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Efficient and rapid capture of uranium(Ⅵ) in wastewater via multiamine modified β-cyclodextrin porous polymer
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作者 Xing Zhong Yubin Tan +6 位作者 Siyuan Wu Caixia Hu Kai Guo Yongchuan Wu Neng Yu Mingyang Ma Ying Dai 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第4期144-155,共12页
It is quite important to ensure the safety and sustainable development of nuclear energy for the treatment of radioactive wastewater. To treat radioactive wastewater efficiently and rapidly, two multi-amine β-cyclode... It is quite important to ensure the safety and sustainable development of nuclear energy for the treatment of radioactive wastewater. To treat radioactive wastewater efficiently and rapidly, two multi-amine β-cyclodextrin polymers(diethylenetriamine β-cyclodextrin polymer(DETA-TFCDP) and triethylenetetramine β-cyclodextrin polymer(TETA-TFCDP)) were prepared and applied to capture uranium. Results exhibited that DETA-TFCDP and TETA-TFCDP displayed the advantages of high adsorption amounts(612.2and 628.2 mg·g-1, respectively) and rapid adsorption rates, which can reach(88 ± 1)% of their equilibrium adsorption amounts in 10 min. Moreover, the adsorbent processes of DETA-TFCDP and TETATFCDP on uranium(Ⅵ) followed the Langmuir model and pseudo-second-order model, stating they were mainly chemisorption and self-endothermic. Besides, TETA-TFCDP also showed excellent selectivity in the presence of seven competing cations and could be effectively reused five times via Na2CO3as the desorption reagent. Meanwhile, X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy illustrated that the enriched multi-amine groups and oxygen-containing functional groups on the surface of TETA-TFCDP were the main active sites for capturing uranium(Ⅵ). Hence, multi-amine β-cyclodextrin polymers are a highly efficient, rapid, and promising adsorbent for capturing uranium(Ⅵ)from radioactive wastewater. 展开更多
关键词 Adsorption waste water Pollution Uranium(VI) b-Cyclodextrin
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Design and Sizing of an Ecological Wastewater Treatment System in a School Environment: A Case Study of Ndiebene Gandiol 1 School
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作者 Falilou Coundoul Abdou Khafor Ndiaye +1 位作者 Abdoulaye Deme David de la Varga 《Journal of Water Resource and Protection》 CAS 2024年第1期41-57,共17页
The primary objective of this study was to design and size a sustainable sanitation solution for the Ndiebene Gandiol 1 school located in the eponymous commune in northern Senegal. Field investigations led to the coll... The primary objective of this study was to design and size a sustainable sanitation solution for the Ndiebene Gandiol 1 school located in the eponymous commune in northern Senegal. Field investigations led to the collection of wastewater samples. Their analysis revealed specific pollutant loads, including loads of BOD5 3.6966 kgO<sub>2</sub>/day and COD of 12.8775 kgO<sub>2</sub>/day, which were central to the design phase. Following a rigorous assessment of the existing sanitation infrastructure, constructed wetland (CWs) emerged as the most appropriate ecological solution. This system, valued for its ability to effectively remove contaminants, was tailored to the specific needs of the site. Consequently, the final design of the filter extends over 217.16 m<sup>2</sup>, divided into two cells of 108.58 m<sup>2</sup> each, with dimensions of 12.77 m in length and 8.5 m in width. The depth of the filtering medium is approximately 0.60 m, meeting the standards while ensuring maximized purification. Typha, an indigenous and prolific plant known for its purification abilities, was selected as the filtering agent. Concurrently, non-crushed gravel was chosen for its proven filtration capacity. This study is the result of a combination of scientific rigor and design expertise. It provides a holistic view of sanitation for Ndiebene Gandiol. The technical specifications and dimensions of the constructed wetland filter embody an approach that marries indepth analysis and practical application, all aimed at delivering an effective and long-lasting solution to the local sanitation challenges. By integrating precise scientific data with sanitation design expertise, this study delivers a holistic solution for Ndiebene Gandiol. The detailed dimensions and specifications of the constructed wetland filter reflect a methodology that combines meticulous analysis with practical adaptation, aiming to provide an effective and sustainable response to the challenges of rural and school sanitation in the northern region of Senegal. 展开更多
关键词 water Review Hydraulic Engineering water Treatment Agricultural Irrigation SANITATION Engineering Environment
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Stable Isotopic Signatures of NO3 in Waste Water Effluent and Los Angeles River
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作者 Isaac Hall Mohammad Hassan Rezaie Boroon 《Journal of Water Resource and Protection》 CAS 2024年第1期102-122,共21页
A metropolitan city such as Los Angeles (LA) is an ideal study site with a very high population density, and it houses at least 3 treatment plants where sewage is treated preliminarily and then progressing to tertiary... A metropolitan city such as Los Angeles (LA) is an ideal study site with a very high population density, and it houses at least 3 treatment plants where sewage is treated preliminarily and then progressing to tertiary treatment before discharging into the LA River. We will gain a better understanding of the water quality in the LA River and the nitrate load in the watershed system by examining the influence of waste water treatment plants (WWTPs). The goal of this study is to pinpoint the exact source of nitrate in the LA River using the isotope signatures. We have selected sampling locations both upstream and downstream of the WWTP. This serves to monitor nitrate levels, aiding in the assessment of treatment plant effectiveness, pinpointing nitrate pollution sources, and ensuring compliance with environmental regulations. The research explores the isotopic composition of NO3 in relation to atmospheric nitrogen and Vienna Standard Mean Ocean Water, shedding light on the contributions from various sources such as manure, sewage, soil organic nitrogen, and nitrogen fertilizers. Specifically, there is a change in the δ15NAir value between the dry and wet seasons. The isotope values in the Tillman WWTP sample changed between dry and wet seasons. Notably, the presence of nitrate originating from manure and sewage is consistent across seasons, emphasizing the significant impact of anthropogenic and agricultural activities on water quality. This investigation contributes to the broader understanding of nitrogen cycling in urban water bodies, particularly in the context of wastewater effluent discharge. The findings hold implications for water quality management and highlight the need for targeted interventions to mitigate the impact of nitrogen-containing compounds on aquatic ecosystems. Overall, the study provides a valuable framework for future research and environmental stewardship efforts aimed at preserving the health and sustainability of urban water resources. This data informs decisions regarding additional treatment or mitigation actions to safeguard downstream water quality and ecosystem health. 展开更多
关键词 Metropolitan City Los Angeles Treatment Plants Sewage Treatment Nitrate Source Isotope Signatures water Quality
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Digital Twins for Wastewater Treatment:A Technical Review
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作者 Ai-Jie Wang Hewen Li +6 位作者 Zhejun He Yu Tao Hongcheng Wang Min Yang Dragan Savic Glen TDaigger Nanqi Ren 《Engineering》 SCIE EI CAS CSCD 2024年第5期21-35,共15页
The digital twins concept enhances modeling and simulation through the integration of real-time data and feedback.This review elucidates the foundational elements of digital twins,covering their concept,entities,domai... The digital twins concept enhances modeling and simulation through the integration of real-time data and feedback.This review elucidates the foundational elements of digital twins,covering their concept,entities,domains,and key technologies.More specifically,we investigate the transformative potential of digital twins for the wastewater treatment engineering sector.Our discussion highlights the application of digital twins to wastewater treatment plants(WWTPs)and sewage networks,hardware(i.e.,facilities and pipes,sensors for water quality and activated sludge,hydrodynamics,and power consumption),and software(i.e.,knowledge-based and data-driven models,mechanistic models,hybrid twins,control methods,and the Internet of Things).Furthermore,two cases are provided,followed by an assessment of current challenges in and perspectives on the application of digital twins in WWTPs.This review serves as an essential primer for wastewater engineers navigating the digital paradigm shift. 展开更多
关键词 Digital twins Urban water systems wastewater treatment
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Facile synthesis of composite polyferric magnesium-silicate-sulfate coagulant with enhanced performance in water and wastewater
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作者 Xiangtao Huo Rongxia Chai +2 位作者 Lizheng Gou Mei Zhang Min Guo 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第3期574-584,共11页
The coagulation process is a widely applied technology in water and wastewater treatment.Novel composite polyferric mag-nesium-silicate-sulfate(PFMS)coagulants were synthesized using Na_(2)SiO_(3)·9H_(2)O,Fe_(2)(... The coagulation process is a widely applied technology in water and wastewater treatment.Novel composite polyferric mag-nesium-silicate-sulfate(PFMS)coagulants were synthesized using Na_(2)SiO_(3)·9H_(2)O,Fe_(2)(SO_(4))_(3),and MgSO_(4) as raw materials in this paper.The effects of aging time,Fe:Si:Mg,and OH:M molar ratios(M represents the metal ions)on the coagulation performance of the as-pre-pared PFMS were systematically investigated to obtain optimum coagulants.The results showed that PFMS coagulant exhibited good co-agulation properties in the treatment of simulated humic acid-kaolin surface water and reactive dye wastewater.When the molar ratio was controlled at Fe:Si:Mg=2:2:1 and OH:M=0.32,the obtained PFMS presented excellent stability and a high coagulation efficiency.The removal efficiency of ultraviolet UV254 was 99.81%,and the residual turbidity of the surface water reached 0.56 NTU at a dosage of 30 mg·L^(-1).After standing the coagulant for 120 d in the laboratory,the removal efficiency of UV254 and residual turbidity of the surface wa-ter were 88.12%and 0.68 NTU,respectively,which accord with the surface water treatment requirements.In addition,the coagulation performance in the treatment of reactive dye wastewater was greatly improved by combining the advantages of magnesium and iron salts.Compared with polyferric silicate-sulfate(PFS)and polymagnesium silicate-sulfate(PMS),the PFMS coagulant played a better decolor-ization role within the pH range of 7-13. 展开更多
关键词 polyferric-magnesium-silicate-sulfate composite coagulants water and wastewater excellent stability high coagulation ef-ficiency DECOLORIZATION
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A Comparative Analysis of Vetiver and Typha in Ecological Wastewater Treatment Using a Horizontal Flow Constructed Wetlands in Rural Setting
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作者 Falilou Coundoul Abdou Khafor Ndiaye +1 位作者 Abdoulaye Deme Antonina Torrens Armegnol 《Journal of Agricultural Chemistry and Environment》 2024年第1期67-82,共16页
This study presents an assessment of wastewater ecological treatment processes utilizing a horizontal flow bio-reactor at the Ndiebene Gandiol 1 school. It primarily aims to juxtapose the filtration efficacy of two di... This study presents an assessment of wastewater ecological treatment processes utilizing a horizontal flow bio-reactor at the Ndiebene Gandiol 1 school. It primarily aims to juxtapose the filtration efficacy of two distinct vegetative cells, Vetiver and Typha, in the pursuit of sustainable wastewater management strategies for rural scholastic institutions. A synergistic approach was employed, integrating on-site surveys for site-specific insights and laboratory analyses to quantify the pollutant loads pre- and post-treatment. Our findings indicate that both Vetiver and Typha-infused filter beds significantly reduce most contaminants, with particular success in diminishing chemical oxygen demand (COD) and biological oxygen demand (BOD5). Vetiver was notable for its superior reduction of COD, achieving an average effluent concentration of 74 mg/L, in contrast to Typha’s 155 mg/L. Conversely, Typha excelled in suspended solids removal, registering 1 mg/L against Vetiver’s 3 mg/L. While both systems notably surpassed the target metrics across several indicators, including fecal coliform reduction, our results pinpoint the need for refinement in phosphate remediation. Conclusively, the study underscores the efficacy of both Vetiver and Typha systems in rural wastewater treatment contexts, with their integrative application potentially paving the way for enhanced system robustness and efficiency. The outcomes herein highlight the imperative for continued research to further hone these ecological treatment modalities, especially concerning phosphate elimination. 展开更多
关键词 Hydraulics water Treatment Agricultural Irrigation SANITATION Engineering Environment
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Performance of a Horizontal Flow Constructed Reed Bed Filter for Municipal Wastewater Treatment: The Case Study of the Prototype Installed at Gaston Berger University, Saint-Louis, Senegal
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作者 Abdou Khafor Ndiaye Falilou Coundoul +2 位作者 Abdoulaye Deme Antonina Torrens Armengol Abdoulaye Senghor 《Natural Resources》 2024年第1期1-16,共16页
In Saint-Louis, Senegal, a constructed wetland with horizontal flow reed beds (FHa and FHb) has demonstrated significant efficacy in treating municipal wastewater. Analyzing various treatment stages, the system showed... In Saint-Louis, Senegal, a constructed wetland with horizontal flow reed beds (FHa and FHb) has demonstrated significant efficacy in treating municipal wastewater. Analyzing various treatment stages, the system showed only a slight temperature variation, from an influent average of 26.3°C to an effluent of 24.7°C. Electrical conductivity decreased from 1331 mS/cm to 974.5 mS/cm post-primary treatment, with suspended solids (SS) dramatically reduced from 718.9 mg/L to 5.7 mg/L in the final effluent. Biochemical oxygen demand (BOD5) and chemical oxygen demand (COD) saw a notable decrease, from initial levels of 655.6 mg/L and 1240 mg/L to 2.3 mg/L and 71.3 mg/L, respectively. Nitrogenous compounds (N-TN) and phosphates () also decreased significantly, indicating the system’s nutrient removal capacity. Microbiological analysis revealed a reduction in fecal coliforms from 7.5 Ulog/100ml to 1.8 Ulog/100ml and a complete elimination of helminth eggs. The presence of Phragmites and Typha was instrumental in enhancing these reductions. The system’s compliance with the Senegalese standards for disposal into natural environments, WHO recommendations for unrestricted water reuse in irrigation, and the European legislation for water reuse was established. The effluent quality met the stringent criteria for various classes of agricultural reuse, illustrating the system’s potential for sustainable water management. This wetland model presents a robust solution for water-stressed regions, ensuring environmental protection while supporting agricultural needs. The study calls for ongoing research to further refine the system for optimal, reliable wastewater treatment and water resource sustainability. 展开更多
关键词 Constructed Wetlands Horizontal Flow Reed Beds wastewater Treatment Phragmites and Typha Plants Physicochemical Pollutant Removal Microbiological Indicators Fecal Coliforms and Helminth Eggs water Quality Improvement Senegal water Reuse Standards Sustainable water Management Agricultural Irrigation Reuse Nutrient Removal Efficiency Environmental Engineering Ecological Sanitation Systems
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Progress of Electrocatalytic Technology in Treating Organic Chemical Wastewater
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作者 Lun Deng Hemei Wang 《Expert Review of Chinese Chemical》 2024年第1期9-14,共6页
In recent years,extensive research has been conducted on the preparation of high catalytic performance electrodes and the development of electrocatalytic water treatment processes.This article introduces the basic pri... In recent years,extensive research has been conducted on the preparation of high catalytic performance electrodes and the development of electrocatalytic water treatment processes.This article introduces the basic principles of electrochemical water treatment,the preparation of electrode materials,and the research progress of electrocatalytic technology for degrading organic chemical wastewater.It analyzes the problems faced by electrocatalytic degradation of organic chemical wastewater and looks forward to the development trend of electrocatalytic technology in the field of organic chemical wastewater treatment. 展开更多
关键词 ELECTROCATALYSIS electrode preparation organic chemical wastewater water treatment
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Energy,exergy,economic and environmental comprehensive analysis and multi-objective optimization of a sustainable zero liquid discharge integrated process for fixed-bed coal gasification wastewater
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作者 Yanli Zhang Zhengkun Hou +7 位作者 Dong Yao Xiaomin Qiu Hongru Zhang Peizhe Cui Yinglong Wang Jun Gao Zhaoyou Zhu Limei Zhong 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第6期341-354,共14页
For a long time,China's regional water resource imbalance has restricted the development of coal chemical industry,and it is imperative to achieve zero liquid discharge(ZLD).Therefore,the game relationship between... For a long time,China's regional water resource imbalance has restricted the development of coal chemical industry,and it is imperative to achieve zero liquid discharge(ZLD).Therefore,the game relationship between technical indicators,costs and emissions in ZLD process of fixed-bed coal gasification wastewater treatment process should be explored in detail.According to the accurate model,the simulation for ZLD of fixed-bed coal gasification wastewater treatment process is established,and this process is assessed from the perspective of thermodynamics,economy,and environment.The total energy consumption of ZLD process before optimization is 4.032×10^(8)W.The results of exergy analysis show exergy destruction of ZLD process is 94.55%.For economic and environmental results,the total annual cost is 1.892×10^(7)USD·a^(-1)and the total environmental impact is 4.782×10^(-8).The total energy consumption of the optimal six-step ZLD process based on multi-objective optimization is 4.028×10^(8)W.The CO_(2)content in the treated wastewater is 0.1%.This study will have an important role in promoting the establishment of the ZLD process for coal chemistry industry. 展开更多
关键词 waste water Case study ENERGY EXERGY ECONOMY Environment
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Univariate imputation method for recovering missing data in wastewater treatment process
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作者 Honggui Han Meiting Sun +2 位作者 Huayun Han Xiaolong Wu Junfei Qiao 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第1期201-210,共10页
High-quality data play a paramount role in monitoring,control,and prediction of wastewater treatment process(WWTP)and can effectively ensure the efficient and stable operation of system.Missing values seriously degrad... High-quality data play a paramount role in monitoring,control,and prediction of wastewater treatment process(WWTP)and can effectively ensure the efficient and stable operation of system.Missing values seriously degrade the accuracy,reliability and completeness of the data quality due to network collapses,connection errors and data transformation failures.In these cases,it is infeasible to recover missing data depending on the correlation with other variables.To tackle this issue,a univariate imputation method(UIM)is proposed for WWTP integrating decomposition method and imputation algorithms.First,the seasonal-trend decomposition based on loess method is utilized to decompose the original time series into the seasonal,trend and remainder components to deal with the nonstationary characteristics of WWTP data.Second,the support vector regression is used to approximate the nonlinearity of the trend and remainder components respectively to provide estimates of its missing values.A self-similarity decomposition is conducted to fill the seasonal component based on its periodic pattern.Third,all the imputed results are merged to obtain the imputation result.Finally,six time series of WWTP are used to evaluate the imputation performance of the proposed UIM by comparing with existing seven methods based on two indicators.The experimental results illustrate that the proposed UIM is effective for WWTP time series under different missing ratios.Therefore,the proposed UIM is a promising method to impute WWTP time series. 展开更多
关键词 Univariate SELF-SIMILARITY waste water ALGORITHM INTEGRATION
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Arsenic removal from acidic industrial wastewater by ultrasonic activated phosphorus pentasulfide
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作者 Bo Yu Guang Fu +6 位作者 Xinpei Li Libo Zhang Jing Li Hongtao Qu Dongbin Wang Qingfeng Dong Mengmeng Zhang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第8期46-52,共7页
Arsenic is one of the main harmful elements in industrial wastewater.How to remove arsenic has always been one of the research hotspots in academic circles.In the process of arsenic removal by traditional sulfuration,... Arsenic is one of the main harmful elements in industrial wastewater.How to remove arsenic has always been one of the research hotspots in academic circles.In the process of arsenic removal by traditional sulfuration,the use of traditional sulfurizing agent will introduce new metal cations,which will affect the recycling of acid.In this study,phosphorus pentasulfide (P_(2)S_(5)) was used as sulfurizing agent,which hydrolyzed to produce H_(3)PO_(4) and H_(2)S without introducing new metal cations.The effect of ultrasound on arsenic removal by P_(2)S_(5) was studied.Under the action of ultrasound,the utilization of P_(2)S_(5) was improved and the reaction time was shortened.The effects of S/As molar ratio and reaction time on arsenic removal rate were investigated under ultrasonic conditions.Ultrasonic enhanced heat and mass transfer so that the arsenic removal rate of 94.5%could be achieved under the conditions of S/As molar ratio of 2.1:1 and reaction time of 20 min.In the first 60 min,under the same S/As molar ratio and reaction time,the ultrasonic hydrolysis efficiency of P_(2)S_(5) was higher.This is because P_(2)S_(5) forms ([(P_(2)S_(4))])^(2+)under the ultrasonic action,and the structure is damaged,which is easier to be hydrolyzed.In addition,the precipitation after arsenic removal was characterized and analyzed by X-ray diffraction,scanning electron microscope-energy dispersive spectrometer,X-ray fluorescence spectrometer and X-ray photoelectron spectroscopy.Our research avoids the introduction of metal cations in the arsenic removal process,and shortens the reaction time. 展开更多
关键词 Arsenic removal Mass transfer PRECIPITATION waste water Ultrasound
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An internal circulation iron-carbon micro-electrolysis reactor for aniline wastewater treatment:Parameter optimization,degradation pathways and mechanism
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作者 Yanhe Han Han Xu +4 位作者 Lei Zhang Xuejiao Ma Yang Man Zhimin Su Jing Wang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第11期96-107,共12页
Aniline is a vital industrial raw material.However,highly-toxic aniline wastewater usually deteriorated effluent quality,posed a threat to human health and ecosystem safety.Therefore,this study reported a novel intern... Aniline is a vital industrial raw material.However,highly-toxic aniline wastewater usually deteriorated effluent quality,posed a threat to human health and ecosystem safety.Therefore,this study reported a novel internal circulation iron-carbon micro-electrolysis(ICE)reactor to treat aniline wastewater.The effects of reaction time,pH,aeration rate and iron-carbon(Fe/C)ratio on the removal rate of aniline and the chemical oxygen demand were investigated using single-factor experiments.This process exhibited high aniline degradation performance of approximately 99.86% under optimal operating conditions(reaction time=20 min,pH=3,aeration rate=0.5 m3·h^(-1),and Fe/C=1:2).Based on the experimental results,the response surface method was applied to optimize the aniline removal rate.The Box–Behnken method was used to obtain the interaction effects of three main factors.The result showed that the reaction time had a dominant effect on the removal rate of aniline.The highest aniline removal rate was obtained at pH of 2,aeration rate of 0.5 m^(3)·h^(-1)and reaction time of 30 min.Under optional experimental conditions,the aniline content of effluent was reduced to 3 mg·L^(-1)and the removal rate was as high as 98.24%,within the 95% confidence interval(97.84%-99.32%)of the predicted values.The solution was treated and the reaction intermediates were identified by high-performance liquid chromatography,ultraviolet-visible spectroscopy,Fourier-transform infrared spectroscopy,gas chromatography-mass spectrometry,and ion chromatography.The main intermediates were phenol,benzoquinone,and carboxylic acid.These were used to propose the potential mechanism of aniline degradation in the ICE reactor.The results obtained in this study provide optimized conditions for the treatment of industrial wastewater containing aniline and can strengthen the understanding of the degradation mechanism of iron-carbon micro-electrolysis. 展开更多
关键词 ANILINE Iron-carbon micro-electrolysis Circulating fluidized bed waste water DEGRADATION
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UnderwaterWaste Recognition and Localization Based on Improved YOLOv5 被引量:2
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作者 Jinxing Niu Shaokui Gu +1 位作者 Junmin Du Yongxing Hao 《Computers, Materials & Continua》 SCIE EI 2023年第8期2015-2031,共17页
With the continuous development of the economy and society,plastic pollution in rivers,lakes,oceans,and other bodies of water is increasingly severe,posing a serious challenge to underwater ecosystems.Effective cleani... With the continuous development of the economy and society,plastic pollution in rivers,lakes,oceans,and other bodies of water is increasingly severe,posing a serious challenge to underwater ecosystems.Effective cleaning up of underwater litter by robots relies on accurately identifying and locating the plastic waste.However,it often causes significant challenges such as noise interference,low contrast,and blurred textures in underwater optical images.A weighted fusion-based algorithm for enhancing the quality of underwater images is proposed,which combines weighted logarithmic transformations,adaptive gamma correction,improved multi-scale Retinex(MSR)algorithm,and the contrast limited adaptive histogram equalization(CLAHE)algorithm.The proposed algorithm improves brightness,contrast,and color recovery and enhances detail features resulting in better overall image quality.A network framework is proposed in this article based on the YOLOv5 model.MobileViT is used as the backbone of the network framework,detection layer is added to improve the detection capability for small targets,self-attention and mixed-attention modules are introduced to enhance the recognition capability of important features.The cross stage partial(CSP)structure is employed in the spatial pyramid pooling(SPP)section to enrich feature information,and the complete intersection over union(CIOU)loss is replaced with the focal efficient intersection over union(EIOU)loss to accelerate convergence while improving regression accuracy.Experimental results proved that the target recognition algorithm achieved a recognition accuracy of 0.913 and ensured a recognition speed of 45.56 fps/s.Subsequently,Using red,green,blue and depth(RGB-D)camera to construct a system for identifying and locating underwater plastic waste.Experiments were conducted underwater for recognition,localization,and error analysis.The experimental results demonstrate the effectiveness of the proposed method for identifying and locating underwater plastic waste,and it has good localization accuracy. 展开更多
关键词 Underwater image enhancement detection of waste underwater target localization RGB-D camera
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Waste-Derived Catalysts for Water Electrolysis:Circular Economy-Driven Sustainable Green Hydrogen Energy 被引量:3
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作者 Zhijie Chen Sining Yun +7 位作者 Lan Wu Jiaqi Zhang Xingdong Shi Wei Wei Yiwen Liu Renji Zheng Ning Han Bing-Jie Ni 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第1期43-79,共37页
The sustainable production of green hydrogen via water electrolysis necessitates cost-effective electrocatalysts.By following the circular economy principle,the utilization of waste-derived catalysts significantly pro... The sustainable production of green hydrogen via water electrolysis necessitates cost-effective electrocatalysts.By following the circular economy principle,the utilization of waste-derived catalysts significantly promotes the sustainable development of green hydrogen energy.Currently,diverse waste-derived catalysts have exhibited excellent catalytic performance toward hydrogen evolution reaction(HER),oxygen evolution reaction(OER),and overall water electrolysis(OWE).Herein,we systematically examine recent achievements in waste-derived electrocatalysts for water electrolysis.The general principles of water electrolysis and design principles of efficient electrocatalysts are discussed,followed by the illustration of current strategies for transforming wastes into electrocatalysts.Then,applications of waste-derived catalysts(i.e.,carbon-based catalysts,transitional metal-based catalysts,and carbon-based heterostructure catalysts)in HER,OER,and OWE are reviewed successively.An emphasis is put on correlating the catalysts’structure-performance relationship.Also,challenges and research directions in this booming field are finally highlighted.This review would provide useful insights into the design,synthesis,and applications of waste-derived electrocatalysts,and thus accelerate the development of the circular economy-driven green hydrogen energy scheme. 展开更多
关键词 waste-derived electrocatalysts water splitting Sustainable hydrogen energy Catalyst design Circular economy
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Production of Biogas from Olive Mill Waste Waters Treated by Cow Manure
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作者 Fatma Laabidi Rafik Besbès Bassem Jamoussi 《Green and Sustainable Chemistry》 CAS 2023年第1期62-71,共10页
The olive mill waste waters (OMWW) generated from olive oil extraction is a major environmental concern since they are characterized by their role as a pollutant (high organic and mineral matters) and their pH acid. T... The olive mill waste waters (OMWW) generated from olive oil extraction is a major environmental concern since they are characterized by their role as a pollutant (high organic and mineral matters) and their pH acid. The aim of this study was to valorize (OMWW) by anaerobic fermentation in the presence of cow manure in order to produce biogas and reduce their toxic load. Many tests were carried out by fermenting (OMWW) with polyphenols in the presence of cow manure in thermophile temperatures. The performance of this treatment was valuated through measurements of biogas production and by the determination of different parameters of fermented media (pH, volume of the biogas and polyphenols). 展开更多
关键词 Olive Mill waste waters Anaerobic Fermentation Cow Manure BIOGAS POLYPHENOLS
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Synthesis of waterborne polyurethane-humic acid cross-linked biomass porous materials for the adsorption of methylene blue
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作者 Shanghong Ma Jianbo Qu +4 位作者 Haitao Zhang Xiubin Cui Peng Ye Qingfei Hu Mingzhen Chao 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第3期27-38,共12页
A series of adsorbent materials(WPU-HAx-y)with a three-dimensional porous structure,green sustainability,and excellent performance were prepared and evaluated for the removal of methylene blue using nontoxic and envir... A series of adsorbent materials(WPU-HAx-y)with a three-dimensional porous structure,green sustainability,and excellent performance were prepared and evaluated for the removal of methylene blue using nontoxic and environmentally friendly waterborne polyurethane as the matrix material and humic acid,a biomass material,as the functional material.The newly synthesized adsorbents were characterized by infrared spectroscopy,scanning electron microscopy,specific surface area,and thermogravimetric.The effects of contact time(0-8 h),starting concentration(10-100 mg·L^(-1)),pH(3-11),solution temperature(30-60℃),and coexisting ions(Ca2+,Na+,K+,Mg2+)on the performance were investigated.Pseudo-first-order,pseudo-second-order,elovich,and intra-particle diffusion models were used to analyze the adsorption kinetics;the Langmuir,Freundlich,Temkin,and Dubin-Radushkovich adsorption isotherms were evaluated;and the adsorption behavior of the adsorbent materials was found to be more appropriate for the pseudo-second-order model for chemical pollutant removal than the Langmuir model,which depends on monolayer adsorption.WPU-HA2-3 stood out with a maximum adsorption capacity of 813.0081 mg·g^(-1) fitted to the pseudo-second-order and 309.2832 mg·g^(-1) fitted to the Langmuir model,showing superior adsorption performance and regenerability. 展开更多
关键词 Porous media BIOENERGY Sustainability waste water
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Ultralow-voltage hydrogen production and simultaneous Rhodamine B beneficiation in neutral wastewater 被引量:1
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作者 Xiang Peng Song Xie +8 位作者 Shijian Xiong Rong Li Peng Wang Xuming Zhang Zhitian Liu Liangsheng Hu Biao Gao Peter Kelly Paul K.Chu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第6期574-582,I0013,共10页
Electrocatalytic water splitting for hydrogen production is hampered by the sluggish oxygen evolution reaction(OER)and large power consumption and replacing the OER with thermodynamically favourable reactions can impr... Electrocatalytic water splitting for hydrogen production is hampered by the sluggish oxygen evolution reaction(OER)and large power consumption and replacing the OER with thermodynamically favourable reactions can improve the energy conversion efficiency.Since iron corrodes easily and even self-corrodes to form magnetic iron oxide species and generate corrosion currents,a novel strategy to integrate the hydrogen evolution reaction(HER)with waste Fe upgrading reaction(FUR)is proposed and demonstrated for energy-efficient hydrogen production in neutral media.The heterostructured MoSe_(2)/MoO_(2) grown on carbon cloth(MSM/CC)shows superior HER performance to that of commercial Pt/C at high current densities.By replacing conventional OER with FUR,the potential required to afford the anodic current density of 10 m A cm^(-2)decreases by 95%.The HER/FUR overall reaction shows an ultralow voltage of 0.68 V for 10 m A cm^(-2)with a power equivalent of 2.69 k Wh per m^(3)H_(2).Additionally,the Fe species formed at the anode extract the Rhodamine B(Rh B)pollutant by flocculation and also produce nanosized magnetic powder and beneficiated Rh B for value-adding applications.This work demonstrates both energy-saving hydrogen production and pollutant recycling without carbon emission by a single system and reveals a new direction to integrate hydrogen production with environmental recovery to achieve carbon neutrality. 展开更多
关键词 Energy-saving hydrogen production Hydrogen evolution reaction Neutral water splitting MoSe_(2)/MoO_(2)heterostructure Environmental recovery
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Development of advanced anion exchange membrane from the view of the performance of water electrolysis cell 被引量:2
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作者 Chao Liu Zhen Geng +6 位作者 Xukang Wang Wendong Liu Yuwei Wang Qihan Xia Wenbo Li Liming Jin Cunman Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第3期348-369,I0009,共23页
Green hydrogen produced by water electrolysis combined with renewable energy is a promising alternative to fossil fuels due to its high energy density with zero-carbon emissions.Among water electrolysis technologies,t... Green hydrogen produced by water electrolysis combined with renewable energy is a promising alternative to fossil fuels due to its high energy density with zero-carbon emissions.Among water electrolysis technologies,the anion exchange membrane(AEM) water electrolysis has gained intensive attention and is considered as the next-generation emerging technology due to its potential advantages,such as the use of low-cost non-noble metal catalysts,the relatively mature stack assembly process,etc.However,the AEM water electrolyzer is still in the early development stage of the kW-level stack,which is mainly attributed to severe performance decay caused by the core component,i.e.,AEM.Here,the review comprehensively presents the recent progress of advanced AEM from the view of the performance of water electrolysis cells.Herein,fundamental principles and critical components of AEM water electrolyzers are introduced,and work conditions of AEM water electrolyzers and AEM performance improvement strategies are discussed.The challenges and perspectives are also analyzed. 展开更多
关键词 HYDROGEN water electrolysis Anion exchange membrane Electrolysis cell
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Insights on advanced substrates for controllable fabrication of photoanodes toward efficient and stable photoelectrochemical water splitting 被引量:1
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作者 Huilin Hou Gang Shao +2 位作者 Yang Wang Wai‐Yeung Wong Weiyou Yang 《Carbon Energy》 SCIE EI CAS CSCD 2024年第4期164-221,共58页
Conversion of solar energy into H_(2) by photoelectrochemical(PEC)water splitting is recognized as an ideal way to address the growing energy crisis and environmental issues.In a typical PEC cell,the construction of p... Conversion of solar energy into H_(2) by photoelectrochemical(PEC)water splitting is recognized as an ideal way to address the growing energy crisis and environmental issues.In a typical PEC cell,the construction of photoanodes is crucial to guarantee the high efficiency and stability of PEC reactions,which fundamentally rely on rationally designed semiconductors(as the active materials)and substrates(as the current collectors).In this review work,we start with a brief introduction of the roles of substrates in the PEC process.Then,we provide a systematic overview of representative strategies for the controlled fabrication of photoanodes on rationally designed substrates,including conductive glass,metal,sapphire,silicon,silicon carbide,and flexible substrates.Finally,some prospects concerning the challenges and research directions in this area are proposed. 展开更多
关键词 hydrogen PHOTOANODE PHOTOELECTROCHEMICAL SUBSTRATES water splitting
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Experimental study on the effect of water absorption level on rockburst occurrence of sandstone 被引量:1
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作者 Dongqiao Liu Jie Sun +3 位作者 Pengfei He Manchao He Binghao Cao Yuanyuan Yang 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第1期136-152,共17页
To investigate the mechanism of rockburst prevention by spraying water onto the surrounding rocks,15 experiments are performed considering different water absorption levels on a single face.High-speed photography and ... To investigate the mechanism of rockburst prevention by spraying water onto the surrounding rocks,15 experiments are performed considering different water absorption levels on a single face.High-speed photography and acoustic emission(AE)system are used to monitor the rockburst process.The effect of water on sandstone rockburst and the prevention mechanism of water on sandstone rockburst are analyzed from the perspective of energy and failure mode.The results show that the higher the ab-sorption degree,the lower the intensity of the rockburst after absorbing water on single side of sand-stone.This is reflected in the fact that with the increase in the water absorption level,the ejection velocity of rockburst fragments is smaller,the depth of the rockburst pit is shallower,and the AE energy is smaller.Under the water absorption level of 100%,the magnitude of rockburst intensity changes from medium to slight.The prevention mechanism of water on sandstone rockburst is that water reduces the capacity of sandstone to store strain energy and accelerates the expansion of shear cracks,which is not conducive to the occurrence of plate cracking before rockburst,and destroys the conditions for rockburst incubation. 展开更多
关键词 ROCKBURST water Prevention effect Crack evolution
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