Waterproof and Oil Repellent Treatments of Cotton Fabric

The waterproof and oil-repellent finishing of the dyed single-sided plain cotton fabric was carried out by two-dip and two-pad process. The influences of baking temperature (°C), baking time (min), concentration of finishing solution (g/L) and percentage of liquid on waterproof effect of fabric were analyzed;the influences of the contact angle and the baking temperature (°C), the baking time (min) and the concentration of the finishing agent (g/L) on the oil repellency of the fabric were investigated. The results showed that the best water-repellent finishing technology for cotton fabric was the concentration of finishing agent 30 g/L, the baking temperature 110°C, the baking time 1.5 min and the liquid-uptake 70%. The best oil-repellent finishing process for cotton fabric is 35 g/L for finishing agent, 150°C for baking temperature, and 1.5 min for baking time and pick up rate of 80%. After cotton fabric is treated with water-repellent and oil-repellent agent, the water-repellent contact angle of the fabric can reach 128°and the oil-repellent grade 6. The best finishing effect is obtained at this time. After the finishing agent acts on the surface of the fibre, the surface properties of the fibre can be changed, and the surface of the fibre can be changed from hydrophilicity to hydrophobicity. The finishing agent has good film-forming property, which makes the surface of cotton fibre smooth and has good waterproof and oil-repellent performance.

A Study on Water Repellent Effectiveness of Natural Oil-Applied Soil as a Building Material

This study was performed to investigate the water repellent effectiveness of natural oil-applied soil when it is used as a building material. Natural oil types such as olive oil, bean oil, perilla oil and linseed oil, which are being used for producing water repellent timber, are selected for the experiments. It is expected that perilla oil and in seed oil, which are drying oil types will have better water repellent effectiveness than the other types. For the evaluation of water repellence of natural oil-applied soil, a contact angle test was performed. A contact angle of water drop on various surface conditions were tested, and large differences were seen between the natural oil-applied soil and untreated soil. As a result, it is showed that all natural oil types have water repellent effectiveness. However, linseed oil, which is a drying oil type, shows an outstanding water repellent effectiveness value, while perila oil, which is also a drying oil type, shows the lowest value. Additionally, results show that there is no link between water repellent effectiveness and the number of applications of natural oil. Nevertheless, existing commercial water repellents show better performance than natural oil, and it is anticipated that the results of this study will provide essential information for further research to enhance the water repellent effectiveness of soil as a building material.

Larvicidal and repellent properties of some essential oils against Culex tritaeniorhynchus Giles and Anopheles subpictus Grassi(Diptera:Culicidae)

Objective:To investigate the larvicidal and repellent properties of essential oils from various parts of four plant species Cymbopogan citrates,Cinnamomum zeylanicum,Rosmarinus of ficinalis and Zingiber of ficinale against Culex tritaeniorhynchus（Cx.tritaeniorhynchus） and Anopheles subpictus（An.subpktus）.Methods:Essential oils were obtained by hydro-distillation method.The mosquitoes were reared in the vector control laboratory and twenty five late third ins tar larvae of Cx.tritaeniorhynchus and An.subpictus were exposed to based on the wide range and narrow range test,essential oil tested at various concentrations ranging from 25 to 250 ppm.The larval mortality was observed after 24 h under the laboratory conditions.The repellent efficacy was determined against two mosquito species at three concentrations viz., 1.0,2.5 and 5.0 mg/cm2 under laboratory conditions.Results:Results showed all the four plant essential oil produced significant larval mortality against two mosquito species.However,the highest larvicidal activity was observed in the essential oil from Zingiber of ficinale against Cx. tritaeniorhynchus and An.subpktus with the LC50 and LC90 values as 98.83,57.98 ppm and 186.55, 104.23 ppm,respectively.All the four essential oil shows significant repellency against Cx. tritaeniorhynchus than An.subpktus.Among four essential oil tested the highest repellency was observed in Zingiber of ficinale,a higher concentration of 5.0 mg/cm2 provided 100%protection up to 150 and 180 min against Cx.tritaeniorhynchus and An.subpktus,respectively.Conclusions: In this work,it can be concluded that four essential oils which were distilled from Cymbopogan citrates,Cinnamomum zeylanicum,Rosmarinus of ficinalis and Zingiber of ficinale showed promising larvicidal and repellent agent against Cx.tritaeniorhynchus and An.subpktus.

Fumigant and repellent properties of sesquiterpene-rich essential oil from Teucrium polium subsp,capitatum(L.)

Objective:To test fumigant and repellent properties of sesquiterpene—rich essential oil from Teucrium polium subsp.capitation(L.).Methods:The fumigant toxicity test was performed at(27±1)℃.(65± 5)%relative humidity,and under darkness condition and 24 h exposure time.The chemical composition of the isolated oils was examined by gas chromatography—mass spectrometry.Results:The major compounds were α-cadiuol(46.2%),earyophyllene oxide(25.9%),α muurolol epi(8.1%),cadalene(3.7%) and longiverbenone(2.9%).In all cases,considerable differences in mortality of insect to essential oil vapor were observed in different concentrations and exposure times.Callosobruchus maculatus(C.maculates)(LC_(50)=148.9μL/L air) was more susceptible to the tested plant product than Teucrium castaneum(T.castaneum)(LC_(50)=360.2μL/L ain based on LC_(50)values.In the present investigation,the concentration of 3μ L /mL acetone showed 60% and 52% repellency against T.casteneum and C.maculatus adults,respectively.Conclusions:The results suggests that sesquiterpene—rich essential oils from the tested plant could be used as a potential control agent for stored—product insects.

Nanoemulsified Mentha piperita and Eucalyptus globulus oils exhibit enhanced repellent activities against Anopheles stephensi

Objective:To formulate nanoemulsion from essential oils of Mentha(M.)piperita L.and Eucalyptus(E.)globulus L.and to compare their repellant activity with normal essential oils and N,N-diethyl-m toluamide(DEET)as a standard chemical compound.Methods:In this study,protection time of essential oils and DEET was evaluated on four human subjects using test cage,and their values were determined against Anopheles stephensi.Furthermore,ED50 values for the above essential oils were determined using the ASTM E951-94 method.The compositions of essential oils were determined using GC-MS,and droplet size and zeta potential of the nanoemulsion were measured with dynamic light scattering.Results:The results(expressed as mean±SD)showed that protection time of M.piperita 50%,M.piperita Nano 50%,E.globulus 50%,E.globulus Nano 50%,and DEET 25%was(2.89±0.45)h,(4.17±0.28)h,(0.96±0.27)h,(5.51±0.02)h,and(6.10±0.47)h,respectively.ED50 values were 29.10(95%CI:23.36-36.06)μg/cm^2 for Mentha,19.39(15.35-23.99)μg/cm^2 for Mentha Nano,36.10(28.70-48.01)μg/cm^2 for Eucalyptus,18.50(14.65-23.23)μg/cm^2 for Eucalyptus Nano,and 3.62(2.68-4.55)μg/cm^2 for DEET,respectively.E.globulus Nano and M.piperita Nano provided significantly longer protection than normal essential oils E.globulus and M.piperita(P<0.01).Conclusions:The preparation of nanoemulsion from the essential oils of M.piperita and E.globulus,significantly increases the protection time and reduces ED50 values of these essential oils,hence,M.piperita Nano and E.globulus Nano can be good alternatives to DEET and other chemical compounds.

Characteristics of soil water repellency after sand dune stabilization in the Tengger Desert

Soil water repellency （SWR） is one of the most important physical properties of soils found all over the world, and it may have significant effects on the eco-hydrological processes of land ecosystems. In this study, the Capillary Rise Method was used to measure the SWR in the artificial vegetation area in Shapotou, located in the southeast area of the Tengger Desert, Ningxia Prov- ince of western China. The variation of the soil water repellency among different minor topographies, different depths and differ- ent particle sizes was analyzed. The results of the study indicate that the SWR shows distinct changes with vegetation restoration, and it increases with an increase in the period of dune stabilization. In the same vegetation area, the SWR of soils in inter-dune depressions or windward slopes is slightly greater than that in crest or leeward slopes. The SWR of 0-3 cm topsoil is significantly greater than that in the 3-6 cm soil layer. The SWR decreases with an increase in grain size and the differences among the SWRs of different sieved soil fractions are found to be significant. There is also a significantly positive correlation between the SWR and the proportion of soils with grain sizes of 0-0.05, 0.05-0.01 and 0.01-0.15 mm, and a significantly negative correlation between the SWR and the propotion of soils with grain sizes exceeding 0.15 mm. The increase of SWR in revegetation areas may depend on the continuous depositing of atmospheric dust on the stabilized dune surface as well as the formation of biological soil crusts, especially on the formation of algal and lichen crusts. Enhanced SWR influences the effectiveness of water use of sand plants in- habiting the sand dunes.

Repellent,larvicidal and adulticidal activities of essential oil from Dai medicinal plant Zingiber cassumunar against Aedes albopictus

Zingiber cassumunar is an important plant used in traditional medicine and as a natural mosquito re-pellent.However,the compounds responsible for the repellent activity of the plant are still unknown.The aim of the study is to identify the components of Z.cassumunar essential oil that show repellent activity against Aedes albopictus.We also evaluated the larvicidal and adulticidal activities of Z.cassumunar essential oil against Ae.albopictus.In-cage mosquito repellent experiments showed that Z.cassumunar essential oil possessed moderate repellent activity with a minimum effective dose(MED)of 0.16±0.01 mg/cm^(20,compared to reference standard N,N-diethyl-3-methylbenzamide(DEET,0.03±0.01 mg/cm^(20).Bioassay-guided fractionation identified the major active compound of Z.cassumunar essential oil as(-)-terpinen-4-ol(1)(MED:0.19±0 mg/cm^(20).We also found that Z.cassumunar essential oil showed moderate larvicidal activity against first instar larvae of Ae.albopictus with a LC50(50%lethal concentration)of 44.9 mg/L after 24 h.Fumigation bioassays showed that Z.cassumunar essential oil exhibits moderate adulticidal activity against Ae.albopictus with a LC50 of 5.44%,while(-)-terpinen-4-ol showed significant adulticidal activity with a LC50 of 2.10%after 24 h.This study verifies that the Z.cassumunar essential oil has mosquito repellent activity,and that(-)-terpinen-4-ol is mainly responsible for this activity.Furthermore,this study provides scientific support for the folk usage of Z.cassumunar essential oil as mosquito repellent and indicates that Z.cassumunar essential oil and(-)-terpinen-4-ol can be used as plant-derived repellents and insecticides for mosquito control.

Repellent and Fumigant Effects of Essential Oil from Clove Buds Syzygium aromaticum L. against Tribofium castaneum （Herbest） （Coleoptera： Tenebrionidae）

Essential oil from clove buds Syzygium aromaticum L. Merr. ＆ Perry （Myrtaceae） was extracted using petroleum ether in Soxhlet apparatus. The resultant oil contained eugenol （48.92%）, caryophyllene （18.55%）, α-caryophyllene （3.25%）, eugenol acetate （23%）, cis-13-docosenamide （3.2 1%）, presenting more than 96% of the oil. This oil was examined as a fumigant and repellent agent against adults of the red flour beetle, Tribolium castaneum. Data showed that various concentrations of the oil have revealed dramatic repellent activity against the tested insect, where it gave 100% repellency by 1.0, 0.8, and 0.2% clove oil at 4, 8, 10 min, respectively. The RTs0 and RT95 were 1.1 and 8.0 min at 0.2% and 0.4, 2.6 min at 0.8%, respectively. In addition, fumigation assay has also exhibited strong fumigant activity toward the adults of T. castaneum. At 100 μL oil/L air, mortality was 75, 80 and 100% after 6, 7, and 8 days exposure period with LCs0 and LC95 17 and 70 μL/L air, respectively. The utilization of clove oil for its potential effects against stored product insect is discussed.

Impact of Different Water Repellent Finishes on Cotton Double Jersey Fabrics

This study demonstrated that the variation in physical and chemical performance on cotton double jersey knit fabrics was decided by the knit structure, water repellent chemicals types and their concentration. Here, two types of double jersey fabrics were treated with different types of water repellent chemicals at different formulations to evaluate the performance of water repellent finishes on knit fabrics properties. The levels of water repellency of the fabrics were assessed by AATCC 127 hydrostatic head test method and by ISO 4920:2012 spray rating test method. To evaluate the performance of water repellent finishes on knit fabric properties, GSM, bursting strength test according to ASTM (D 3786-87) method, air permeability, color fastness to wash, water, perspiration, chlorinated water and color fastness to rubbing with ISO method were done. The results showed that both physical and chemical properties of the finished cotton knits, depend to a great extent on knit structure, the water repellent finish type and concentration to obtain water repellent fabrics with desirable properties.

Water Repellent Finishing on Cotton Fabric via Atom Transfer Radical Polymerization

In order to enhance the water repellence property of cotton fabric, cotton fabric was grafted using hexafluorobutyl methacrylate( HFMT) monomer via atom transfer radical polymerization( ATRP) method. Water repellent cotton fabric was successfully prepared, and characterized by scanning electron microscopy( SEM),Fourier transform infrared spectroscopy( FTIR), and X-ray photoelectron spectroscopy( XPS). The SEM images of the HFMT-treated cotton displayed significant difference from the untreated one. FT-IR characterization of the HFMTtreated cotton indicated that HFMT was successfully grafted onto the surface of the cotton fabric. XPS analysis indicated that the fluorine element of the HFMT-treated cotton existing on the surface of the cotton fabric. The surface contact angle test as well as the water repellence rating test showed that the water repellence of the HFMTtreated cotton fabric was much better than that of the untreated cotton fabric. The surface contact angle of the HFMT-treated cotton fabric could reach( 132. 4 ± 2. 2) °,and the water repellence rating could achieve grade 3. The washing durability of the HFMT-treated fabric was also investigated. The surface contact angle of the HFMTtreated cotton fabric could reach( 121. 1 ± 2. 1) ° after 20 washing times. Furthermore, the whiteness, air permeability, breaking strength,and breaking elongation of the HFMT-treated cotton fabric decreased slightly compared with the untreated cotton fabric.Finally,cotton fabric with good water repellence property and excellent washing durability could be obtained with little effect on the intrinsic properties of cotton fabric.

Plasma Treatment for Preparing Durable Water Repellent and Anti-Stain Synthetic Fabrics for Automotive Applications

This paper describes the development of a plasma process to produce a durable water repellent and anti-stain thin film on synthetic textile, utilized for the upholstery in the automotive field. The coatings were deposited in non equilibrium low pressure plasmas fed with 1H, 1H, 2H-perfluo-ro- 1-decene employing, as substrates, polyethylene terephthalate and polyethylene terephthalate thermo-coupled to polyurethane foam. It was found that the XPS F/C ratio of the deposit was higher than 1.4 and that the treated textile was always very hydrophobic (WCA > 140?) and oil resistant (motor oil CA > 110?), even after wear.

Conception by a Process for Extruding Plastic Mulching Film with Cade Oil and Study of Snail Repellent and Anti-bacterial Adhesion Effects

In organic lettuce cultivation,snails can cause great economic loss.There is a lack of effective control methods for these molluscs.This work is focused on the development of a new agricultural plastic mulch material based on low density polyethylene(LDPE),as it is the most widely used polymer in plasticulture.The objective was to develop a new bio-based plastic mulch material that is insect repellent and anti-biofilm by incorporating a bioactive substance into the conventional formulation of the material.A new plastic mulching film made of 0.1%cade oil as was produced using the extrusion process.Bioadhesion tests carried out with aqueous suspensions of Escherichia coli and Pseudomonas aeruginosa show that this material is endowed with anti-biofilm effects.This study will demonstrate how to act by repulsive effect to Helix aspersa against this devastating mollusk in salads culture.

STUDY ON INSECT-REPELLENT COMPONENTS IN THE VOLATILE OILS CASTOR LEAVEST

This paper studied the insect-repellent components from castorleaves. By Gc-Ms and UV, IR analysis, four components were identified: 2-hexanal, cyclohexyl formate, 5-methyl hexanal, 4,4-dimethyl hexanal, among them, 2-hexanal was the main insect-repellent component.

Water-repellent efficiency of thermally modified wood as affected by its permeability

This study shows how the air permeability of thermally modified wood contributes to its water-repellent efficiency. For this purpose, freshly cut boards of hornbeam(Carpinus betulus), poplar(Populus nigra), and heartwood of oak(Quercus castanifolia) were modified at a steam temperature of 180 °C for 3 h inside a Thermo Wood kiln.The porous structure, permeability, and water uptake of wood were affected differently by thermal modification,depending on the wood species. The creation of microcracks in the cell walls, due to collapsing of fiber cells,resulted in a noticeable increase in the permeability of hornbeam. Despite checking in the poplar wood structure,its permeability was negatively affected by thermal modification. In contrast to oak and poplar, a negative waterrepellent efficiency was observed for the modified hornbeam, caused by an increase in the permeability.

Preliminary Exploration of a Novel Type High-effi-ciency Mosquito-repellent Compound Essential Oils

The essential oils were extracted from flowers and branches of Cestrum genus plant Telosma cordata(Burm. F.) Merr.,and used for purifying the mosquito-repellent refined oils. The yielded extracts were mixed with single nerve-smoothing or nerve-exciting components from lavender and peppermint or mixed with basal oils(like evening primrose),in order to prepare the novel type compound essential oils conferring mosquito-repellent and air-refreshing actions. The resulted compound was prepared into solid air freshener.

Comprehensive Overview and Analytical Study on Automatic Bird Repellent Laser System for Crop Protection

Birds are a huge hazard to agriculture all around the world,causing harm to profitable field crops.Growers use a variety of techniques to keep them away,including visual,auditory,tactile,and olfactory deterrents. This study presents a comprehensive overview of current bird repellant approaches used in agricultural contexts,as well as potential new ways. The bird repellent techniques include Internet of Things technology,Deep Learning,Convolutional Neural Network,Unmanned Aerial Vehicles,Wireless Sensor Networks and Laser biotechnology. This study’s goal is to find and review about previous approach towards repellent of birds in the crop fields using various technologies.

Huntsman Textile Effects raises the bar for non-fluorinated durable water repellents

PHOBOTEX~? RSY durable water repellent delivers best-in-class performance to support the industry's shift to non-fluorinated formulations Continuing to lead the textile sector’s transition to more sustainable and eco-friendly business models,Huntsman Textile Effects has introduced the new PHOBOTEX~?RSY non-fluorinated durable water repellent(DWR)that raises the standard for repellency especially on high-performance synthetic textiles.This new product will allow brands and retailers to meet global demand for eco-friendly clothing that require extreme rain-and stain-protection.

Morphological basis for the waterproof characteristic of bird plumage

A surface variable, density of water-feather touching points （Dp） was proposed in this paper to express surface property of water repellency of contour feather. Tests in 29 species using breast contour feathers indicated that Dp was small in tericolous species, medium in wading and diving species, large in swimming species, with only a few exceptions. This implied that birds achieve appropriate Dp by optimizing the microstructure of feather to meet the requirement of water repellency. Therefore, Dp was a morphological marker linking structure and function of feather in studies of adaptive evolution of birds.

Larvicidal and repellent activities of Sida acuta Burm.F.(Family:Malvaceae) against three important vector mosquitoes

Objective:To determine the larvicidal and repellent activities of Sida acuta Burm.F.（Family: Malvaceae）extract against Culex quinquefasciatus,Aedes aegypti and Anopheles stephensi. Methods:Twenty five late III instar larve of three mosquito species were exposed to various concentrations（15-90 mg/L） and were assayed in the laboratory by using the protocol of WHO 2005:the 24 h LC50 values of the Sida acuta leaf extract was determined following Probit analysis. The repellent efficacy was determined against three mosquito species at three concentrations viz.,1.0,2.5 and 5.0 mg/cm2 under the laboratory conditions.Results:Results showed varying degree of larvicidal activity of crude extract of Sida acuta against three important mosquitoes with LC50 values ranging between 38 to 48 mg/L.The crude extract had strong repellent action against three species of mosquitoes as it provided 100%protection against Anopheles stephensi for 180 min followed by Aedes aegypti（150 min） and Culex quinquefasciatus（120 min）.Conclusions: From the results it can be concluded the crude extract of Sida acuta was an excellent potential for controlling Culex quinquefasciatus,Aedes aegypti and Anopleles stephensi mosquitoes.

Ovicidal and repellent activities of botanical extracts against Culex quinquefasciatus,Aedes aegypti and Anopheles stephensi(Diptera:Culicidae)

Objective:To determine the ovicidal and repellent activities of methanol leaf extract of Ervatamia coronaria(E.coronaria) and Caeslpinia pulckerrima(C.pulcherrima) against Culex quinquefasciatus(Cx.quinquefasciatus),Aedes aegypti(Ae.aegypti) and Anopheles stephensi(An. stephensi).Methods:The ovicidal activity was determined against three mosquito species at various concentrations ranging from 50-450 ppm under the laboratory conditions.The hatch rates were assessed 48 h after treatment.The repellent efficacy was determined against three mosquito species at three concentrations viz.,1.0,2.5 and 5.0 mg/cm under the laboratory conditions. Results:The crude extract of E.coronaria exerted zero hatchability(100%mortality) at 250.200 and 150 ppm for Cx.quinqitefasciatus,Ae.aegypti and An.stephensi,respectively.The crude extract of C.pulchenima exerted zero hatchability(100%mortality) at 375.300 and 225 ppm for Cx.quinquefasciatus,Ae.aegypti and An.Stephensi,respectively.The methanol extract of E. coronaria found to be more repellenct than C.pukherrima extract.A higher concentration of 5.0 mg/cm^2 provided 100%protection up to 150.180 and 210 min against Cx.quinquefasciatus,Ae. aegypti and An.stephensi,respectively.The results clearly showed that repellent activity was dose dependent.Conclusions:From the results it can be concluded the crude extracts of E.coronaria and C.pukherrima are an excellent potential for controlling Cx.quinquefasciatus,Ae.aegypti and An.stephensi mosquitoes.