Waste heat recovery from hot steel slag on the production line:Numerical simulation,validation and industrial test

Waste heat recovery from hot steel slag was determined in a granular bed through the combination of numerical simulation and an industrial test method.First,the effective thermal conductivity of the granular bed was calculated.Then,the unsteady-state model was used to simulate the heat recovery under three different flow fields(O-type,S-type,and nonshielding type(Nontype)).Second,the simulation results were validated by in-situ industrial experiments.The two methods confirmed that the heat recovery efficiencies of the flow fields from high to low followed the order of Nontype,S-type,and O-type.Finally,heat recovery was carried out under the Nontype flow field in an industrial test.The heat recovery efficiency increased from~76%and~78%to~81%when the steel slag thickness decreased from 400 and 300 to 200 mm,corresponding to reductions in the steel slag mass from 3.96 and 2.97 to 1.98 t with a blower air volume of 14687 m^(3)/h.Therefore,the research results showed that numerical simulation can not only guide experiments on waste heat recovery but also optimize the flow field.Most importantly,the method proposed in this paper has achieved higher waste heat recovery from hot steel slag in industrial scale.

Off-Design Simulation of a CSP Power Plant Integrated with aWaste Heat Recovery System

Concentrating Solar Power(CSP)plants offer a promising way to generate low-emission energy.However,these plants face challenges such as reduced sunlight during winter and cloudy days,despite being located in high solar radiation areas.Furthermore,their dispatch capacities and yields can be affected by high electricity consumption,particularly at night.The present work aims to develop an off-design model that evaluates the hourly and annual performances of a parabolic trough power plant(PTPP)equipped with a waste heat recovery system.The study aims to compare the performances of this new layout with those of the conventional Andasol 1 plant,with the aim of assessing the improvements achieved in the new design.Based on the results,it can be concluded that the new layout has increased the annual generated power to almost 183 GWh(an increase of about 7.60% is achieved compared to the Andasol 1 layout that generates 169 GWh annually).Additionally,the proposed installation has achieved an efficiency of 20.55%,which represents a 7.87% increase compared to the previous design(19.05%).The Levelized Cost of Electricity(LCOE)of the new layout has been reduced by more than 5.8% compared to the Andasol 1 plant.Specifically,it has decreased from 13.11 to 12.35 c/kWh.This reduction in LCOE highlights the improved cost-effectiveness of the newlayout,making it amore economically viable option for generating electricity compared to the conventional Andasol 1 plant.

A review on current development of thermophotovoltaic technology in heat recovery

The burning of fossil fuels in industry results in significant carbon emissions,and the heat generated is often not fully utilized.For high-temperature industries,thermophotovoltaics(TPVs)is an effective method for waste heat recovery.This review covers two aspects of high-efficiency TPV systems and industrial waste heat applications.At the system level,representative results of TPV complete the systems,while selective emitters and photovoltaic cells in the last decade are compiled.The key points of components to improve the energy conversion efficiency are further analyzed,and the related micro/nano-fabrication methods are introduced.At the application level,the feasibility of TPV applications in high-temperature industries is shown from the world waste heat utilization situation.The potential of TPV in waste heat recovery and carbon neutrality is illustrated with the steel industry as an example.

A power plant for integrated waste energy recovery from liquid air energy storage and liquefied natural gas

Liquefied natural gas(LNG)is regarded as one of the cleanest fossil fuel and has experienced significant developments in recent years.The liquefaction process of natural gas is energy-intensive,while the regasification of LNG gives out a huge amount of waste energy since plenty of high grade cold energy(-160℃)from LNG is released to sea water directly in most cases,and also sometimes LNG is burned for regasification.On the other hand,liquid air energy storage(LAES)is an emerging energy storage technology for applications such as peak load shifting of power grids,which generates 30%-40%of compression heat(-200℃).Such heat could lead to energy waste if not recovered and used.The recovery of the compression heat is technically feasible but requires additional capital investment,which may not always be economically attractive.Therefore,we propose a power plant for recovering the waste cryogenic energy from LNG regasification and compression heat from the LAES.The challenge for such a power plant is the wide working temperature range between the low-temperature exergy source(-160℃)and heat source(-200℃).Nitrogen and argon are proposed as the working fluids to address the challenge.Thermodynamic analyses are carried out and the results show that the power plant could achieve a thermal efficiency of 27%and 19%and an exergy efficiency of 40%and 28%for nitrogen and argon,respectively.Here,with the nitrogen as working fluid undergoes a complete Brayton Cycle,while the argon based power plant goes through a combined Brayton and Rankine Cycle.Besides,the economic analysis shows that the payback period of this proposed system is only 2.2 years,utilizing the excess heat from a 5 MW/40 MWh LAES system.The findings suggest that the waste energy based power plant could be co-located with the LNG terminal and LAES plant,providing additional power output and reducing energy waste.

Simulation Analysis of Flue Gas Waste Heat Utilization Retrofit Based on ORC System

Recovery of waste heat from boiler flue gas is an effective way to improve energy utilization efficiency.Taking a heating station heating project as an example,the existing heating system of this heating station was analyzed for its underutilized flue gas waste heat and low energy utilization rate.Rankine cycle is an effective waste heat recovery method,and a steam boiler organic Rankine cycle(ORC)cogeneration waste heat utilization method is proposed.The system model simulation is constructed and verified.First,a thermodynamic model was constructed in MATLAB and five suitable work gases were selected to analyze the effects of evaporation temperature and condensation temperature on the network and thermal efficiency of the waste heat cycle power system.Secondly,the ORC model is invoked in TRNSYS to construct the improved cogeneration system,and the rationality of the remaining heat utilization methods is determined by calculating and analyzing the thermal performance,economy,and environmental protection of the improved system.The simulation results show that the system can generate about 552,000 kWh of electricity per year,and improving the energy utilization rate from 0.72 to 0.78.

Application of the waste heat recovery system and energy-saving in the strip continuous annealing furnace

The common problem of cold strip continuous annealing furnaces is high exhaust gas temperature and great energy consumption. Taking the cold-strip continuous annealing furnaces of Baosteel No. 4 cold mill plant as an example, several waste heat recovery systems in the annealing furnaces are compared and their advantages and disadvantages are analyzed through different energy-saving technologies.

Novel Technology and Products: Fluidized Bed Incineration and Energy Recovery for Waste Disposal——Developed by the Institute for Thermal Power Engineering, Zhejiang University

The waste referred to includes solid waste and sludge. Solid waste is mainly from urban garbage and industrial waste. Sludge is from water treatment factories, paper mills, chemical factories, pharmaceutical factories, rivers and lakes. The waste and sludge are very harmful to water organisms, human health and drinking water, and directly affect the environment. Sludge and waste also occupy large areas of land. There are several methods to treat waste and sludge, such as burial, chemical treatment and incineration. Incineration is more effective than the

Preparation of high-purity fluorite and nanoscale calcium carbonate from low-grade fluorite

Flotation separation of calcite from fluorite is a challenge on low-grade fluorite flotation that limits the recovery and purity of fluorite concentrate.A new acid leaching–flotation process for fluorite is proposed in this work.This innovative process raised the fluor-ite’s grade to 97.26wt%while producing nanoscale calcium carbonate from its leachate,which contained plenty of calcium ions.On the production of nanoscale calcium carbonate,the impacts of concentration,temperature,and titration rate were examined.By modifying the process conditions and utilizing crystal conditioning agents,calcite-type and amorphous calcium carbonates with corresponding particle sizes of 1.823 and 1.511μm were produced.The influence of the impurity ions Mn^(2+),Mg^(2+),and Fe^(3+)was demonstrated to reduce the particle size of nanoscale calcium carbonate and make crystal shape easier to manage in the fluorite leach solution system compared with the calcium chloride solution.The combination of the acid leaching–flotation process and the nanoscale calcium carbonate preparation method improved the grade of fluorite while recovering calcite resources,thus presenting a novel idea for the effective and clean usage of low-quality fluorite resources with embedded microfine particles.

Characteristics of gaseous product from municipal solid waste gasification with hot blast furnace slag

Possibility of combustible gas production from municipal solid waste （MSW） using hot blast furnace （BF） slag has been studied.The objective of this work is to generate combustible gas from MSW using heated BF slag.In this experiment,the thermal stability of the MSW was analyzed by thermogravimetric analysis,and effects of temperature,gasifying agent （air,N2,steam） and BF slag on the gas products were investigated at 600？900 ？C.The thermogravimetric analysis indicates that the weight loss of MSW includes four stages：evaporation of the moisture,combustion of volatile materials,burning of carbon residue and burnout of ash.The contents of the combustible gas increase with increasing temperature,and the lower calorific value （LCV） increases rapidly at 600？900 ？C.It is found that volume fraction of CO,H2 and CH4 at different atmospheres increases in the order N2〈air〈steam.It is believed that BF slag acts as the catalyst and the heat carrier,which promotes the gasification reactivity of MSW.

Environmental and economic vision of plasma treatment of waste in Makkah

An environmental and economic assessment of the development of a plasma-chemical reactor equipped with plasma torches for the environmentally friendly treatment of waste streams by plasma is outlined with a view to the chemical and energetic valorization of the sustainability in the Kingdom of Saudi Arabia（KSA）. This is especially applicable in the pilgrimage season in the city of Makkah, which is a major challenge since the amount of waste was estimated at about 750 thousand tons through Arabic Year 1435 H（2015）, and is growing at a rate of 3%–5% annually. According to statistics, the value of waste in Saudi Arabia ranges between 8 and 9 billion EUR. The Plasma-Treatment Project（PTP） encompasses the direct plasma treatment of all types of waste（from source and landfill）, as well as an environmental vision and economic evaluation of the use of the gas produced for fuel and electricity production in KSA, especially in the pilgrimage season in the holy city Makkah. The electrical power required for the plasmatreatment process is estimated at 5000 kW（2000 kW used for the operation of the system and 3000 kW sold）, taking into account the fact that：（1） the processing capacity of solid waste is 100 tons per day（2） and the sale of electricity amounts to 23.8 MW at 0.18 EUR per kWh.（3） The profit from the sale of electricity per year is estimated at 3.27 million EUR and the estimated profit of solid-waste treatment amounts to 6 million EUR per year and（4） the gross profit per ton of solid waste totals 8 million EUR per year. The present article introduces the first stage of the PTP, in Makkah in the pilgrimage season, which consists of five stages：（1） study and treatment of waste streams,（2） slaughterhouse waste treatment,（3） treatment of refuse-derived fuel,（4）treatment of car tires and（5） treatment of slag（the fifth stage associated with each stage from the four previous stages）.

The heat recovery simulation in the system of dry granulation of the steel slag

In present,the wet-based pattern is mainly adopted to deal with the steel slag by steel plant at home and abroad,the wet-based technology has some defects;Wasting of water,pollution of the environment,and the slag has not been fully recycled.This paper presents a new method,which is aimed to realize dry granulation,waste heat recovery and comprehensive utilizing the steel slag.According to the ideas of wind quenching granulation,the heating slag from the converter furnace,was bring to the granulation heat exchange system,through the process of breaking in a container,the granulation heat exchange system has the functions of feeding continuously and heat exchange.The heat air,through the diversion tubes,could be recycled in removing the dust.The granulation slag could be bring to a confined roller,granulating and cooling secondarily.The roller export was connected to a magnetic separator.The separated iron could be recycled,and the remaining slag could also be reused as building materials,in process of stabilization and secondary magnetic separation.The heated air could be guided into the boiler to generate the steam,which can be used to generate electricity,or use as cleaned energy,realizing the target to recycle the waste heat in steel slag.The highlights of the new method are dry granulation and waste heat recovery.This paper states the process of heat exchange between the air and the steel slag in the system of granulation heat exchange in the new technical process.In theory,it has been proved reasonable with the the system of granulation heat exchange,and also the work conditions has been optimized.

Processing, Recovery and Analysis of Precious Metals Using Molecular Recogntion Technology

IBC Advanced Technologies' Molecular Recognition Technology(MRT) products,trade named SuperLig,selectively and rapidly bind with target metal ions to remove them from solution.The MRT process can produce a high purity separation product of maximum added value at low cost.In this paper,applications of MRT in the precious metals industry,including selective commercial separations involving Au,Pd,Pt,Rh,and Ru,are described and discussed.Application of MRT to the analytical determination of precious metals is presented.Potential use of MRT in recovering precious metals from end-of-life(EOL) products is discussed.

Recovery of Biomass Incinerated as Struvite-K Precipitates Followed Aluminium Removal

Phosphorus (P) and potassium (K) are non-renewable materials and widely in many industries such as agricultural sectors. On the other hand, the demand of P and K as fertilizers increases which following global population. The nutrient source of P and K which get from biomass waste i.e. incinerated of activated sludge and coffee husk biochar, respectively. The present study was conducted recovery of P and K as struvite-K (KMgPO4·6H2O) precipitates. The results showed that aluminium was released simultaneously with P from incinerated activated sludge with precipitate of Al:P of 1:1, K:P of 0.5, and Mg:P of 3. However, aluminium was inhibited to form struvite-K. Then, we examined cation removal especially for removed Al by dissolved 0.5 M HNO3 and the solution was mixed with KH2PO4 and MgCl2·6H2O as source of K and Mg, respectively. The results showed aluminium (Al) was removed with precipitate K:P of 0.5, and Mg:P of 0.8. This study was confirmed that recovery of biomass incinerated was successful as struvite-K and can be used as fertilizers.

Transforming Waste Heat into“Renewable Heat”

Introduction:The current worldwide electric power&heat&cool production has a negative impact on the environment by emissions and enormous leaks of low-potential waste heat.Transformation of unused industrial low power heat into“renewable heat”useful to enhance the efficiency of the system is essential and actual innovation in the field of worldwide environmental protection.By introducing and defining the terminology of low-potential,“renewable”,“green heat”has created a new,parallel category of research in the energy sector.Traditional co-generation systems produce heat for space heating and hot water and generate electricity.Moving to tri-generation allows growing demand for air conditioning for homes,offices and commercial spaces such as server rooms and switchboards to be met simultaneously or on a seasonal basis.Tri-generation,or combined cooling,heat and power,is the process by which some of the heat produced by a co-generation plant is used to generate chilled water for air conditioning or refrigeration.Usually an absorption chiller is linked to the plant to provide this functionality.The technical solution is related to the new efficient manner and system of simultaneous generation of heat/cold from multiple heat sources,which has not yet been known,but in practice required.New system also enables advantageous utilization of solar power in supporting of the cooling output.The innovative system can be operated also within the existing central heating distribution systems.

双燃料船用发动机废能回收系统的技术经济比较

Nowadays alternative and innovative energy recovery solutions are adopted on board ships to reduce fuel consumption and harmful emissions.According to this,the present work compares the engine exhaust gas waste heat recovery and hybrid turbocharger technologies,which are used to improve the efficiency of a dual-fuel four-stroke(DF)marine engine.Both solutions aim to satisfy partly or entirely the ship’s electrical and/or thermal loads.For the engine exhaust gas waste heat recovery,two steam plant schemes are considered:the single steam pressure and the variable layout(single or dual steam pressure plant).In both cases,a heat recovery steam generator is used for the electric power energy generation through a steam turbine.The hybrid turbocharger is used to provide a part of the ship’s electric loads as well.The thermodynamic mathematical models of DF engines,integrated with the energy recovery systems,are developed in a Matlab-Simulink environment,allowing the comparison in terms of performance at different engine loads and fuels,which are Natural Gas(NG)and High Fuel Oil(HFO).The use of NG always involves better efficiency of the system for all the engine working conditions.It results that the highest efficiency value achievable is 56%at 50%maximum continuous rating(MCR)engine load.

Energy,Exergy,and Exergoeconomic Analysis of Solar-Driven Solid Oxide Electrolyzer System Integrated with Waste Heat Recovery for Syngas Production

Syngas fuel generated by solar energy integrating with fuel cell technology is one of the promising methods for future green energy solutions to carbon neutrality.This paper designs a novel solar-driven solid oxide electrolyzer system integrated with waste heat for syngas production.Solar photovoltaic and parabolic trough collecter together drive the solid oxide electrolysis cell to improve system efficiency.The thermodynamic models of components are established,and the energy,exergy,and exergoeconomic analysis are conducted to evaluate the system’s performance.Under the design work conditions,the solar photovoltaic accounts for 88.46%of total exergy destruction caused by its less conversion efficiency.The exergoeconomic analysis indicates that the fuel cell component has a high exergoeconomic factor of 89.56%due to the large capital investment cost.The impacts of key parameters such as current density,operating temperature,pressure and mole fraction on system performances are discussed.The results demonstrate that the optimal energy and exergy efficiencies are achieved at 19.04%and 19.90%when the temperature,pressure,and molar fraction of H_(2)O are 1223.15 K,0.1 MPa,and 50%,respectively.

Exergy Analysis of Organic Rankine Cycles with Zeotropic Working Fluids

Waste heat recovery is one of the possible solutions to improve the efficiency of internal combustion engines.Instead of wasting the exhaust stream of an energy conversion system into the environment,its residual energy content can be usefully recovered,for example in Organic Rankine Cycles(ORC).This technology has been largely consolidated in stationary power plants but not yet for mobile applications,such as road transport,due to the limitations in the layout and to the constraints on the size and weight of the ORC system.An ORC system installed on the exhaust line of a bus powered by a natural gas spark ignition engine has been investigated.The thermal power available at engine exhaust has been evaluated by measuring gas temperature and mass flow rate during real driving operation.The waste thermal power has been considered as heat input for the ORC plant simulation.A detailed heat exchanger model has been developed because it is a crucial component for the ORC performance.The exergy analysis of the ORC was performed comparing different working fluids:R601,R1233zd(E)and two zeotropic blends of the two organic pure fluids.The model allowed the evaluation of the ORC produced energy over the driving cycle and the potential benefit on the engine efficiency.

Effect of flue gas outlet temperature in evaporator on thermal economic performance of organic Rankine cycle system for sinter waste heat recovery

In order to improve the recovery and utilization rates of sinter waste heat effectively,the organic Rankine cycle(ORC)system with subcritical cycle was designed to recover the low-temperature sinter cooling flue gas waste heat in an annular cooler for power generation.The thermodynamic,economic and multi-objective optimization models of ORC system were established,and R600a was selected as the ORC working medium.Subsequently,the variations in system thermodynamic performance and economic performance with the ORC thermal parameters were discussed in detail,and the optimal ORC thermal parameters were determined.The results show that the system net output power increases with increasing the evaporation temperature and decreasing the condensation temperature and increases first and then,decreases with the increase in superheat degree for a given flue gas outlet temperature in the evaporator,while the heat transfer area per unit net output power appears different variation trends in various ranges of flue gas outlet temperature.Taking the sinter cooling flue gas waste heat of 160℃as the ORC heat source,the optimal thermal parameters of ORC system were the flue gas outlet temperature of 90℃,the evaporation temperature of 95℃,the superheat degree of 10℃,and the condensation temperature of 28℃.

Experiment Study on the Exhaust-Gas Heat Exchanger for Small and Medium-Sized Marine Diesel Engine

This paper aims to design a special exchanger to recover the exhaust gas heat of marine diesel engines used in small and medium-sized fishing vessels,which can then be used to heat water up to 55°C–85°C for membrane desalination devices to produce fresh water.A new exhaust-gas heat exchanger of fins and tube,with a reinforced heat transfer tube section,unequal spacing fins,a mixing zone between the fin groups and four routes tube bundle,was designed.Numerical simulations were also used to provide reference information for structural design.Experiments were carried out for exhaust gas waste heat recovery from a marine diesel engine in an engine test bench utilizing the heat exchanger.The experimental results show that the difference between heat absorption by water and heat reduction of exhaust gas is less than 6.5%.After the water flow rate was adjusted,the exhaust gas waste heat recovery efficiency was higher than 70%,and the exhaust-gas heat exchanger’s outlet water temperature was 55°C–85°C at different engine loads.This means that the heat recovery from the exhaust gas of a marine diesel engine meets the requirement to drive a membrane desalination device to produce fresh water for fishers working in small and medium-sized fishing vessels.

Kinetic degradation of amoxicillin by using the electro-Fenton process in the presence of a graphite rods from used batteries

This study reports the removal of amoxicillin(AMX)in aqueous media using the electroFenton process in the presence of a graphite cathode recovered from used batteries.The impact of the relevant parameters on the electroFenton process,namely the applied current intensity,the temperature,the initial concentration of AMX and the initial concentration of ferrous ions were investigated.The results showed that the optimal values were:I=600 mA,T=25℃,[AMX]_(0)=0.082 mmol·L^( 1) and[Fe^(2+)]=1 mmol·L^(1),leading to 95%degradation and 74%mineralization.The model parameters of AMX mineralization were determined using nonlinear methods,showing that it follows a pseudosecondorder kinetic.The Energy consumption(EC)calculated under the optimal values was found to be 0.79 kWhg 1,which was of the same order of magnitude of those reported in other findings;while it is noteworthy that the electrodes used in our study are of a lower cost.