Composition analysis of colored dissolved organic matter in Taihu Lake based on three dimension excitation-emission fuorescence matrix and PARAFAC model, and the potential application in water quality monitoring

Taihu Lake is one of the five biggest lakes in China. Surface water samples from 26 sampling sites of Taihu Lake were collected. Furthermore wet chemical analysis （CODCr and BOD5） and measurement of three dimensional excitation-emission matrix （3DEEM） spectra in the laboratory have been conducted. Using parallel factor analysis （PARAFAC） model, three components of colored dissolved organic matter （CDOM） have been identified successfully, based on the analysis of 3DEEM data. The characteristics of the three components also have been described by comparing them to some components of CDOM, identified in earlier researches. Meanwhile, spatial variations of concentration for the three components in Taihu Lake have been analyzed, and the result indicates that the concentration of component 1 depends more on the situation of wastewater pollution and can be used as the indicator of wastewater pollution. The relationship between the concentrations of the three components and results of the wet chemical analysis show that none of the three components can be used as indicators of gross organic matter in water. However, the concentrations of all the three components have obvious linear relationships with the BOD5 value, especially for component 1 （r = 0.72878）. Finally, the potential applications of the composition analysis based on 3DEEM and PARAFAC model in water quality monitoring have been illuminated.

Study on the water quality of the Taihu Lake using genotoxicological methods

The micronucleus(MCN) test of Vicia faba root tip cell was used to screen the water quality of the Taihu Lake. The MCN ‰ and the pollution index ( PI ) were examined and the F test was carried out to evaluate the statistical difference in mean MCN ‰ among various samples. There were significant difference among thirty nine samples and there were six sites whose PI values are above 2. The authors suggest that the Taihu Lake has partly been polluted to different degrees and the whole water body can be divided into three types. Ames tests were then conducted to detect mutagenicity at five significant sites. The results showed that rivers flowing through urban area carried large amount of mutagenic pollutants into the lake and these pollutants contaminated the source of main waterworks.

Setting up the Goal of Eliminating Outbreaks of Blue-green Alga, Innovating the Idea of Controlling the Taihu Lake, and Ensuring the Safety of Water Supply in the Taihu Lake

Since the water supply crisis in the Taihu Lake on May 29,2007,the control of the Taihu Lake has achieved remarkable results,and the eutrophication has been greatly reduced.Existing problems are as follows:outbreaks of blue-green alga still appear seriously every year,and there is no goal to eliminate outbreaks of blue-green alga;the load into the lake greatly exceeds the environmental capacity;reed wetlands are greatly reduced;there is still the possibility of a water supply crisis;the research of eliminating outbreak of blue-green alga is weak.In this paper,the experience of controlling the Taihu Lake is summarized,and the ultimate goals of eliminating eutrophication and outbreaks of blue-green alga and restoring wetlands and biodiversity are proposed.Control measures are proposed,such as deepening the promotion of the lake chief system,establishing the lake chief system in an all-round way,and increasing applied scientific and technological efforts and capital investment.The necessity and possibility of further controlling the Taihu Lake to eliminate outbreaks of blue-green alga should be recognized.Relying on controlling eutrophication alone cannot eliminate outbreaks of blue-green alga.The point that phosphorus control is the key to eliminate outbreaks of blue-green alga is not suitable for the Taihu Lake.The integration ideas of"three types"of technologies should be innovated.The first one is"double reduction and double increase"measures to eliminate eutrophication,of which"double reduction"is to reduce external point sources and non-point sources and internal blue-green alga in sediment;for external sources,the treatment standard of sewage plants should be paid special attention to.The second one is"double algae removal"measures to salvage blue-green alga,suppresses and kills algae.The blue-green alga on the surface,middle and bottom of water should be thoroughly salvaged and eliminated from various water areas.The third one is"double restoration"measures to restore wetlands and biodiversity.The area of wetlands should be restored to the area from the 1960s to the 1970s before outbreaks of blue-green alga,and vegetation coverage reaches 25%-30%.The Taihu Lake is controlled in different waters to ensure water supply safety in water sources.Five suggestions are proposed,such as revising the"Overall Plan for the Comprehensive Treatment of Water Environment in the Taihu Lake Basin"again,incorporating the goal of eliminating outbreaks of blue-green alga in the plan,setting up this research topic,greatly improving sewage treatment standards in local legislation.

DYNAMIC VARIATIONS OF WATER QUALITY IN TAIHU LAKE AND MULTIVARIATE ANALYSIS OF ITS INFLUENTIAL FACTORS

Dynamic variation of water quality in Meiliang Bay and part of West Taihu Lake has been analysed based on data from 1991 to 1992. Principal Component Analysis is used to reveal the mutual relationships of various factors. It is shown that there existis an obvious spatial and temporal variation in the main factors of water quality. Annual values of TP, CON, TN, Chl-a and conductivity decrease evidently from inner Meiliang Bay to the outer from north to south. TP and TN fluctuate seasonally with much higher value in winter. This is particularly true for the mouth of Liangxi River. In addition, the Chl-1 has a synchronous variation with water temperature, although being lagged a little, and closely relates to TP and TN. Finally, the results from Principal Component Analysis show that TP, TN, SS (or SD), water temperature and Chl-a are the most influential factors to water qualuty in this area, and both suspensions and algae can contribute to transparency to Taihu Lake.

Impact assessment of climate change and human activities on annual highest water level of Taihu Lake

The annual highest water level of Taihu Lake （Zm） is very significant for flood management in the Taihu Basin. This paper first describes the inter-annual and intra-annual traits of Zm from 1956 to 2000. Then, using the Mann-Kenall （MK） and Spearman （SP） nonparametric tests, the long-term change trends of area precipitation and pan evaporation in the Taihu Basin are determined. Meanwhile, using the Morlet wavelet transformation, the fluctuation patterns and change points of precipitation and pan evaporation are analyzed. Also, human activities in the Taihu Basin are described, including land use change and hydraulic project construction. Finally, the relationship between Zm, the water level of Taihu Lake 30 days prior to the day of Zm （Z0）, and the 30-day total precipitation and pan evaporation prior to the day of Zm （P and E0, respectively） is described based on multi-linear regression equations. The relative influence of climate change and human activities on the change of Zm is quantitatively ascertained. The results demonstrate that： （1） Zm was distinctly higher during the 1980-2000 period than during the 1956-1979 period, and the 30 days prior to the day of Zm are the key phase influencing Zm every year; （2） P increased significantly at a confidence level of 95% during the 1956-2000 period, while the reverse was true for E0; （3） The relationship between Zm, P and E0 distinctly changed after 1980; （4） Climate change and human activities together caused frequent occurrences of high Zm after 1980; （5） Climate change caused a substantially greater Zm difference between the 1956-1979 and 1980-2000 periods than human activities. Climate change, as represented by P and E0, was the dominant factor raising Zm, with a relative influence ratio of 83.6%, while human activities had a smaller influence ratio of 16.4%.

Assessment of Nitrogen Pollutant Sources in Surface Waters of Taihu Lake Region

The nitrogen （N） pollution status of the 12 most important rivers in Changshu, Taihu Lake region was investigated. Water samples were collected from depths of 0.5-1.0 m with the aid of the global positioning system （GPS）. The seasonal variations in the concentrations of different N components in the rivers were measured. Using tension-free monolith lysimeters and ^15N-labeled fertilizer, field experiments were carried out in this region to determine variations of iSN abundance of NO3^- in the leachate during the rice and wheat growing seasons, respectively. Results showed that the main source of N pollution of surface waters in the Taihu Lake region was not the N fertilizer applied in the farmland but the urban domestic sewage and rural human and animal excreta directly discharged into the water bodies without treatment. Atmospheric dry and wet N deposition was another evident source of N pollutant of the surface waters. In conclusion, it would not be correct to attribute the N applied to farmlands as the source of N pollution of the surface waters in this region.

Water quality, nutrient budget, and pollutant loads in Chinese mitten crab (Eriocheir sinensis) farms around East Taihu Lake

To understand the factors causing frequent outbreaks of harmful algae blooms in the Taihu Lake, China, we studied water quality and nutrient budget in Chinese mitten crab (Eriocheir sinensis) farm ponds in the eastern part of the lake from November 2007 to December 2009. We estimated the nitrogen (N), phosphorus (P), and chemical oxygen demand (COD) loads. Materials input and output ponds, water exchange, and applied management practices of 838.5-hm2 crab ponds were surveyed using questionnaires. Water quality of 12 ponds, which were located no more than 2 km from East Taihu Lake, were monitored. The results show that water quality in the crab ponds was better than reference data. Feeds, including corn seed, commercial feed, trash fish, and gastropod, were the major sources of N and P input in the crab ponds, contributing 88.7% and 94.9%, respectively. In total, 60.5% of N and 37.3% of P were sequestered by macrophytes, and only 15.7% and 8.5% of them were discharged as effluent. The net loads of N and P in effluent were 16.43 kg/hm2/cycle and 2.16 kg/hm2/cycle, respectively, while the COD load was -17.88 kg/hm2/cycle. This indicated that crab farming caused minor negative impact on the trophic status of the lake area, which was attenuated by macrophytes. However, wastewater purification is still necessary in crab faming.

Relationship Between Changes of River-lake Networks and Water Levels in Typical Regions of Taihu Lake Basin,China

The typical regions of the Taihu Lake Basin,China,were selected to analyze the variation characteristics of river-lake networks under intensive human activities.The characteristics of the fractal dimension of river networks and lakes for different periods were investigated and the influences of river system evolution on water level changes were further explored through the comparison of their fractal characters.The results are as follows:1) River network development of the study area is becoming more monotonous and more simple;the number of lakes is reducing significantly,and the water surface ratio has dropped significantly since the 1980s.2) The box dimension of the river networks in all the cities of the study area decreased slowly from the 1960s to the 1980s,while the decrease was significant from the 1980s to the 2000s.The variations of lake correlation dimension are similar to those of the river network box dimensions.This is unfavorable for the storage capacity of the river networks and lakes.3) The Hurst exponents of water levels were all between 0.5 and 1.0 from the 1960s to the 1980s,while decreased in the 2000s,indicating the decline in persistence and increase in the complexity of water level series.The paper draws a conclusion that the relationship between the fractal dimension of river-lake networks and the Hurst exponents of the water level series can reveal the impacts of river system changes on flood disasters to some extent:the disappearance of river networks and lakes will increase the possibility of flood occurrence.

Maintaining healthy rivers and lakes through water diversion from Yangtze River to Taihu Lake in Taihu Basin

On the basis of the Taihu water resources assessment, an analysis of the importance and rationality of the water diversion from the Yangtz,e River to Taihu Lake in solving the water problem and establishing a harmonious eco-environment in the Taihu Basin is performed. The water quantity and water quality conjunctive dispatching ＇decisi＂ofi-makifig support system, which ensures flood control, water supply and eco-aimed dispatching, is built by combining the water diversion with flood control dispatching and strengthening water resources monitoring and forecasting. With the practice and effect assessment, measures such as setting the -integrated basin management format, further developing water diversion and improving the hydraulic engineering projects system and water monitoring system are proposed in order to maintain healthy rivers and guarantee the development of the economy and society in the Taihu Basin.

Analysis of black water aggregation in Taihu Lake

Black water aggregation （BWA） in Taihu Lake is a disaster for the lake environment. It is a phenomenon resulting from water environmental deterioration and eutrophication caused by accumulation of pollutants in the lake, according to research on the water quality, pollutants of BWA, and occurrence mechanisms of BWA. Dead algae are the material base of BWA, the polluted sediment is an important factor for the formation of BWA, and hydrological and meteorological conditions such as sun light, air temperature, wind speed, and water flow are the other factors that may lead to the formation of BWA. Thioether substances such as dimethyl trisulfide are the representative pollutants of BWA. Parameters such as chlorophyll-a, DO, pH, and water temperature are sensitive indicators of BWA. Measures such as algae collection, ecological dredging, pollution control, and water diversion from the Yangtze River to the lake, are effective, and strengthening aeration is an emergency measure to control BWA.

DYNAMIC VARIATIONS OF WATER QUALITY IN TAIHU LAKE AND MULTIVARIATE ANALYSIS OF ITS INFLUENTIAL FACTORS

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Improvement of Taihu water quality by the technology of immobilized nitrogen cycle bacteria

Experimental studies were carried out on the purification of eutrophicTaihu Lake water by dynamic experiment using immobilized nitrogen cycle bacteria(INCB). The results showed that the eutrophic water of Taihu Lake can be purifiedeffectively as it passes through the experimental reactor into which some immobilizednitrogen cycle bacteria were put. The removal efficiencies for Total N (TN), NH4+-Nwith immobilized nitrogen cycle bacteria were 72.4% and 85.6%, respectively. It wasfound that the immobilized nitrogen cycle bacteria also have purificatory effect oneutrophic water of Taihu Lake at winter temperature (7°C), and that the removalmefficiencies for Total N (TN), NH4+-N were 55.6%, and 58.9%, respectively. Theremoval efficiencies for TN and NH4+-N depend on the time the water stays in theexperimental reactor.

Identification and Determination of Microcystins in Source Water and Waterbloom Sample From Meiliang Bay,Taihu Lake,China

Objective To identify and determine the congener and level of microcystins in the source water of Taihu Lake. Methods Improved method of SPE combined with HPLC was employed to detect the concentration and varieties of microcystins in source water and bloom samples collected from Meiliang Bay, Taihu Lake. Results The contents of two predominant microcystin components, MC-RR, and MC-LR, were relatively high in samples during warm months and correlated with the phase of algae growth. The maximum concentrations of MC-RR and MC-LR in water sample reached 3.09±0.53μg/L and 2.39±0.41μg/L during the period of water bloom in September 2004, respectively. Even without waterbloom, the concentration of MC-LR in source water sample was still higher than the guideline value. Conclusion The status of microcystin pollution in this region is serious and measures to monitor and control the growth of cyanobacteria are urgently needed.

Effects of temperature and nutrients on phytoplankton biomass during bloom seasons in Taihu Lake

Long-term variations of phytoplankton chlorophyll-a （Chl-a）, nutrients, and suspended solids （SS） in Taihu Lake, a large shallow freshwater lake in China, during algal bloom seasons from May to August were analyzed using the monthly investigated data from 1999 to 2007. The effective accumulated water temperature （EAWT） in months from March to June was calculated with daily monitoring data from the Taihu Laboratory for Lake Ecosystem Research （TLLER）. The concentrations of Chl-a and nutrients significantly decreased from Meiliang Bay to Central Lake. Annual averages of the total nitrogen （TN）, total phosphorus （TP）, and Chl-a concentrations, and EAWT generally increased in the nine years. In Meiliang Bay, the concentration of Chl-a was significantly correlated with EAWT, ammonia nitrogen （NH4＋N）, TN, the soluble reactive phosphorus （SRP）, TP, and SS. In Central Lake, however, the concentration of Chl-a was only correlated with EAWT, TP, and SS. Multiple stepwise linear regression revealed that EAWT, dissolved total phosphorus （DTP）, and TP explained 99.2% of the variation of Chl-a in Meiliang Bay, and that EAWT, NH4＋-N, and TP explained 98.7% of the variation of Chl-a in Central Lake. Thus EAWT is an important factor influencing the annual change of phytoplankton biomass. Extreme climate change, such as extremely hot springs or cold springs, could cause very different bloom intensities in different years. It is also suggested that both nutrients and EAWT played important roles in the growth of phytoplankton in Taihu Lake. The climate factors and nutrients dually controlled the risk of harmful algal blooms in Taihu Lake. Cutting down phosphorus and nitrogen loadings from catchments should be a fundamental strategy to reduce the risk of blooms in Taihu Lake.

Flume simulation of wave-induced release of internal dissolved nitrogen in Taihu Lake,China

A wave flume simulator was used to study internal nitrogen release from the surface sediment collected from Taihu Lake, China. Particulate nitrogen concentrations were positively correlated with the concentrations of suspended solids, primarily from surface erosion related to the shear stress and duration of wave action. In response to 4 cm- and 10 cm-high wave production representing waves generated in Taihu Lake by gentle and gusty winds, respectively, the mean dynamic release rate of ammonium （NH4＋） from the sediment to the overlying water was 1 × 10-3 mg/（m2.s） and the NH4＋ concentration in the overlying water increased by 0.016 mg/L, indicating that waves resulting from strong wind can induce the rapid release of dissolved nitrogen from Taihu Lake sediments. The decrease in interstitial NH4＋ concentrations at all sediment depths was associated with an increase in NH4＋ concentrations in the overlying water by 0.01 mg/L, showing that sediment below the eroded layer was the main source of internal nitrogen release. Changes in the interstitial dissolved oxygen and NH4＋ concentrations showed that wave-induced pore water movement can greatly increase the diffusion rate, and that these 15 cm. Diffusion induced by pore water movement sediment layer in Taihu Lake. effects can influence the sediment to a depth of at least may be very important for the formation of an active

Hydrological behaviour and water balance analysis for Xitiaoxi catchment of Taihu Basin

With the rapid social and economic development of the Taihu region, Taihu Lake now faces an increasingly severe eutrophication problem. Pollution from surrounding catchments contributes greatly to the eutrophication of water bodies in the region. Investigation of surface flow and associated mass transport for the Xitiaoxi catchment is of a significant degree of importance as the Xitiaoxi catchment is one of the major catchments within the Taihu region. A SWAT-based distributed hydrological model was established for the Xitiaoxi catchment. The model was calibrated and verified using hydrometeorological data from 1988 to 2001. The results indicate that the modeled daily and annual stream flow match the observed data both in the calibration period and the verification period, with a linear regression coefficient R2 and a coefficient e for modeled daily stream flow greater than 0.8 at Hengtangcun and Fanjiacun gauge stations. The results show that the runoff process in the Xitiaoxi catchment is affected both by rainfall and human activities （e.g., reservoirs and polder areas）. Moreover, the human activities weaken flood peaks more noticeably during rainstorms. The Water balance analysis reveals the percentages of precipitation made up by surface flow, evapotranspiration, groundwater recharge＇ and the change of soil storage, all of which are considered useful to the further understanding of the hydrological processes in the Xitiaoxi catchment. This study provides a good base for further studies in mass transport modeling and comparison of modeling results from similar hydrological models.

Sediment transport following water transfer from Yangtze River to Taihu Basin

To meet the increasing ：need of fresh water and to improve the water quality of Taihu Lake, water transfer from the Yangtze River was initiated in 2002. This study was performed to investigate the sediment distribution along the river course following water transfer. A rainfall-runoff model was first built to calculate the runoff of the Taihu Basin in 2003. Then, the flow patterns of river networks were simulated using a one-dimensional river network hydrodynamic model. Based on the boundary conditions of the flow in tributaries of the Wangyu River and the water level in Taihu Lake, a one-dimensional hydrodynamic and sediment transport numerical model of the Wangyu River was built to analyze the influences of the inflow rate of the water transfer and the suspended sediment concentration （SSC） of inflow on the sediment transport. The results show that the water transfer inflow rate and SSC of inflow have significant effects on the sediment distribution. The higher the inflow rate or SSC of inflow is, the higher the SSC value is at certain cross-sections along the ：river course of water transfer. Higher inflow rate and SSC of inflow contribute to higher sediment deposition per kilometer and sediment thickness. It is also concluded that a sharp decrease of the inflow velocity at the entrance of the Wangyu River on the river course of water transfer induces intense sedimentation at the cross-section near the Changshu hydro-junction. With an increasing distance from the Changshu hydro-junction, the sediment deposition and sedimentation thickness decrease gradually along the river course.

Spectral Geometric Triangle Properties of Chlorophyll-A Inversion in Taihu Lake Based on TM Data

The main objective of this study was to develop and validate the applicability of the Area Chlorophyll-a Concentration Retrieved Model (ACCRM), Height Chlorophyll-a Concentration Retrieved Model (HCCRM), Angle Chlorophyll-a Concentration Retrieved Model (AgCCRM), and Ratio Model of TM2/TM3 (RM) in estimating the chlorophyll-a concentration in Case II water bodies, such as Taihu Lake in Jiangsu Province, China. Water samples were collected from 23 stations on the 27th and 28th of October, 2003. The four empirical models were calibrated against the calibration dataset (samples from 19 stations) and validated using the validation dataset (samples from 4 stations). The regression analysis showed higher correlation coefficients for the ACCRM and the HCCRM than for the AgCCRM and the Ratio Model;and the HCCRM was slightly superior to the ACCRM. The performance of the ACCRM and the HCCRM was validated, and the ACCRM underestimated concentration values more than the HCCRM. The distribution of chlorophyll-a concentrations in Taihu Lake on October 27, 2003 was estimated based on the Landsat/TM data using the ACCRM and the HCCRM. Both models indicated higher chlorophyll-a concentrations in the east, north and center of the lake, but lower concentrations in the south. The accuracy of results obtained from the HCCRM and the ACCRM were also supported by the validation dataset. The study revealed that the HCCRM and the ACCRM had the best potential for accurately assessing the chlorophyll-a concentration in the highly turbid water bodies.

太湖流域洪水与水量调度方案修订的认识与思考

太湖流域经济社会的快速发展对流域调度工作提出新的更高要求。回顾了《太湖流域洪水与水量调度方案》实施以来流域防洪与水量调度的实践,总结分析了方案修订背景、总体考虑以及修订的主要内容,并作出展望与思考。

“哨兵-2”卫星影像及C2RCC算法在太湖冬春季水色分析中的应用

利用太湖2019—2022年冬春季“哨兵-2”卫星10 m分辨率的MSI影像和SNAP软件C2RCC(Case 2 Regional CoastColour)模块,以适合浑浊、富营养程度较高、光学复杂的“二类水体”的C2X-nets为模式,开展太湖叶绿素a、总悬浮物浓度、透明度等水色参数反演。结果表明:冬春季太湖各湖区叶绿素a浓度处于较低水平,但4月中旬起有明显抬升;太湖西部沿岸区、南部沿岸区和湖心区总悬浮物浓度较高,表明这些湖区易受风浪影响,造成沉积物再悬浮;太湖东部沿岸区、北部湖湾及东太湖遥感反演的水体清澈度较高,可能与这些湖区冬春季沉水植物菹草的分布有关,菹草生长对水质有较好的净化效果。总体来看,基于C2X-nets模式的C2RCC反演算法从较高分辨率卫星遥感影像中提取的水色信息,能有效反映太湖冬春季水色指标的空间分布特征,可为湖体生态状况及动态变化的长期监测评估提供有价值的参考。