic evolution, their original magma is a product of partial melting of the metasomatically enriched mantle in the tensional tectonic setting within the continent plate, and the crystallization differentiation plays an important role in the process of magmatic evolution.
基金sponsored by the National Natural Science Foundation Program of China (Nos.40772072 and 40802023)the Uranium Deposit Geological Program of Bureau of Geology,CNNC,the National Important Basic Research Program of China (No.2003CB214603 and No.2015CB453003)the Dongsheng coal and uranium exploration program of Central Geological exploration Fund (No.2008150013)
文摘Outcrop and drill hole data show that the Jurassic coal measures in the northeastern Ordos Basin are composed mainly of the Yan’an Formation and the lowstand system tract of the Zhiluo Formation, and there is a regional unconformity between them. The Dongsheng uranium deposit is associated with the Jurassic coal measures. Research data indicate that the Jurassic coal measures in the study area have a certain hydrocarbon-generating capacity, although the metamorphic grade is low (Ro=0.40%–0.58%). In the Dongsheng region alone, the accumulative amount of generated coalbed methane (CBM) is about 2028.29 × 108 –2218.72 × 108 m3; the residual amount is about 50.92 × 108 m3, and the lost amount is about 1977 × 108 m3. Analysis of the burial history of the host rocks and the evolutionary history of the Dongsheng uranium deposit suggests that the Jurassic coal measures generated hydrocarbon mainly from Middle Jurassic to Early Crataceous, which is the main mineralization phase of the Dongsheng uranium deposit. By the Late Cretaceous, a mass of CBM dissipated due to the strong tectonic uplift, and the Dongsheng uranium deposit stepped into the preservation phase. Therefore, the low-mature hydrocarbon-containing fluid in the Jurassic coal measures not only served as a reducing agent for the formation of sandstone-type uranium deposits, but also rendered the second reduction of paleo-interlayer oxidation zone and become the primary reducing agent for ore conservation. Regional strata correlation reveals that the sandstone-type uranium reservoir at the bottom of the Zhiluo Formation is in contact with the underlying industrial coal seams in the Yan’an Formation through incision or in the form of an unconformity surface. In the Dongsheng region with poorly developed fault systems, the unconformity surface and scour surface served as the main migration pathways for low-mature hydrocarbon-containing fluid migrating to the uranium reservoir.