Reuse of waste frying oil for production of rhamnolipids using Pseudomonas aeruginosa zju.u1M

In this work,rhamnolipid production was investigated using waste frying oil as the sole carbon source. By culture in shaking flasks,a naturally isolated strain synthesized rhamnolipid at concentration of 12.47 g/L and its mutant after treatment by UV light increased this productivity to 24.61 g/L. Fermentation was also conducted in a 50 L bioreactor and the productivity reached over 20 g/L. Hence,with a stable and high productive mutant strain,it could be feasible to reuse waste frying oil for rhamnolipid production on industrial scale.

The Kinetics of the Esterification of Free Fatty Acids in Waste Cook- ing Oil Using Fe2（SO4）3/C Catalyst

The esterification of free fatty acids(FFA) in waste cooking oil with methanol in the presence of Fe2(SO4)3/C(ferric sulfate/active carbon) catalyst was studied.The effects of different temperature,methanol/FFA mole ratio and amount of catalyst on the conversion of FFA were investigated.The results demonstrated that under optimal esterification conditions the final acid value of the resultant system can be reduced to ～1(mg KOH)·g-1,which met fully the requirements in post-treatment for efficient separation of glycerin and biodiesel.The kinetics of the esterification were also investigated under different temperatures.The results indicated that the rate-control step could be attributed to the surface reaction and the esterification processes can be well-depicted by the as-calculated kinetic formula in the range of the experimental conditions.

Effect of ethanol addition on flame characteristics of waste oil biodiesel

Biodiesel is a kind of clean and renewable energy. The effect of ethanol addition on the flame characteristics of waste oil biodiesel is studied by using OH-PLIF technique from the perspective of OH radical evolution. Ethanol addition leads to the appearance of diffusion flame reaction interface ahead of schedule and shortens the diffusion flame height. The experimental results show a linear correlation between the flame height and the fuel flow rate for a given fuel and oxidant. The same conclusion is drawn from the theoretical analysis of the approximate model. In addition. ethanol addition makes the average OH signal intensity of flame at different fuel flow rate tend to be consistent and the fuel flow rate enlarge where the flame field shows the strongest oxidation performance. Average OH signal intensity begins to weaken at larger fuel flow rate, which indicates that fuel flow rate of fuels blended with ethanol can change in larger range and does not significantly affect the uniformity of combustion.

Diffusion and Regeneration Mechanism of Waste Composite Oils Rejuvenator in Aged Asphalt

The physical performance of recycled asphalt was used as the main evaluation index to study the optimal range of a self-made rejuvenator.Through the penetration,viscosity and gel permeation chromatography(GPC)tests,the diffusion degree of the rejuvenator under different temperatures and time process was analyzed,and the diffusion efficiency of the rejuvenator was evaluated from the macro and micro perspective.The regeneration mechanism of the rejuvenator in the aged asphalt was also analyzed using the Fourier transform infrared spectroscopy(FTIR),scanning electron microscope(SEM)and chemical composition tests.The research results showed that the optimum rejuvenator content was about 3%.Higher temperature and longer time were beneficial to improving the permeability and diffusion of the rejuvenator.During the aging process,the light components were reduced,and more macromolecular asphaltenes were generated as well as a large number of carbonyl and sulfoxide.After diffusion and regeneration,the light components in the asphalt were supplemented,the wrinkles and gullies of the aged asphalt were almost improved to the surface state of the matrix asphalt.

Investigation of performance and emission characteristics of waste cooking oil as biodiesel in a diesel engine

Biodiesel is one of the most popular prospective alternative fuels and can be obtained from a variety of sources. Waste frying oil is one such source along with the various raw vegetable oils. However, some specific technical treatments are required to improve certain fuel properties such as viscosity and calorific value of the biodiesel being obtained from waste cooking oil methyl ester （WCOME）. Various treatments are applied depending on the source and therefore the composition of the cooking oil. This research investigated the performance of WCOME as an alternative biofuel in a four-stroke direct injection diesel engine. An 8-mode test was undertaken with diesel fuel and five WCOME blends. The best compromise blend in terms of performance and emissions was identified. Results showed that energy utilization factors of the blends were similar within the range of the operational parameters （speed, load and WCOME content）. Increasing biodiesel content produced slightly more smoke and NOx for a great majority of test points, while the CO and THC emissions were lower.

Solid- liquid phase separation and resource recycling study for waste rolling oily sludge

On the basis of the characteristics of a highly emulsified solid-liquid phase （fine particles, sticky consistency,black color, and low reuse ratio）, waste rolling oily sludge has been a focal problem in the steel industry. In this article, a solid-liquid phase separation and resource recycling process was described, with pilot test results showing that flocculation-sedimentation is an effective pretreatment, and that the filtration-coagulationvacuum distillation process is simple and feasible with a 53.5% recovery rate for regenerated oil that is qualified for return to the roiling production line. Then,solid phase oil-sludge was extracted by solvents with a 77% metal resource recovery rate and a wide utilization range. Finally, according to the experimental results, a set of feasibility plans for a 50 t/a waste rolling oily sludge solid-liquid separation and resource recycle project was designed, with the expectation of 50% regenerated oil yield, 70% solid metal resource recovery, and a 2. 5-year investment payback period.

Efficient catalytic conversion of jatropha oil to high grade biofuel on Ni-Mo_(2)C/MCM-41 catalysts with tuned surface properties

The activity of Mo_(2) C-based catalyst on vegetable oil conversion into biofuel could be greatedly promoted by tuning the carbon content,while its modification mechanism on the surface properties remained elusive.Herein,the exposed active sites,the particle size and Lewis acid amount of Ni-Mo_(2) C/MCM-41 catalysts were regulated by varying CH_(4) content in carbonization gas.The activity of Ni-Mo_(2) C/MCM-41 catalysts in jatropha oil(JO)conversion showed a volcano-like trend over the catalysts with increasing CH_(4) content from 15%to 50%in the preparation process.The one prepared by 25%CH_(4) content(NiMo_(2) C(25)/MCM-41)exhibited the outstanding catalytic performance with 83.9 wt%biofuel yield and95.2%C_(15)-C_(18) selectivity.Such a variation of activity was ascribed to the most exposed active sites,the smallest particle size,and the lowest Lewis acid amount from Ni^(0) on the Ni-Mo_(2) C(25)/MCM-41 catalyst surface.Moreover,the Ni-Mo_(2) C(25)/MCM-41 catalyst could also effectively catalyze the conversion of crude waste cooking oil(WCO)into green diesel.This study offers an effective strategy to improve catalytic performance of molybdenum carbide catalyst on vegetable oil conversion.

Optimizing rhamnolipid production by Pseudomonas aeruginosa ATCC 9027 grown on waste frying oil using response surface method and batch-fed fermentation

Rhamnolipid production by Pseudomonas aeruginosa ATCC 9027 with waste frying oil as sole carbon source was studied using response surface method. Cultures were incubated in shaking flask with temperature, NO3- and Mg2+ concentrations as the variables. Meanwhile, fed-batch fermentation experiments were conducted. The results show that the three variables are closely related to rhamnolipid production. The optimal cultivation conditions are of 6.4 g/L NaNO3 , 3.1 g/L MgSO4 at 32 ℃, with the maximum rhamnolipid production of 6.6 g/L. The results of fed-batch fermentation experiments show that feeding the oil in two batches can enhance rhamnolipid production. The best time interval is 72 h with the maximum rhamnolipid production of 8.5 g/L. The data are potentially useful for mass production of rhamnolipid on oil waste with this bacterium.

Diester Derivatives from Chemically Modified Waste Cooking Oil as Substitute for Petroleum Based Lubricating Oils

In order to provide a new way for waste cooking oil(WCO) resource utilization, several diester derivatives were obtained from WCO through a three-step chemical modifications, viz.: transesterification, epoxidation and oxirane ring opening with carboxylic acids. The effects of the chain length of side chain groups on the viscosity, acid value, low temperature fluidity, thermo-oxidative stability, tribological properties and surface tension of diester derivatives were investigated. The results showed that increasing the chain length of side chain groups had a positive influence on the viscosity, viscosity index, acid value, pour point, friction coefficient and wear scar diameter along with a negative influence on the oxidation onset temperature, volatile loss, insoluble deposit, maximum non-seizure load and surface tension. These diester derivatives exhibited improved physicochemical and tribological properties that make themselves promising environmentally friendly biolubricant basestocks.

Biodiesel Production from Waste Cooking Oil by Enzymatic Catalysis Process

Biodiesel is an excellent option for reducing dependence on fossil fuels with environmental advantages by reducing hazardous emissions. The enzymatic transesterification has attracted the attention of researchers in the last decade and the advantages of enzymatic catalysis show that the production of biodiesel by this route has good potential, mainly because it is friendly environment. For biodiesel, production process by enzyme catalysis is chosen the response surface methodology. It is an experimental strategy to find the best operating conditions oftransesterification reaction to improve the biodiesel quality. The Process has three variables： temperature, molar ratio oil-alcohol and catalyst quantity. The process was monitored by GC-FID （gas chromatography with flame ionization detector）. The yield of the transesterification reaction by enzymatic catalysis decreases with increasing temperature, and may be due to inactivation of the enzyme by denaturation at temperatures above 50 ℃. The second-order design used was the ＂CDC （central design composition）＂ which produced a maximum yield of 95.5% in the transesterification reaction by enzymatic catalysis obtained at a temperature of 45 ℃, molar ratio methanol：oil of 8：1 and a catalyst loading of 8% wt.

Extraordinary Compatibility to Mass Loading and Rate Capability of Hierarchically Porous Carbon Nanorods Electrode Derived from the Waste Tire Pyrolysis Oil

The conversion of waste tire pyrolysis oil(WTPO)into S-doped porous carbon nanorods(labeled as WPCNs)with hierarchical pore structure is realized by a simple template-directed approach.The specific surface area of as-obtained porous carbon nanorods can reach up to 1448 m^(2) g^(−1) without the addition of any activating agent.As the capacitive electrode,WPCNs possess the extraordinary compatibility to capacitance,different electrolyte systems as well as long-term cycle life even at a commercial-level areal mass loading(10 mg cm^(−2)).Besides,only an extremely small capacitance fluctuation is observed under the extreme circumstance(−40 to 80℃),reflecting the excellent high-and low-temperature performance.The relationship between the pore structure and capacitive behavior is analyzed by comparing WPCNs with mesopores-dominated asphalt-derived porous carbon nanorods(APCNs)and micropores-dominated activated carbon.The molecular dynamics simulation further reveals the ion diffusion and transfer ability of the as-prepared carbon materials under different pore size distribution.The total ion flow(NT)of WPCNs calculated by the simulation is obviously larger than APCNs and the N_(T) ratio between them is similar with the experimental average capacitance ratio.Furthermore,this work also provides a valuable strategy to prepare the electrode material with high capacitive energy storage ability through the high value-added utilization of WTPO.

Novel efficient procedure for biodiesel synthesis from waste oils with high acid value using 1-sulfobutyl-3-methylimidazolium hydrosulfate ionic liquid as the catalyst

Preparation of biodiesel from waste oils containing 72% of free fatty acids catalyzed by a novel Br?nsted acidic ionic liquid 1-sulfobutyl-3-methylimidazolium hydrosulfate([BHSO_3MIM][HSO_4]) was systematically investigated.The optimum molar ratio of methanol to waste oils,catalyst amount,reaction temperature and reaction time were 8/1,10%(based on the mass of waste oils),140°C and 6 h,respectively,under which the obtained yield of biodiesel reached 94.9%.Also,[BHSO_3MIM][HSO_4] as a catalyst still retained around 97% of its original catalytic activity after successive re-use of 5 batches(6 h per batch),showing the excellent operational stability.Moreover,the acidic IL [BHSO_3MIM][HSO_4] was able to ef ficiently catalyze conversions of waste oils with different amounts of FFAs(free fatty acids) into biodiesel,and showed tremendous application potential.Therefore,an ef ficient and environmentally friendly catalyst is provided for the synthesis of biodiesel from waste oils with high acid value.

Utilization of Waste Cooking Oil as Diesel Fuel and Improvement in Combustion and Emission

Due to high price of Straight Vegetable Oil （SVO） for bio-diesel production, the use of Waste Cooking Oil （WCO） will be cost effective. Furthermore, utilization of WCO will refrain waterways pollution and endanger ecosystem. In Malaysia, more than 50-tone of WCO from various sources was produced every day. This study evaluates combustion performance and exhaust emission characteristics of several WCOs with different sources. Modification on fuel properties has been done to improve the combustion and exhaust emission of using WCO as diesel fuel. Regular diesel fuel also has been used for comparison in the test. A 0.6 liter, single-cylinder, air-cooled direct injection diesel engine was used to perform this experiment. Experiment was done at variable engine loads at constant speed.

Rheological properties and microscopic mechanism of waste cooking oil activated waste crumb rubber modified asphalt

In this paper,the surface activated crumb rubber with waste cooking oil(WCO)was studied to improve the performance of crumb rubber modified asphalt.The activated waste crumb rubber modified asphalt(OCRMA)with different amount of crumb rubber was prepared to study the microscopic appearance of OCRMA by scanning electron microscope and fluorescence microscope and analyze the surface performance.The rheological properties and microscopic mechanism of OCRMA were characterized by dynamic shear rheological test,multiple stress creep recovery(MSCR)test,BBR test and infrared spectroscopy.The results show that the dissolution degree of waste crumb rubber is improved after WCO activation,and the compatibility with asphalt components is enhanced,and the stable cross-linking structure is formed,which improves the asphalt performance.The several new absorption peaks,which were obvious,were all caused by the composition of WCO,that is,there was no significant chemical change during the interaction between the activated crumb rubber and base asphalt.Compared with the common waste crumb rubber modified asphalt(CRMA),activation with WCO can significantly reduce the viscosity of CRMA,decrease the difference of segregation softening point by 27%,and enhance the low temperature performance by 30%.The aging degree is greatly reduced,and the anti-aging performance of OCRMA is increased by about 20%with the same dosage.The high temperature performance,though higher than that of base asphalt,decreases to some extent.After comprehensive analysis,the optimal dosage of crumb rubber for OCRMA is 30%.

Application and circular economy prospects of palm oil waste for eco-friendly asphalt pavement industry:A review

During the production of palm oil,a significant amount of waste is generated.However,because of inefficient handling and utilization,these wastes are becoming a larger issue.As a result,one initiative is to use these wastes in the pavement industry as sustainable materials.However,there is still a lack of understanding about the wider incorporation of palm oil waste in asphalt pavement and its performance.This study examines existing literature on the use of various wastes in the pavement industry,including palm oil clinker(POC),palm oil fibre(POF),palm kernel shell(PKS),and palm oil fuel ash(POFA).As a result,this paper presents a systematic review and scientometric investigation of related study publications on many uses of palm oil waste in the asphalt pavement industry and its performance from 2009 to 2022.The VOS viewer application was used to conduct the sciento-metric study analysis.The relationship between interactions detected in co-authored country studies cited sources of co-citation,and the keyword of the co-occurrence and publication source enabled the identification of the research gap.According to the systematic literature review,40%–60% POC can be used to fine aggregate for optimal performance,while 0–100%PKS can be used to replace coarse aggregate.In addition,50%–80% POFA or POC fine(POCF)can be used as a filler replacement,5%–8% POCF or POFA as a bitumen modifier,and 0.3% POF as a stabilizing additive.Furthermore,the study demonstrates that the safety of utilizing wastes with more than 50% CO_(2) emissions can be curtailed with minimal heavy metal leaching and radioactivity levels.The scientometric analysis may encourage researchers to seek out gaps in the literature that will aid in the long-term,multifaceted use of palm oil wastes in the asphalt pavement industry.Furthermore,the study recommends employing and researching the enormous potential of using palm oil waste in the pavement sectors because they are more sustainable and have better performance.However,there are some barriers to using palm oil waste in the asphalt pavement industry,such as a lack of design standards and guidelines,inefficient raw material pro-cessing conversion facilities,and large-scale production equipment.

Biodiesel Production from Waste Cooking Oil over Mesoporous SO42-/Zr-SBA-15

Biodiesel production from waste cooking oils over SO42-/Zr-SBA-15 catalyst was successfully carried out and investigated. SO42-/Zr-SBA-15 catalyst was prepared by one-step process using anhydrous zirconium nitrate as zirconium resource, and endowed with the strong Lewis acid sites formed by supporting the zirconium species onto the SBA-15 surface. The asprepared SOt2-/Zr-SBA-15 showed excellent triglyceride conversion efficiency of 92.3% and fatty acid methyl esters （FAME） yield of 91.7% for the transesterification of waste cooking oil with methanol under the optimized reaction conditions： the methanol/oil molar ratio of 30, the reaction temperature of 160 ℃, the reaction time of 12 h and 10wt% of catalyst. It was noticed that the as-prepared SOa2-/Zr-SBA-15 materials with the higher area surface of mesoporous framework and the surface acidity displayed excellent stability and reusability, maintaining high FAME yield of （74±1）% after seven runs of reaction.

Esterification of Free Fatty Acids in Waste Cooking Oil by Heterogeneous Catalysts

Waste cooking oil(WCO) is becoming the most promising alternative feedstock to produce biodiesel due to its low cost in China. In this study, NKC-9 ion-exchange resin and H-beta zeolite were selected as heterogeneous catalysts in the WCO esterification process and their esterification characteristics were compared by orthogonal experiments. NKC-9 resin showed higher activity and achieved a higher final conversion compared with H-beta zeolite under the same reaction conditions. Reusability experiments showed that NKC-9 resin still exhibited high activity after 5 runs. The effects of the mole ratio of alcohol to oil, reaction time, reaction temperature and the catalyst dose were investigated by multifactor orthogonal analysis. The influence of the free fatty acid(FFA) content was also investigated, and the result showed that the esterification rate could be as high as 98.4% when the FFA content was 6.3wt%.

Engine performance and combustion characteristics of a direct injection compression ignition engine fueled waste cooking oil synthetic diesel

Biodiesels produced from various feedstocks have been considered as alternative fuels used in internal combustion engines without major modifications.This research focuses on producing biodiesel from waste cooking oil(WCOSD)by the catalytic cracking method using MgO as the catalyst and comparing the engine operating characteristics of the test engine when using WCOSD and traditional diesel(CD)as test fuels.As a result,the brake power of the test engine fueled WCOSD,and traditional diesel is similar.However,the engine fuel consumption in the case of using WCOSD is slight increases in some operating conditions.Also,the nitrogen oxides emissions of the test engine fueled WCOSD are higher than those of CD at all tested conditions.The trend is opposite for hydrocarbon emission as the HC emission of the engine fueled by WCOSD reduces 26.3%on average.The smoke emission of the test engine in case of using WCOSD is lower 17%on average than that of CD.However,the carbon monoxide emissions are lower at the low and medium loads and higher at the full loads.These results show that the new biodiesel has the same characteristics as those of commercial biodiesel and can be used as fuel for diesel engines.

Production Optimization of Biodiesel from Frying Oil Waste to Reduce the Environmental Impacts

The objective of this study was to reduce the environmental impacts of used frying oil waste through the production of biodiesel. A 22 factorial planning has been used to evaluate the influences of alcohol/oil and reaction time on the biodiesel production yield. The optimal condition to produce the biodiesel has been found by use of the response surface methodology and analysis of variance to obtain the fitting model. This study was conducted in Campinas city, Brazil, where were collected the waste oil. An analysis of ecological cost also has been developed. Cooking oils collected from Campinas homes were mixed with ethanol in planned proportions （1：9, 1：7 and 1：5） and were transesterified at 60 ℃ and planned reaction times （30, 60 or 90 min）, in order to obtain biodiesel, using 0.1% NaOH as a catalyst. The results of the physical-chemical analyses demonstrated that the biodiesels obtained possessed characteristics close to those required by Brazilian standards. This fuel could be used in fleets of buses, trucks and machines, or even sold to fuel distributors, which results in a solving between US$0.8 and US$4.5 millions. Thus, Campinas would gain environmental credits and become a sustainable city.

Characterization and Modification of Indonesian Natural Zeolite for Hydrocracking of Waste Lubricant Oil into Liquid Fuel Fraction

Modification and characterization of natural zeolite under some various methods for hydrocracking catalyst of waste lubricant to gasoline and diesel fractions have been conducted. Natural zeolite from Klaten was activated using hydrothermal treatment at temperature 500 ℃ for 6 h （produced ZAAHd）, the ZA sample was treated with hydrothermal followed by Microwave （produced ZAAHdM）, the ZA sample was treated with HCI 3 N at temperature of 90 ℃ for 30 min （produced ZAAH）, the ZAAH sample was heated in to microwave （produced ZAAHM）, the ZAAHM was treated hydrothermal （produced ZAAHMHd）, the ZAAHMHd sample was heated in to microwave （produced ZAAHMHdM）, soaking of natural zeolit activated by HCl-microwave-hydrothermal-microwave in NH4NO3 1 N which was stirred using stirer at room temperature for 24 h （produced ZAAHMHdMN） and the ZAAHMHdMN sample was heated into microwave （ZAAHMHdMNM）. The heating process by microwave was conducted at 550 watt for 15 rain. Catalyst characterization involved determination of the number of total acid sites using gravimetric method with vapour adsorption of NH3 and pyridine, catalyst crystallinity by XRD （X-ray diffraction） and TO4 （T= Si and AI） site by infra red spectrophotometer （IR）. Hydrocracking of waste lubricants oil was performed in a fixed bed reactor of stainless steel at temperature of 450 ℃, H2 flow rate of 15 mL/min., feed/catalyst ratio of 5. Liquid products of the hydrocracking were analyzed using GC （gas chromatography）. The characterization results showed that various modification of natural zeolite increased acidity and dealumination degree of the catalysts. Products of the hydrocracking were liquid, coke, and gas fractions. Liquid products consisted of gasoline fraction （C5-C12）, diesel fraction （C12-C20）, and heavy oil fraction （〉 C20）.Thc conversion of liquid products was increased with the increase of catalyst acidity. The greatest liquid product conversion was produced by the ZAAHMHdMNM catalyst, i.e., 56.80%, with selectivity towards gasoline, diesel, and heavy oil fractions was 88.37%, 8.61% and 3.02%, respectively. The increase of catalyst acidity increased the selectivity of gasoline fraction.