Fluorescence Quenching of a Novel Eu(Ⅲ) Coordination Compound for the Detection of Trace Amounts of Water： Synthesis, Structure and Photoluminescent Property

A novel luminescent coordination compound Eu（TTA）3（DEDAF）（1, TTA = 1,1,1-trifluoro-3-（2-thenoyl）acetone, DEDAF = 9,9-diethyl-4,5-diazafluoren） has been synthesized and fully characterized by infrared spectrum, elemental analysis, UV-vis spectrum, etc. X-ray single-crystal diffraction analysis reveals that compound 1 shows a mononuclear structure with the europium atom in coordinating to one DAF and three TTA ligands. The mononuclear structure units are assembled into a 3-D polymer by hydrogen bonds and π-π interactions. Photoluminescent property of 1 was investigated in detail at room temperature. Complex 1 emits strong red luminescence. However, it could be quenched even by small amount of water. The fluorescence intensity at 614 nm decreases linearly with the water content increasing（vol% in acetonitrile） in the range of 0.025~0.2% under 278 nm excitation. Thermogravimetric analysis has also been studied, which demonstrates good thermal stability of 1.

Study on the Key and Sensitive Stage of Winter Wheat Responses to Water and Nitrogen Coordination

Pot experiments were carried out to study the effect of nitrogen application on winter wheat under different status of soil moisture, so that the key and sensitive stage of winter wheat responses to water and nitrogen coordination were determined. The results showed that the application of N fertilizer was more effective in early stage than in later stage, and at the lower N rates than at the higher N rates under non-irrigated conditions. N treatments had great effect on spikelet bearing number and grain number per spike, but had no effect on 1 000-grain weight; Grain yield and yield component responses to N treatment were greater under irrigated conditions than under non-irrigated conditions. The joining stage was the key and sensitive stage of winter wheat responses to water and nitrogen coordination, and the grain yield, grain number per spike and 1000-grain weight increased, when water and N Fertilizer were applied at this stage. The mechanism is that water and fertilizer supply at joining stage can speed up the growth of above-ground crops, enhance the abilities to absorb and utilize nitrogen fertilizer, and meanwhile, delay the aging of the root and keep the root vigor for a longer period.

Unprecedented Pseudo Water Tapes Stabilized by a One-dimensional Cu(Ⅱ) Coordination Polymer

A new compound,[Cu（mal）（tmdpy）（H2O）]·4H2O（1,H2mal = malonic acid,tmdpy = 4,4＇-trimethylenedipyridine） has been synthesized by the hydrothermal synthesis and structurally characterized by X-ray crystallography. It crystallizes in triclinic,space group P1^- with a = 9.1662（6）,b = 10.6266（7）,c = 11.3056（7）A,α = 84.6390（10）,β = 72.1030（10）,γ = 73.0420（10） o,V = 1002.37（11）A^3,C16H26CuN2O9,Mr = 453.93,Z = 2,Dc = 1.504 g/cm^3,μ = 1.140 mm^-1,F（000） = 474,R = 0.0375 and wR = 0.0975 for 3187 observed reflections（I 〉 2σ（I）） . In the structure of 1,the tmdpy ligands link the [Cu（mal）（H2O） ] units into an infinite chain,and the water molecules and carboxylate oxygen donors（O（2） and O（4）） from the mal ligands cooperatively built an interesting hydrogen bonding network with unprecedented pseudo water tape substructures.

Coordination of Urbanization and Water Ecological Environment in Shayinghe River Basin,China

During the rapid industrialization and urbanization of China,urban agglomeration in river basin areas raises the problems of over-use of water resources and pollution of the water environment.Related research in China has mainly focused on the conflicts among economic growth,urban expansion and water resource shortages within admin-istrative boundaries.However,water environments are much more dependent on their physical boundaries than their administrative boundaries.Consistent with the nature of water environment,this study aims at analyzing coordination relationships between urban development and water environment changes within physical river basin boundaries.We chose the Shayinghe River Basin,China,as our case study area which is facing serious challenges related to water en-vironment protection.Then we classified 35 county-level administrative units into upstream,midstream and down-stream regions based on their physical characteristics;analyzed the coordination degree of urban agglomeration using the Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) method;and constructed cooperative models using the Linear Programming (LP function) to simulate four scenarios of the coordination relationship be-tween urban population increase and water environment protection based on existing water resources and water pollu-tion data.The results show that the present coordinative situation in Shayinghe River Basin is not sustainable.In gen-eral,more than 50% administrative units are in the bad coordinative situation.In particular,the downstream region is under worse condition than the upstream and midstream regions.Cooperative models in scenario analyses indicate that the population scale set in existing urban master plannings is not coordinated with the water environment protection.To reach the goal of regional sustainable development,the total population needs to be controlled such that it will re-main at 4.5×10 7 or below by 2020 given the capacity of water environment.

A Novel Three-dimensional Mn(Ⅱ) Coordination Polymer Constructed from Biphenyl-3,3',5,5'-tetracarboxylic Acid and Water

The title Mn（Ⅱ） coordination polymer,poly{[heptaaqua-（μ4-bi-phenyl-3,3？,5,5？-tetracarboxylate）-bimanganese（Ⅱ）] pentahydrate},[Mn_2（bpta）（H_2O）_7]_n·5n H_2O（I）,is crystallized from a mixture of biphenyl-3,3？,5,5？-tetracarboxylic acid（H_4bpta） and MnCl_2·4H_2O in waterethanol under room temperature. Its asymmetric unit consists of one and two halves of crystallographically independent Mn（Ⅱ） cations,one fully deprotonated H4 bpta ligand,seven coordinated water molecules and five solvent water as guest molecules. In I,each Mn（Ⅱ） atom is octahedrally coordinated by six oxygen atoms from bpta^（4-） anions and coordinated water molecules. In the Mn（Ⅱ） cations,one half Mn（Ⅱ） ion of them located at a 2-fold axis generating a trinuclear [Mn_3（H_2O）_2（RCOO）_2] linker by μ1,1-O（water） and μ1,3-O,O？（carboxylate） bridges and another half Mn（Ⅱ） ion with an inversion is a mononuclear linker. These neighbouring trinuclear and mononuclear Mn（Ⅱ） cations are linked together by biphenyl-3,3？,5,5？-tetracarboxylates to form a three-dimensional framework with a（42.84） topology of a（4,4）-connected net,in which the positions of the trinuclear [Mn_3（H_2O）_2（R-COO）_2] linker as a 4-connector linking four bpta^（4-） ligands in I reproduce an eagle-shaped arrangement. The polymeric structure exhibits a water channel with an accessible void of 797.1 ？~3,amounting to 15.7% of the total unit-cell volume. Each of the cavities in the network is occupied by solvent water molecules.

The Coupling Coordination Evolution Research of Economy - Ecology - Society System in Xinjiang：Based on the Interaction Perspective of Water Resources

Under the water resources perspective,coupling coordination of economy-ecology-society system in Xinjiang was taken as the research object. By building the coupling evaluation index system of the water resources-economy-ecology-society system,quantitative evaluation and analysis of the coupling coordination of the water resources-economy-ecology-society system from 2001 to 2014 were conducted. The results showed that benefit indexes of economic system and social system grew rapidly,while benefit indexes of water resources system and ecosystem fluctuated smoothly from 2001 to 2014; coupling state of the whole system was at rival stage,and coupling coordination was reluctant coordination type,and the coupling index was slightly higher than the coupling coordination index. Moreover,it showed that the more the coupling systems,the lower indices of coupling and the coupling coordination.

Engineering the Local Coordination Environment of Single-Atom Catalysts and Their Applications in Photocatalytic Water Splitting:A Review

Single-atom catalysts(SACs),with atomically dispersed metal atoms anchored on a typical support,representing the utmost utilization effi ciency of the atoms,have recently emerged as promising catalysts for a variety of catalytic applications.The electronic properties of the active center of SACs are highly dependent on the local environment constituted by the single metal atom and its surrounding coordination elements.Therefore,engineering the coordination environment near single metal sites,from the fi rst coordination shell to the second shell or higher,would be a rational way to design effi cient SACs with optimized electronic structure for catalytic applications.The wide range of coordination confi gurations,guaranteed by the multiple choices of the type and heterogeneity of the coordination element(N,O,P,S,etc.),further off er a large opportunity to rationally design SACs for satisfactory activities and investigate the structure-performance relationship.In this review,the coordination engineering of SACs by varying the type of coordination element was elaborated and the photocatalytic water splitting of SACs was highlighted.Finally,challenging issues related to the coordination engineering of SACs and their photocatalytic applications were discussed to call for more eff orts devoted to the further development of single-atom catalysis.

Regulating local charges of atomically dispersed Moδ+ sites by nitrogen coordination on cobalt nanosheets to trigger water dissociation for boosted hydrogen evolution in alkaline media

Now,Pt-based materials are still the best catalysts for hydrogen evolution reaction(HER).Nevertheless,the scarcity of Pt makes it impossible for the large-scale applications in industry.Although cobalt is taken as an excellent HER catalyst due to its suitable H*binding,its alkali HER catalytic property need to be improved because of the sluggish water dissociation kinetics.In this work,nitrogen with small atomic radius and metallophilicity is employed to adjust local charges of atomically dispersed Mo^(δ+)sites on Co nanosheets to trigger water dissociation.Theoretical calculations suggest that the energy barrier of water dissociation can be effectively reduced by introducing nitrogen coordinated Mo^(δ+)sites.To realize this speculation,atomically dispersed Mo^(δ+)sites with nitrogen coordination of Mo(N)/Co were prepared via reconstruction of CoMoO_(4).High angle annular dark-field scanning transmission electron microscopy(HAADF-STEM)and X-ray absorption spectroscopy(XAS)demonstrate the coordination of N atoms with atomically dispersed Mo atoms,leading to the local charges of atomically dispersed Mo^(δ+)sites in Mo(N)/Co.The measurement from ambient pressure X-ray photoelectron spectroscopy(AP-XPS)reveals that the Mo^(δ+)sites promote the adsorption and activation of water molecule.Therefore,the Mo(N)/Co exhibits an excellent activity,which need only an overpotential of 39 mV to reach the current density of 10 mA cm^(-2).The proposed strategy provides an advance pathway to design and boost alkaline HER activity at the atomic-level.

A New Hybrid Vertical Coordinate Ocean Model and Its Application in the Simulation of the Changjiang Diluted Water

Based on the analysis of the advantages and disadvantages of some vertical coordinates applied in the calculation of the Changjiang diluted water （CDW）, a new hybrid vertical coordinate is designed, which uses σ coordinate for current and σ-z coordinate for salinity. To combine the current and salinity, the Eulerian-Lagrangian method is used for the salinity calculation, and the baroclinic pressure gradient （BPG） is calculated on the salinity sited layers. The new hybrid vertical coordinate is introduced to the widely used model of POM （Princeton Ocean Model） to make a new model of POM-σ-z. The BPG calculations of an ideal case show that POM-σ-z model brings smaller error than POM model does. The simulations of CDW also show that POM-σ-z model is better than POM model on simulating the salinity and its front.

Synthesis,Crystal Structure and Photoluminescent Property of a Novel Dy^(3+) Coordination Compound Containing Rare(H_2O)_(22) Clusters

A novel Dy^（3＋） coordination compound,（H_2pipz）（H_3O）[Dy（pydc）_3]·11H_2O（1,pipz = piperazine and H_2pydc = pyridine-2,6-dicarboxylic acid）,has been hydrothermally synthesized and characterized by X-ray single-crystal diffraction,elemental analysis. It is interesting that the packing structure of compound 1 contains 22-core water clusters. Compound 1 is extended into a threedimensional supramolecular structure via O···H···O hydrogen bonding interactions. Furthermore,the luminescent property of compound 1 was also investigated.

Structure and Magnetic Properties of a Bipyridine-bridged One-dimensional Ni(Ⅱ) Coordination Polymer

A polymer, [NiL（bipy）·2H2O]n（1, bipy = 4,4ˊ-bipyridine）, has been acquired by the reaction of Ni（OAc）2·4H2O with N,Nˊ-bis（2-hydroxyl-5-fluorobenzyl）-2-hydrxylpropane dii- mine in the presence of 4,4ˊ-bipyridine. X-ray crystallographic analysis shows that it is comprised of a mononuclear Ni（Ⅱ） complex [NiL] linked by 4,4ˊ-bipyridine. Its crystal crystallizes in the orthorhombic system, space group C2/c with a = 22.595（3）, b = 18.395（2）, c = 15.434（2） , V = 6155（1）3, Dc = 1.259 g/cm-3, Z = 8, Mr = 583.23, F（000） = 2416.0, μ（MoKa） = 0.681 mm-1, S = 1.049, R = 0.0512 and wR = 0.1108 for 6032 observed reflections（I 〉 2σ（I））. There are water hexamers in the complex. A weak overall ferromagnetic behavior has been evaluated by Curie-Weiss rule and by the formula of alternating ferro-ferromagnetic coupling in one-dimensional Ni（Ⅱ） chain, which gives g = 2.005（1） and J1 = 0.31（3） cm-1.

Strategic Coordination for Sustainable Investment in Critical Infrastructure

In demonstrating the prime place of infrastructure investment in its national long-term development framework encapsulated in Vision 2030, as well as in the related New Growth Path, South Africa recently put together a comprehensive National Infrastructure Plan. Aside from mapping out short and medium-term priorities for scaling up investment in strategic sectors and enhancing infrastructure links across the country, the initiative underscores development objectives such as community empowerment and skills development. This paper zeroes into one of the 18 strategic programs in the plan—specifically devoted to water and sanitation infrastructure—and presents the principal elements for pursuing effective inter-project coordination and integration, as well as, ultimately, for ensuring the sustainable implementation of critical infrastructure. The approaches that have influenced the success of strategic coordination include participatory planning, project prioritization, regular tracking and unblocking of implementation hurdles, localization, active stakeholder engagement and ongoing program integration.

Water exchange through the Kerama Gap estimated with a 25-year Pacific HYbrid Coordinate Ocean Model

Variations in water exchange through the Kerama Gap(between Okinawa Island and Miyakojima Island) from 1979 to 2003 were estimated with the 0.08° Pacific HYbrid Coordinate Ocean Model(HYCOM). The model results show that the mean transport through the Kerama Gap(KGT) from the Pacific Ocean to the East China Sea(ECS) was 2.1 Sv, which agrees well with the observed mean KGT(2.0 Sv) for 2009–2010. Over the time period examined, the monthly KGT varied from-10.9 Sv to 15.8 Sv and had a standard deviation of ? 5.0 Sv. The water mainly enters the ECS via the subsurface layer(300–500 m) along the northeastern slope of the Kerama Gap and mainly flows out of the ECS into the southwest of the Kerama Gap. The seasonal and interannual variations of the KGT and the Kuroshio upstream transport were negatively correlated. The Kuroshio upstream transport was largest in summer and smallest in autumn while the KGT was smallest in summer(1.02 Sv) and largest in spring(2.94 Sv) and autumn(2.44 Sv). The seasonal and interannual variations in the Kuroshio downstream(across the PN-line) transport dif fered significantly from the Kuroshio upstream transport but corresponded well with the KGT and the sum of the transport through the Kerama Gap and the Kuroshio upstream, which indicates that information about variation in the KGT is important for determining variation in the Kuroshio transport along the PN-line.

The coordinated development of China’s inland water transport

The coordinated development is the core of sustainable development and the hot issue of international research.Inland water transport(IWT) is an important part of the water resources exploiting system and comprehensive transport system under socio-economic context of river basin,and also the country's sustainable development priorities to achieve resource-conserving and environment-friendly strategy.Based on the coordinated development content,the paper combined Germany's successful development experience,explored the elements and problem of the coordinated development of IWT system of China's national economic strategy and basin economy,water resourse system,comprehensive transport system,and system itself,and their countermeasures and suggestions,in order to facilitate rapid and coordinated development of China's inland water transport.

The Relationship between Water Resources Use Efficiency and Scientific and Technological Innovation Level: Case Study of Yangtze River Basin in China

The Yangtze River Basin’s water resource utilization efficiency(WUE)and scientific and technological innovation level(STI)are closely connected,and the comprehension of these relationships will help to improve WUE and promote local economic growth and conservation of water.This study uses 19 provinces and regions along the Yangtze River’s mainstream from 2009 to 2019 as its research objects and uses a Vector Auto Regression(VAR)model to quantitatively evaluate the spatiotemporal evolution of the coupling coordination degree(CCD)between the two subsystems of WUE and STI.The findings show that:(1)Both the WUE and STI in the Yangtze River Basin showed an upward trend during the study period,but the STI effectively lagged behind the WUE;(2)The CCD of the two subsystems generally showed an upward trend,and the CCD of each province was improved to varying degrees,but the majority of regions did not develop a high-quality coordination stage;(3)The CCD of the two systems displayed apparent positive spatial autocorrelation in the spatial correlation pattern,and there were only two types:high-high(H-H)urbanization areas and low-low(L-L)urbanization areas;(4)The STI showed no obvious response to the impact of the WUE,while the WUE responded greatly to the STI,and both of them were highly dependent on themselves.Optimizing their interaction mechanisms should be the primary focus of high-quality development in the basin of the Yangtze River in the future.These results give the government an empirical basis to enhance the WUE and promote regional sustainable development.

2000-2020年黄河流域水-能源-粮食系统耦合协调时空演变特征

[目的]探讨黄河流域水—能源—粮食系统的耦合协调时空演化特征,可为定量评估流域高质量发展和区域可持续发展提供科学依据。[方法]通过耦合协调度模型分析水—能源—粮食系统的综合发展水平和耦合协调特征,并利用灰色关联度对各子系统内部指标进行排序,进而判断对水—能源—粮食系统耦合协调度的影响程度。[结果](1)黄河流域水—能源—粮食系统的综合发展指数呈上升趋势,水资源子系统波动幅度最大。(2) 2000—2020年黄河流域水—能源—粮食系统耦合协调度从初级协调向良好协调阶段发展;不同省区间的系统耦合协调发展水平差异较为明显,整体上可表现为上游地区>中下游地区。(3)各子系统与系统耦合协调度的影响程度排名可表示为水资源子系统>粮食子系统>能源子系统,其中水资源子系统内部指标与系统耦合协调度关联度均在85%以上,水资源子系统相对其他子系统的严格管理尤为重要。[结论]水—能源—粮食系统的耦合协调发展水平有待提高,为促进系统协调发展和流域高质量发展应综合考虑各子系统的相互作用关系。

水资源-能源-粮食-生态系统耦合协调及驱动力分析

为加深对我国水资源、能源、粮食、生态系统协同演变趋势的认识,构建水资源-能源-粮食-生态多维系统指标体系,运用耦合协调度模型对我国2005—2020年水资源-能源-粮食-生态系统耦合协调度进行评价,并采用多因素归因分析法进行驱动力分析。结果表明:我国水资源-能源-粮食-生态系统耦合协调度从2005年的0.55增长到2020年的0.84,各地区耦合协调度从勉强协调发展水平过渡到中级协调发展水平,各子系统对耦合协调度上升的驱动分别经历了由粮食子系统到生态子系统再到水资源子系统主导的过程;能源子系统的贡献率虽然比较小,但是未来可能是各地区提升水资源-能源-粮食-生态系统多维系统协调发展水平的突破口。

面向流域治理与城镇发展统筹的城市水系统规划协同机制探讨 ——广东东莞生态园实证研究

统筹流域治理与城镇发展是系统解决当前城市发展过程中遇到的水资源短缺、水生态破坏、洪涝灾害频发的关键路径。本文在辨析流域治理与城镇发展统筹面临的主要问题及其辩证关系的基础上,以东莞市中部地区的生态园及其所在的寒溪河流域为研究对象,系统探讨了城市水系统规划在流域治理与城镇发展统筹中的协同作用机制。结果表明,以城镇-流域水系统耦合模型为支撑,城市水系统规划及其协同机制可通过空间、设施等要素的协同,实现保障城市及流域防洪排涝安全、保护水环境和节约水资源的目标,促进流域安全与城镇发展的良性互动。

黄河流域城市水土资源利用效率的耦合协调时空特征研究

论文利用2009—2020年黄河流域69个城市的面板数据,采用Windows-DEA模型测度城市土地资源利用效率与水资源利用效率,采用耦合协调度模型分析水土资源利用效率之间的协同与冲突,利用莫兰指数模型与空间杜宾模型分析水土资源利用效率协调度的时空演变特征与空间溢出效应,结论如下:(1)黄河流域城市土地资源与水资源利用效率呈现缓慢上升态势,但土地资源利用效率为下游>上游>中游,水资源利用效率为中游>上游/下游。(2)不同城市的水资源利用综合效率出现两极分化现象,但土地资源利用效率则逐步趋于稳态,而且,城市土地资源利用效率始终存在空间邻接的正相关特性。(3)研究时期内大部分城市处于高水平耦合阶段与协调过渡阶段,协调度水平相对较低,2018年前土地资源利用效率与水资源利用效率之间协调度也存在空间邻接的正相关特性。(4)经济增长对本地水土资源利用效率协调度具有促进作用,但对其他城市水土资源利用效率具有抑制作用;三产比重对本地与其他城市的水土资源利用效率协调度也具有相反作用。建议流域内各城市从严从细规划和集约利用水土资源,注重提升整个流域的三产比重与产业升级,保证流域内水土资源利用效率的协同发展。