A low Reynolds number k-ε model is used in the numeri cal study on a circular semi-confined turbulent impinging jet . The result is c ompared with that of the standard k-ε model and a refined k-ε mode l, which re-c...A low Reynolds number k-ε model is used in the numeri cal study on a circular semi-confined turbulent impinging jet . The result is c ompared with that of the standard k-ε model and a refined k-ε mode l, which re-consi-dered the fluctuating pressure diffusion term in the dissipa tion rate equation (ε-equation) through modeling. It shows that the low Re ynolds number k-ε model and the standard k-ε model yield very poor performance, while the predicting ability of the refined k-ε model is mu ch improved , especially for the turbulent kinetic energy k. So it can be co ncluded that the poor performance of the standard k-ε model is owing to t he incorrect considering the effect of the fluctuating pressure diffusion term r ather than the use of the wall function near the wall just as presumed in the re ference.展开更多
Narrow fractions of light gas oils obtained from various upgrading processes of Athabasca oilsands bitumen were investigated as diesel and jet fuels. The relationship among the boiling range, cetane number, smoke poin...Narrow fractions of light gas oils obtained from various upgrading processes of Athabasca oilsands bitumen were investigated as diesel and jet fuels. The relationship among the boiling range, cetane number, smoke point, and other properties such as aromatics content, aniline point, and the sulfur and nitrogen content was also studied. The study reveals that when appropriate processes and distillation boiling ranges are selected, oilsands bitumen can produce diesel and jet fuels that meet stringent environmental regulations and future product specifications. New correlations to predict CN and smoke point were developed as a function of density, boiling ranges by simulated distillation, and mono- and total aromatics by supercritical fluid chromatography. The correlations apply to bitumen-derived middle distillates that have a wide range of boiling points.展开更多
Catalytic hydrodeoxygenation(HDO)of biomass-derived oxy-compounds to advanced hydrocarbon fuels usually requires bifunctional catalysts containing metals and acidic sites.The appropriate tuning of metal and/or acidic ...Catalytic hydrodeoxygenation(HDO)of biomass-derived oxy-compounds to advanced hydrocarbon fuels usually requires bifunctional catalysts containing metals and acidic sites.The appropriate tuning of metal and/or acidic active sites at interfaces of bifunctional catalysts can significantly improve catalyst activity and product selectivity.Here,4-trifuoromethyl salicylic acid(TFMSA),as a hydrothermal stable organic acid,was employed to tailor the bifunctional interface of Ru/γ-Al_(2)O_(3)to enhance the catalytic performance on converting lignin-derived phenols to jet fuel range cycloalkanes.More than 80%phenol was converted into cyclohexane at 230°C for 1 h over Ru/γ-Al_(2)O_(3)modified by TFMSA,which was about three times higher than that over unmodified Ru/γ-Al_(2)O_(3).X-ray diffraction(XRD),Transmission electron microscope(TEM),H2 chemisorption,and energy dispersive X-ray spectroscopy(EDS)elemental mapping results indicated that Ru nanoparticles and TFMSA were well distributed onγ-Al_(2)O_(3),and a nanoscale intimacy between Ru and TFMSA was reached.Meanwhile,Fourier transform infrared spectroscopy after pyridine adsorption(Py-FT-IR)analysis proved that Brønsted acidic sites on the catalytic interfaces of TFMSA modified Ru/γ-Al_(2)O_(3)had been improved.Moreover,the kinetic and density functional theory(DFT)results suggested that the synergistic effects of adjacent Ru nanoparticles and acidic sites were crutial for promoting the rate-limiting conversion step of phenol HDO to cyclohexane.展开更多
A new route was developed for the synthesis of renewable decalin with cyclopentanone which can be derived from lignocellulose.It was found that 1,2,3,4,5,6,7,8-octahydronaphthalene could be selectively produced by the...A new route was developed for the synthesis of renewable decalin with cyclopentanone which can be derived from lignocellulose.It was found that 1,2,3,4,5,6,7,8-octahydronaphthalene could be selectively produced by the hydrogenation/dehydration/rearrangement of [1,1-bi(cyclopentylidene)]-2-one(i.e.the selfaldol condensation product of cyclopentanone) over a dual-bed catalyst system.Among the investigated catalysts,the Ru/C and Amberlyst-15 resin exhibited the highest activities for the hydrogenation of [1,1-bi(cyclopentylidene)]-2-one to [1,1-bi(cyclopentan)]-2-ol and the dehydration/rearrangement of [1,1-bi(cyclopentan)]-2-ol to 1,2,3,4,5,6,7,8-octahydronaphthalene,respectively.Using Ru/C and Amberlyst-15 resin as the first bed and the second bed catalysts,1,2,3,4,5,6,7,8-octahydronaphthalene was directly produced in high carbon yield(83.7%) under mild conditions(393 K,1 MPa).After being hydrogenated,the1,2,3,4,5,6,7,8-octahydronaphthalene was converted to decalin which can be used as additive to improve the thermal stability and volumetric heat value of jet fuel.展开更多
Active control of wall his is important in both application and basic researches. In order to establish a solid background for the expected application,it is necessary to perform detailed studies on the base nows,on t...Active control of wall his is important in both application and basic researches. In order to establish a solid background for the expected application,it is necessary to perform detailed studies on the base nows,on their stability characteristics and on the identification technique of coherent structures. This paper is a summarizing article rather than a detailed technical report, Its main purpose is just to introduce the recent progress in the related area.展开更多
To explore further the launch mechanism of the new underwater launching technology proposed in this paper, the expansion characteristics of four wall combustion-gas jets in confined liquid space must be studied firstl...To explore further the launch mechanism of the new underwater launching technology proposed in this paper, the expansion characteristics of four wall combustion-gas jets in confined liquid space must be studied firstly. The experimental device is designed, and the high-speed digital photographic system is adopted to obtain the expansion sequence processes of Taylor cavities formed by the four wall jets. Meanwhile, the influence of the injection pressure on the axial expansion property of the four wall jets is discussed. Based on the experiments, a three-dimensional unsteady mathematical model is established to simulate the turbulent flow process of the four wall jets expanding in liquid, and the temporal and spatial distribution laws of phase, pressure, temperature, and velocity and the evolution rules of vortices are illustrated in detail. Results show that, accompanied by the jets expanding downstream, the four wall combustion-gas jets get close to each other and achieve convergence eventually under induction of the interference effect between multiple jets. Meanwhile, the heads of the Taylor cavities separate from the observation chamber wall and offset to the central axis of the observation chamber with time going on. The numerical simulation results of the four wall combustion-gas jets coincide well with the experimental data.展开更多
The aim of this study is to examine the effects of local curvature and elastic wall effects of an isothermal hot wall for the purpose of jet impingement cooling performance.Finite element method was used with ALE.Diff...The aim of this study is to examine the effects of local curvature and elastic wall effects of an isothermal hot wall for the purpose of jet impingement cooling performance.Finite element method was used with ALE.Different important parametric effects such as Re number(between 100 and 700),Ha number(between 0 and 20),elasticity(between 104 and 109),curvature of the surface(elliptic,radius ratio between 1 and 0.25) and nanoparticle volume fraction(between 0 and 0.05) on the cooling performance were investigated numerically.The results showed that the average Nu number enhances for higher Hartmann number,higher values of elastic modulus of partly flexible wall and higher nanoparticle volume fraction.When the magnetic field is imposed at the highest strength,there is an increase of3.85% in the average Nu for the curved elastic wall whereas it is 89.22% for the hot part above it,which is due to the vortex suppression effects.Nanoparticle inclusion in the base fluid improves the heat transfer rate by about 27.6% in the absence of magnetic field whereas it is 20.5% under the effects of magnetic field at Ha=20.Curvature effects become important for higher Re numbers and at Re=700,there is 14.11% variation in the average Nu between the cases with the lowest and highest radius ratio.The elastic wall effects on the heat transfer are reduced with the increased curvature of the bottom wall.展开更多
Antioxidants addition is believed as a facile and effective way to improve jet fuel thermal oxidation stability.However,amine antioxidants,as one of the most important antioxidants,have not received sufficient attenti...Antioxidants addition is believed as a facile and effective way to improve jet fuel thermal oxidation stability.However,amine antioxidants,as one of the most important antioxidants,have not received sufficient attention in the field of jet fuel autoxidation yet.Herein,the inhibition efficiency and mechanism of decane and exo-tetrahydrodicyclopentadiene(THDCPD)oxidation by di-4-tert-butylphenylamine(diarylamine)was experimentally and theoretically investigated.The results show that diarylamine can significantly inhibit decane oxidation but is less efficient for THDCPD oxidation,which is attributed to the higher energy barrier of retro-carbonyl-ene reaction(rate-determining step)in THDCPD than that in decane during diarylamine regeneration.However,the addition of diarylamine will cause undesirable color change after accelerated oxidation and produce slightly more deposits during high-temperature thermal oxidative stress for both decane and THDCPD.The results provide significant implications for the future design of effective antioxidant additives for high-performance jet fuel.展开更多
This paper investigated lateral diffusion of a confined two-dimensional wall jet (air inlet height: 5 cm) through a perforated plate. We considered two plates with porosities of and . The plates were positi...This paper investigated lateral diffusion of a confined two-dimensional wall jet (air inlet height: 5 cm) through a perforated plate. We considered two plates with porosities of and . The plates were positioned at distances of 10 cm and 20 cm below the jet inlet. The experiments were realized using 2D Laser Doppler Anemometer (LDA). Different profiles of mean and fluctuating velocities are presented. The presence of a perforated plate strongly modified the airflow pattern compared to an empty enclosure. The velocities above and below the plate depend on several parameters, including the porosity and the plate’s position relative to the inlet slot and the longitudinal position. The difference between the flow velocity above and below the plates could not be related using a universal formula that depends on these parameters. We also investigated the influence of a porous media of a height of 20 cm (a stack of spheres having a diameter of 3.75 cm) located below the perforated plate. The results highlight that the porous medium strengthens the effects of the perforated plate on the flow.展开更多
Since the 1990 s, the kerosene fuel(code: JP-8) had been applied in the ground equipment provided with direct injection compression ignition engines in the U.S. Army, resulting in increased occurrence of injection pum...Since the 1990 s, the kerosene fuel(code: JP-8) had been applied in the ground equipment provided with direct injection compression ignition engines in the U.S. Army, resulting in increased occurrence of injection pump failures. Anti-wear additives must be used in the single fuel due to its poor lubricity. In the present work, lubricity improvers were selected on the basis of molecular simulation theoretically and these agents were evaluated to improve the lubricity of jet fuel using the high frequency reciprocating rig(HFRR) apparatus and the ball-on-cylinder lubricity evaluator(BOCLE). It was revealed that dimer acid with higher value of adsorption energy on the Fe(110) plane surface had more efficient lubricity promoting properties than that of naphthenic acid. The experimental results suggested that the dimer acid had a better tribological behavior compared with that of naphthenic acid used as lubricity improver of jet fuel. And addition of anti-wear additives at a dosage of 15 μg/g was able to promote the lubricity of jet fuel to a required level on BOCLE, while a higher concentration over 80 μg/g was needed to improve the lubricity to a demanded value of diesel on HFRR.展开更多
Based on a current coherent jet,this study proposes a supersonic combustion(SC)coherent jet in which the main oxygen jet is surrounded by a supersonic fuel gas.The characteristics of the proposed coherent jet are anal...Based on a current coherent jet,this study proposes a supersonic combustion(SC)coherent jet in which the main oxygen jet is surrounded by a supersonic fuel gas.The characteristics of the proposed coherent jet are analyzed using experimental methods and numerical simulations in the high-temperature environment of electric arc furnace(EAF)steelmaking.The SC coherent jet achieved stable combustion in the EAF steelmaking environment.The simulated combustion temperature of the supersonic shrouding methane gas was 2930 K,slightly below the theoretical combustion temperature of methane–oxygen gas.The high speed and temperature of the supersonic flame effectively weakened the interaction between the main oxygen jet and the external ambient gas,inhibiting the radial expansion of the main oxygen jet and maintaining its high speed and low turbulence over a long distance.These features improved the impact capacity of the coherent jet and strengthened the stirring intensity in the EAF bath.展开更多
The bubble dynamic near a rigid wall with a wall jet was investigated by codynamics(CFD)method with the volume of fluid(VOF)model,which had been validated by vious experimental data.The effects of different velocities...The bubble dynamic near a rigid wall with a wall jet was investigated by codynamics(CFD)method with the volume of fluid(VOF)model,which had been validated by vious experimental data.The effects of different velocities of the wall jet and ditances on the bubble dynamics were studied.The results show that the bubble is squjet due to more force added on the bubble.When the velocity of the wall jet increa,the wall anthe pressure along the wall at collapse time increase because of the extra push indAs the stand-off distance increases,the pressure along the wall first increases then decrethe distance from the bubble to the wall increases.展开更多
Long-chain alcohols were considered to be promising alternative fuels and fuel additives. This study was aimed at figuring out the influences of blending long-chain alcohols with jet fuel on the macroscopic spray char...Long-chain alcohols were considered to be promising alternative fuels and fuel additives. This study was aimed at figuring out the influences of blending long-chain alcohols with jet fuel on the macroscopic spray characteristic. n-Butanol and n-pentanol were chosen as tested alternative fuels. A common-rail injection system was used to create high-pressure injection conditions. The Schlieren imaging system was used to capture spray processes. Results showed that with the addition of long-chain alcohols, the spray tip penetration and the peak spray tip velocity increased, whereas the spray cone angle and the spray area decreased. Comparisons between those macroscopic spray characteristics of AKB blends and AKP blends were also conducted. Compared to AKB blends, AKP blends showed similar spray tip penetration, larger peak tip velocity, smaller spray cone angle, and smaller spray area.展开更多
One of the proposed concepts for spark ignition engines is advanced port fuel injection(APFI),which suggests using two port injectors for each cylinder.In this research,we numerically examine the capabilities of this ...One of the proposed concepts for spark ignition engines is advanced port fuel injection(APFI),which suggests using two port injectors for each cylinder.In this research,we numerically examine the capabilities of this concept in reducing fuel consumption and increasing engine performance.The results demonstrated that the use of this concept is very effective due to the use of two injectors and the possibility of reducing the spraying time and bringing the injection start time closer to the air inlet valve opening time.The maximum amount of fuel film formed on the walls is reduced by about 75%,naturally,which leads to better and more homogeneous fuel distribution inside the combustion chamber and increases combustion efficiency.The results showed that under the same boundary conditions and engine operating point,the use of two port injectors for each cylinder leads to an increase of more than 20%of the maximum combustion chamber pressure and about 4%combustion efficiency.On the other hand,fuel film formation becomes worse in cold conditions.So in this study,the capabilities of this concept in cold conditions were investigated too.Investigations have shown that the advanced port fuel injection,unlike conventional engines,is almost insensitive to inlet temperature changes.展开更多
In this work,a“cyclopentanone-vanillin”strategy was proposed for the preparation of jet fuel range cycloalkanes from lignocellulose-derived ketones and lignin-derived aldehydes via aldol condensation and hydrodeoxyg...In this work,a“cyclopentanone-vanillin”strategy was proposed for the preparation of jet fuel range cycloalkanes from lignocellulose-derived ketones and lignin-derived aldehydes via aldol condensation and hydrodeoxygenation(HDO).Ethanolamine lactate ionic liquid(LAIL)exhibited excellent catalytic activity in the aldol condensation of cyclopentanone and vanillin.Desired mono-condensation and bicondensation products were obtained with yield of 95.2%at 100℃.It is found that the synergy effects between amino group of ethanolamine and hydroxyl group of lactic acid play a key role in the aldol condensation.The condensation products were converted into cycloalkanes by HDO over 5%Pd/Nb_(2)O_(5)catalyst.The density of the obtained HDO products is 0.89 g/cm^(3)and the freezing point is lower than-60℃.These results suggest that the resulted cycloalkanes can be used as additives to improve the density and low-temperature fluidity of the jet fuels.展开更多
A numerical model of a coupled bubble jet and wall was built on the assumption of potential flow and calculated by the boundary integral method. A three-dimensional computing program was then developed. Starting with ...A numerical model of a coupled bubble jet and wall was built on the assumption of potential flow and calculated by the boundary integral method. A three-dimensional computing program was then developed. Starting with the basic phenomenon of the interaction between a bubble and a wall, the dynamics of bubbles near rigid walls were studied systematically with the program. Calculated results agreed well with experimental results. The relationship between the Bjerknes effect of a wall and characteristic parameters was then studied and the calculated results of various cases were compared and discussed with the Blake criterion based on the Kelvin-impulse theory. Our analyses show that the angle of the jet’s direction and the pressure on the rigid wall have a close relationship with collapse force and the bubble’s characteristic parameters. From this, the application range of Blake criterion can be determined. This paper aims to provide a basis for future research on the dynamics of bubbles near a wall.展开更多
The critical heat flux (CHF) in the forced convective boiling with a wall jet has been investigated.The experiments of CHF with a wall jet have been performed over a wide range of ρ l/ρ g=6.6-1 603 and ΔT sub =0-60...The critical heat flux (CHF) in the forced convective boiling with a wall jet has been investigated.The experiments of CHF with a wall jet have been performed over a wide range of ρ l/ρ g=6.6-1 603 and ΔT sub =0-60 K. The mechanism on CHF is discussed and a CHF model based on heat balance in sublayer can provide a good clue for analyzing and deriving CHF.Finally,a generalized correlation is presented, which can predict CHF for saturated and subcooled conditions.展开更多
RP-3 jet fuel could be an alternative fuel for diesel engines.In this study,the injection characteristics of RP-3jet fuel under single and split injection strategies were investigated and compared with diesel fuel.The...RP-3 jet fuel could be an alternative fuel for diesel engines.In this study,the injection characteristics of RP-3jet fuel under single and split injection strategies were investigated and compared with diesel fuel.The experimental results indicate that RP-3 jet fuel has slightly shorter injection delay time than diesel fuel,but this difference is negligible in actual engine operations.Further,although the lower density and viscosity of RP-3 jet fuel lead to higher volumetric injection rates and cycle-based injection quantities,the cycle-based injection mass and the mass injection rates at the stable injection stage of RP-3 jet fuel are close to or slightly lower than those of diesel fuel.Based on these experimental observations,it could be concluded that fuel physical properties are the secondary factor influencing the injection characteristics in both single and split injection strategies,as RP-3 jet fuel and diesel fuel are taken for comparison.展开更多
When performing numerical modeling of fluid flows where a clear medium is adjacent to a porous medium, a degree of difficulty related to the condition at the interface between the two media, where slip velocity exists...When performing numerical modeling of fluid flows where a clear medium is adjacent to a porous medium, a degree of difficulty related to the condition at the interface between the two media, where slip velocity exists, is encountered. A similar situation can be found when a jet flow interacts with a perforated plate. The numerical modeling of a perforated plate by meshing in detail each hole is most often impossible in a practical case (many holes with different shapes). Therefore, perforated plates are often modeled as porous zones with a simplified hypothesis based on pressure losses related to the normal flow through the plate. Nevertheless, previous investigations of flow over permeable walls highlight the impossibility of deducing a universal analytical law governing the slip velocity coefficient since the latter depends on many parameters such as the Reynolds number, porosity, interface structure, design of perforations, and flow direction. This makes the modeling of such a configuration difficult. The present study proposes an original numerical interface law for a perforated plate. It is used to model the turbulent jet flow interacting with a perforated plate considered as a fictitious porous medium without a detailed description of the perforations. It considers the normal and tangential effects of the flow over the plate. Validation of the model is realized through comparison with experimental data.展开更多
A space-dispersed double-wall jet combustion system was developed by adopting the wall-guiding spray method and the stratification theory.The experimental test was carried out to optimize the structural parameters of ...A space-dispersed double-wall jet combustion system was developed by adopting the wall-guiding spray method and the stratification theory.The experimental test was carried out to optimize the structural parameters of the diesel-engine combustion system,including chamber structure,swirl ratio of cylinder head,included angle of jet orifice,number and diameter of jet orifice,fuel injection pressure and timing.The effect of double-wall jet combustion system on combustion and engine performance was tested to obtain the best performance indexes,and the double-wall jet combustion system was compared to the prototype.The results show that NOx is reduced from 712 PPm to 487 PPm at 2 100 r/min,and from 593 PPm to 369 PPm at 3 000 r/min,which are reduced by 31.6% and 37.7%,respectively.The smoke intensity was reduced form 3.67 BSU to 2.1 BSU,and the oil consumption was reduced from 240.5 g/(kW·h) to 225.4 g/(kW·h),which was decreased by 6.3% at low speed.The pressure in the cylinder was obviously reduced from 115 bar to 108 bar,which was reduced by 6%.展开更多
文摘A low Reynolds number k-ε model is used in the numeri cal study on a circular semi-confined turbulent impinging jet . The result is c ompared with that of the standard k-ε model and a refined k-ε mode l, which re-consi-dered the fluctuating pressure diffusion term in the dissipa tion rate equation (ε-equation) through modeling. It shows that the low Re ynolds number k-ε model and the standard k-ε model yield very poor performance, while the predicting ability of the refined k-ε model is mu ch improved , especially for the turbulent kinetic energy k. So it can be co ncluded that the poor performance of the standard k-ε model is owing to t he incorrect considering the effect of the fluctuating pressure diffusion term r ather than the use of the wall function near the wall just as presumed in the re ference.
文摘Narrow fractions of light gas oils obtained from various upgrading processes of Athabasca oilsands bitumen were investigated as diesel and jet fuels. The relationship among the boiling range, cetane number, smoke point, and other properties such as aromatics content, aniline point, and the sulfur and nitrogen content was also studied. The study reveals that when appropriate processes and distillation boiling ranges are selected, oilsands bitumen can produce diesel and jet fuels that meet stringent environmental regulations and future product specifications. New correlations to predict CN and smoke point were developed as a function of density, boiling ranges by simulated distillation, and mono- and total aromatics by supercritical fluid chromatography. The correlations apply to bitumen-derived middle distillates that have a wide range of boiling points.
基金supported by the National Key R&D Program of China(2018YFB1501500)the 2115 Talent Development Program of China Agricultural University+3 种基金the National Natural Science Foundation of China(21903001)the Natural Science Foundation of Anhui Province(1908085QB58)the Chinese Universities Scientific Fund(2020TC116)the Research Innovation Fund for Graduate Students of CAU(2020XYZC05A)。
文摘Catalytic hydrodeoxygenation(HDO)of biomass-derived oxy-compounds to advanced hydrocarbon fuels usually requires bifunctional catalysts containing metals and acidic sites.The appropriate tuning of metal and/or acidic active sites at interfaces of bifunctional catalysts can significantly improve catalyst activity and product selectivity.Here,4-trifuoromethyl salicylic acid(TFMSA),as a hydrothermal stable organic acid,was employed to tailor the bifunctional interface of Ru/γ-Al_(2)O_(3)to enhance the catalytic performance on converting lignin-derived phenols to jet fuel range cycloalkanes.More than 80%phenol was converted into cyclohexane at 230°C for 1 h over Ru/γ-Al_(2)O_(3)modified by TFMSA,which was about three times higher than that over unmodified Ru/γ-Al_(2)O_(3).X-ray diffraction(XRD),Transmission electron microscope(TEM),H2 chemisorption,and energy dispersive X-ray spectroscopy(EDS)elemental mapping results indicated that Ru nanoparticles and TFMSA were well distributed onγ-Al_(2)O_(3),and a nanoscale intimacy between Ru and TFMSA was reached.Meanwhile,Fourier transform infrared spectroscopy after pyridine adsorption(Py-FT-IR)analysis proved that Brønsted acidic sites on the catalytic interfaces of TFMSA modified Ru/γ-Al_(2)O_(3)had been improved.Moreover,the kinetic and density functional theory(DFT)results suggested that the synergistic effects of adjacent Ru nanoparticles and acidic sites were crutial for promoting the rate-limiting conversion step of phenol HDO to cyclohexane.
基金funded by the National Natural Science Foundation of China (nos.21776273 21721004+6 种基金 21690080 21690082)the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB17020100)the National Key Projects for Fundamental Research and Development of China (2016YFA0202801)Dalian Science Foundation for Distinguished Young Scholars (no.2015R005)Department of Science and Technology of Liaoning Province (under contract of 2015020086-101)100-talent project of Dalian Institute of Chemical Physics (DICP)
文摘A new route was developed for the synthesis of renewable decalin with cyclopentanone which can be derived from lignocellulose.It was found that 1,2,3,4,5,6,7,8-octahydronaphthalene could be selectively produced by the hydrogenation/dehydration/rearrangement of [1,1-bi(cyclopentylidene)]-2-one(i.e.the selfaldol condensation product of cyclopentanone) over a dual-bed catalyst system.Among the investigated catalysts,the Ru/C and Amberlyst-15 resin exhibited the highest activities for the hydrogenation of [1,1-bi(cyclopentylidene)]-2-one to [1,1-bi(cyclopentan)]-2-ol and the dehydration/rearrangement of [1,1-bi(cyclopentan)]-2-ol to 1,2,3,4,5,6,7,8-octahydronaphthalene,respectively.Using Ru/C and Amberlyst-15 resin as the first bed and the second bed catalysts,1,2,3,4,5,6,7,8-octahydronaphthalene was directly produced in high carbon yield(83.7%) under mild conditions(393 K,1 MPa).After being hydrogenated,the1,2,3,4,5,6,7,8-octahydronaphthalene was converted to decalin which can be used as additive to improve the thermal stability and volumetric heat value of jet fuel.
文摘Active control of wall his is important in both application and basic researches. In order to establish a solid background for the expected application,it is necessary to perform detailed studies on the base nows,on their stability characteristics and on the identification technique of coherent structures. This paper is a summarizing article rather than a detailed technical report, Its main purpose is just to introduce the recent progress in the related area.
基金supported by the National Natural Science Foundation of China (Grant 11372139)
文摘To explore further the launch mechanism of the new underwater launching technology proposed in this paper, the expansion characteristics of four wall combustion-gas jets in confined liquid space must be studied firstly. The experimental device is designed, and the high-speed digital photographic system is adopted to obtain the expansion sequence processes of Taylor cavities formed by the four wall jets. Meanwhile, the influence of the injection pressure on the axial expansion property of the four wall jets is discussed. Based on the experiments, a three-dimensional unsteady mathematical model is established to simulate the turbulent flow process of the four wall jets expanding in liquid, and the temporal and spatial distribution laws of phase, pressure, temperature, and velocity and the evolution rules of vortices are illustrated in detail. Results show that, accompanied by the jets expanding downstream, the four wall combustion-gas jets get close to each other and achieve convergence eventually under induction of the interference effect between multiple jets. Meanwhile, the heads of the Taylor cavities separate from the observation chamber wall and offset to the central axis of the observation chamber with time going on. The numerical simulation results of the four wall combustion-gas jets coincide well with the experimental data.
文摘The aim of this study is to examine the effects of local curvature and elastic wall effects of an isothermal hot wall for the purpose of jet impingement cooling performance.Finite element method was used with ALE.Different important parametric effects such as Re number(between 100 and 700),Ha number(between 0 and 20),elasticity(between 104 and 109),curvature of the surface(elliptic,radius ratio between 1 and 0.25) and nanoparticle volume fraction(between 0 and 0.05) on the cooling performance were investigated numerically.The results showed that the average Nu number enhances for higher Hartmann number,higher values of elastic modulus of partly flexible wall and higher nanoparticle volume fraction.When the magnetic field is imposed at the highest strength,there is an increase of3.85% in the average Nu for the curved elastic wall whereas it is 89.22% for the hot part above it,which is due to the vortex suppression effects.Nanoparticle inclusion in the base fluid improves the heat transfer rate by about 27.6% in the absence of magnetic field whereas it is 20.5% under the effects of magnetic field at Ha=20.Curvature effects become important for higher Re numbers and at Re=700,there is 14.11% variation in the average Nu between the cases with the lowest and highest radius ratio.The elastic wall effects on the heat transfer are reduced with the increased curvature of the bottom wall.
基金the financial support from the Postdoctoral Science Foundation of China(2021M702810)the Haihe Laboratory of Sustainable Chemical Transformations(CYZC202103)the National Natural Science Foundation of China(21978200 and 22222808)。
文摘Antioxidants addition is believed as a facile and effective way to improve jet fuel thermal oxidation stability.However,amine antioxidants,as one of the most important antioxidants,have not received sufficient attention in the field of jet fuel autoxidation yet.Herein,the inhibition efficiency and mechanism of decane and exo-tetrahydrodicyclopentadiene(THDCPD)oxidation by di-4-tert-butylphenylamine(diarylamine)was experimentally and theoretically investigated.The results show that diarylamine can significantly inhibit decane oxidation but is less efficient for THDCPD oxidation,which is attributed to the higher energy barrier of retro-carbonyl-ene reaction(rate-determining step)in THDCPD than that in decane during diarylamine regeneration.However,the addition of diarylamine will cause undesirable color change after accelerated oxidation and produce slightly more deposits during high-temperature thermal oxidative stress for both decane and THDCPD.The results provide significant implications for the future design of effective antioxidant additives for high-performance jet fuel.
文摘This paper investigated lateral diffusion of a confined two-dimensional wall jet (air inlet height: 5 cm) through a perforated plate. We considered two plates with porosities of and . The plates were positioned at distances of 10 cm and 20 cm below the jet inlet. The experiments were realized using 2D Laser Doppler Anemometer (LDA). Different profiles of mean and fluctuating velocities are presented. The presence of a perforated plate strongly modified the airflow pattern compared to an empty enclosure. The velocities above and below the plate depend on several parameters, including the porosity and the plate’s position relative to the inlet slot and the longitudinal position. The difference between the flow velocity above and below the plates could not be related using a universal formula that depends on these parameters. We also investigated the influence of a porous media of a height of 20 cm (a stack of spheres having a diameter of 3.75 cm) located below the perforated plate. The results highlight that the porous medium strengthens the effects of the perforated plate on the flow.
文摘Since the 1990 s, the kerosene fuel(code: JP-8) had been applied in the ground equipment provided with direct injection compression ignition engines in the U.S. Army, resulting in increased occurrence of injection pump failures. Anti-wear additives must be used in the single fuel due to its poor lubricity. In the present work, lubricity improvers were selected on the basis of molecular simulation theoretically and these agents were evaluated to improve the lubricity of jet fuel using the high frequency reciprocating rig(HFRR) apparatus and the ball-on-cylinder lubricity evaluator(BOCLE). It was revealed that dimer acid with higher value of adsorption energy on the Fe(110) plane surface had more efficient lubricity promoting properties than that of naphthenic acid. The experimental results suggested that the dimer acid had a better tribological behavior compared with that of naphthenic acid used as lubricity improver of jet fuel. And addition of anti-wear additives at a dosage of 15 μg/g was able to promote the lubricity of jet fuel to a required level on BOCLE, while a higher concentration over 80 μg/g was needed to improve the lubricity to a demanded value of diesel on HFRR.
基金financially supported by Fundamental Research Funds for the Central Universities (No. FRF-GF18-008B)
文摘Based on a current coherent jet,this study proposes a supersonic combustion(SC)coherent jet in which the main oxygen jet is surrounded by a supersonic fuel gas.The characteristics of the proposed coherent jet are analyzed using experimental methods and numerical simulations in the high-temperature environment of electric arc furnace(EAF)steelmaking.The SC coherent jet achieved stable combustion in the EAF steelmaking environment.The simulated combustion temperature of the supersonic shrouding methane gas was 2930 K,slightly below the theoretical combustion temperature of methane–oxygen gas.The high speed and temperature of the supersonic flame effectively weakened the interaction between the main oxygen jet and the external ambient gas,inhibiting the radial expansion of the main oxygen jet and maintaining its high speed and low turbulence over a long distance.These features improved the impact capacity of the coherent jet and strengthened the stirring intensity in the EAF bath.
基金National Natural Science Foundation of China(51422906,51609177)Key Projects in the National Science & Technology Pillar Program During the Twelfth Five-Year Plan Period(2012BAD08B03)
文摘The bubble dynamic near a rigid wall with a wall jet was investigated by codynamics(CFD)method with the volume of fluid(VOF)model,which had been validated by vious experimental data.The effects of different velocities of the wall jet and ditances on the bubble dynamics were studied.The results show that the bubble is squjet due to more force added on the bubble.When the velocity of the wall jet increa,the wall anthe pressure along the wall at collapse time increase because of the extra push indAs the stand-off distance increases,the pressure along the wall first increases then decrethe distance from the bubble to the wall increases.
基金supported by the National Natural Science Foundation of China(No.51376171)
文摘Long-chain alcohols were considered to be promising alternative fuels and fuel additives. This study was aimed at figuring out the influences of blending long-chain alcohols with jet fuel on the macroscopic spray characteristic. n-Butanol and n-pentanol were chosen as tested alternative fuels. A common-rail injection system was used to create high-pressure injection conditions. The Schlieren imaging system was used to capture spray processes. Results showed that with the addition of long-chain alcohols, the spray tip penetration and the peak spray tip velocity increased, whereas the spray cone angle and the spray area decreased. Comparisons between those macroscopic spray characteristics of AKB blends and AKP blends were also conducted. Compared to AKB blends, AKP blends showed similar spray tip penetration, larger peak tip velocity, smaller spray cone angle, and smaller spray area.
文摘One of the proposed concepts for spark ignition engines is advanced port fuel injection(APFI),which suggests using two port injectors for each cylinder.In this research,we numerically examine the capabilities of this concept in reducing fuel consumption and increasing engine performance.The results demonstrated that the use of this concept is very effective due to the use of two injectors and the possibility of reducing the spraying time and bringing the injection start time closer to the air inlet valve opening time.The maximum amount of fuel film formed on the walls is reduced by about 75%,naturally,which leads to better and more homogeneous fuel distribution inside the combustion chamber and increases combustion efficiency.The results showed that under the same boundary conditions and engine operating point,the use of two port injectors for each cylinder leads to an increase of more than 20%of the maximum combustion chamber pressure and about 4%combustion efficiency.On the other hand,fuel film formation becomes worse in cold conditions.So in this study,the capabilities of this concept in cold conditions were investigated too.Investigations have shown that the advanced port fuel injection,unlike conventional engines,is almost insensitive to inlet temperature changes.
基金funded by grants from the National Natural Science Foundation of China(No.52236010,51876210)the Fundamental Research Funds for the Central Universities(No.2242022R10058)。
文摘In this work,a“cyclopentanone-vanillin”strategy was proposed for the preparation of jet fuel range cycloalkanes from lignocellulose-derived ketones and lignin-derived aldehydes via aldol condensation and hydrodeoxygenation(HDO).Ethanolamine lactate ionic liquid(LAIL)exhibited excellent catalytic activity in the aldol condensation of cyclopentanone and vanillin.Desired mono-condensation and bicondensation products were obtained with yield of 95.2%at 100℃.It is found that the synergy effects between amino group of ethanolamine and hydroxyl group of lactic acid play a key role in the aldol condensation.The condensation products were converted into cycloalkanes by HDO over 5%Pd/Nb_(2)O_(5)catalyst.The density of the obtained HDO products is 0.89 g/cm^(3)and the freezing point is lower than-60℃.These results suggest that the resulted cycloalkanes can be used as additives to improve the density and low-temperature fluidity of the jet fuels.
基金the National Natural Science Foundation of China under Grant No. 50779007the Specialized Research Fund for the Doctoral Program of Higher Education of China under Grant No. 20070217074)+1 种基金the Defence Advance Research Program of Science and Technology of Ship Industry under Grant No. 07J1.1.6Harbin Engineering University Foundation under Grant No. HEUFT07069
文摘A numerical model of a coupled bubble jet and wall was built on the assumption of potential flow and calculated by the boundary integral method. A three-dimensional computing program was then developed. Starting with the basic phenomenon of the interaction between a bubble and a wall, the dynamics of bubbles near rigid walls were studied systematically with the program. Calculated results agreed well with experimental results. The relationship between the Bjerknes effect of a wall and characteristic parameters was then studied and the calculated results of various cases were compared and discussed with the Blake criterion based on the Kelvin-impulse theory. Our analyses show that the angle of the jet’s direction and the pressure on the rigid wall have a close relationship with collapse force and the bubble’s characteristic parameters. From this, the application range of Blake criterion can be determined. This paper aims to provide a basis for future research on the dynamics of bubbles near a wall.
文摘The critical heat flux (CHF) in the forced convective boiling with a wall jet has been investigated.The experiments of CHF with a wall jet have been performed over a wide range of ρ l/ρ g=6.6-1 603 and ΔT sub =0-60 K. The mechanism on CHF is discussed and a CHF model based on heat balance in sublayer can provide a good clue for analyzing and deriving CHF.Finally,a generalized correlation is presented, which can predict CHF for saturated and subcooled conditions.
基金Project(52022058)supported by the National Natural Science Foundation of ChinaProject(19160745400)supported by the Shanghai Science and Technology Committee,China。
文摘RP-3 jet fuel could be an alternative fuel for diesel engines.In this study,the injection characteristics of RP-3jet fuel under single and split injection strategies were investigated and compared with diesel fuel.The experimental results indicate that RP-3 jet fuel has slightly shorter injection delay time than diesel fuel,but this difference is negligible in actual engine operations.Further,although the lower density and viscosity of RP-3 jet fuel lead to higher volumetric injection rates and cycle-based injection quantities,the cycle-based injection mass and the mass injection rates at the stable injection stage of RP-3 jet fuel are close to or slightly lower than those of diesel fuel.Based on these experimental observations,it could be concluded that fuel physical properties are the secondary factor influencing the injection characteristics in both single and split injection strategies,as RP-3 jet fuel and diesel fuel are taken for comparison.
文摘When performing numerical modeling of fluid flows where a clear medium is adjacent to a porous medium, a degree of difficulty related to the condition at the interface between the two media, where slip velocity exists, is encountered. A similar situation can be found when a jet flow interacts with a perforated plate. The numerical modeling of a perforated plate by meshing in detail each hole is most often impossible in a practical case (many holes with different shapes). Therefore, perforated plates are often modeled as porous zones with a simplified hypothesis based on pressure losses related to the normal flow through the plate. Nevertheless, previous investigations of flow over permeable walls highlight the impossibility of deducing a universal analytical law governing the slip velocity coefficient since the latter depends on many parameters such as the Reynolds number, porosity, interface structure, design of perforations, and flow direction. This makes the modeling of such a configuration difficult. The present study proposes an original numerical interface law for a perforated plate. It is used to model the turbulent jet flow interacting with a perforated plate considered as a fictitious porous medium without a detailed description of the perforations. It considers the normal and tangential effects of the flow over the plate. Validation of the model is realized through comparison with experimental data.
文摘A space-dispersed double-wall jet combustion system was developed by adopting the wall-guiding spray method and the stratification theory.The experimental test was carried out to optimize the structural parameters of the diesel-engine combustion system,including chamber structure,swirl ratio of cylinder head,included angle of jet orifice,number and diameter of jet orifice,fuel injection pressure and timing.The effect of double-wall jet combustion system on combustion and engine performance was tested to obtain the best performance indexes,and the double-wall jet combustion system was compared to the prototype.The results show that NOx is reduced from 712 PPm to 487 PPm at 2 100 r/min,and from 593 PPm to 369 PPm at 3 000 r/min,which are reduced by 31.6% and 37.7%,respectively.The smoke intensity was reduced form 3.67 BSU to 2.1 BSU,and the oil consumption was reduced from 240.5 g/(kW·h) to 225.4 g/(kW·h),which was decreased by 6.3% at low speed.The pressure in the cylinder was obviously reduced from 115 bar to 108 bar,which was reduced by 6%.