In the municipal solid waste incineration process,it is difficult to effectively control the gas oxygen content by setting the air flow according to artificial experience.To address this problem,this paper proposes an...In the municipal solid waste incineration process,it is difficult to effectively control the gas oxygen content by setting the air flow according to artificial experience.To address this problem,this paper proposes an optimization control method of gas oxygen content based on model predictive control.First,a stochastic configuration network is utilized to establish a prediction model of gas oxygen content.Second,an improved differential evolution algorithm that is based on parameter adaptive and t-distribution strategy is employed to address the set value of air flow.Finally,model predictive control is combined with the event triggering strategy to reduce the amount of computation and the controller's frequent actions.The experimental results show that the optimization control method proposed in this paper obtains a smaller degree of fluctuation in the air flow set value,which can ensure the tracking control performance of the gas oxygen content while reducing the amount of calculation.展开更多
This paper researched a promising biological treatment of methyl violet waste water by methods of activated sludge.Effects of temperature and pH were studied on this process.Kinetic equation ...This paper researched a promising biological treatment of methyl violet waste water by methods of activated sludge.Effects of temperature and pH were studied on this process.Kinetic equation of the substrate biodegradation was investigated in the experimental range.It was studied and simulated that flow within the bubble region of this bioreactor according to the κ ε two fluid equation.Simulation results agree well with experimental data.展开更多
Accumulating operational experience in both aerobic and anaerobic mechanical biological waste treatment (MBT) makes it increasingly obvious that controlled water management would substantially reduce the cost of MBT...Accumulating operational experience in both aerobic and anaerobic mechanical biological waste treatment (MBT) makes it increasingly obvious that controlled water management would substantially reduce the cost of MBT and also enhance resource recovery of the organic and inorganic fraction. The MBT plant at Gescher, Germany, is used as an example in order to determine the quantity and composition of process water and leachates from intensive and subsequent rotting, pressing water from anaerobic digestion and scrubber water from acid exhaust air treatment, and hence prepare an MBT water balance. The potential of, requirements for and limits to internal process water reuse as well as the possibilities of resource recovery from scrubber water are also examined. Finally, an assimilated process water management concept with the purpose of an extensive reduction of wastewater quantity and freshwater demand is presented.展开更多
The paper described the coking plant and Lurgi gasifier plant waste water types and characteristics , comparing the COD and ammonia-N level in different source of waste water in the plant.The currently maturity coking...The paper described the coking plant and Lurgi gasifier plant waste water types and characteristics , comparing the COD and ammonia-N level in different source of waste water in the plant.The currently maturity coking plant waste water treatment method was statement in the paper and analyzed the pros and cons of each method.The primary cost analysis of each type of waste water treatment was also completed in the paper.According to these analyses , recommendation was prepared for coking plant and Lurgi gasifier plant waste water treatment.展开更多
This paper studies the application of renewable energy sources in wastewater treatment plants to achieve self-sustain- ability of power. The data of wastewater treatment plant in the rural city of Toukh-EGYPT are pres...This paper studies the application of renewable energy sources in wastewater treatment plants to achieve self-sustain- ability of power. The data of wastewater treatment plant in the rural city of Toukh-EGYPT are presented as a case-study. The primary objective is to provide an entirely renewable standalone power system, which satisfies lowest possible emissions with the minimum lifecycle cost. Mass balance principle is applied on the biodegradable components in the wastewater to evaluate the volume of digester gas that is produced from sludge through anaerobic digestion process. Using digester gas as a fuel lead to study combined-heat-and-power technologies, where fuel cell is selected in order to abide by the low emissions constraint. The study assessed the electrical power obtained from fuel cell and the utilization of the exhausted heat energy for additional electrical power production using a micro-turbine. After covering the major part of load demand, the use of other renewable energy sources was studied. The strength of both solar and wind energy was determined by the case-study location. Hybrid optimization model for electric renewable (HOMER) software was used to simulate the hybrid system composed of combined-heat-and-power units, wind turbines and photovoltaic systems. Simulation results gave the best system configuration and optimum size of each component beside the detailed electrical and cost analysis of the model.展开更多
The high water content of municipal solid waste(MSW)will reduce the effciency of mechanical sorting,consequently unfavorable for beneficial utilization.In this study,a combined hydrolytic-aerobic biodrying technology ...The high water content of municipal solid waste(MSW)will reduce the effciency of mechanical sorting,consequently unfavorable for beneficial utilization.In this study,a combined hydrolytic-aerobic biodrying technology was introduced to remove water from MSW.The total water removals were proved to depend on the ventilation frequency and the temporal span in the hydrolytic stage. The ventilation frequency of 6 times/d was preferable in the hydrolytic stage.The hydrolytic span should not be prolonged more than ...展开更多
Possibility of combustible gas production from municipal solid waste (MSW) using hot blast furnace (BF) slag has been studied.The objective of this work is to generate combustible gas from MSW using heated BF slag...Possibility of combustible gas production from municipal solid waste (MSW) using hot blast furnace (BF) slag has been studied.The objective of this work is to generate combustible gas from MSW using heated BF slag.In this experiment,the thermal stability of the MSW was analyzed by thermogravimetric analysis,and effects of temperature,gasifying agent (air,N2,steam) and BF slag on the gas products were investigated at 600?900 ?C.The thermogravimetric analysis indicates that the weight loss of MSW includes four stages:evaporation of the moisture,combustion of volatile materials,burning of carbon residue and burnout of ash.The contents of the combustible gas increase with increasing temperature,and the lower calorific value (LCV) increases rapidly at 600?900 ?C.It is found that volume fraction of CO,H2 and CH4 at different atmospheres increases in the order N2〈air〈steam.It is believed that BF slag acts as the catalyst and the heat carrier,which promotes the gasification reactivity of MSW.展开更多
The emission of microplastics into nature poses a threat to aquatic and terrestrial ecosystems. Their penetration of the food chain presents a danger to human health as well. Wastewater treatment plants can be seen as...The emission of microplastics into nature poses a threat to aquatic and terrestrial ecosystems. Their penetration of the food chain presents a danger to human health as well. Wastewater treatment plants can be seen as the last barrier between microplastics and the environment. This review focuses on the impact of waste treatment plants in retaining microplastics. Studies show that no wastewater treatment method leads to a complete retention of microplastics, and so wastewater treatment plants themselves are viewed as point sources for the discharge of microplastics into the aquatic environment. Problems associated with the utilization of microplastic loaded sewage sludge are also discussed in the review.展开更多
This paper adopts a medium pressure mercury lamp as light source and ZnO powder as catalyst to investigate the effect of radioactive wave length, component of phenol ZnO suspension and st...This paper adopts a medium pressure mercury lamp as light source and ZnO powder as catalyst to investigate the effect of radioactive wave length, component of phenol ZnO suspension and stirring method on phenol decomposition rate. The optimized conditions for the phenol decomposition are: (1) Radioactive wave length: 360~420 nm; (2)Phenol concentration in the suspension is less than 200 mg/l; (3)ZnO concentration is 3~8 g/l; (4)pH value is 5~7; (5)Reaction temperature is 25℃~40℃; (6)Agitation at atmosphere. Phenol can decompose in two ways: (1)Reacting with photogenerated cavity; (2)Reacting with ·OH radical.展开更多
This study demonstrated the importance, process, activation and applications of Membrane in bioreactor to treat the waste water. Membrane Bioreactor (MBR) process consists of a biological reactor integrated with membr...This study demonstrated the importance, process, activation and applications of Membrane in bioreactor to treat the waste water. Membrane Bioreactor (MBR) process consists of a biological reactor integrated with membranes that combine clarification and filtration of an activated sludge process into a simplified, single step process. Operating as an MBR allows conventional activated sludge plants to become single step processes, which produce high quality effluent potentially suitable for reuse. Application of MBR technology for industrial wastewater treatment has also gained attention because of the robustness of the process. Theoretically, maintenance of long SRT in MBR is in favor of the retention and development of special microorganisms, which may lead to better removal of refractory organic matter and make the system more robust to load variations and toxic shocks. Literature suggested the conceptual expectation of enhanced biodegradation of hardly biodegradable compounds in MBR does not often come true. Improved biodegradation to certain extent has been reported in a few studies;however the underlying factors leading to such improvement still remains to be elucidated. This is comprehensive review of the studies dealing with recalcitrant industrial wastewater treatment by MBR, and casts light on the strategies to achieve enhanced biodegradation of hardly biodegradable industrial pollutants in MBR.展开更多
This work aims to understand the gasification performance of municipal solid waste (MSW) by means of thermodynamic analysis. Thermodynamic analysis is based on the assumption that the gasification reactions take pla...This work aims to understand the gasification performance of municipal solid waste (MSW) by means of thermodynamic analysis. Thermodynamic analysis is based on the assumption that the gasification reactions take place at the thermodynamic equilibrium condition, without regard to the reactor and process characteristics. First, model components of MSW including food, green wastes, paper, textiles, rubber, chlorine-free plastic, and polyvinyl chloride were chosen as the feedstock of a steam gasification process, with the steam temperature ranging from 973 K to 2273 K and the steam-to-MSW ratio (STMR) ranging from 1 to 5. It was found that the effect of the STMR on the gasification performance was almost the same as that of the steam temperature. All the differences among the seven types of MSW were caused by the variation of their compositions. Next, the gasification of actual MSW was analyzed using this thermodynamic equilibrium model. It was possible to count the inorganic components of actual MSW as silicon dioxide or aluminum oxide for the purpose of simplification, due to the fact that the inorganic components mainly affected the reactor temperature. A detailed comparison was made of the composition of the gaseous products obtained using steam, hydrogen, and air gasifying agents to provide basic knowledge regarding the appropriate choice of gasifying agent in MSW treatment upon demand.展开更多
In this work, an analysis of the generation, composition and management of the urban solid waste in Mexico and its relation to greenhouse gas emissions is described;as well a case study in Morelos, a state in the cent...In this work, an analysis of the generation, composition and management of the urban solid waste in Mexico and its relation to greenhouse gas emissions is described;as well a case study in Morelos, a state in the central region of the country. Data were collected from the scientific literature and existing data bases at state and national levels. In addition, the emissions of greenhouse gas were calculated for a period of 14 years, using the Intergovernmental Panel on Climate Change (IPCC) methodology. The municipal solid waste data collected from 1998 to 2012 reveal an increase in the amount of waste generated in Mexico and in Morelos (38% and 43%, respectively), which have been influenced by the urbanization process and the population increase. According to the official data, the composition of the urban solid waste in Mexico, is mostly organic matter (50%), represented by food and garden residues, as well as paper and cardboard (near to 14%). While in Morelos, the percentages of generation for these materials are 44% and 9%, respectively. The management of the urban waste mainly consists of house collection, principally in metropolitan zones and medium and small cities, representing 78.7% in Mexico and 89.2% in Morelos. The second way to eliminate the solid wastes is open burning (mostly in semi-urban and rural areas), representing 14.5% and 6.7% for Mexico and Morelos, respectively. During this period, the nationwide greenhouse gas emissions derived from solid waste management (SWM) increased by 180%, while in Morelos, an increase of 42.5% was calculated. Thus, the population increment and urbanization process were correlated with the rise in the amount of residues generated in Mexico and Morelos.展开更多
Membrane bioreactor (MBR) used in water and waste water treatment is a developing technique for water pollution control and water reuse. This paper described a membrane bioreactor for treatment of waste water in a pet...Membrane bioreactor (MBR) used in water and waste water treatment is a developing technique for water pollution control and water reuse. This paper described a membrane bioreactor for treatment of waste water in a petrochemical complex. The experimental MBR was a lab scale one composed of an activated sludge bioreactor unit and an ultrafiltration membrane unit. The relationship of COD removal with MLSS and HRT in this MBR was studied. The effects of crossflow velocity, backwash interval and volume of flush liquid on the flux were discussed. The results showed that average removal of COD, oil, SS and turbidity in petrochemical waste water by the MBR was 91%, 86%, 92% and 99%, respectively. The average removal of NH 3 N and total phosphorous was 85% and 82% respectively. A coefficient of COD removal, k , was 0017—0080 L/(mg.d). The membrane flux maintained higher than 60 L/hm 2 bar for 34 days without chemical cleaning when the velocity of crossflow was 35—39 m/s and the backwash interval was 30 minutes and backwash duration at 20 seconds. The results indicated that it is feasible for MBR technology to be used in petrochemical waste water treatment. The treated water could be considered as a source of to make up water for industrial cooling system or to be reused for other purposes.展开更多
The electrochemical oxidation of chlorimuron-ethyl on metry. The electrochemical behaviour of the electrode in a sodium Ti/SnO2-Sb2O5/PbO2 electrode was studied by cyclic voltamsulfate solution and in the mixture solu...The electrochemical oxidation of chlorimuron-ethyl on metry. The electrochemical behaviour of the electrode in a sodium Ti/SnO2-Sb2O5/PbO2 electrode was studied by cyclic voltamsulfate solution and in the mixture solution of sodium sulfate and chlorimuron-ethyl was studied. The experimental results of cyclic voltammetry show that the acidic medium was suitable for the efficient electrochemical oxidation of chlorimuron-ethyl. Some electro-generated reagent was formed in the electrolysis process and chlorimuron-ethyl could be oxidized by the electro-generated reagent. A Ti/SnO2-Sb2O5/PbO2 electrode was used as the anode and the electrolysis experiment was carried out under the optimized conditions. The electrolysis process was monitored by UV-Vis spectrometry and high performance liquid chromatography(HPLC), and the chemical oxygen demand(COD) was determined by the potassium dichromate method. The mechanism of chlorimuron-ethyl to be oxided was studied primarily by the cyclic voltammetry and UV-Vis spectrometry. The results of electrolysis experiment demonstrate the possibility of the electrode to be used as an anode for the electrochemical treatment of chlorimuron-ethyl contained in waste water.展开更多
Water quality protection in Sweden has a more than 80-year history. The needed knowledge has by large been imported. Now, to some extent the development of phosphorus removal technology may be Swedish contribution to ...Water quality protection in Sweden has a more than 80-year history. The needed knowledge has by large been imported. Now, to some extent the development of phosphorus removal technology may be Swedish contribution to advanced knowledge. This paper presents the development in Sweden, mainly a close to 50-year period. Starting in the late 1960s, a standard of <0.5 mg P/l was the normally raised effluent criteria, regardless of the magnitude of the discharge flow. The successive sharpening of the discharge levels has today resulted in a level of 0.2 to 0.3 mg P/l typically. As a matter of fact, even levels of 0.1 to 0.15 mg P/l have been discussed. The period should a large extent demonstrated both improved technologies and a far better efficiency with respect to the use of chemicals and energy. Some important points in this development may be the understanding of the Oxygen Consumption Potential, as well as the identified needs for an improved nitrogen removal. Lately the problems of complex pollution agents and predominantly the remains of pharmaceutical agents have been identified. To illustrate the development during the 50-year period, two examples are presented from the Swedish context. The main conclusion in this paper is that the Swedish history on phosphorus removal illustrates how empirical science in practice sometimes works, including a never-ending need for an open mind and a readiness to take revised and improved knowledge on board.展开更多
Most of water treatments require higher expenditure. Chemical coagulant requires higher cost and has some drawback after treatment such as pH changes. Moringa oleifera cake residue (MOCR) is one of the alternatives to...Most of water treatments require higher expenditure. Chemical coagulant requires higher cost and has some drawback after treatment such as pH changes. Moringa oleifera cake residue (MOCR) is one of the alternatives to replace chemical coagulant. A jar test apparatus was used to monitor water treatment. Water quality of Gebeng River (GR) and waste water (WW) was examined before and after treatment. Different parameters using (MOCR) was investigated. Preliminary laboratory results showed the great potential of the (MOCR) to be used in water treatment. MOCR shows an excellent reduction in turbidity (97 % was removed). The bacteria were reduced from 1.7 × 105 to 8 × 103 CFU/ml. Dissolved oxygen (DO) was improved that elevated from 1.06 ± 0.04 to 5.09 ± 0.03 mg/L. However, chemical oxygen demand (COD) and biological oxygen demand (BOD) were increased from 520.5 ± 0.71 to 865.0 ± 2.12 mg/L and from 120.5 ± 2.12 to 270.5 ± 2.12 mg/L respectively. Nevertheless, there is no significant alteration of pH, conductivity, salinity and total dissolved solid (TDS) after treatment. The iron (Fe) was fully removed while copper (Cu) and cadmium (Cd) were successfully removed up to 98%. The reduction of lead (Pb) also achieved 82.17%. Also, (MOCR) can be stored for long time up to 6 months without affecting the biological properties of MO.展开更多
Nowadays, with regard to environmental issues, proper operation of wastewater treatment plants is of particular importance that in the case of inappropriate utilization, they will cause serious problems. Processes tha...Nowadays, with regard to environmental issues, proper operation of wastewater treatment plants is of particular importance that in the case of inappropriate utilization, they will cause serious problems. Processes that exist in environmental systems and environmental engineers are dealing with them mostly have two major characteristics: they are dependent on many variables;and there are complex relationships between its components which make them very difficult to analyze. Being familiar with characteristics of industrial town effluents from various wastewater treatment units, which have high qualitative and quantitative variations and more uncertainties compared to urban wastewaters, plays very effective role in governing them. In order to achieve a better and efficient control over the operation of an industrial wastewater treatment plant, powerful mathematical tool can be used that is based on recorded data from some basic parameters of wastewater during a period of treatment plant operation. In this study, the multilayer perceptron (MLP) feed forward neural network with a hidden layer and stop training method was used to predict quality parameters of the industrial effluent. Data of this study are related to the Fajr Industrial Wastewater Treatment Plant located in Mahshahr—Iran that qualitative and quantitative characteristics of its units were used for training, calibration and evaluation of the neural model. Also, Principal Component Analysis technique was applied to modify and improve performance of generated models of neural networks. The results of this model showed good accuracy of the model in estimating qualitative pro- file of wastewater. This model facilitates evaluating the performance of each treatment plant units through comparing the results of prediction model with the standard amount of output.展开更多
Based on the degradation characteristics of municipal solid waste(MSW)in China,the traditional anaerobic sequencing batch bioreactor landfill(ASBRL)was optimized,and an improved anaerobic sequencing batch bioreactor l...Based on the degradation characteristics of municipal solid waste(MSW)in China,the traditional anaerobic sequencing batch bioreactor landfill(ASBRL)was optimized,and an improved anaerobic sequencing batch bioreactor landfill(IASBRL)was put forward on the basis of leachate self-recirculation.By monitoring MSW composition,leachate characteristics variation and landfill gas(LFG)generation,the effect of IASBRL was comparatively studied by simulation landfill.Based on the adjusting,scouring and carrying effects of leachate self-recirculation,IASBRL can rapidly decrease Eh value to about-500mV and form a suitable biochemical environment for methanogens,which provides a precondition for stable cooperation between non-methanogens and methanogens.IASBRL can avoid the accumulation of organic acids,make VFA(volatile fatty acid)concentration and CODCr decrease along with the small range fluctuations,and form a stable decomposition-consumption synergy during MSW degradation,therefore,the hydrolysis rate of easy hydrolyze material reaches 71.2% in IASBRL.From the viewpoint of LFG resources in IASBRL,the cumulative LFG production increases to 2327.0L,CH4 mass fraction stabilizes at about 50%,and these provide a favorable precondition for LFG development.展开更多
Water samples from four water bodies that flow through some solid waste dump sites in the Accra metropolitan area of Ghana were analysed over a period of six months for Cd, Pb, Cu, Zn and Mn contents;coliform bacteria...Water samples from four water bodies that flow through some solid waste dump sites in the Accra metropolitan area of Ghana were analysed over a period of six months for Cd, Pb, Cu, Zn and Mn contents;coliform bacteria and helminth eggs. Other water quality parameters such as BOD, DO, suspended solids and turbidity were also assessed. Cd, Pb, Zn, Mn, and Cu were determined using flame atomic absorption spectrometry (FAAS). Faecal coliforms, total coliforms and helminth eggs were determined by the membrane filtration (MF) method. The water samples contain various levels of Cd, Pb and Mn;Zn and Cu levels were low and found to be below the detection levels of the instrument in most cases. Helminth egg counts in water samples were high;an indication that the water bodies were polluted with pathogens. It has been observed that the major sources of pollutants into the water bodies were organic waste as well as coliform bacteria derived from these waste dumps. The elevated levels of bacteria make the water bodies unsafe for both primary and secondary contacts.展开更多
Wastewaters from the chemical industry are usually of high-strength and may contain minor inhibitory and recalcitrant organics that are at times not readily identifiable. This paper describes the experience of a biolo...Wastewaters from the chemical industry are usually of high-strength and may contain minor inhibitory and recalcitrant organics that are at times not readily identifiable. This paper describes the experience of a biological waste water treatment plant (WWTP) processing a COD concentration of 43000 mg·L^-1 wastewater from an oxochemical manufacturing plant. Stage improvements of the plant process by dilution of the inhibitory influent using other chemical wastewater streams resulting in a synergistic process effect, and removal of inhibitory organics by phase separation via acidification, effectively achieved process optimization producing a high quality effluent. In particular, the COD removal efficiency of granular sludge based anaerobic reactors increased from 56% to 90%. The final effluent COD decreased from 250mg·L^-1 to 50mg·L^-1, consistently meeting the COD concentration of 100 mg·L^-1 regulatory discharge limit. The success of the process enhancements supports the hypothesis that long-chain quaternary carboxylic acids act as substrate inhibitors in the biological process.展开更多
基金supported by the National Natural Science Foundation of China(62373017,62073006)and the Beijing Natural Science Foundation of China(4212032)。
文摘In the municipal solid waste incineration process,it is difficult to effectively control the gas oxygen content by setting the air flow according to artificial experience.To address this problem,this paper proposes an optimization control method of gas oxygen content based on model predictive control.First,a stochastic configuration network is utilized to establish a prediction model of gas oxygen content.Second,an improved differential evolution algorithm that is based on parameter adaptive and t-distribution strategy is employed to address the set value of air flow.Finally,model predictive control is combined with the event triggering strategy to reduce the amount of computation and the controller's frequent actions.The experimental results show that the optimization control method proposed in this paper obtains a smaller degree of fluctuation in the air flow set value,which can ensure the tracking control performance of the gas oxygen content while reducing the amount of calculation.
文摘This paper researched a promising biological treatment of methyl violet waste water by methods of activated sludge.Effects of temperature and pH were studied on this process.Kinetic equation of the substrate biodegradation was investigated in the experimental range.It was studied and simulated that flow within the bubble region of this bioreactor according to the κ ε two fluid equation.Simulation results agree well with experimental data.
文摘Accumulating operational experience in both aerobic and anaerobic mechanical biological waste treatment (MBT) makes it increasingly obvious that controlled water management would substantially reduce the cost of MBT and also enhance resource recovery of the organic and inorganic fraction. The MBT plant at Gescher, Germany, is used as an example in order to determine the quantity and composition of process water and leachates from intensive and subsequent rotting, pressing water from anaerobic digestion and scrubber water from acid exhaust air treatment, and hence prepare an MBT water balance. The potential of, requirements for and limits to internal process water reuse as well as the possibilities of resource recovery from scrubber water are also examined. Finally, an assimilated process water management concept with the purpose of an extensive reduction of wastewater quantity and freshwater demand is presented.
文摘The paper described the coking plant and Lurgi gasifier plant waste water types and characteristics , comparing the COD and ammonia-N level in different source of waste water in the plant.The currently maturity coking plant waste water treatment method was statement in the paper and analyzed the pros and cons of each method.The primary cost analysis of each type of waste water treatment was also completed in the paper.According to these analyses , recommendation was prepared for coking plant and Lurgi gasifier plant waste water treatment.
文摘This paper studies the application of renewable energy sources in wastewater treatment plants to achieve self-sustain- ability of power. The data of wastewater treatment plant in the rural city of Toukh-EGYPT are presented as a case-study. The primary objective is to provide an entirely renewable standalone power system, which satisfies lowest possible emissions with the minimum lifecycle cost. Mass balance principle is applied on the biodegradable components in the wastewater to evaluate the volume of digester gas that is produced from sludge through anaerobic digestion process. Using digester gas as a fuel lead to study combined-heat-and-power technologies, where fuel cell is selected in order to abide by the low emissions constraint. The study assessed the electrical power obtained from fuel cell and the utilization of the exhausted heat energy for additional electrical power production using a micro-turbine. After covering the major part of load demand, the use of other renewable energy sources was studied. The strength of both solar and wind energy was determined by the case-study location. Hybrid optimization model for electric renewable (HOMER) software was used to simulate the hybrid system composed of combined-heat-and-power units, wind turbines and photovoltaic systems. Simulation results gave the best system configuration and optimum size of each component beside the detailed electrical and cost analysis of the model.
基金supported by the National Key Technolo-gy R&D Program(No.2006BAC06B04,2006BAC02A03)the Key Grant Project of Shanghai Committee of Science and Technology(No.06dz12308).
文摘The high water content of municipal solid waste(MSW)will reduce the effciency of mechanical sorting,consequently unfavorable for beneficial utilization.In this study,a combined hydrolytic-aerobic biodrying technology was introduced to remove water from MSW.The total water removals were proved to depend on the ventilation frequency and the temporal span in the hydrolytic stage. The ventilation frequency of 6 times/d was preferable in the hydrolytic stage.The hydrolytic span should not be prolonged more than ...
基金supported by the Applied Basic Research Key Project of Yunnan Province (No.2007E0014Z)
文摘Possibility of combustible gas production from municipal solid waste (MSW) using hot blast furnace (BF) slag has been studied.The objective of this work is to generate combustible gas from MSW using heated BF slag.In this experiment,the thermal stability of the MSW was analyzed by thermogravimetric analysis,and effects of temperature,gasifying agent (air,N2,steam) and BF slag on the gas products were investigated at 600?900 ?C.The thermogravimetric analysis indicates that the weight loss of MSW includes four stages:evaporation of the moisture,combustion of volatile materials,burning of carbon residue and burnout of ash.The contents of the combustible gas increase with increasing temperature,and the lower calorific value (LCV) increases rapidly at 600?900 ?C.It is found that volume fraction of CO,H2 and CH4 at different atmospheres increases in the order N2〈air〈steam.It is believed that BF slag acts as the catalyst and the heat carrier,which promotes the gasification reactivity of MSW.
文摘The emission of microplastics into nature poses a threat to aquatic and terrestrial ecosystems. Their penetration of the food chain presents a danger to human health as well. Wastewater treatment plants can be seen as the last barrier between microplastics and the environment. This review focuses on the impact of waste treatment plants in retaining microplastics. Studies show that no wastewater treatment method leads to a complete retention of microplastics, and so wastewater treatment plants themselves are viewed as point sources for the discharge of microplastics into the aquatic environment. Problems associated with the utilization of microplastic loaded sewage sludge are also discussed in the review.
文摘This paper adopts a medium pressure mercury lamp as light source and ZnO powder as catalyst to investigate the effect of radioactive wave length, component of phenol ZnO suspension and stirring method on phenol decomposition rate. The optimized conditions for the phenol decomposition are: (1) Radioactive wave length: 360~420 nm; (2)Phenol concentration in the suspension is less than 200 mg/l; (3)ZnO concentration is 3~8 g/l; (4)pH value is 5~7; (5)Reaction temperature is 25℃~40℃; (6)Agitation at atmosphere. Phenol can decompose in two ways: (1)Reacting with photogenerated cavity; (2)Reacting with ·OH radical.
文摘This study demonstrated the importance, process, activation and applications of Membrane in bioreactor to treat the waste water. Membrane Bioreactor (MBR) process consists of a biological reactor integrated with membranes that combine clarification and filtration of an activated sludge process into a simplified, single step process. Operating as an MBR allows conventional activated sludge plants to become single step processes, which produce high quality effluent potentially suitable for reuse. Application of MBR technology for industrial wastewater treatment has also gained attention because of the robustness of the process. Theoretically, maintenance of long SRT in MBR is in favor of the retention and development of special microorganisms, which may lead to better removal of refractory organic matter and make the system more robust to load variations and toxic shocks. Literature suggested the conceptual expectation of enhanced biodegradation of hardly biodegradable compounds in MBR does not often come true. Improved biodegradation to certain extent has been reported in a few studies;however the underlying factors leading to such improvement still remains to be elucidated. This is comprehensive review of the studies dealing with recalcitrant industrial wastewater treatment by MBR, and casts light on the strategies to achieve enhanced biodegradation of hardly biodegradable industrial pollutants in MBR.
文摘This work aims to understand the gasification performance of municipal solid waste (MSW) by means of thermodynamic analysis. Thermodynamic analysis is based on the assumption that the gasification reactions take place at the thermodynamic equilibrium condition, without regard to the reactor and process characteristics. First, model components of MSW including food, green wastes, paper, textiles, rubber, chlorine-free plastic, and polyvinyl chloride were chosen as the feedstock of a steam gasification process, with the steam temperature ranging from 973 K to 2273 K and the steam-to-MSW ratio (STMR) ranging from 1 to 5. It was found that the effect of the STMR on the gasification performance was almost the same as that of the steam temperature. All the differences among the seven types of MSW were caused by the variation of their compositions. Next, the gasification of actual MSW was analyzed using this thermodynamic equilibrium model. It was possible to count the inorganic components of actual MSW as silicon dioxide or aluminum oxide for the purpose of simplification, due to the fact that the inorganic components mainly affected the reactor temperature. A detailed comparison was made of the composition of the gaseous products obtained using steam, hydrogen, and air gasifying agents to provide basic knowledge regarding the appropriate choice of gasifying agent in MSW treatment upon demand.
文摘In this work, an analysis of the generation, composition and management of the urban solid waste in Mexico and its relation to greenhouse gas emissions is described;as well a case study in Morelos, a state in the central region of the country. Data were collected from the scientific literature and existing data bases at state and national levels. In addition, the emissions of greenhouse gas were calculated for a period of 14 years, using the Intergovernmental Panel on Climate Change (IPCC) methodology. The municipal solid waste data collected from 1998 to 2012 reveal an increase in the amount of waste generated in Mexico and in Morelos (38% and 43%, respectively), which have been influenced by the urbanization process and the population increase. According to the official data, the composition of the urban solid waste in Mexico, is mostly organic matter (50%), represented by food and garden residues, as well as paper and cardboard (near to 14%). While in Morelos, the percentages of generation for these materials are 44% and 9%, respectively. The management of the urban waste mainly consists of house collection, principally in metropolitan zones and medium and small cities, representing 78.7% in Mexico and 89.2% in Morelos. The second way to eliminate the solid wastes is open burning (mostly in semi-urban and rural areas), representing 14.5% and 6.7% for Mexico and Morelos, respectively. During this period, the nationwide greenhouse gas emissions derived from solid waste management (SWM) increased by 180%, while in Morelos, an increase of 42.5% was calculated. Thus, the population increment and urbanization process were correlated with the rise in the amount of residues generated in Mexico and Morelos.
文摘Membrane bioreactor (MBR) used in water and waste water treatment is a developing technique for water pollution control and water reuse. This paper described a membrane bioreactor for treatment of waste water in a petrochemical complex. The experimental MBR was a lab scale one composed of an activated sludge bioreactor unit and an ultrafiltration membrane unit. The relationship of COD removal with MLSS and HRT in this MBR was studied. The effects of crossflow velocity, backwash interval and volume of flush liquid on the flux were discussed. The results showed that average removal of COD, oil, SS and turbidity in petrochemical waste water by the MBR was 91%, 86%, 92% and 99%, respectively. The average removal of NH 3 N and total phosphorous was 85% and 82% respectively. A coefficient of COD removal, k , was 0017—0080 L/(mg.d). The membrane flux maintained higher than 60 L/hm 2 bar for 34 days without chemical cleaning when the velocity of crossflow was 35—39 m/s and the backwash interval was 30 minutes and backwash duration at 20 seconds. The results indicated that it is feasible for MBR technology to be used in petrochemical waste water treatment. The treated water could be considered as a source of to make up water for industrial cooling system or to be reused for other purposes.
基金Supported by the Science and Technology Foundation of the Education Department of Liaoning Province,China (No.2009A557)
文摘The electrochemical oxidation of chlorimuron-ethyl on metry. The electrochemical behaviour of the electrode in a sodium Ti/SnO2-Sb2O5/PbO2 electrode was studied by cyclic voltamsulfate solution and in the mixture solution of sodium sulfate and chlorimuron-ethyl was studied. The experimental results of cyclic voltammetry show that the acidic medium was suitable for the efficient electrochemical oxidation of chlorimuron-ethyl. Some electro-generated reagent was formed in the electrolysis process and chlorimuron-ethyl could be oxidized by the electro-generated reagent. A Ti/SnO2-Sb2O5/PbO2 electrode was used as the anode and the electrolysis experiment was carried out under the optimized conditions. The electrolysis process was monitored by UV-Vis spectrometry and high performance liquid chromatography(HPLC), and the chemical oxygen demand(COD) was determined by the potassium dichromate method. The mechanism of chlorimuron-ethyl to be oxided was studied primarily by the cyclic voltammetry and UV-Vis spectrometry. The results of electrolysis experiment demonstrate the possibility of the electrode to be used as an anode for the electrochemical treatment of chlorimuron-ethyl contained in waste water.
文摘Water quality protection in Sweden has a more than 80-year history. The needed knowledge has by large been imported. Now, to some extent the development of phosphorus removal technology may be Swedish contribution to advanced knowledge. This paper presents the development in Sweden, mainly a close to 50-year period. Starting in the late 1960s, a standard of <0.5 mg P/l was the normally raised effluent criteria, regardless of the magnitude of the discharge flow. The successive sharpening of the discharge levels has today resulted in a level of 0.2 to 0.3 mg P/l typically. As a matter of fact, even levels of 0.1 to 0.15 mg P/l have been discussed. The period should a large extent demonstrated both improved technologies and a far better efficiency with respect to the use of chemicals and energy. Some important points in this development may be the understanding of the Oxygen Consumption Potential, as well as the identified needs for an improved nitrogen removal. Lately the problems of complex pollution agents and predominantly the remains of pharmaceutical agents have been identified. To illustrate the development during the 50-year period, two examples are presented from the Swedish context. The main conclusion in this paper is that the Swedish history on phosphorus removal illustrates how empirical science in practice sometimes works, including a never-ending need for an open mind and a readiness to take revised and improved knowledge on board.
文摘Most of water treatments require higher expenditure. Chemical coagulant requires higher cost and has some drawback after treatment such as pH changes. Moringa oleifera cake residue (MOCR) is one of the alternatives to replace chemical coagulant. A jar test apparatus was used to monitor water treatment. Water quality of Gebeng River (GR) and waste water (WW) was examined before and after treatment. Different parameters using (MOCR) was investigated. Preliminary laboratory results showed the great potential of the (MOCR) to be used in water treatment. MOCR shows an excellent reduction in turbidity (97 % was removed). The bacteria were reduced from 1.7 × 105 to 8 × 103 CFU/ml. Dissolved oxygen (DO) was improved that elevated from 1.06 ± 0.04 to 5.09 ± 0.03 mg/L. However, chemical oxygen demand (COD) and biological oxygen demand (BOD) were increased from 520.5 ± 0.71 to 865.0 ± 2.12 mg/L and from 120.5 ± 2.12 to 270.5 ± 2.12 mg/L respectively. Nevertheless, there is no significant alteration of pH, conductivity, salinity and total dissolved solid (TDS) after treatment. The iron (Fe) was fully removed while copper (Cu) and cadmium (Cd) were successfully removed up to 98%. The reduction of lead (Pb) also achieved 82.17%. Also, (MOCR) can be stored for long time up to 6 months without affecting the biological properties of MO.
文摘Nowadays, with regard to environmental issues, proper operation of wastewater treatment plants is of particular importance that in the case of inappropriate utilization, they will cause serious problems. Processes that exist in environmental systems and environmental engineers are dealing with them mostly have two major characteristics: they are dependent on many variables;and there are complex relationships between its components which make them very difficult to analyze. Being familiar with characteristics of industrial town effluents from various wastewater treatment units, which have high qualitative and quantitative variations and more uncertainties compared to urban wastewaters, plays very effective role in governing them. In order to achieve a better and efficient control over the operation of an industrial wastewater treatment plant, powerful mathematical tool can be used that is based on recorded data from some basic parameters of wastewater during a period of treatment plant operation. In this study, the multilayer perceptron (MLP) feed forward neural network with a hidden layer and stop training method was used to predict quality parameters of the industrial effluent. Data of this study are related to the Fajr Industrial Wastewater Treatment Plant located in Mahshahr—Iran that qualitative and quantitative characteristics of its units were used for training, calibration and evaluation of the neural model. Also, Principal Component Analysis technique was applied to modify and improve performance of generated models of neural networks. The results of this model showed good accuracy of the model in estimating qualitative pro- file of wastewater. This model facilitates evaluating the performance of each treatment plant units through comparing the results of prediction model with the standard amount of output.
基金Project(41072236)supported by the National Natural Science Foundation of ChinaProject supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions,ChinaProject(2009A027)supported by Youth Research Foundation of China University of Mining and Technology
文摘Based on the degradation characteristics of municipal solid waste(MSW)in China,the traditional anaerobic sequencing batch bioreactor landfill(ASBRL)was optimized,and an improved anaerobic sequencing batch bioreactor landfill(IASBRL)was put forward on the basis of leachate self-recirculation.By monitoring MSW composition,leachate characteristics variation and landfill gas(LFG)generation,the effect of IASBRL was comparatively studied by simulation landfill.Based on the adjusting,scouring and carrying effects of leachate self-recirculation,IASBRL can rapidly decrease Eh value to about-500mV and form a suitable biochemical environment for methanogens,which provides a precondition for stable cooperation between non-methanogens and methanogens.IASBRL can avoid the accumulation of organic acids,make VFA(volatile fatty acid)concentration and CODCr decrease along with the small range fluctuations,and form a stable decomposition-consumption synergy during MSW degradation,therefore,the hydrolysis rate of easy hydrolyze material reaches 71.2% in IASBRL.From the viewpoint of LFG resources in IASBRL,the cumulative LFG production increases to 2327.0L,CH4 mass fraction stabilizes at about 50%,and these provide a favorable precondition for LFG development.
文摘Water samples from four water bodies that flow through some solid waste dump sites in the Accra metropolitan area of Ghana were analysed over a period of six months for Cd, Pb, Cu, Zn and Mn contents;coliform bacteria and helminth eggs. Other water quality parameters such as BOD, DO, suspended solids and turbidity were also assessed. Cd, Pb, Zn, Mn, and Cu were determined using flame atomic absorption spectrometry (FAAS). Faecal coliforms, total coliforms and helminth eggs were determined by the membrane filtration (MF) method. The water samples contain various levels of Cd, Pb and Mn;Zn and Cu levels were low and found to be below the detection levels of the instrument in most cases. Helminth egg counts in water samples were high;an indication that the water bodies were polluted with pathogens. It has been observed that the major sources of pollutants into the water bodies were organic waste as well as coliform bacteria derived from these waste dumps. The elevated levels of bacteria make the water bodies unsafe for both primary and secondary contacts.
文摘Wastewaters from the chemical industry are usually of high-strength and may contain minor inhibitory and recalcitrant organics that are at times not readily identifiable. This paper describes the experience of a biological waste water treatment plant (WWTP) processing a COD concentration of 43000 mg·L^-1 wastewater from an oxochemical manufacturing plant. Stage improvements of the plant process by dilution of the inhibitory influent using other chemical wastewater streams resulting in a synergistic process effect, and removal of inhibitory organics by phase separation via acidification, effectively achieved process optimization producing a high quality effluent. In particular, the COD removal efficiency of granular sludge based anaerobic reactors increased from 56% to 90%. The final effluent COD decreased from 250mg·L^-1 to 50mg·L^-1, consistently meeting the COD concentration of 100 mg·L^-1 regulatory discharge limit. The success of the process enhancements supports the hypothesis that long-chain quaternary carboxylic acids act as substrate inhibitors in the biological process.