Health risk assessment of heavy metal pollution in groundwater of a karst basin,SW China

To investigate the presence of metal elements and assess their health risk for the populace in the Nandong Underground River Basin(NURB),we conducted an analysis of eleven common heavy metals in the water body.A Health risk assessment(HRA)model was employed to analyze 84 water samples from the NURB.The detection results revealed the following order of heavy metals concentrations:Fe>Al>Mn>Zn>As>Cd>Pb>Cr>Ni>Cu>Hg.Correlation analysis indicated a certain similarity in material source and migration transformation among these eleven metal elements.Our study identified that the health risks for local residents exposed to metal elements in the water of NURB primarily stem from carcinogenic risk(10^(−6)–10^(−4)a^(−1))through the drinking water pathway.Moreover,the health risk of heavy metal exposure for children through drinking water was notably higher than for adults.The maximum health risks of Cr in both underground and surface water exceeded the recommendation standard(5.0×10^(−5)a^(−1))from ICRP,surpassing the values recommended by the Swedish Environmental Protection Agency,the Dutch Ministry of Construction and Environment and the British Royal Society(5.0×10^(−6)a^(−1)).The results of the health risk assessment indicate that Cr in the water of NURB is the primary source of carcinogenic risk for local residents,followed by Cd and As.Consequently,it is imperative to control these three carcinogenic metals when the water was used as drinking water resource.

Beta-cyclodextrin adsorbents to remove water pollutants-a commentary

Beta-cyclodextrin-based adsorbent is a promising adsorbent because it has unique characteristics and able to form host-guest complexes with various organic compounds.Adsorption using beta-cyclodextrin-based adsorbent has continuously improved by various preparation strategies and crosslinking agents.This commentary aims to highlight the preparation strategies,properties,and adsorption mechanisms of beta-cyclodextrin-based adsorbents.The adsorbents can be generally classified according to the preparation methods and display high adsorption capacity especially for dyes.Particularly,composite/nanocomposite beta-cyclodextrin-based adsorbents exhibit outstanding adsorption capacity even though the surface area is lower than that of porous and magnetic betacyclodextrin-based adsorbents.The beta-cyclodextrin/chitosan functionalized graphene oxide hydrogel with specific surface of 17.6 m^(2)·g^(–1)yields an extraordinarily maximum adsorption capacity of 1499 mg·g^(–1)methylene blue,while beta-cyclodextrin/chitosan modified with iron(Ⅱ,Ⅲ)oxide nanoparticles displays a much greater maximum adsorption capacity at 2780 mg·g^(–1).The hydrophobic interaction,functional groups,hydrogen bonding,and electrostatic interaction govern the adsorption to a greater capacity.Although this commentary is not exhaustive,the preparation strategies and illustrated mechanisms provide useful insights into the adsorbent–adsorbate interactions,costeffective analysis,challenges,and future directions of betacyclodextrin-based adsorbents in wastewater treatment.

Pollution and health risk assessment of heavy metals in waters around mine sites of Elazig(Eastern Turkey)

Turkey’s Eastern Anatolia Region is the oldest known mineral mining area of Maden and Alacakaya.Chromite production in the Alacakaya field constitutes 50% of the country’s exports,and copper mines in the Maden region account for approximately 12% of the country’s copper production.There is a risk of water pollution due to significant mine waste which affects the Inci and Maden rivers.The water needs of many settlements are met from these streams,which run through these two mine sites.This study investigated the water pollution in the rivers.25 water samples were collected during the dry and rainy periods,and the Al,Cr,Cu,Fe,Li,Mn,Ni,Pb,Sr and Zn contents of these samples were examined in terms of health.Evaluation of element concentrations and creation of spatial distribution maps were performed using ArcGIS software.Spatial distribution maps,correlation and cluster analysis indicate that the source of heavy metals observed in waters is mine fields.The heavy metal content of the samples is higher in the dry period,the high concentration values are obtained from the mine sites,the decrease in the concentrations throughout the flow during the rainy period,are indicators of the effect of the mines on the water pollution.As a result of the comparison from the analysis results of water samples with World Health Organization(WHO),Environmental Protection Agency(EPA)and European Commission(EC)standards,the element values of Al,Cr,Fe,Mn,Ni and Pb exceeded the permissible values for health.The concentrations of these elements for dry period samples are:0-6.411 mg L^(-1),0.006-0.235 mg L^(-1),0-13.433 mg L^(-1),0-0.316 mg L^(-1),0-0.495 mg L^(-1),0-0.065mg L^(-1),and for rainy period samples are 0-1.698mg/L,0-0.2 mg L^(-1),0-9.033 mg L^(-1),0-0.173 mg L^(-1),0-0.373 mg L^(-1),0-0.034 mg L^(-1),respectively.Although the waters in the region are polluted by heavy metals,it has been determined that there is no noncarcinogenic hazard as a result of the calculation of the hazard index(HI<1)by ingestion and dermal contact within the scope of human health risk assessment.This study will be beneficial as it draws attention to the prevention of the negative effects of water pollution,which may cause serious health problems in the future as a result of mining activities in the region.

Macroinvertebrates as Bio Indicators of Water Quality in Pinyinyi River, Arusha Tanzania

Rivers are important for aquatic biodiversity. Anthropogenic activities degrade rivers and decrease their capacity to offer ecosystem services. This study used macroinvertebrates to assess the impact of anthropogenic activities on the Pinyinyi River during dry and wet season. Abundance of macroinvertebrates, average score per taxon and Shannon Weiner Species Diversity Index were used to state the ecological status of Pinyinyi River. Because the abundance of macroinvertebrates can be affected by change in water quality, some of the physicochemical parameters were also measured. A macroinvertebrates hand net is used to collect the macroinvertebrates per sampling point. DO, temperature, pH, turbidity and TDS were measured in-situ using HI-9829 Multiparameter and BOD was measured in the laboratory using Oxydirect levibond method. A total of 164 macroinvertebrates were collected and identified from Pinyinyi River during dry and wet season. They belong to 13 families. The most abundant taxa were mosquito larva, Diptera (41.07%) and aquatic caterpillar, Lepidoptera (23.21%) during dry season representing about 64.28% of the total macroinvertebrates whereas the least abundant taxa were pouch snail (16.07%) and dragonflies, Odonata (19.64%) during dry season representing about 35.72% of the total macroinvertebrates. The most abundant taxa collected during wet season were aquatic earthworm, haplotaxida (19.44%), midges, Diptera (17.59%), black flies, Diptera (15.74%) and creeping water bugs, hemiptera (12.96%) whereas the least abundant were pigmy back swimmers, hemiptera (2.78%), snail (3.7%), predacious dividing beetle (4.63%) and coleopteran (4.63%). Average Score per taxon of Pinyinyi River during dry season was 5.25 and 3.6 during wet season. The Shannon Weiner Species Diversity Index was 1.318 during dry season and 2.138 during wet season. Based on the score, Pinyinyi River is moderately polluted during dry season and seriously polluted during wet season. Based on index, Pinyinyi River has low diversity of macroinvertebrates during dry season and highly in diversity of macroinvertebrates during wet season. Moreover, it was found that, agricultural activities, livestock keeping, bathing and washing alter physicochemical parameters of Pinyinyi River and hence change the abundance of macroinvertebrates as well as the quality of water. The study, therefore, recommends that the source of pollutants should be controlled and the river regularly monitored by the relevant authorities.

Suitability and Sustainability of Rainwater QualityMonitoring System in Cistern for Domestic Use

Rainwater harvesting(RWH)systems have been the source of domestic water for many years and still becoming essential in many communities of developing countries.However,due to various reasons,there are several sources of contamination in the rainwater cistern systems.Dissolved chemicals from the roofing,storage,and conveyance materials,together with the suspended particulate matter from the airborne,are examples of water contamination.In this work,the water quality monitoring system has been designed and implemented.Chemical and physical parameters of water samples were collected from three locations using a data acquisition(DAQ)system and rainwater quality was analyzed using Water Pollution Index(WPI).Results obtained from three locations have been presented.

The Fulfillment of Government Responsibilities in the Collaborative Governance of Rural Water Pollution

Rural environmental pollution is becoming more and more serious, which has become an important problem to be solved urgently in our country under the background of the new era. Protecting the ecological environment is one of the important functions of the government, and protecting the rural water environment is the unshirkable responsibility of the local governments. As the main body of rural water pollution control, how to define and fulfill the local governments’ responsibilities is of great significance to the advancement of the overall governance work. This paper starts from the local governments, which are the important main body of rural environmental governance. By comparing the similarities and differences between the performance of government responsibilities under the traditional governance model and the collaborative governance model, clarifies the governance responsibilities of the local governments. And further explores the effective measures for the government to play the main role, fulfill the main responsibilities, and participate in the collaborative governance of rural water pollution.

THE STUDY ON NOVEL MICROELECTRODE ARRAY CHIPS FOR THE DETECTION OF HEAVY METALS IN WATER POLLUTION

Qualitative and quantitative analysis of trace heavy metals in aqueous environment are rapidly assuming significance along with the rapid development of industry.In this paper,gold microelectrode array(MEA)plated with mercury film was used for simultaneous voltammetric detection of zinc,cadmium,lead and copper ions in water.The electrochemical behavior and the actual surface area of the MEA were investigated by cyclic voltammetry in K_(3)[Fe(CN)_(6)].Electrochemical impedance spectrum(EIS)was utilized to examine the deposition of mercury on the electrode surface.Based on anodic stripping voltammetry,mercury film
Au MEA was applied to the detection of heavy metals in artificial analyte,where good calibrate linearity was obtained for cadmium,lead and copper ions,but with zinc exhibiting poor linearity.

Investigation on Water Pollution of Four Rivers in Coastal Wetland of Yellow River Estuary

[Objective] The study aimed at analysing water pollution of four rivers in coastal wetland of Yellow River estuary. [Method] Taking four seriously polluted rivers (Guangli River, Shenxian Ditch, Tiao River and Chao River) in coastal wetland of Yellow River estuary as study objects, water samples were collected from the four rivers in May (dry period), August (wet period) and November (normal period) in 2009 and 2010 respectively, then pollution indices like nutritive salts, COD, chlorophyll-a, petroleum, etc. were measured. Afterwards, the status quo of water pollution was assessed based on Nemero index and comprehensive trophic level index (TLI), so as to find out the integral status quo of water quality of wetland rivers and damages to aquatic ecological environment. [Result] On the whole, water pollution of four rivers in coastal wetland of Yellow River estuary was serious, in the eutrophication state, and the main pollutants were TN, TP, NH+4-N and petroleum. In addition, excessive N and P in the four rivers resulted in water eutrophication of Bohai Bay, so further leading to ride tide, which destroyed the coastal ecological environment of Bohai Sea. Moreover, compared with historical data, water pollution by nitrogen and phosphorus became more serious, while there was no obvious aggravation in the water pollution by petroleum. In a word, water pollution wasn't optimistic on the whole. [Conclusion] The research could provide theoretical bases for the protection and utilization of river water in coastal wetland of Yellow River estuary and its coastal sea area.

A Study on Water Quality Monitoring in Urban Watercourse of Xinli River in Binzhou City

This paper aims to explore the pH,COD,ammonia nitrogen,total nitrogen,total phosphorus and other indices regarding Xinli River water in Binzhou City.The results show that the pH of the water quality index is between 7.3 and 7.8,slightly alkaline;the COD content of Xinli River is about 140-163 mg/L,and the COD pollution is serious in some water sections;the ammonia nitrogen content of Xinli River is 0.2-2.17 mg/L,the total nitrogen content is about 0.799-1.3 mg/L,the total phosphorus content is about 0.54-0.92 mg/L,suggesting that the water eutrophication is very serious.Due to the large amount of domestic sewage discharged into Xinli River without treatment,slow circulation of river water and other factors,the eutrophication is serious in the urban watercourse.

Analysis of Rural Water Pollution Sources of Lushui Reservoir in Hubei Province

Pollution resulting from increased human activities is threatening the drinking water quality in China.Lushui Reservoir was selected as a typical example to represent polluted drinking water sources with rapid social economic development.This study analyzed the pollution load of Lushui Reservoir from rural areas by estimating the chemical oxygen demand(COD),ammonia nitrogen,total nitrogen and total phosphorus contributed by domestic sewage,agricultural activity,livestock breeding and aquaculture activity.Results show that the annual chemical oxygen demand,ammonia nitrogen,total nitrogen and total phosphorus loads in Lushui Reservoir were 180.44,22.99,33.15,and 3.99 t,respectively.The highest contribution to pollution load in all four aspects is domestic sewage,which was 89%,96%,82%,and 79%,respectively.Therefore,policies for sustainable development in the region should be directed primarily towards a reduction of domestic pollution.

Characteristics of water contamination in abandoned coal mines:a case study on Yudong River area,Kaili,Guizhou Province,China

The seasonal and spatial changes in the chemical composition of the water in abandoned mine drainages and rivers in Yudong River area in the years of 2017-2018 were analyzed.The effects of mine water drainage on the seasonality and physicochemical properties of the river water after mine closure were evaluated,and the feasibility of irrigation using river water and the degree of pollution to farmland were assessed using the Water Quality Standard for Farmland Irrigation.The results show that the mine water has low pH value(<3.5-4)and high levels of total hardness,SO_(4)^(2−),Fe,Al,and Zn.In addition,the pH of the mine water is negatively correlated with the presence of other metal ions.The correlation coefficient between the chemical oxygen demand(COD)and Fe reached 0.989.While the pollution levels of Pinglu and Baishui rivers were low,the confluence region of the two rivers was seriously polluted.However,only the levels of Fe and Cd slightly exceeded the Surface Water Environmental Quality Standard after the confluence of Yudong and Chongan rivers.Overall,the heavy pollution type of the confluent river is consistent with mine water pollution.The water quality is slightly better in the dry season compared than in the high-water period.Sulfate and Fe content decreased by 39 and 16 mg/L,respectively,and Cd content decreased two-fold.Despite these findings,this study shows that from 2017 to 2018,the pH and Cd content of the rivers at the confluence exceeded the irrigation limit and the water quality continued to deteriorate,which may pose a soil contamination risk.Long-term use of the river for irrigation water may cause toxic elements such as Cd,Fe,Mn,SO_(4)^(2−),Al,and F-to enter the food chain,thereby endangering the life and health of villagers in Yudong River area.

Analysis of Water Pollution Causes and Control Countermeasures in Liaohe Estuary via Support Vector Machine Particle Swarm Optimization under Deep Learning

This study explores the loss or degradation of the ecosystem and its service function in the Liaohe estuary coastal zone due to the deterioration ofwater quality.Aprediction systembased on support vectormachine(SVM)-particle swarm optimization(PSO)(SVM-PSO)algorithm is proposed under the background of deep learning.SVM-PSO algorithm is employed to analyze the pollution status of the Liaohe estuary,so is the difference in water pollution of different sea consuming types.Based on the analysis results for causes of pollution,the control countermeasures of water pollution in Liaohe estuary are put forward.The results suggest that the water pollution index prediction model based on SVM-PSO algorithm shows the maximum error of 2.41%,the average error of 1.24%in predicting the samples,the root mean square error(RMSE)of 5.36×10^(−4),and the square of correlation coefficient of 0.91.Therefore,the prediction system in this study is feasible.At present,the water pollution status of Liaohe estuary is of moderate and severe levels of eutrophication,and the water pollution status basically remains at the level of mild pollution.The general trend is fromphosphorus moderate restricted eutrophication to phosphorus restricted potential eutrophication.To sumup,the SVM-PSO algorithm shows good sewage prediction ability,which can be applied and promoted in water pollution control and has reliable reference significance.

Effects of Urban Metabolism on the Well Water Quality in Cotonou (Benin) and Lomé(Togo)

Urban metabolism, a process of material, energy and water flows, consumption or transformation in the cities and outflows of wastes, has impacts on the shallow groundwater. This study addressed the relationship between the urban metabolic system and well water physicochemical and bacteriological quality in the coastal cities of Cotonou and Lomé. A participatory transdisciplinary approach, involving non-academics and academics stakeholders was used to analyse urban inflows and outflows related to groundwater quality. Standard methods were used to measure well water quality from 100 seasonal samples. Waste management revealed poor sanitation and hence a linear urban metabolism with no solid and liquid wastes and excreta recycling. This form of city metabolism reinforced by the seawater inflow is the main source of groundwater quality deterioration in Cotonou and Lomé. The principal water types Ca2+–Mg2+–Cl-– SO2-4 (48.21%), Na+–K+–Cl-–SO2-4 (65.9%) and the Gibbs diagram suggested water-rock interactions and dominance of cations exchange on the hydrogeological compositions, also seasonally controlled by saltwater intrusion or anthropogenic salinization. The water quality index on the range of 35.90 to 169.60 in Cotonou and 82.94 to 364.68 in Lomé indicated well water very poor quality to unsuitable for drinking. Moreover, the bacteriological quality was bad due to total coliforms (112 - 1812;1 - 1000 UFC/100 mL respectively in Cotonou and Lomé), Escherichia coli (40 - 780;1 - 112 UFC/100 mL), faecal enterococci/streptococcus (18 - 736;1 - 118 UFC/100 mL). The findings could help to sustain groundwater quality by controlling the pollution sources linked to urban metabolism.

Water Resources, Infrastructure Restoration, and Protection of the Upper Mississippi River Basin

The Upper Mississippi River flows approximately 2000 km from Lake Itasca, Minnesota to Cairo, Illinois where it is confluences with the Ohio River to form the Lower Mississippi River. North of the confluence, numerous snags, sand bars, rapids, and other obstructions made the Upper Mississippi River travel difficult. This paper highlights how the geological and landscape resources of the Upper Mississippi River and tributary watershed were responsible for the successful economic development of this historically rich region of North America. Environmental challenges include an attempt to keep invasive species such as the Asian carp out of the rivers and lakes north of the Twin Cities. In an attempt to protect the Mississippi River resource, Environmental and Conservation groups have opposed continued navigation through Minneapolis and St. Paul and the planned Upper Mississippi River navigation infrastructure restoration by the United States Corps of Engineers including the upper and lower St. Anthony locks and dams. These Environmental, Conservation and Save the River groups are attempting to mitigate the historic highest and best use of the Mississippi River and adjacent watershed, navigation, and economic development, by having the urban river restored to the natural state.

Effect of Water Ammonia Nitrogen Concentration on Survival of Mosquitofish Gambusia affinis

In this study, the relationship of the growth of invasion fish with water eutrophication processes was explored in Yangtze estuary, China. High water ammonia nitrogen concentration produced high effects on the growth and survival of mosquitofish Gambusia affinis. When the ammonia nitrogen was higher than 51.75 mg/l, the fish death rate obviously increased with days, and at the 4th day fish presented the highest mortality, while 23.72 mg/l ammonia nitrogen conditions have been able to ensure fish survival for two days in experiment treatment. Therefore, ammonia nitrogen of Grade V polluted water (national water quality criteria) is just 3 mg/l, and the water can be enough to support fish normal survival. Our results suggest mosquitofish was a suitable pioneer species for restoring polluted water ecology and purify water.

Study on sea water pollution mechanism of Xiuying Bathing Beach in Haikou

ＳｔｕｄｙｏｎｓｅａｗａｔｅｒｐｏｌｌｕｔｉｏｎｍｅｃｈａｎｉｓｍｏｆＸｉｕｙｉｎｇＢａｔｈｉｎｇＢｅａｃｈｉｎＨａｉｋｏｕ￥ＣｈｅｎＣｈｕｎｈｕａ；ＷａｎｇＬｕａｎｄＷａｎｇＤａｏｒｕ（ＯｃｅａｎＥｘｐｌｏｉｔａｔｉｏｎＰｌａｎｎｉｎｇａｎｄＤｅｓ...

Spatial Availability of Nitrogen and Pesticides in the Surface Layers of Agricultural Soils of Tropical Hydrosystems in the Wet Season: Case of the BéréWatershed in Côte d’Ivoire (West Africa)

The objective of this study was to assess the contribution of the spatial organization of cropping systems and the physicochemical properties of surface layers of the agricultural zones soils in tropical hydrosystems to the spatial availability of nitrogen and pesticides during the wet season, such as the Béré watershed (BW) in C?te d’Ivoire. For this purpose, after mapping the spatial distribution of the BW cropping systems based on the likelihood classification methodology of satellite images of the study area, 27 samples from the 0 - 20 cm horizon of the soil surface layers of the agricultural areas were taken during the wet and agricultural season of the year 2016. The Kjeldahl method has been used to evaluate the total nitrogen concentration and high-performance liquid chromatography (HPLC) chain made it possible for the analysis of pesticide residues in the soil solutions. Geostatistical analysis and processing of spatial data and physicochemical and agrochemical soil parameters revealed that two major agricultural areas stand out in the BW, namely the Béré upstream watershed (BUW) dominated at 32.65% by annual croppings (maize, cotton, rainfed or lowland rice, market gardening, etc.) and the Béré downstream watershed (BDW) by large areas of perennial croppings (cashew nuts, cocoa, etc.), i.e. 21.47%. Agricultural soils in BW are usually of the moderately desaturated ferralitic type with a low acid pH and a quite strong temperature, such as those of tropical soils’ characteristics. However, agricultural soils in the BUW are characterized by higher proportions of sand and coarse sand. The parameters such as total porosity, cation exchange capacity, clay, organic matter, silt, fine silt, coarse silt, and potassium ions, are higher in the soils of the agricultural area of the BDW. Moreover, soils in the agricultural areas of the BUW are less rich in total nitrogen (0.84 g·kg-1) in contrast to those of the BDW (1.2 g·kg-1). On the other hand, the median concentrations of total pesticides remain very high in the BUW (193.80 μg·kg-1) in front of those of the BDW (94.81 μg·kg-1). In addition, the biological family of herbicides was the most notable in BW. The chemical families of triazines (100% detection;79.37 μg·kg-1) are the most important in the agricultural area of the BUW with the very significant presence of active molecules of pesticides such as simazine (92.86% detection;13.17 μg·kg-1). However, in the BDW, urea substitute (100% detection;44.02 μg·kg-1) dominate, including the active substance chlortoluron (84.62% detection;10.12 μg·kg-1). The presence and abundance of nitrogen and pesticides in the soils of the agricultural areas of BW are strongly linked to the intensive use of these agrochemicals in cropping systems in recent decades in West African countries, even though most of the active molecules found are forbidden in several countries, especially in European countries. These are applied to tropical agricultural soils with physicochemical characteristics favorable to their retention in wet weather, as confirmed by the case of BW’s agricultural soils. Therefore, the BW’s water resources present worrying risks of contamination during rainy events that deserve to be assessed and monitored. Hence the need to take mitigating measures to this effect in order to preserve the quality of the environment.

Wet Coffee Processing Discharges Affecting Quality of River Water at Kayanza Ecological Zone, Burundi

Wet coffee processing leads to the generation of large volumes of wastewater, whose discharge to the environment leads to pollution of freshwater bodies. Kayanza is a major coffee growing area in Burundi with more than 40 wet coffee processing factories (WCPF) that discharge effluents directly to receiving water bodies without treatment. This study was carried out to assess the effect of coffee wastewater on the physicochemical properties of receiving waterbodies in Kayanza coffee growing ecological zone. Currently, no study has been done to analyze the effluent from the WCPF and assess the level of pollution. This study will therefore provide valuable data on the water pollution from coffee processing plants. Ten (10) rivers in the Kayanza coffee growing zone were studied during the months of April and June, 2020. Water samples were collected upstream (U) and downstream (D) of the effluent discharge points in triplicate. Samples were analyzed for pH, Chemical Oxygen Demand (COD), Biochemical Oxygen Demand (BOD5), Temperature, Salinity, Electrical Conductivity (EC), Total Dissolved Solids (TDS), Dissolved Oxygen (DO), Total Suspended Solids (TSS), Nitrates, Nitrites, Lead (Pb), Copper (Cu), Chlorides and Ammonium ions using standard methods. Physical parameters were analyzed in situ whereas chemical parameters were analyzed in the laboratories in Burundi Institute of Agricultural Sciences (ISABU) and University of Burundi. Data were analyzed using R-studio-1.0.153, GenStat 64-bit Release 14.1 and SSPS. Results on the physicochemical parameters indicated that coffee factory effluent has a polluting potential during coffee processing peak. The concentrations of the physicochemical parameters were significantly (p < 0.05) higher downstream (D) compared to upstream (U) of the river water sampling points. All downstream sites had COD, BOD5, TSS and pH values above allowable limits set by WHO and Burundi. The polluting impact of public wet coffee processing factories was significantly higher than that of private and cooperatives owned factories (p < 0.05). Measures should be taken in order to protect water bodies.

Examination of Surface Water Along River-Rima Floodplain in Wamakko, Sokoto State, Nigeria

This study examined the hydrochemistry of surface water along the River-Rima floodplain area.Five sampling locations were purposively selected,and,in each point,three samples were taken from surface water(river).The sampling was repeated after 20 days.Thus,a total of 30 samples were collected.Water samples obtained were subjected to laboratory tests.Results revealed that BOD,TDS,Mg2+,and Fe3+are above the World Health Organization(WHO)and Standard Organization of Nigeria(SON)reference guidelines for drinking water quality.Isolates detected from the coliform bacteriological analysis include Enterobacter aerogene,Escherichia coli,and Citrobacter freundii with most of the samples showing coliform bacteria growth above the SON standard for drinking water.Hence,the water in the River-Rima floodplain of the Wamakko area is of low quality and unsafe for drinking.Results of principal component analysis(PCA)revealed external influences such as pollutant wash off and rock weathering as controls on hydrochemistry of surface water.There is some indication of anthropogenic inputs(Cl-,NO3-,and PO42-)based on hierarchical cluster analysis.Elements including Cl-,NO3-,and PO42-are increasingly added into surface water from human activities,mainly agriculture,and municipal sewage.