Preparation and Water Retention Properties of Montmorillonite Modified by EL-10 Emulsifying Agent

Aiming at the problem of available water conservation in desertification ecological restoration, we prepared the water retention materials with montmorillonite（MMT） modified by Castor Oil Polyoxyethylene Ether（10）（EL-10） emulsifying vegetable waxes. The water retention property was studied in simulated desertification climate, and the materials were analyzed and characterized by UV-Vis, SEM, FTIR and XRD measurements. Moreover, a UV carbon arc lamp was used to test the resistance to aging. The experimental results show that the emulsion has good dispersity. Both the water retention property and the aging resistance performance of the modified clay were excellent. The lamellar structure and chemical composition of MMT had no obvious changes before and after modification. The surfaces of clay particles were coated uniformly with modified MMT, so the loose clay particles were cemented together by vegetable waxes. Meanwhile, the original big hydrophilic pores between the clay particles turned into capillary hydrophobic pores. So the clay particles formed a bonding layer which could inhibit water evaporation. Grass-planting experiment showed that reasonable mass ratio of vegetable waxes and EL-10 was 1：18. The materials not only had great water retention property but also maintained sound air permeability so that the germination rate of grass seed significantly increased from 8% to 52%.

Nanomechanical Properties of Amyloid Fibrils Formed in a Water Nanofilm on Mica Surface

The assessment of nanomechanical properties of a single amyloid fibril in a confined space provides important information for understanding the role of fibrils in a cell microenvironment. In this study, the structure and nanomechanical properties of different fibrils formed in water nanofilms on mica surface are carefully investigated by using the new atomic force microscopy imaging mode-peak force quantitative nanomechanics （PF-QNM）. We find that two types of fibrils with different morphologies are formed in water nanofilm on mica. The compression elasticities of these two types of fibrils are 3.9±0.9 and 2.5±0.6 GPa, respectively. The remarkable difference is possibly due to the structural discrepancy in two types of fibrils.

Decomposition and Mineralization Effect of Various Sources of Pig Manure on Water Quality and Nutrients Availability for Agro-Fish System in Benin

In spite of the relevance of current studies on the importance of organic fertilizers such as animal manure in improving the health of ecosystems, little is known about the biochemical mechanisms affecting the availability of nutrients released from the organic fertilizer in water. A litter bag study during 6 weeks was carried out in pots containing 25 liters of water with 15 g of pig dejections as organic fertilizers. The experimental design was a completely randomized block design with three replications. The treatments consisted of dejections of pigs nourished with: recommended diet composition T1, partially improved diet with Azolla filiculoides T2, improved diet with Azolla filiculoides T3, improved diet with cereal bran T4. A control treatment without dejection (T0) was considered in the study for comparison purpose. Four pigs per type of diet were considered leading to 16 white landrace pigs of six months age followed for dejection collections. Strong release of nutrients for better yield for agro-fish system was obtained in the manure T1 with ??(10.85 ± 0.00) mg/L;?( 0.011 ± 0.00) mg/L;?(2.13 ± 0.07) mg/L and K+ (10.76 ± 0.57) mg/L;Ca2+ (2.92 ± 0.11) mg/L and Mg2+ (2.53 ± 0.00) mg/L followed by manure T3 and T4 with high N content. The relatively low ratio C/N (14.25) for T1 and (15.84) for T3 induced more nutrients releasing. This study showed an important N loss probably due to microorganism activities which fluctuate nutrient availability. Also significant correlations were noted between the nutrient dynamics in water and physicochemical parameters showing the effect of abiotic factors on organic matter decomposition and mineralization which depend on microbial activities in water and pig manure composition.

Features and spatial distribution of circumpolar deep water in the southern Indian Ocean and the effects of Antarctic circum polar current

The data from the Southern Ocean observations of World Ocean Circulation Experiment （WOCE） are used for analysis and illustration of the features and spatial distributions of Circumpolar Deep Water （CDW） in the southern Indian Ocean. It is learnt from the comparison among the vertical distributions of temperature/ salinity/oxygen along the 30°E, 90°E and 145°E sections respectively that some different features of CDW and the fronts can be found at those longitudes, and those differences can be attributed to the zonal transoceanic flow and the merizonal movement in the Circumpolar Deep Water. In fact, the zonal transoceanic flow is the main dynamic factor for the water exchange between the Pacific Ocean and the /ndian Ocean or between the Atlantic Ocean and the Indian Ocean, and for the effects on the spatial distributions of the physical properties in CDW.

The Industrial Production of Water Dedicated to Absorption of Gases

The paper presents a flow plasma reactor permitting modification of the properties of water/aqueous solutions by stochastic resonance amplification of vibrations of selected chemical species in water with electromagnetic noise generated during a plasma discharge. The main parameters characterizing the quality for super-pure water, tap water and water from the intake in Besko (Poland) before and after the process in the plasma reactor were presented for comparison. In addition, the 17O NMR (the full width at half maximum) and electrospray ionization mass spectrometry (ESI MS) methods were used to determine differences in physicochemical parameters between the untreated and plasma-treated water. It has been established that the water subjected to plasma treatment shows much different gas absorption properties than the untreated water samples, as a function of temperature and pressure, in this paper we report exemplary data for CO2, oxygen and acetylene. The improved gas absorption properties of the plasma-treated water make it attractive for the use in industrial processes. It is worth pointing to a great capacity of the new reactor (4000 l/h), and low energy consumption (20 MJ/h) for the treatment of the above mentioned volume flow rate of water.

Tribological performance under different environments of Ti-C-N composite films for marine wear-resistant parts

The need for reducing the wear in mechanical parts used in the industry makes self-lubricant films one of the sustainable solutions to achieve long-term protection under different environmental conditions.The purpose of this work is to study the influence of C additions on the tribological behavior of a magnetron-sputtered TiN film in air,water,and seawater.The results show that the addition of C into the TiN binary film induced a new amorphous phase,and the films exhibited a dual phase of fcc(face-centered cubic)-TiN and amorphous carbon.The antifriction and wear-resistance properties were enhanced in air and water by adding 19.1at%C.However,a further increase in the C concentration improved anti-frictional properties but also led to higher wear rates.Although the amorphous phase induced microbatteries and accelerated the corrosion of TiN phases in seawater,the negative abrasion state was detected for all Ti-C-N films due to the adhesion of the tribocorrosion debris on the wear track.

Coagulation behavior and floc properties of compound bioflocculant–polyaluminum chloride dual-coagulants and polymeric aluminum in low temperature surface water treatment

This study was intended to compare coagulation behavior and floc properties of two dualcoagulants polyaluminum chloride–compound bioflocculant（PAC–CBF）（PAC dose first） and compound bioflocculant–polyaluminum chloride（CBF–PAC）（CBF dose first） with those of PAC alone in low temperature drinking water treatment. Results showed that dualcoagulants could improve DOC removal efficiency from 30% up to 34%. Moreover, CBF contributed to the increase of floc size and growth rate, especially those of PAC–CBF were almost twice bigger than those of PAC. However, dual-coagulants formed looser and weaker flocs with lower breakage factors in which fractal dimension of PAC–CBF flocs was low which indicates a looser floc structure. The floc recovery ability was in the following order：PAC–CBF 〉 PAC alone 〉 CBF–PAC. The flocculation mechanism of PAC was charge neutralization and enmeshment, meanwhile the negatively charged CBF added absorption and bridging effect.

EFFECT OF NANO-FILLER DISPERSION ON THE THERMAL,MECHANICAL AND WATER SORPTION PROPERTIES OF GREEN ENVIRONMENTAL POLYMER

Partially exfoliated nanocomposite （2） has been synthesized by intercalation of poly（propylene carbonate） （PPC） into commercial clay, Cloisite 20B （PPC/C-20B）. Nanocomposite 2 was characterized phiso-chemically and exhibited high thermal, mechanical and anti-water sorption properties as compared to PPC and intercalated nanocomposite （1） of PPC/C- 20B having same amount of clay. TGA results revealed that the thermal decomposition temperature （Td, 50%） of 2 increased significantly, being 40 K and 17 K higher than that of pure PPC and 1, respectively, while DSC measurements indicated that the nano-filler dispersion of 2 increased the glass transition temperature from 21℃ to 31℃. Accordingly, 2 showed high elastic modulus, hardness and anti-water absorption capacity. These thermal, mechanical alad anti-water absorption improvements are of great importance for the application of PPC as packaging and biomaterials.

Effects of mineralogy on thermo-hydro-mechanical parameters of MX80 bentonite

Thermal conductivity, water retention curve and swelling behavior of two MX80 bentonite samples were studied in the present work. The difference obtained from these two MX80 bentonite samples was then analyzed in terms of mineralogical effects （effects of the proportion of quartz and montmorillonite）. It was concluded that the mineralogical effect was significant on the thermal conductivity and the swelling capacity; on the contrary, it was negligible on the water retention property.

Influence of Calcination on the Physical Characteristics and Nitrogen Removal Performance of Clinoptilolites

The influences of roasting activation on the particle morphology, microscopic structure, and adsorption properties of natural clinoptilolites were investigated. The experimental results show that the optimal modified conditions include a calcination temperature at 400 ℃, a roasting time of 0.5 h, and furnace cooling. The ammonia nitrogen removal rate from analog renewable water of the modified clinoptilolites reached 72% in the optimized conditions, which is 12% higher than that of natural ones. Scanning electron microscopy analysis showed that the surface morphology changed, the micro-hole size increased, and the surface became smoother and more uniform after calcination. The single-point total adsorption average pore width increased from 7.74 nm to 10.64 nm.

Baiyun Cave in Naigu Shilin,Yunnan Karst,China

The Baiyun cave is a 380 m long karst cave in the Naigu Shilin, situated 70 km southeast of Kunming, Yunnan Province, China. The prevailing orientations of the cave passages are N110°–120°E and N0°-10°W and those of the fissures in the cave are N30°–40°W and N20°–30°W. The cave is developed in the thick-bedded Lower Permian Qixia Formation. The cave has an active water flow and is currently at the near water-table stage. There are large amounts of different infills of cave sediments. The cave shows different stages of paragenesis. The palaeomagnetic analysis of cave sediments shows that their ages are younger than 780 ka B.P. (the Brunhes Chron). The upper part of the sampled profile belongs to the reverse Blake event (112.3–117.9 ka B.P.). The formation of the Baiyun cave is directly connected with the development of the Naigu Shilin. The formation of karst underground and surface features depends on the regional tectonic deformation and the Cenozoic extension of the study area.

Synthesis,Crystal Structure and Photoluminescent Property of a Novel Dy^(3+) Coordination Compound Containing Rare(H_2O)_(22) Clusters

A novel Dy^（3＋） coordination compound,（H_2pipz）（H_3O）[Dy（pydc）_3]·11H_2O（1,pipz = piperazine and H_2pydc = pyridine-2,6-dicarboxylic acid）,has been hydrothermally synthesized and characterized by X-ray single-crystal diffraction,elemental analysis. It is interesting that the packing structure of compound 1 contains 22-core water clusters. Compound 1 is extended into a threedimensional supramolecular structure via O···H···O hydrogen bonding interactions. Furthermore,the luminescent property of compound 1 was also investigated.

Effects of water vapor in high vacuum chamber on the properties of HfO_2 films

The influence of water vapor content in high vacuum chamber during the coating process on physical properties of HfO2 films was investigated. Coatings were deposited on BK7 substrates by electron beam evaporation and photoelectric maximum control method. An in situ residual gas analyzer （RGA） was used to monitor the residual gas composition in the vacuum chamber. The optical properties, microstructure, absorption and laser-induced damage threshold （LIDT） of the samples were characterized by Lambda 900 spectrophotometer, X-ray diffraction （XRD）, surface thermal lensing （STL） technique and 1064-nm Qswitched pulsed laser at a pulse duration of 12 ns respectively. It was found that a cold trap is an effective equipment to suppress water vapor in the vacuum chamber during the pumping process, and the coatings deposited in the vacuum atmosphere with relatively low water vapor composition show higher refractive index and smaller grain size. Meanwhile, the higher LIDT value is corresponding to lower absorbance.

Design of Collagen-Based Hemostatic Material for Use in Plastic and Reconstructive Surgery

This study aims to develop collagen-based hemostatic materials. The sheet-shaped collagen sponge was manufactured by freeze-vacuum drying the aqueous solution of collagen (Col) and heat-denatured collagen (Col’) at a composition ratio of 2/1. The both sides or one side of sponge was treated with ultraviolet (UV) irradiation for 15 minutes to introduce intermolecular crosslinks between collagen molecules. The elution behavior of collagen sponge was investigated by immersing the sponge in water for a predetermined time and then by measuring the weight change. The double-sided UV-irradiated sponge showed very slow elution properties. On the other hand, the single-sided UV-irradiated sponge showed initially fast elution and subsequent very slow elution properties. Such initially fast elution of collagen molecules from the surface without UV-irradiation allows an adhesion of collagen sponge to the wound surface and results in hemostatic effect. In addition, the water absorption and retention properties of sponge were investigated by placing the hydrated sponge on a mesh for a predetermined time and then by measuring the weight change. The double-sided UV-irradiated sponge absorbed 81 times more water than own weight and showed a value of 45 times even after 7 days. The single-sided UV-irradiated sponge absorbed 80 times more water than own weight and showed a value of 39 times even after 7 days. The sponge with high water absorption and retention properties allows a wound healing effect because such sponge can absorb large amounts of blood plasma and exudates containing various cell growth factors. The double-sided UV-irradiated sponge is a good candidate for the wound dressing. On the other hand, the single-sided UV-irradiated sponge is a good candidate for the hemostatic material.

STATISTIC PROPERTIES OF NOISE FIELD OF MOVING SOURCE IN SHALLOW WATER AND ITS EFFECTS ON SIGNAL PROCESSING FOR THE NOISE RANGING SONAR

In this paper the properties of space- time correlation function of the noise field of moving source in layered statistic inhomogeneous medium are studied and the effects of random fluctuating boundary are considered as well.It has been shown, theoretically and experimentally, multi-path propergating effects cause the dispersion of the correlation function and fluctuations of the medium refraction index and the boundary cause the fluctuation of it.The effect of the movement of the noise source on the output of real- time correlator is equivalent to a low- pass filter added the drift of space- time correlation function.These properties of the correlation function cause grave degradation of the signal processing gain of noise ranging sonar system.The fluctuating and the distortion of conrrelation function made it difficult to realize the noise ranging.So in this paper, a method of space correlation ranging by a linear array of four points with short separation and long span and a technigue of dual- correlation signal processing are presented. By this, the influences of previously mentioned factors are greatly overcomed.Futhermore, for the long period and great delay fluctuation of the dual- correlation function output caused by internal wave, a method of limited memory Quasi- Kalman filtering is developed and the effective accurate ranging and tracing of noise ranging sonar are able to be tralized finally.

Role of membrane and compound properties in affecting the rejection of pharmaceuticals by different RO/NF membranes

This study was conducted to assess the merits and limitations of various high-pressure membranes, tight nanofiltration （NF） membranes in particular, for the removal of trace organic compounds （TrOCs）. The performance of a low-pressure reverse osmosis （LPRO） membrane （ESPA1）, a tight NF membrane （NF90） and two loose NF membranes （HL and NF270） was compared for the rejection of 23 different pharmaceuticals （PhACs）. Efforts were also devoted to understand the effect of adsorption on the rejection performance of each membrane. Difference in hydrogen bond formation potential （HFP） was taken into consideration. Results showed that NF90 performed similarly to ESPA1 with mean rejection higher than 95%. NF270 outperformed HL in terms of both water permeability and PhAC rejection higher than 90%. Electrostatic effects were more significant in PhAC rejection by loose NF membranes than tight NF and LPRO membranes. The adverse effect of adsorption on rejection by HL and ESPA1 was more substantial than NF270 and NF90, which could not be simply explained by the difference in membrane surface hydrophobicity, selective layer thickness or pore size. The HL membrane had a lower rejection of PhACs of higher hydrophobicity （log D〉0） and higher HFP （〉0.02）. Nevertheless, the effects of PhAC hydrophobicity and HFP on rejection by ESPA1 could not be discerned. Poor rejection of certain PhACs could generally be explained by aspects of steric hindrance, electrostatic interactions and adsorption. High-pressure membranes like NF90 and NF270 have a high promise in TrOC removal from contaminated water.

The migration and transformation of dissolved organic matter during the freezing processes of water

This study investigated the partitioning behavior of dissolved organic matter（DOM） in liquid and ice phases, as well as the changes in the optical properties and chlorine reactivity of DOM during the freezing processes of water. DOM was rejected from the ice phase and accumulated in the remaining liquid phase during water freezing. Moreover, the decrease in freezing temperature, as well as the increase in dissolved organic carbon（DOC）concentration of feed water, caused an increase in DOM captured in the ice phase. The ultraviolet-absorbing compounds, trihalomethane precursors, as well as fulvic acid- and humic acid-like fluorescent materials, were more liable to be to be rejected from the ice phase and were more easily retained in the unfrozen liquid phase during water freezing, as compared with organics（on average） that comprise DOC. In addition, it was also found a higher accumulation of these organics in the unfrozen liquid phase during water freezing at higher temperature. The freeze/thaw processes altered the quantity, optical properties, and chlorine reactivity of DOM. The decrease in ultraviolet light at 254 nm as well as the production of aromatic protein- and soluble microbial byproduct-like fluorescent materials in DOM due to freeze/thaw were consistently observed. On the other hand, the changes in DOC, trihalomethane formation potential, and fulvic acid- and humic acid-like fluorescence caused by freeze/thaw varied significantly between samples.

Magnetic and electro-catalytic properties of a copper complex with 2-(pyridylmethyl)amino-N,N-bis(2-methylene-4,6-difluorophenol)

A new material for both magnetic coupling and electrocatalytic hydrogen generation based on a copper complex,[（HL）CuCl-CuCl（HL）]HCl 1 is prepared by the reaction of 2-（pyridylmethyl）amino-N,N-bis（2-methylene-4,6-difluorophenol）（H2L） and CuCl2·2H2O.In solid,complex 1 is built from two copper units（[（HL）CuCl]）,and exhibits an antiferromagnetic exchange interaction between copper（Ⅱ） ions（J=-160cm^-1）.In liquid,1 can electrocatalyze hydrogen generation both from acetic acid with a turnover frequency（TOF） of 16.3 moles of hydrogen per mole of catalyst per hour at an overpotential（OP）of 941.6 mV（in DMF）,and a neutral buffer with a TOF of 1415.6 moles of hydrogen per mole of catalyst per hour at an OP of 787.6 mV.

Influence of SiC Nanoparticles Reinforcement in Areca/Tamarind Hybrid Biopolymer Composites:Thermo-mechanical,Tribological and Morphological Features

Natural fibers are displacing synthetic fibers as reinforcement in polymer composites due to their ease of processing,low cost,wide availability,biodegradability and sustainability.In this study,industrially discarded agro-waste areca fruit husk and tamarind fruit fibers were processed and used as reinforcement with unsaturated polyester resin to create a hybrid composite containing SiC nano filler particles.The SiC nano filler particles were varied from 1 to 4 wt.%in incremental steps of 1 wt.%with a constant 40 wt.%fiber reinforcement to determine its impact on the thermo-mechanical,morphological,wear and hygro-aging properties of the developed hybrid composite.However,the composite made of 3 wt.%SiC nano filler particles exposed overall better properties with better tensile(9.137 MPa),flexural(104.056 MPa),impact(7.983 J/cm^(2)),hardness(91.577 HRRW),wear(2.2×10^(-6)µm),crystallite size(7.9 nm)and thermal stability(360℃).Further advancement in weight percent of filler material,has worsened the properties due to poor dispersion and agglomeration factors by reducing the tensile,flexural,impact and hardness characteristics by 4.6%,6.4%,4.5%and 2.18%respectively.Also,the microstructural investigation revealed the failure pattern,information on interfacial adhesion between the reinforcement,filler and matrix of the hybrid composites.In addition,the crystalline characteristics and availability of functional groups in hybrid polymer composite with 3 wt.%SiC nano filler particles were disclosed by X-ray diffraction(XRD)and Fourier Transform Infrared(FTIR)spectrum analysis,respectively.The above findings reflects that the produced hybrid polymer composites suits well for interiors of automobiles and maritime interior applications to support loads with in the specified range.